7. Match the List-I with List-II.

(1) A-(Q); B-(P); C-(S); D-(R)

List-I List-II (2) A-(R); B-(S); C-(P); D-(Q)
A. KMn*O4
(3) A-(S); B-(P); C-(R); D-(Q)
P. +4
(4) A-(P); B-(R); C-(S); D-(Q)
B. Ni*(CO)4 Q. +7
C. [Pt*(NH3)2Cl2]Cl2 R. 0 CORRECT-INCORRECT STATEMENT MCQs
D. Na2O2* S. –1 11. Which of the following statements is incorrect:
(1) A-(Q); B-(R); C-(P); D-(S) (1) 0.2 moles of KMnO4 will oxidise one mole of ferrous
(2) A-(S); B-(Q); C-(P); D-(R) ions to ferric ions in an acidic medium.
(3) A-(R); B-(S); C-(P); D-(Q) (2) 1.5 moles of KMnO4 will oxidise 1 mole of ferrous
oxalate to one mole of ferric ion and carbon dioxide in
(4) A-(Q); B-(S); C-(P); D-(R)
acidic medium.
8. Match the List-I with List-II. (3) 0.6 moles of KMnO4 will oxidise 1 mole of ferrous
List-I List-II oxalate to one mole of ferric ion and carbon dioxide in
A. V2O5(s) + 5Ca(s) → acidic medium.
P. Disproportionation
2V(s) + 5CaO(s) reaction (4) 1 mole of K2Cr2O7 will oxidise 2 moles of ferrous
oxalate to ferric ions and carbon dioxide in an acidic
B. Q. Decomposition
∆
CH4(g) + 2O2(g)  → medium.
reaction
CO2(g) + 2H2O(l) 12. H2C2O4 and NaHC2O4 behave as acids as well as reducing
C. P4(s) + 3OH–(aq) + R. Combustion agents. Which are the incorrect statements?
3H2O(l) → PH3(g) + reaction (1) The equivalent weight of H2C2O4 and NaHC2O4 are
3H2PO2–(aq) equal to their molecular weights when behaving as
reducing agents.
D. ∆ S. Displacement
2KClO3(s)  → (2) 100 ml of 1 (N) solution of each is neutralised by an
reaction
2KCl(s) + 3O2(g) equal volume of 1 (M) Ca(OH)2
(1) A-(S); B-(R); C-(P); D-(Q) (3) 100 ml of (N) solution H2C2O4 is neutralised by equal
(2) A-(S); B-(Q); C-(P); D-(R) volumes of 1 (N) Ca(OH)2
(3) A-(R); B-(S); C-(P); D-(Q) (4) 100 ml of (M) solution of each is oxidised by an equal
volume of 1 (M) KMnO4
(4) A-(Q); B-(S); C-(P); D-(R)
13. Reaction (A) S2– + 4H2O2 → SO42– + 4H2O
9. Match the List-I with List-II.
(B) Cl2 + H2O2 → 2HCl + O2
List-I List-II
The true statement regarding the above reactions is:
A. CuO P. 4 (1) H2O2 acts as a reductant in both reactions
B. MnO2 Q. 3 (2) H2O2 acts as an oxidant in reaction (A) and reductant
C. HAuCl4 R. 2 in reaction (B)
D. Tl2O S. 1 (3) H2O2 acts as an oxidant in both reactions
(1) A-(S); B-(R); C-(P); D-(Q) (4) H2O2 acts as the reductant in reaction (A) and oxidant
in reaction (B)
(2) A-(S); B-(Q); C-(P); D-(R)
(3) A-(R); B-(S); C-(P); D-(Q) 14. Which of the following statement is false regarding the
change: CN– → CNO– ?
(4) A-(R); B-(P); C-(Q); D-(S)
(1) Carbon is losing two electrons per atom.
10. Match the List-I with List-II.
(2) The oxidation state of carbon changes from +2 to +4.
List-I List-II (3) Oxidation state of nitrogen is not changing.
A. 2Mg + O2 → 2MgO P. Removal of hydrogen (4) Oxidation state of nitrogen changes from –3 to –1.

B. Mg + Cl2 → MgCl2 Q. Removal of electropositive 15. The n-factor of HCl in the equation
element K2Cr2O7 + 14HCl → 2KCl + 2CrCl3 + 3Cl2 + 7H2O is?
(1) 2/3 (2) 11/3
C. 2H2S + O2 → 2S + R. Addition of oxygen
(3) 3/7 (4) 7/3
2H2O
COOH COOK
D. 2Kl + H2O + O3 → S. Addition of electronegative 16. and behaves as an acid as well as a reducing
2KOH + I2 + O2 element, chlorine COOH COOH

Redox Reactions 53