TITLE: SOLUBILITY TRENDS IN GROUP II COMPOUNDS
Aim: To demonstrate the trends in solubility of Group II carbonates, sulfates, chromates, and hydroxides.
Introduction
The periodic table organizes elements based on increasing atomic number, revealing periodic trends in
their properties. Elements within the same vertical column, called a group, share similar chemical and
physical properties due to their identical outer-shell electron configurations. Solubility, the ability of a
substance (solute) to dissolve in a solvent to form a homogeneous solution, is influenced by factors
including temperature, pressure, pH, and the chemical nature of the solute and solvent. This experiment
investigates the solubility trends of compounds formed by elements in Group II of the periodic table.
Reagents
1. 0.1M solutions of Mg2+, Ca2+ Ba2+, Pb2+.
2. 0.1M Sodium hydroxide
3. 0.1M Sodium sulphate
4. 0.1M Potassium chromate
5. 0.1M Sodium carbonate
6. Distilled water
Apparatus
1. Test tubes
2. Test tube racks
3. Teat pipettes
Procedure
1. Prepare four rows of four test tubes each.
2. Label the test tubes in each row as Mg2+, second as Ca2+, the third as Ba2+, and the fourth test as Pb2+
3. To a few cm3 of each of the solutions add using a teat pipettes a small amout of 0.1M sodium sulphate.
Note your results.
4. Repeat procedure three using sodium carbonate solution instead of sodium sulphate solutions. Note
your results.
5. Repeat procedure three using potassium chromate solution instead of sodium sulphate solutions. Note
your results.
6. Repeat procedure three using using sodium hydroxide solution instead of sodium sulphate solutions.
Note your results.
Results
Sulphates: Magnesium sulphate is soluble; Calcium sulphate is slightly soluble while Barium and Lead
sulphates are insoluble.
Carbonates of Magnesium, Calcium, Barium and Lead are insoluble
Chromates of Magnesium, Calcium, Barium and Lead are insoluble.
Hydroxides of Magnesium, Calcium Barium and Lead are insoluble.
Questions
1. Write balanced full and ionic equations for each reaction.
2. Briefly explain the solubility trends in group IIA.
The observed solubility trends in group IIA compounds can be explained by the relationship
between cation size and charge density. As you move down Group IIA, the cation size increases,
leading to a decrease in charge density. The lower charge density results in weaker attraction
between the cation and the anions in the compound, making it less soluble.
For example, the solubility of sulphates decreases as you move down the group (MgSO 4 > CaSO4 >
BaSO4 > PbSO4) due to the increasing size and decreasing charge density of the cations.
References
1. Mount Kenya University Laboratory Manual (provided source document)