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Thermodynamic Relationships and Equations

The document presents three thermodynamic relationships. It demonstrates that the specific heat at constant volume relates to temperature and the compressibility coefficients under adiabatic and isothermal conditions. Additionally, it shows that the internal energy of a material is independent of its volume based on its equation of state.

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5 views1 page

Thermodynamic Relationships and Equations

The document presents three thermodynamic relationships. It demonstrates that the specific heat at constant volume relates to temperature and the compressibility coefficients under adiabatic and isothermal conditions. Additionally, it shows that the internal energy of a material is independent of its volume based on its equation of state.

Uploaded by

mustimprove69
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

𝜕𝐶 𝜕2 𝑃

1. Show that ( 𝜕𝑉𝑉 ) = 𝑇 (𝜕𝑇2 )


𝑇

Cv
2. Show that κad = κT
Cp
1 ∂V 1 ∂V
where κad = − V ( ∂P) and κT = − V ( ∂P) are the adiabatic and isothermal compressibility
ad T

3. Equation of state of a material is P=f(V)T. Show that the internal energy of the material is
independent of the volume.

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