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N2 Solubility and Vapor Pressure at 300 K

The document discusses various concepts related to solutions, including isohydric solutions, vapor pressure, and colligative properties. It presents calculations involving the vapor pressure of solutions, solubility of salts, and osmotic pressure of insulin. Additionally, it includes a reaction involving the inversion of cane sugar and its effect on freezing point depression.

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3 views10 pages

N2 Solubility and Vapor Pressure at 300 K

The document discusses various concepts related to solutions, including isohydric solutions, vapor pressure, and colligative properties. It presents calculations involving the vapor pressure of solutions, solubility of salts, and osmotic pressure of insulin. Additionally, it includes a reaction involving the inversion of cane sugar and its effect on freezing point depression.

Uploaded by

PINNACLE
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

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4m
Isohydric solutions are the solutions having the same concentration of
hydronium ion. if 0.2 M HA (monobasic acid) solution is isohydric with
4 × 10-7 M HCl solution, then Kb for A– is
The vapour pressure of an aqueous solution is found to be 750 torr at certain temperature 'T'. If
'T' is the temperature at which pure water boils under atmospheric pressure (Kb = 0.52 K kg
mol-1)
(A) 777 (B) 779 (C) 782 (D) 746
The Henry law constant for O2(g) and N2(g) in water at 0°C are 2.5 × 104 bar and 5.0 × 104 bar
respectively. Calculate DTf of solution made by dissolving air at 1 bar pressure.
Given : mole % of O2 in air = 20 & mole % of N2 in air = 80
Kf of H2O = 1.86 kg mol-1

[Ans. 2.48 × 10-3]


The vapour pressure of a saturated solution of sparingly soluble salt (XCl3)
was 17.20 mm Hg at 27°C. If the vapour pressure of pure H2O is 17.25 mm
Hg at 300 K, what is the solubility of sparingly soluble salt XCl3 in
mole/ Litre.

4.04 × 10-2
At 300 K, the vapour pressure of an ideal solution containing 3 mole of A and 2 mole of B is 600
torr. At the same temperature, if 1.5 mole of A & 0.5 mole of C (non-volatile) are added to this
solution the vapour pressure of solution increases by 30 torr. What is the value of PB0 ?

90
The solubility of common salt is 36.0 gm in 100 gm of water at 20°C. If systems I, II and III
contain 20.0, 18.0 and 15.0 g of the salt added to 50.0 g of water in each case, the vapour
pressures would be in the order.
(A) I < II < III (B) I > II > III (C) I = II > III (D) I = II < III
Insulin is dissolved in a suitable solvent & the osmotic pressure (p in atm) of solution of various
concentration 'C'' in gm/cc is measured at 27°C. The slope of the plot p against 'C'' is found to
be 5 × 10-3 . The molecular weight of insulin is:
(A) 4.9 × 105 B) 4.9 × 103 (C*) 4.9 × 106 (D) 4.9 × 104
Cane sugar underoges the inversion as follow
C12H22O11 + H2O → C6H12O6 + C6H12O6
If solution of 0.025 moles of sugar in 200 gm of water show depresion in freezing point 0.372ºC,
then what % sucrose has inverted. (Kf(H2O) = 1.86 K kg mol–1)

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