21-05-2025

7101CJA101021250004 JM

PHYSICS

SECTION-I

1) Two point charges q1 and q2 are kept as shown. One of the electric
field line coming out from q1 makes an angle 30° with the line joining q1q2, terminates at q2 making

an angle 60°. The ratio is

(A)

(B)

(C)

(D) 2

2) In a potential field, V = 4x + 3y, where V is in volt, x and y are in metre, a particle with charge
and mass 1 mg is released from point (1 m, 1 m) at rest. The time taken by it to cross the x axis
is

(A)

(B)

(C)

(D)

3) A charge +q is fixed at each of the points x = x0, x = 3x0, x = 5x0...... infinite, on the x-axis and a
charge –q is fixed at each of the points x = 2x0, x = 6x0,... infinite. Here x0 is a positive constant. Take
the electric potential at a point due to charge Q at a distance r from it to be Q/(4πε0r). Then, the
potential at the origin due to the above system of charges is:-

(A) 0

(B)

(C) ∞
(D)

4) A uniform electric field of strength E exists in a region. An electron (charge–e, mass m) enters a
point A with velocity V . It moves through the electric field & exits at point B. Then :-

(A)

(B)
Rate of work done by the electric field at B is
(C) Rate of work by the electric field at A is not zero.

(D)
Velocity at B is

5)

Find the force experienced by the semicircular rod charged with a charge q, placed as shown in
figure. Radius of the wire is R and the infinitely long line of charge with linear density λ is passing
through its centre and perpendicular to the plane of wire.

(A)

(B)

(C)

(D)

6)

A cuboid is of dimension [a × a × b]. Charge q is placed at the center of edge having length 'b'. If

flux through face 'ABCD' is then select the correct statement(s) :

(A)
Flux through the entire cuboid is
(B) Flux through the face 'ABEH' is zero.

(C)
Flux through the face 'BEFD' is
(D) All of these

7) The diagram shows a uniformly charged hemisphere of radius ρ, of volume charge density r. If
field at a distance 2R above its center (i.e. at A) is E, then field at distance 2R below it (i.e. at B) is :-

(A)

(B)

(C)

(D) None of these

8) Figure shows a wire, hinged at A and B, and given the shape of half ring of radius R, the assembly
is now free to rotate about an axis passing through AB in a uniform electric field E as shown in the
figure. Linear charge density of wire is λ1 and linear mass density is λ2. If assembly is slightly
disturbed from unstable equilibrium position, then find maximum angular velocity of ring during

ensuing motion.

(A)

(B)
(C)

(D)

9) Two bodies A and B each of mass 'm' and carrying charge 'Q' are rotating with constant speed 'v'
in a circle of radius r/2 on a smooth horizontal surface and are connected by spring of natural length
l0 and spring constant 'k' the total energy of the system is.

(A)

(B)

(C)

(D) None of these

10) Two identical thin rings each of radius R meters are coaxially placed at a distance R meters
apart. If Q1 coulomb and Q2 coulomb are respectively the charges uniformly spread on the two rings,
the work done in moving a charge q from the centre of the ring having charge Q2 to the centre of
other ring having charge Q1 is

(A) Zero

(B)

(C)

(D)

11)

In a regular polygon of n sides, each corner is at a distance r from the center. Identical charges are
placed at (n–1) corners. At the centre, the intensity is E and the potential is V. The ratio V/E has
magnitude :

(A) nr
(B) (n–1)r
(C) (n–1) /r
(D) r (n–1)/n

12) The plotting for equipotential lines are shown in the figure.
Find V = f(x, y).

(A)

(B)

(C)

(D) V = 5x

13) A circular disc of radius R carries surface charge density σ(r) = σ0 , where σ0 is a
constant and r is the distance from the center of the disc. Assume that the disc is in xz plane and its

axis is y axis. We have a sphere of radius R and centre at . What is the flux of electric

field through this sphere?

(A)

(B)

(C)

(D)

14) Three charged conducting metal spheres of radius R1, R2 and R3 are connected together by very
thin wires and they are separated by large distances from each other. If R1 < R2 < R3, at equilibrium,
which of the following sets of relations involving the electric field strength E generated by a sphere
at a point just outside the surface, its potential V and its charge Q must hold between the spheres ?

(A) V1 = V2 = V3, E1 < E2 < E3, Q1 < Q2 < Q3

(B) V1 = V2 = V3, E1 > E2 > E3, Q1 < Q2< Q3
(C) V1 < V2 < V3, E1 < E2 < E3, Q1 = Q2 = Q3
(D) V1 > V2 > V3, E1 < E2 < E3, Q1 > Q2 > Q3

15) Two identical spherical masses are kept at some distance as shown. Potential energy when a
mass m is taken from surface of one sphere to the other.

(A) Increases continuously.

(B) Decreases continuously.
(C) First increase then decreases.
(D) First decreases then increases.

16) A solid sphere of uniform density and radius 4 units is located with its centre at the origin O of
coordinates. Two spheres of equal radii 1 unit with their centres at A(–2, 0, 0) and B(2, 0, 0)
respectively are taken out of the solid leaving behind spherical cavities as shown in figure. Then

choose the incorrect statement:

(A) The gravitational field due to this object at the origin is zero
(B) The gravitational field at the point B (2, 0, 0) is zero
(C) The gravitational potential is the same at all points of the circle y2 + z2 = 36
(D) The gravitational potential is the same at all points on the circle y2 + z2 = 4

17) What is the minimum velocity with which particle must be projected from point A so that it will
hit point B. A & B are on same longitudinal plane.
M = Mass of earth
R = Radius of earth

(neglect rotation of earth)

(A)

(B)

(C)

(D)

18) A planet of radius has the same mass density as Earth. Scientists dig
a well of depth on it and lower a wire of the same length and of linear mass
density into it. If the wire is not touching anywhere, the force applied at the top of the wire by a
person holding it in place is (take the radius of Earth = and the acceleration due to
-2
gravity on Earth is 10 ms )

(A) 96 N
(B) 108 N
(C) 120 N
(D) 150 N

19) A planet orbits around a star S, as shown in the figure. The semi-major axis of the orbit is a. The
perigee, namely the shortest distance between the planet and the star is 0.5a. When the planet
passes point P (on the line through the star and perpendicular to the major axis), its speed is v1.

What is its speed v2 when it passes the perigee?

(A)

(B)

(C)

(D)

20) Two identical thin uniform rods of mass M and length L are placed in a line at separation of L.

Find the gravitational force acting between them :-

(A)

(B)

(C)

(D)

SECTION-II
1) A rod of finite length having linear charge density λ subtends an angle of 15° at a point P which is
also the centre of curvature of a circular arc subtending same angle at P having same linear charge

density λ as shown in figure. If the net electric field at the origin is . Find the value of b:

2) The average time of revolution of the Soviet ship-satel-nick “Vostok” in which Yuri Gagarin flew
around the Earth globe for the first time in April 12, 1961, was T1 = 89 minutes, with an average
altitude above ground h = 254 km. The closest satellite of Mars - Phobos - orbiting the planet during
T2 = 7 hours 39 minutes, while the center of Mars is on average distance of R2 = 9350 km from

Phobos. Determine approximately where, M2 is mass of Mars and M1 is mass of the Earth. It is
given that the average radius of the earth R = 6371 km.

3) A massive planet of radius R has a diametrical hole as shown in figure, such that hole does not
effect the sphericity of the planet. The planet has uniform density. Two equal mass A and B [m <<
M] are simultaneously released, from positions shown. If the collisions are elastic then the total

distance traveled by mass A after being released till the time of 6th collision is . Find N [
M→mass of planet, m→ mass of A and B neglect the gravitational interaction between mass A and

mass B.]

4) On a smooth horizontal surface we have a point charge attached to the free end of a massless rod
hinged at other end as shown. We apply a uniform electric field (E) and slightly deflect the rod. The
force on charge accelerate it during half rotation then the direction of electric field is suddenly
reversed, so that the charge remain accelerating, assuming q = 1C, m = 1kg E = 1N/C, length of rod
L = 1m. The total angle rotated when the point charge attains a speed of 5 m/s is 38 π/n. Then value

of n is.

5) A non-conducting disc of mass = 2kg, total charge = +1C uniformly distributed, is placed on a
rough horizontal non-conducting surface with its cross-section in vertical plane as shown. A uniform
horizontal electric field E is now switched on. If the maximum magnitude of electric field E in so that
–2
the disc rolls purely is 4n N/C then find the value of n. [g = 10 ms ]
 CHEMISTRY

SECTION-I

1) Number of square faces in truncated cube will be -

(A) 6
(B) 8
(C) 12
(D) zero

2) Correct order of coordination number, packing efficiency and number of particles per unit cell for
ccp structure made of identical atoms is respectively -

(A) 12, 68%, 8

(B) 8, 74 %, 4
(C) 12, 74%, 4
(D) 12, 74%, 6

3) Incorrect statement about amorphous solids is :

(A) do not have sharp melting point

(B) anisotropic in nature
(C) are super cooled liquids
(D) do not have definite heat of fusion

4) A compound MpXq has cubic close packing (ccp) arrangement of X. Its unit cell structure is shown

below. The empirical formula of the compound is

(A) MX
(B) MX2
(C) M2X
(D) M5X14
5) What is the percent by mass of titanium in rutile, a mineral that contain titanium and oxygen, if
structure can be described as a closed packed array of oxide ions, with titanium in one half of the
octahedral holes. What is the oxidation number of titanium ? (Ti = 48)

(A) 30%, +4
(B) 60%, +2
(C) 60%, +4
(D) 30%, +2

6) A compound consist of two elements X and Y. ' X ' crystallises in FCC arrangement and ' Y '
occupies all the tetrahedral voids. Find out the molecular formula of the compound, if all the atoms
along one body diagonal in each unit cell are missing

(A) XY2
(B) X2Y3
(C) X5Y8
(D) X5Y4

7) A solution is prepared by mixing 8.5 g of CH2Cl2 and 11.95 g of CHCl3. If vapour pressure of
CH2Cl2 and CHCl3 at 298 K are 415 and 200 mmHg respectively, the mole fraction of CHCl3 in
vapour form is: (Molar mass of Cl = 35.5 g mol–1)

(A) 0.486
(B) 0.325
(C) 0.162
(D) 0.675

8) PtCℓ4 . 6H2O can exist as a hydrated complex. Its 1 molal aq. solution has depression in freezing
point of 3.72. Assume 100% ionisation and Kf (H2O) = 1.86°C mol–1 kg, then complex is :

(A) [Pt (H2O)6]Cl4

(B) [Pt(H2O)4Cl2] Cl2 .2H2O
(C) [Pt(H2O)3 Cl3]Cl.3H2O
(D) [Pt(H2O)2Cl4].4H2O

9) Two components A and B form an ideal solution. The mole fractions of A and B in ideal solution
are XA and XB, while that of in vapour phase, these components have their mole fractions as YA and
YB. Then,

the slope and intercept of plot of vs will be :

(A)

(B)
(C)

(D)

10) If 1m solution of benzoic acid in benzene has a freezing point depression of 2.4°C.
(Kf = 5.12°C mol–1 kg) and boiling point elevation of 2.53°C (Kb = 2.53°C mol–1 kg), then select the
correct statement/s :
Statement I : there is dimer formation when undergoing freezing
Statement II : there is no change when undergoing boiling
Statement III : reverse of I and II
Statement IV : dimer formation in freezing and boiling state

(A) II
(B) II, III
(C) III, I
(D) only I

11) Molar volume of liquid A(d = 0.8gm/ml) increase by factor of 2000 when it vapourises at 200K.
Vapour pressure of liquid A at 200K is [R = 0.08 L-atm/mol-K]
(Molar mass of A = 80g/mol)

(A) 0.4 atm

(B) 8 atm
(C) 0.8 atm
(D) 0.08 atm

12) In the depression of freezing point experiment, it is found that

(I) The vapour pressure of the solution is less than that of pure solvent.
(II) The vapour pressure of the solution is more than that of pure solvent.
(III) Only solute molecules solidify at the freezing point.
(IV) Only solvent molecules solidify at the freezing point.

(A) I, II
(B) II, III
(C) I, IV
(D) I, II, III

13)

For a gaseous reaction

CH3CHO(g) CO(g) + CH4(g)

initial pressure is 80 mm of Hg and total pressure at the end of 20 minutes is 120 mm of Hg. The
rate constant of the reaction assuming first order kinetic is : (Initially only CH3CHO is present)
(A) 3.465 × 10–2 min–1
(B) 34.65 min–1
(C) 3.465 min–1
(D) 0.3465 min–1

14) The compound A decomposed (A → product) by first order kinetics. If the concentration of A
dropped from 0.1 M to 0.05 M in 30 minutes, find the rate of reaction after 60 minutes from start, if
initial concentration of A is taken as 0.4M at same temperature in M min–1

(A)

(B)

(C)

(D)

15) For the reaction

Experiment 1: The value of was, obtained by experiment(s), 2.25 torr/sec for a pressure of 450
torr of NO(g) and 0.25 torr/sec for a pressure of 150 torr, the pressure of H2(g) being constant.
Experiment 2: The value of –dp /dt was 1.90 torr/sec for H2(g) pressure of 290 Torr and 0.951
torr/sec for H2(g) pressure of 145 torr the pressure of NO(g) being constant.
Which analytical statement is correct on the basis of above experiment(s)
(I) Order of reaction is 3
(II) Order with respect to NO(g) and H2(g) are 3 and 0 respectively
(III) Order with respect to H2(g) and NO(g) are 1 and 2 respectively
(IV) Rate of reaction depend upon the concentration/pressure of reactant(s)

(A) I, II and IV
(B) I and III
(C) I, III and IV
(D) I only

16) The results given in the below table were obtained during kinetic studies of the following
reaction:

2A + B → C + D Y and X in the given table are

respectively :

(A) 0.3, 0.4

(B) 0.4, 0.3
(C) 0.4, 0.4
(D) 0.3, 0.3

17) A flask contains a mixture of compounds A and B. Both compounds decompose by first-order
kinetics. The half-lives for A and B are 300 s and 180 s, respectively. If the concentrations of A and B
are equal initially, the time required for the concentration of A to be four times that of B(in s) : (Use
ln 2 = 0.693)

(A) 180
(B) 120
(C) 300
(D) 900

18) The reaction 2X → B is a zeroth order reaction. If the initial concentration of X is 0.2 M, the half-
life is 6 h. When the initial concentration of X is 0.5 M, the time required to reach its final
concentration of 0.2 M will be :-

(A) 18.0 h
(B) 7.2 h
(C) 9.0 h
(D) 12.0 h

19) Rate law of the reaction A → Product is, rate = k[A]. Graphically it is represented as

Hence, rate constant is :

(A) 3 × 10–4 s–1

(B) 1 × 10–2 s–1
(C) 3 × 10–2 s–1
(D) 1 × 10–4 s–1

20) A first order reaction completes 90% in 40 min. The half life of reaction is (log10 2 = 0.30)

(A) 12 minute
(B) 10 minute
(C) 16.8 minute
(D) 14.6 minute

SECTION-II

1) If for a first order reaction, t90% = X.t1/2, t99% = Y.t1/2 and t99.9% = Z.t1/2, then calculate value
of . [log2 = 0.3]

2) If the initial concentration of reactant are doubled, half life becomes half. Then order of reaction
will be ?

3) 26.65 gm of compound having formula [Cr(H2O)5Cl)]Cl2.H2O is mixed with 498.2 gm water. If

complex is 75% ionised in water, then elevation in boiling point in Kelvin for above solution is x. (kb
(water) = 0.50 k kg mol–1) (At. wt. Cr : 52, Cl : 35.5, O : 16). Multiply your answer with 100.
Fill your answer as sum of digits (excluding decimal places) till you get the single digit answer.

4) Find the (A + B)
(A) Nearest neighbour distance in NaCl type structure
(B) Nearest neighbour distance in CsCl type structure
(Assume edge length in each case is 100 unit) given = 1.4 and = 1.7
Fill your answer as sum of digits (excluding decimal places) till you get the single digit answer.

5) In diamond carbon atoms occupy FCC lattice points as well as alternate tetrahedral voids
(structure similar to zinc blende). Find the packing fraction of the diamond unit cell
First multiply your answer with 100. Then fill your answer as sum of digits (excluding

decimal places) till you get the single digit answer.

MATHS

SECTION-I

1) If M = , then which of the following matrices is equal to M2022 ?

(A)

(B)

(C)
(D)

2) If A and B are square matrices of same order and AB = A, BA = B, then (A + I)5 is equal to (where
I is unit matrix)

(A) I + 5A
(B) I + 60A
(C) I + 16A
(D) I + 31A

3) Let and A–1 = A2 + αA + βI, then

(A) α = –11, β = 15
(B) α = 15, β = –11
(C) α = 11, β = –15
(D) α =–15, β = 11

4) If where , then A–1 is equal to -

(A)

(B)

(C)

(D)

5) If A and B are square matrices such that AB = B and BA = A , then A2 + B2 is equal to-

(A) 2AB
(B) 2BA
(C) A + B
(D) AB

6) ax + y + z = 0, x – by + 3z = 0 and x – y – z = 0 has a non-trivial solution, then-

(A) a = 1 or b = 5
(B) a = –1 or b = –3
(C) a = –1 or b = 3
(D) a = 1 or b = 3

7) If a,b,c are distinct & rational numbers then

is always :-

(A) zero
(B) Rational & Positive
(C) Rational & Negative
(D) Irrational and Positive

8) If (x1 – x2)2 + (y1 – y2)2 = a2 ;

(x2 – x3)2 + (y2 – y3)2 = b2 ;
(x3 – x1)2 + (y3 – y1)2 = c2 and

k (a + b + c)(b + c – a)(c + a – b)(a + b – c)

then the value of k is :-

(A) 1
(B) 2
(C) 4

(D)

9) If the system of equation 2x + 3y = –1; 3x + y = 2; λx + 2y = µ is consistent, then :-

(A) λ – µ = 2
(B) λ + µ = –1
(C) λ + µ = –1
(D) λ – µ + 8 = 0

10) If maximum and minimum values of the determinant are α

and β, then:

(A) α + β99 = 5
(B) α3 – β17 = 25
(C) (α2n – β2n) is always an even integer for n ∈ N
(D) a triangle can be constructed having it’s sides as α, β and α – β

11) Let be real valued function defined as Then range of f is

(A)

(B)

(C)

(D)

12) Domain of function is -

(A) [–3, –1] ∪ [1, 2]

(B) (–2, –1) ∪ [2, ∞]
(C) (–∞, –3] ∪ (–2, –1) ∪ (2, ∞)
(D) None of these

13) The range of the function f(x) = cos2 x – 5 cos x – 6 is:

(A) [–5, 0]
(B) [0, 10]
(C) [–10, 0]
(D) None of these

14) The domain of the function ƒ(x) = , is

(A) (–∞, ∞) – [–2, 2]

(B) (–∞, ∞) – [–1, 1]
(C) [–1, 1] ∪ (–∞, –2) ∪ (2, ∞)
(D) None of these

15) Let ƒ : R → R be a function defined by , then ƒ is:

(A) one-one but not onto

(B) one-one and onto
(C) onto but not one-one
(D) neither one-one nor onto

16) Range of the function f(x) = log2 is:

(A) (1, 2)
(B) R
(C) [–1, 2]
(D) [1, 2]

17) If 3x + 3y = 3, then Range of y is:

(A) R
(B) (–∞, –1)
(C) (–∞, 1)
(D) (–∞, 1]

18) The number of integral solutions of the equation

3 + |x2 – 5x + 6| + (x – 3)2 = 0 is

(A) 3
(B) 1
(C) 4
(D) 7

19) The domain of the function

where the symbols have their usual meanings, is the set

(A) {2, 3}
(B) {2, 3, 4}
(C) {1, 2, 3, 4, 5}
(D) None of the above

20) Solution set of the inequality is

(A)

(B)

(C)
(D) (0, 1)

SECTION-II
1)

Let Dk = . If , then n is equal to

2) Let for all , then find number of integers involved in the range of
f(x), where ([.] denotes the greatest integer function)

3) Number of positive integers in the domain of the function

4) Let A = {1, 2, 3, 4} and R be a relation on the set A × A defined by

. Then the number of elements in R is:

5) If the domain of (where [x] denotes G.I.F) is then a + b

=
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B A D D B D B A D B B C C B C B B B A A

SECTION-II

Q. 21 22 23 24 25
A. 0 9 2 6 3

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. D C B B C C B C B A D C A A C B D A B A

SECTION-II

Q. 46 47 48 49 50
A. 3 2 7 9 7

MATHS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A D A A C B B C A C A C C C D D C B A B

SECTION-II

Q. 71 72 73 74 75
A. 6 8 6 6 8
 SOLUTIONS

PHYSICS

1)

2)

To cross x-axis, y-displacement to be covered is –1 m

3)
4)
5)

6)

according to gases law

8)

Centre of charge of ring lies at its centre of mass.

Centre of charge moves by a distance "x" along electric field from 1 to 2.

Charge on ring (Q) = (λ1)πR
mass of ring (M) = (λ2)πR
Work on ring by field (w) = QEx {x = 2a}
λ1 = linear charge density
w = λ1πRE (2)
λ2 = linear mass density
w = 4λ1ER2π

kinetic energy of ring (K) =

I (moment of inertia) =
ω → angular velocity at final position
Since initially ring is at rest –
w = k (Work energy theorem)

4πλ1ER2 =

ω2 =

ω=

9) Total energy of system

= kE + electrostatic PE + spring pE

10)
Electric potential at centre of ring 1 = V1

V1 =

V1 =
Electric potential at centre of ring 2 = V2

V2 =
work done (w) = q[Vfinal – Vinitial]
W = q[V1 – V2]

W=

W=
W=

W=

11)

12) (A) Since V varies linearly with x with a rate of we have

V = 5x + C;
where x = 0, V = 5 or C = 5
Then, V = 5x+ 5 .......(i)

Since,
.......(ii)

Hence .......(iii)
Adding Eqs. (i) and (iii),

13)
14) All the spheres are at same potential So, V1 = V2 = V3 and E1 : E2 : E3 =

15) Centre point is the unstable equilibrium position where potential energy is maximum.

16) Both cavities are symmetrical about centre

gravitational field at centre = 0

At (2, 0, 0) gravitational field is not zero.
Both equations represent circle in y-z plane
every point on circle is quidistant from centre
So gravitational field is constant.
Both equations represent circle in y-z plane
every point on circle is quidistant from centre
So gravitational field is constant.

17) For min velocity we want orbit with smallest possible total energy or smallest possible

major axis.

for a minimum, PF2 should be minimum and it is minimum when PF2 perpendicular to major
axis.
K.E. + P.E. = T.E

18)

Acceleration due to gravity at a depth x

Force on a small segment of wire at a depth x from surface

19) Question is too lengthy By Ruchir Tyagi Sir

We present two approaches to this problem.
Approach 1: The vis-viva equation 4 states that in any Keplerian orbit, the speed of the
orbiting body is given by

where r is the distance from the central body, a is the length of the semimajor axis, M is the
central body’s mass, and G is the universal gravitational constant. Since the sum of the
distances from a point on the ellipse to the two foci is constant, we can solve for the length SP,
as
Then, by the vis-viva equation,

Thus, , so the answer is A.

Approach 2: Like the previous solution, we begin by using the Pythagorean theorem to
calculate SP = 3a/4. The key to this approach is that if we can express v2 in terms of G, M, and
a, then we can use conservation of energy to calculate v1.
We will write a system of equations to solve for v1. Let v3 be the speed of the planet at the
apogee. By conservation of energy, we get the equation

Also, by conservation of angular momentum (or Kepler’s Second Law), we have that

We can plug this into the energy conservation equation and rearrange to get

Great, we got a formula for v2 Now, to calculate v1, we can use conservation of energy between
the perigee and point P to get

We can then plug in our expression for and simplify to get

Finally, dividing our formulas for v2 and v1 yields

Thus, the answer is A.

Note: In this approach, one may try to skip v3 entirely and write a similar system of equations
for v1 and v2. However, this doesn’t work, as the velocity of the planet at point P is not
perpendicular to SP, so the angular momentum is harder to write in terms of v1.

20)
21)

Enet = Erod – Ering

⇒ Enet = =0

22)

23) Each particle performs SHM of same time period. At every collision they exchange
velocity.

24) At each reversal, work done by electric force = qE(2L), and KE keeps on increasing after N

reversal, work done = NqE(2L) =

work done in rotating θ angle,

F × L(1 – cos θ) = ΔKE =

so total work done,

NqE(2L) + F × L(1 – cosθ) =

& F = qE,

we get v2 =
 for v = 5 ; N = 6 and θ =

so, total angle rotated is, =

25)
aCM = αr

CHEMISTRY

26)

Truncated cube have only triangular and octagon faces.

27)

C.N = 12

Number of atoms =

28)

Amorphous solids are isotropic in nature.

29)

Effective atoms of M in a unit cell = 2

Effective atoms of X in a unit cell = 4

30)

1. ⇒ O2⊝ = FCC ⇒ No. of O2⊝ ions in unit cell = 4

⇒
⇒ total negative charge = 8
⇒ total positive change = 8
⇒ x = +4
 ⇒ Ti2O4
2. Rutile is the most common natural form of TiO2
The oxidation number of Ti = +4

Percentage mass of Ti = 48 × = 60%

31)
=
= X5Y8

32) Raoult's law;

; where
XA ; XB = mole fractions of A & B in the liquid phase, respectiely
= Vapour pressures of pure A & pure B; respectively
PS = Vapour pressure of the binary solution of A & B
Applying Dalton's & Raoult's law;
wher
yA = mole fraction of A in the vapours above the solution

Given:

33)

ΔTf = i kf m
i=2

34)

YAPT = XAPA°
YA [PB° + (PA° – PB°) XA] = XAPA°

35)

ΔTf = i kf m
i < 1 when freezing takes place.

36) Consider 1 mole of liquid A.

⇒ mass = 80g/mol × 1 mol = 80 gm

⇒ volume of liquid A =
⇒ Given that volume increases by 2000 times upon vaporisation;

⇒ volume of vapour A =
⇒ If vapour pressure of pure A = ; applying ideal gas equation,
PV = nRT

⇒
⇒

37) The freezing point of solution is lesser than that of the pure solvent since pure solvent has
a higher vapour pressure
During freezing, the following equilibrium exists;

∴ statements I & IV are correct.

38) CH3CHO(g) → CH4(g) + CO(g)

t=0 80 0 0
t = 20min 80 – x x x
(80 –x) + x + x = 120 ⇒ x = 40
t1/2 = 20min

K= = 3.465 × 10–2 min–1

39) Half life = 30 min.

Concentration of A after 60 minutes, if initial concentration is 0.4 = 0.1M

Rate =

40)
For 1st experiment, hydrogen pressure is

constant
2.25 torr/sec = K1 (450 torr)a __(I)
0.25 torr/sec = k1 (150 torr)a ____ (II)

On dividing
For IInd experiment, NO pressure is constant
1.90 = kii(290)b ___(III)
0.951 = kii(145)b ___(IV)

On Diving

41) From rate law

= K[A]x [B]y
6 × 10–3 = K(0.1)x (0.1)y ……(1)
2.4 × 10–2 = K(0.1)x (0.2)y ……(2)
1.2 × 10–2 = K(0.2)x (0.1)y ……(3)
(3) ÷ (1) ⇒ x = 1
(2) ÷ (3) ⇒ x = 2
So, order with respect to A = 1
Order with respect to B = 2
(4) ÷ (3)

x = 0.3 M
(5) ÷ (4)

y2 = 4 × 0.22
y = 0.4 M

42) [A]t = 4[B]t

[A]0

43) For zero order

[A0]–[At] = kt
0.2 – 0.1 = k×6
k= M/hr

and 0.5–0.2 =
t = 18 hrs.

44)

r=K×A

= 1 × 10–2

45) ⇒ 40 =
∴ t1/2 = 12 minute.

46)

Given

t90% = xt1/2 = x

x=
Similarly t99% = yt1/2 = y.

y=
t99.9% = z.t1/2 = z.

z=

47)

n–1=1
n = 2 so order of reaction will be (2)
 48) Mole of [Cr(H2O)5Cl)]Cl2.H2O] =
Total water = 498.2+ 18 = 500 gm

= 0.25
Answer = 0.25 × 10 = 25 ⇒ 2 + 5 = 7

49) Nearest neighbour distance in NaCl type structure (A) =

Nearest neighbour distance in CsCl type structure (B) = a

where, a = 100

∴A+B= + a

= (1 + ) = 135 unit.

50)

MATHS

51)

Let

= I + 3033A
52) AB = A, BA = B A(BA) = A2
AB = A2 ⇒ A2 = A ⇒ A3 = A ⇒ A4 = A
⇒ A5 = A .....
(A + I)5 = 5C0A5 + 5C1A4I + 5C2A3I + 5C3A2I + 5C4AI + 5C5I
= I + 31A

53) A =
A–1 = A2 + αA + BI
I = A3 + αA2 + BA
A3 + αA2 + βA – I = 0
By Cayley Hemilton rule |A – λI| = 0

=0
2
(5 – λ) {5 – 6λ + λ –4} – 7(1 – λ – 6) + 3(2 – 15 + 3λ) = 0
(5 – λ) (l2 – 6λ + 1) + 35 + 7λ – 39 + 9λ = 0
5λ2 – 30λ + 5 – λ3 + 6λ2 – l – 4 + 16λ = 0
–λ3 + 11λ2 – 15λ+ 1 = 0
λ3 – 11λ2 + 15λ – 1 = 0
α = –11 β = +15

54) A =

A–1 =

55) AB = B ; BA = A
pre multiplication by B pre multiplication by A
BAB = B2 ABA = A2
A2 + B2 = ABA + BAB
= (AB) A + (BA) B (using associative law)
= BA + AB
56)
a(b + 3) + 4 – 1 + b = 0
(ab + b) + 3a + 3 = 0
b = –3 or a = –1

57)

= Rational & Positive

58) area of Δ =

= ∵s=

59) Solve eqn (1) & (2) we get

x = 1 and y = –1 put in eqn (3)
λx + 2y = µ ⇒ λ –2 = µ
⇒λ–µ=2

60) Applying C1 → C1 + C2, we get

Applying R2 → R2 – R1 and R3 → R3 – R1 , we get

= 2 + sin2x
Since the maximum value of sin2x is 1, and min value of sin2x is (–1).
Therefore α = 3, β = 1.

61)

Let y

By cross multiplying

Case 1, y 1

-
Case 2,

So, y can be 1 Hence

62) x2 + 4x + 4 > 0
|x| –1 > 0
|x| –1 ≠ 1
Remember loga x ≥ 0 if 0 < x ≤1, 0 < a <1

63)

Range

64)
⇒ x ε (–∞, –2) ∪ [–1,1] ∪ (2, ∞)
65) Let f(x1) = f(x2)

⇒
⇒
⇒
⇒ 10(x1 – x2)(x1 + x2) = 0
⇒ x1 – x2 = 0 or x1 + x2 = 0
∴ f is not one one
OR

f(1) = f(–1)
(Q f(x) is even function \ many one)
Range :

yx2 + 2y = x2 – 8
(y – 1)x2 + 2y + 8 = 0

Range = [–4, 1)
∴ Not onto

66)
= log2[2, 4]

=
Range = [1, 2]

67) 3x = 3 – 3y; 3x > 0

So 3 – 3y > 0 ⇒ 31 > 3y
=y<1
y ∈ (–∞, 1)
68)
x = 3 ∴ One integral solution

69) and
⇒ 3x ≤ 17 and 7x ≤ 25

∴ and

∴ [ x ∈ I]
∴ x = 2, 3
[ 2x – 1 ≥ 0 and 4x – 5 ≥ 0]

70) We have
.....(i)
2
⇒ x > 0, x ≠ 1 and 2x + x – 1 > 0
⇒ x > 0, x ≠ 1 and (2x – 1) (x + 1) > 0

⇒
We can write (1) as

For , (ii) can be written as

⇒ 2x3 + x2 – x < 2
⇒ 2(x3 – 1) + x(x – 1) < 0
⇒ (x – 1) (2x3 + 3x + 2) < 0
⇒ x<1
For x > 1, (ii) can be written as

⇒ (x – 1) (2x2 + 3x + 2) > 0
This is true for each x > 1.

Thus, (i) holds for

71)

72) Let
Let

for
at x = 1

Range of y is
and Range of f(x) is {0, 1, 2, 3, 4, 5, 6, 7}
Number of integer in f(x) = 8.

73)

Integers are 3,4,5,6,7,8

74)

A = {1, 2, 3, 4}

R = {(a, b), (c, d)}

2a + 3b = 4c + 5d = a let

2a = {2, 4, 6, 8} 4c = {4, 8, 12, 16}

3b = {3, 6, 9, 12} 5d = {5, 10, 15, 20}

 2a+3b = 4c+5d

Possible value of a = 9, 13, 14, 14, 17, 18

Pairs of {(a, b), (c, d)} = 6

75)