MANTHAN PRAJAPATI

Date : 09-Jun-2025 Total Marks : 30

CHAPTER 1 MCQ WORK-SHEET

(1) Show the relation between the osmotic pressure of the solutions prepared in 1 liter water by dissolving 10
gram glucose (P1), 10 gram urea (P2) and 10 gram Sucrose,(P3) respectively.

(a) P2 > P1 > P3 (b) P2 > P3 > P1

(c) P1 > P2 > P3 (d) P3 > P2 > P1

(2) What is the % v/v of a 5 litre petrol solution containing 750 ml kerosene?
(a) 25 (b) 20
(c) 10 (d) 15

(3) A mixture of alcohol and water contains 54% by weight. What is the mole fraction of ethanol?
(a) 0.25 (b) 0.40
(c) 0.5 (d) 0.66

(4) What will be the normality of 1 M KMnO4 solution?

(a) 0.1 N (b) 2 N
(c) 0.5 N (d) 5 N

(5) When 0.6 g urea is dissolved in 200 g H2O, the boiling point elevates by 0.5°C. Calculate molal elevation
constant for the solution.
(a) 1.0 K kg mol-1 (b) 0.10 K kg mol-1
(c) 10 K gram mol-1 (d) 10 K kg mol-1

(6) What is the molality for 10% W/W NaOH(aq) solution?

(a) 2.778 (b) 2.5
(c) 10 (d) 5

(7) What is the normality of 0.04 M H2SO4?

(a) 0.08 N (b) 0.01 n
(c) 0.04 N (d) 0.02 N

(8) What is the value of van't Hoff factor for dilute FeCl3 (aqueous) solution?
(a) 1 (b) <1
(c) >1 (d) zero

(9) Under which of the following conditions, will the solute dissolve spontaneously in water?
(a) ΔH(hydration) > ΔH(lattice) (b) ΔH(hydration) < ΔH(lattice)
(c) ΔH(hydration) = ΔH(lattice) (d) ΔH(hydration) + ΔH(lattice) = 0

(10) The real vapour pressure for non-ideal solution is _____ than by Raoult's law
(a) more (b) less
(c) equal (d) (A) and (B) both

(11) The values of KH for O , N and He are respectively 1.8 × 10-4 bar-1, 4.48 × 10-4 bar-1 and 6.8 × 10-4 bar-1.
2 2
Hence, the order of their solubility in water will be _____ .
(a) He > N2 > O2 (b) He > O2 > N2
(c) O2 > N2 > He (d) N2 > He > o2

(12) What is the correct order of osmotic pressure of equimolal solutions of KCl, H2SO4 and Glucose?

(a) KCl > H2SO4 > Glucose (b) H2SO4 > KCl > Glucose
(c) Glucose > H2SO4 > KCl (d) KCl > Glucose > H2SO4
(13) How much ml. kerosene required to prepare 5 liter 15%V/V kerosene solution in petrol?
(a) 500 (b) 250
(c) 750 (d) 1000

(14) For which of the following pairs of substances, Van't Hoff factor (i) is identical of both the solutes
(substances)?
(a) [Co(NH3)6]Cl2 and [Fe(NH3)4Cl2] NO3 (b) K4 [Fe(CN)6] and K2SO4 · Al2(SO4)3 · 24H)2O
FeSO4 (NH4)2SO4 · 6H2O and K2SO4 · MgSO4 ·
(c) (d) K3[Fe(CN)6] and C6H5 NH3+Cl-
6H2O

(15) 0.1 mili mole = _____ mole.

(a) 10-6 (b) 10-4
(c) 10-3 (d) 10-2

(16) An aqueous solution of 2.05 M CH3COOH has density equal to 1.02 g/mole. What is the molality of this
solution?
(a) 1.14 m (b) 3.28 m
(c) 2.28 m (d) 0.44 m

(17) Which is the correct presentation for degree of association and degree of dissociation?
n i−1 n 1−i
(a) X = (1 − i) (
n−1
), α =
n−1
(b) X = (i − 1) (
n−1
), α =
1−n

n i−1 n 1−i
(c) X = (1 − i) (
n−1
), α =
1−n
(d) X = (1 − i) (
n−1
), α =
n−1

(18) At 300 K temperature, beaker A containing 0.02 M solution of urea and beaker B containing 0.002 M
solution of sugar are separated by semipermiable membrane with respect to water. On which beaker how
much pressure should be applied to prevent osmosis? Molecular weight of urea = 60 g/mol and molecular
weight of sugar= 342 g/mol. R = 0.8082 L atm. mol-1 k-1 .
(a) 0.4428 atm. on beaker B (b) 0.4920 atm. on beaker A
(c) 0.4920 atm. on beaker B (d) None of the above

(19) Which solution has the highest effect of temperature on its vapour pressure?
(a) Sugar solution (b) NaCl solution
(c) BaCl2 Solution (d) Aqueous H2S

(20) What is the mass of the solute ( molar mass = 60 g/mole) required to be dissolved in 180 g water so that
10% decrease in vapour pressure of water is recorded?
(a) 30 g (b) 60 g
(c) 120 g (d) 18 g

(21) When 20 g naphthoic acid (C H O ) is dissolved in 50 g of benzene (Kf = 1.72 Km-1), freezing point
11 8 2
depression of 2 K is observed. The Van't Hoff factor is _____ .
(a) 0.5 (b) 1
(c) 2 (d) 3

(22) For which solution the value of van't Hoff factor is not 1?
(a) Glucose (b) Sugar
(c) Fructose (d) Acetic acid

(23) The average osmotic pressure of human blood is 7.8 bar at 37°C. What is the concentration of an aqueous
NaCl solution that could be used in the blood stream?
(a) 0.16 mol/L (b) 0.31 mol/L
(c) 0.60 mol/L (d) 0.45 mol/L

(24) Which formula is correct to get molecular weight of the substance (M2) with reference to osmotic
pressure?
m2 m2 RT
(a) M2 = (
π
) VRT (b) M2 = (
V
)
π
 m2 π m2

(c) M2 = (
V
)
RT
(d) M2 = (
V
) nRT

(25) The freezing point of the aqueous solution of urea is -0.6°C. How much urea should be added to 3 kg
water to get such solution?(Kf = 1.5°C Kg. mol-1)
(a) 72 gram (b) 6.0 gram
(c) 3.6 gram (d) 2.4 gram

(26) What is the ratio of molar mass to formula mass for potash alum?
(a) 2 : 1 (b) 1 : 2
(c) 1 : 1 (d) 3 : 1

(27) The elevation in boiling point of the solution prepared by dissolving 0.6 gram urea to 200 gram water is
0.50°C. What will be the molal elevation constant?
(a) 10 K kg. mole (b) 10 K kg. mole-1
(c) 1.0 K kg. mole (d) 100 K kg. mole-1

(28) The vapour pressure of mixture of ethanol and propanol is 290 mm at 300 K temp. If the vapour pressure
of propanol is 200 mm at 300 K temp. and the mole fraction of ethanol is 0.6, then what will be the vapour
pressure of ethanol at 300 K temp.?
(a) 350 mm (b) 300 mm
(c) 700 mm (d) 360 mm

(29) On increasing temperature, the solubility of gaseous solute in liquid solvent

(a) Increases (b) Decreases
(c) Remains constant (d) Uncertain

(30) The two solutions, 1.5% urea and 5.25% unknown substance are isotonic. The density of both the solution
is 1 gram/Cm3 .What will be the molar mass of the unknown substance?
(a) 104 (b) 210
(c) 88 (d) 120
 Answer Key
1 - A | 2 - D | 3 - A | 4 - D | 5 - D | 6 - A | 7 - A | 8 - C | 9 - A | 10 - D | 11 - C |
12 - B | 13 - C | 14 - C | 15 - B | 16 - C | 17 - A | 18 - B | 19 - D | 20 - B | 21 - A | 22 - D |
23 - B | 24 - B | 25 - A | 26 - A | 27 - B | 28 - A | 29 - B | 30 - B |