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Stoichiometry-I Tutorial Sheet-4

PART-I (NEUTRALIZATION)
1. Find the volume of a 0.1 M H 2SO 4 solution needed to react completely with a 300 mL of
0.1 M NaOH(aq).

2. 20 mL of Mg(OH) 2 is titrated against a standard solution of H 2SO 4 labelled as “containing 2.45 g/L
of H 2SO 4 ”. The end point was obtained when 60 mL of acid was consumed. Find the strength of
Mg(OH) 2 solution.

3. 1000 mL of a di-acidic base was prepared by dissolving 5.30 gm of it in water. 30 mL of it were titrated
N
against solution of HCl(aq.). 18 mL of acid were used for complete neutralization. Find molecular
6
weight of the base.

4. 15.0 gm of a sample of Mg(OH) 2 is dissolved in H 2 O to prepare a 500 mL solution. 50 mL of this

M
solution when titrated against solution of oxalic acid (H 2C 2O 4 ), it needed 80 mL of it to reach end
5
point. Find % purity of Mg(OH)2 .

5. How many mL’s of a 0.1 N HCl are required to react completely with 1.0 gm of mixture containing
equimolar amounts of NaHCO3 and Na 2 CO3 ?

6. 2.65 gm of Na 2 CO3 (s) is dissolved in water to prepare 500 mL solution. 20 mL of this solution needed
16.0 mL of an unknown solution of H 2SO 4 for complete reaction. Find strength of H 2SO 4 solution.

7. 3.0 gm of a mixture containing CaO and CaCl 2 is mixed with 100 mL of 1.0 M HCl solution.
M
Now the solution is diluted to 200 mL. 20 mL of this diluted solution required 25 mL of KOH
5
solution. Find % of CaO in sample.

8. 0.5 gm of a sample of limestone (CaCO3 ) containing some inert impurities was dissolved “directly” into
M
30 mL of H 2 C2 O4 solution. The solution is then diluted to 100 mL. 25 mL of this solution required
20
N
12.5 mL of NaOH for complete neutralization. Find % CaCO3 in the original sample.
25

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9. 500 mL of 2.0 M HCl, 100 mL of 2.0 M H 2SO 4 and 1.0 gm meq. of a mono-acidic base are mixed
together. 30 mL of this solution required 20 mL of 143 gm of a crystalline salt, Na 2 CO3  xH 2O in
1.0 L of a solution. Find x (water of crystallization).
10. 2.26 gm of a sample of dolomite ore was dissolved in 700 mL of 0.1 M HCl. The solution was diluted to
2500 mL. 25 mL of this solution required 20 mL of 0.01 M NaOH solution for complete neutralization.
Find % composition of the ore.

11. A mixture containing Na 2 CO3 and K 2CO3 weighing 1.22 gm was dissolved in water to form 100 mL
M
of a solution. 20 mL of this solution required 40 mL of HCl for complete neutralization.
10
(a) Find the mass of K 2CO3 in the mixture.
(b) If 40 mL of above solution is treated with excess of BaCl 2 (aq) solution, find the mass of white
precipitate obtained. [MW : K 2CO3  138, BaCO3  197, Na 2CO3  106]
M
12. 25 mL of a solution containing HCl and H 2SO 4 required 30 mL of caustic soda solution. 50 mL of
2
same solution on reaction with BaCl 2 solution, gave 2.33 gm of a white precipitate. Find the strength of
solution w.r.t. HCl and H 2SO 4 . [MW : BaSO 4  233, H 2SO 4  98]

13. Consider titration of NaOH solution versus 1.25 M oxalic acid solution. At the end point following
burette readings were obtained.
(i) 4.5 mL (ii) 4.5 mL (iii) 4.4 mL
(iv) 4.4 mL (v) 4.4 mL
If the volume of oxalic acid taken was 10.0 mL then the molarity of the NaOH solution is ________M.
(Rounded off to nearest integer)
[JEE Main 2021, 25th Feb, Evening Shift]

14. The exact volumes of 1 M NaOH solution required to neutralize 50 mL of 1 M H 3PO3 solution and
100 mL of 2 M H3PO2 solution, respectively, are:
(A) 50 mL and 50 mL (B) 100 mL and 50 mL
(C) 100 mL and 200 mL (D) 100 mL and 100 mL
[JEE Main 2021, 16th Mar, Evening Shift]

15. 10.0 mL of Na 2 CO3 solution is titrated against 0.2 M HCl solution. The following titre values were
obtained in 5 readings:
4.8 mL, 4.9 mL, 5.0 mL, 5.0 mL and 5.0 mL
Based on these readings and convention of titrimetric estimation the concentration of Na 2 CO3 solution
is ________ mM. (Round off to the Nearest integer) [JEE Main 2021, 18th Mar, Evening Shift]

14. The normality of H 2SO 4 in the solution obtained on mixing 100 mL of 0.1 M H 2SO 4 with 50 mL of

0.1 M NaOH is ________ 101 N. (Nearest integer)

[JEE Main 2022, 27th Jul, Evening Shift]

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15. SO 2Cl 2 on reaction with excess of water results into acidic mixture.
SO 2 Cl2  2H 2O 
 H 2SO4  2HCl
16 moles of NaOH is required for the complete neutralization of the resultant acidic mixture. The number
of moles of SO 2Cl 2 used is:
(A) 16 (B) 8 (C) 4 (D) 2
[JEE Main 2022, 25th Jul, Morning Shift]
16. The neutralization occurs when 10 mL of 0.1 M acid ‘A’ allowed to react with 30 mL of 0.05 M base
M(OH)2 . The basicity of the acid ‘A’ is ________. [M is a metal]
[JEE Main 2022, 25th Jun, Evening Shift]
17. The density of a monobasic strong acid (molar mass 24.2 gm/mol) is 1.21 kg/L. The volume of its
solution required for the complete neutralization of 25 mL of 0.24 M NaOH is ________ 102 mL.
[Nearest integer] [JEE Main 2023, 25th Jan, Morning Shift]

18. The volume of HCl, containing 73gm L1, required to completely neutralize NaOH obtained by
reacting 0.69 g of metallic sodium with water, is ________ mL. (Nearest integer)
[Given : Molar masses of Na, Cl, O, H, are 23, 35.5, 16 and 1gm mol1 ]
[JEE Main 2023, 29th Jan, Evening Shift]

19. The volume of 0.02 M aqueous HBr required to neutralize 10.0 mL of 0.01 M aqueous Ba(OH) 2 is:
[Assume complete neutralization]
(A) 2.5 mL (B) 7.5 mL (C) 5.0 mL (D) 10.0 mL
[JEE Main 2023, 6th Apr, Evening Shift]
20. 20 mL of calcium hydroxide was consumed when it was reacted with 10 mL of unknown solution of
H 2SO 4 . Also 20 mL standard solution of 0.5 M HCl containing 2 drops of phenolphthalein was titrated
with calcium hydroxide, the mixture showed pink colour when burette displayed the value of 35.5 mL
whereas the burette showed 25.5 mL initially. The concentration of H 2SO 4 is ________ M.
[Nearest integer]
[JEE Main 2023, 13th Apr, Morning Shift]

PART-II (DOUBLE INDICATORS)

1. A 25 mL solution containing NaOH and Na 2 CO3 required.
(i) 35 mL of 0.1 N HCl till methyl orange end point
(ii) 25 mL of 0.1 N HCl till phenolphthalein end point
in two different experiments for complete titration. Find strength of NaOH and Na 2 CO3 .

2. A 0.1 gm crude sample containing NaOH and Na 2 CO3 with inert impurities was dissolved in H 2 O.
N
(i) 50 mL of this required 30 mL of HCl to reach phenolphthalein end point.
10
(ii) Few drops of methyl orange are added to the above solution and titration is continued with same
HCl solution. 10 mL of acid was further consumed to reach methyl orange end point.
Find strength of NaOH and Na 2 CO3 .

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Answers to Tutorial Sheet-4 | Stoichiometry-I

PART-I (NEUTRALIZATION)
1. 150 mL 2. 4.35 gm/L 3. 106 amu 4. 61.867%
5. 157.89 mL 6. 6.125 gm/L 7. 46.67% 8. 10%
9. 10 10. CaCO3 : 44.25%, MgCO3 : 55.75%
11. (a) 0.69 gm (b) 0.788 gm
12. SHCl  7.3gm / L; SBaCl2  19.6 gm / L 13. 6 14. C

15. 50 16. 1 17. C 18. 3

19. 12 20. 15 mL 21. D 22. 1

PART-II (DOUBLE INDICATORS)

1. SNaOH  2.40 gm / L ; SNa 2CO3  4.24 gm / L

2. SNaOH  1.60 gm / L ; SNa 2CO3  2.12 gm / L

3. SNa 2CO3  5.088gm / L ; SNaHCO3  2.688gm / L

4. 3:5 5. SHCl  3.65gm / L ; SBaCl2  5.20gm / L 6. 4

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