Hydrogen Bonding and Molecular Interactions
Hydrogen Bonding and Molecular Interactions
5(iii - iv)
(b) Which diagram best represents a hydrogen bond between two water molecules?
(1)
180° Specification Reference: 7.2
O
H H H
A
O
180°
O
H H
B H
O
104.5° H
C
O O
H H H
DO NOT WRITE IN THIS AREA
H 104.5°
O
H
D
H
O
10
*P61475A01028*
3 Under certain conditions, graphite burns to form carbon monoxide.
2C(s) + O2(g) 2CO(g) H = −221 kJ mol−1
DO NOT WRITE IN THIS AREA
4 What are the strongest interactions between molecules in solid hydrogen iodide, HI?
Specification Reference: 7.5(iv)
A covalent bonds
B hydrogen bonds
C ionic bonds
DO NOT WRITE IN THIS AREA
D London forces
3
*P61657A0328* Turn over
(iii) The displayed formula of butan-1-ol is shown. Specification Reference: 7.5
H H H H H
H C C C C O
H H H H
DO NOT WRITE IN THIS AREA
DO NOT WRITE IN THIS AREA
13
*P61657A01328* Turn over
(ii) Biobutanol can be mixed with petrol in any proportion whereas bioethanol cannot.
Petrol is a mixture of liquid alkanes.
. . .. .. .. .. .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. .... ... ... . .... ... ... ... .... ... ... ... .... ... ... ... .... ... ... .... ... ... ... .... ... ... ... .... ... ... .... ... ... ... .... ... ... ... .... ... ........ ......................
. .. .. .. .. ... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. ... .... ... . ... .... ... ... ... .... ... ... ... .... ... ... .... ... ... ... .... ... ... ... .... ... ... ... .... ... ... .... ... ... ... .... ... ... ... .... ........ ......................
.. .. .. .. .. .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. ... .... ... . ... ... .... ... ... ... .... ... ... ... .... ... ... .... ... ... ... .... ... ... ... .... ... ... ... .... ... ... .... ... ... ... .... ... ... ... ......... ......................
. .. .. .. .. .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. ... ... .... . ... ... ... .... ... ... ... .... ... ... .... ... ... ... .... ... ... ... .... ... ... .... ... ... ... .... ... ... ... .... ... ... ... .... ... ... ......... ......................
.. .. .. .. .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. ... ... ... . .... ... ... ... .... ... ... ... .... ... ... .... ... ... ... .... ... ... ... .... ... ... .... ... ... ... .... ... ... ... .... ... ... .... ... ... ......... ......................
. .. .. .. .. ... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . .... ... ... . ... .... ... ... ... .... ... ... .... ... ... ... .... ... ... ... .... ... ... ... .... ... ... .... ... ... ... .... ... ... ... .... ... ... .... ... ......... ......................
16
*P61657A01628*
3 Nitrogen reacts with hydrogen to form ammonia.
A 246
B 360
C 376
D 391
4 How many moles of CO2 are formed when 3.0 mol of chloroethene, C2H3Cl, is mixed
with 10.0 mol of oxygen and react as shown?
3
*P60464A0328* Turn over
11 Ethanol can be prepared by reacting chloroethane with aqueous potassium hydroxide.
(b) How do the boiling temperatures of ethanol and chloroethane compare, and
what is the reason for the difference?
Specification Reference: 7.5(ii) (1)
Comparison of boiling
Reason for the difference
temperature
A ethanol is higher ethanol molecules form hydrogen bonds
t
C ethanol is lower ethanol molecules have fewer electrons
7
*P60464A0728* Turn over
(b) The hydration of anhydrous copper(II) sulfate is reversible.
t
CuSO4(s) + 5H2O(l) CuSO4.5H2O(s)
DO NOT WRITE IN THIS AREA
The forward reaction is exothermic. The temperature changes for both the
forward and reverse reactions are difficult to measure.
Suggest a reason in each case.
Specification Reference: 9.10 (2)
Forward ... .. ... .. ... .. ... ... .. .. ..... ...... ..... ...... ..... ...... ...... ..... ...... ..... ...... ..... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. . .. .. .. . .. ... . . . .. . .. . . . .. . . . .. . . .. . . . ..
Bag
Reverse .. .. ... .. ... ... .. ... .. .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. .. .. . .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. .. . . .. . . . . . . .. . . .. . . . .. . . . .. . . .
............ ... .. ... .. ... ... .. ... .. ... ... .. ... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. .. . .. . .. .. . .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. . .. .. . . .. . . ... . . . .. . . .. . . . .. . . . .. .
(c) Describe the processes that occur when solid copper(II) sulfate dissolves in water.
Specification Reference: 7.1 (2)
13
*P60464A01328* Turn over
16 This question is about trends in the Periodic Table.
*(a) The boiling temperatures of some isoelectronic hydrides are shown.
............ .. ... ... .. ... .. ... .. ... ... .. ... ... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. .. . .. .. . .. .. . .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. . .. .. . . .. . . ... . . . .. . . .. . . . .. . . . .. .
............. .. ... .. ... ... .. ... .. ... ... .. ... . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. .. . .. .. . . . . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. .. . .. .. . ... . . . ... .. . . .. . . . .. . . . .. . . . ..
............ .. ... .. ... .. ... ... .. ... .. ... ... ... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. .. .. . .. .. . . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. .. . .. .. . ... . . . ... .. . . .. . . . .. . . . .. . . . ..
.............. .. ... .. ... ... .. ... .. ... .. ... .... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. .. . .. . . . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. .. . .. .. . ... . . . ... .. . . .. . . . .. . . . .. . . . ..
............ ... ... .. ... .. ... .. ... ... .. ... .. ... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. .. . .. .. . . . . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. .. . .. .. . .. .. . .. .. .. . .. .. . ... . . . ... .. . . .. . . . .. . . . .. . . . ..
16
*P60464A01628*
SECTION A
For each question, select one answer from A to D and put a cross in the box .
If you change your mind, put a line through the box and then mark your new answer
with a cross .
A +243.0
B –243.0
7
What is the enthalpy change of atomisation of chlorine in kJ mol–1?
Specification Reference: 6.4(v)
C +121.5
D –121.5
A exothermic increases
B exothermic decreases
C endothermic increases
D endothermic decreases
3 Which of the following statements about water is not due to hydrogen bonding?
A water has a less open structure than ice Specification Reference: 7.2, 7.3
2
*P62588A0224*
4 The skeletal formulae of three isomers are shown.
X Y Z
B X, Y, Z
C Y, Z, X
D X, Z, Y
3
*P62588A0324* Turn over
(iii) Explain, with reference to their intermolecular forces, why the boiling temperatures
of alkanes increase as the number of carbon atoms increases. A detailed
description of the intermolecular forces is not required.
Specification Reference: 7.5(i) (3)
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
12
*P62588A01224*
SECTION A
Answer ALL the questions in this section.
You should aim to spend no more than 20 minutes on this section.
For each question, select one answer from A to D and put a cross in the box . If you change
your mind, put a line through the box and then mark your new answer with a cross .
1 The energy profile for a reaction is shown.
Energy X products
Begg
reactants
Progress of reaction
What is the minimum energy needed for this reaction to occur? Specification Reference: 9.2
A X
B
B Y
C X−Y
D X+Y
2 Which of these isomers with the formula C8H18 has the lowest boiling temperature?
B CH3CH(CH3)CH2CH2CH2CH2CH3
C CH3C(CH3)2CH2CH(CH3)CH3
D CH3CH2CH2CH2CH2CH2CH2CH3
2
*P67748A0228*
3 Which of these pure compounds has hydrogen bonding in the liquid state?
B trimethylamine, (CH3)3N
C hydrogen fluoride, HF
4 The hydrogen ion, H+, bonds to a water molecule forming an H3O+ ion.
For H3O+, what shape and H-O-H bond angle are predicted by the
electron-pair repulsion theory?
Specification Reference: 3.19
Use this space for any rough working. Anything you write in this space will gain no credit.
3
*P67748A0328* Turn over
5 The viscosities of four liquid organic compounds are compared by placing the liquids
in separate identical tubes, each with an air bubble at the top.
Air bubble
Liquid
The tubes are inverted, and the times measured for the air bubble to travel the length
of the tube.
For which compound does the air bubble take the longest time?
B OH
OH
OH
OH
OH
OH
OH
OH
C
OH
OH
OH
OH
HO
HO
HO
HO OH
OH
OH
OH
D O
OO
O
O
OO
O
O O
OO
O OO
O
O O
OO
O OO
O
4
*P67748A0428*
(b) The product of the reaction is a mixture of ethanol and water.
Explain why ethanol and water mix together fully.
You may find it helpful to draw a diagram.
Specification Reference: 7.6(ii) (3)
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
(ii) State the conditions needed to maximise the yield of each product.
Specification Reference: 10.19 (2)
Conditions for maximum yield of Y Mpeg
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
14
*P67748A01428*
(b) DMAA is only slightly soluble in water but dissolves readily in hydrochloric acid to
form an aqueous solution.
NH2 +
NH3
+ HCl −
+ Cl
DMAA
(i) Explain the type of bonding that occurs between the nitrogen atom and the
hydrogen ion, when the positive ion forms.
Specification Reference: 3.11(ii) (3)
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
(ii) Complete the diagrams to show how the ions formed in the reaction between
DMAA and hydrochloric acid interact with water molecules.
Specification Reference: 7.1 (3)
17
*P67748A01728* Turn over
20 This question is about the forces between molecules and ions.
*(a) Some data for three small molecules are shown.
Boiling temperature
Molecule Mr
/ °C
Methanol 32.0 65
Explain the large variation in boiling temperatures, given the small range in
Mr values.
Detailed descriptions of the forces involved are not required.
Specification Reference: 7.1, 7.2, 7.5 (6)
. . .. . . . . .. . ...................... .. .. ... .. .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . . .. ........................................................................................................................ ... ... ... ... .. ... ... .. .. ... ... ... ... ... .. ...
. . .. . . . . .. . ...................... .. .. ... .. .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . . .. ........................................................................................................................ ... ... ... ... .. ... ... .. .. ... ... ... ... ... .. ...
. . .. . . . . .. . ...................... .. .. ... .. .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . . .. ........................................................................................................................ ... ... ... ... .. ... ... .. .. ... ... ... ... ... .. ...
. . .. . . . . .. . ...................... .. .. ... .. .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . . .. ........................................................................................................................ ... ... ... ... .. ... ... .. .. ... ... ... ... ... .. ...
. . .. . . . . .. . ...................... .. .. ... .. .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . . .. ........................................................................................................................ ... ... ... ... .. ... ... .. .. ... ... ... ... ... .. ...
. . .. . . . . .. . ...................... .. .. ... .. .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . . .. ........................................................................................................................ ... ... ... ... .. ... ... .. .. ... ... ... ... ... .. ...
. . .. . . . . .. . ...................... .. .. ... .. .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . . .. ........................................................................................................................ ... ... ... ... .. ... ... .. .. ... ... ... ... ... .. ...
. . .. . . . . .. . ...................... .. .. ... .. .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . . .. ........................................................................................................................ ... ... ... ... .. ... ... .. .. ... ... ... ... ... .. ...
. . .. . . . . .. . ...................... .. .. ... .. .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . . .. ........................................................................................................................ ... ... ... ... .. ... ... .. .. ... ... ... ... ... .. ...
. . .. . . . . .. . ...................... .. .. ... .. .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . . .. ........................................................................................................................ ... ... ... ... .. ... ... .. .. ... ... ... ... ... .. ...
. . .. . . . . .. . ...................... .. .. ... .. .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . . .. ........................................................................................................................ ... ... ... ... .. ... ... .. .. ... ... ... ... ... .. ...
. . .. . . . . .. . ...................... .. .. ... .. .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . . .. ........................................................................................................................ ... ... ... ... .. ... ... .. .. ... ... ... ... ... .. ...
. . .. . . . . .. . ...................... .. .. ... .. .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . . .. ........................................................................................................................ ... ... ... ... .. ... ... .. .. ... ... ... ... ... .. ...
. . .. . . . . .. . ...................... .. .. ... .. .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . . .. ........................................................................................................................ ... ... ... ... .. ... ... .. .. ... ... ... ... ... .. ...
. . .. . . . . .. . ...................... .. .. ... .. .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . . .. ........................................................................................................................ ... ... ... ... .. ... ... .. .. ... ... ... ... ... .. ...
. . .. . . . . .. . ...................... .. .. ... .. .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . . .. ........................................................................................................................ ... ... ... ... .. ... ... .. .. ... ... ... ... ... .. ...
. . .. . . . . .. . ...................... .. .. ... .. .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . . .. ........................................................................................................................ ... ... ... ... .. ... ... .. .. ... ... ... ... ... .. ...
18
*P64624A01828*
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
19
*P64624A01928* Turn over
(b) Calcium chloride is soluble in water.
Complete the diagram to show how water molecules interact with each ion.
You may use to represent a water molecule.
Specification Reference: 7.2 (2)
Ca2+ Cl–
(c) Explain why bromine is a liquid but iodine is a solid at room temperature.
Detailed explanations of the forces involved are not required.
Specification Reference: 7.1 (2)
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
20
*P64624A02028*
6 Which of these isomers has the highest boiling temperature?
Specification Reference: 7.5(i - ii)
Use this space for any rough working. Anything you write in this space will gain no credit.
4
*P67128A0428*
(c) The boiling temperatures of some halogenoalkanes are shown.
Boiling temperature
Halogenoalkane
/ °C
1-chloropropane 47
1-bromopropane 71
1-iodopropane 103
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
15
*P67128A01528* Turn over
(d) Ethanol is hygroscopic, which means it readily absorbs water from the air.
(i) Give a possible reason why ethanol is able to absorb water.
Specification Reference: 7.6(ii) (1)
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
(ii) Suggest a problem arising from the hygroscopic nature of ethanol when using
this fuel in a motor vehicle.
Specification Reference: 4.16 (1)
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
*(i) Typical conditions are 300 °C and 60 atm with a catalyst of phosphoric acid.
Moooooo
Explain why these conditions are used, by describing the effect of changing
the temperature and pressure on rate of reaction, equilibrium yield and cost.
Specification Reference: 9.1, 9.2, 9.5, 9.7, 9.11 (6)
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
the
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
C
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
LEGGE
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
22
*P67128A02228*
5 Which sequence shows the molecules in order of increasing boiling temperature?
A H2O < Br2 < Cl2 < CH4 Specification Reference: 7.2, 7.4
7 Which intermolecular forces exist between the molecules of the compound shown?
Specification Reference: 7.1, 7.4
HO O
4
*P69501A0428*
8 This question is about alkanes.
B hexane
C pentane
D propane
5
*P69501A0528* Turn over
SECTION C
Answer all the questions. Write your answers in the spaces provided.
24 Some diesel cars contain an extra catalytic converter for the reduction of
nitrogen oxides (NOx) in exhaust gases.
A solution of urea is used for this process.
H C H
N N
urea
H H
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
(b) A saturated solution of urea has a concentration of 9.07 mol dm–3 at 25 °C.
Calculate the mass of urea in 150 cm3 of a saturated solution.
Specification Reference: 1.8 (2)
20
*P69501A02028*
SECTION A
Answer ALL the questions in this section.
You should aim to spend no more than 20 minutes on this section.
For each question, select one answer from A to D and put a cross in the box . If you change
your mind, put a line through the box and then mark your new answer with a cross .
1 Which equation represents the standard enthalpy change of formation, ΔfH d , for
aluminium oxide?
Specification Reference: 6.4(ii)
A 2Al(s) + 1½O2(g) → Al2O3(s)
B 2Al(s) + 3O(g) → Al2O3(s)
A (CH3)3COH
B CH3CH2CH2CH2OH
C CH3CH2CH(CH3)2
D CH3CH2CH2CH2CH3
2
*P70965A0228*
(d) The graph shows the boiling temperatures of the hydrogen halides.
350
300
250
200
Boiling temperature
/K 150
100
50
0
HF HCl HBr HI
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
. . . .. . . . . . ........................ .. .. .. ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . .. . .. . . ............................................................................................................................ .. ... .. ... .. ... ... . . .. ... ... ... ... ... .. ..
15
*P70965A01528* Turn over