18-05-2025

1001CJA101002250001 JA

PART-1 : PHYSICS

SECTION-I (i)

1) sin330o =

(A)

(B)

(C)

(D)

2) The potential energy (U) of a particle can be expressed in certain case as . Where m is
the mass and r is distance . Find the dimensional formulae for A.

(A) [M1L2T–1]
0 0
(B) [M L T1]
0 0
(C) [ML T ]
0 0
(D) [M L1T ]

3) If velocity (v), time (t) & force (F) were chosen as basic quantities then find the dimensions of
mass.

(A) [M] = FTV−1

(B) [M] = FTV
(C) [M] = F2TV
(D) [M] = FT−1V

4) A vector perpendicular to is

(A)
(B)
(C)
(D)

5) A car travels 30 km at a uniform speed of 40km/h and the next 30 km at a uniform speed of 20
km/h. Find its average speed (in km/hr).
(A)

(B)

(C)

(D)

6) A ball is thrown upwards from the ground. It crosses a point at a height of 25 m twice at an
interval of 4 secs. The ball was thrown with the velocity of :-

(A) 20 m/sec
(B) 25 m/sec
(C) 30 m/sec
(D) 35 m/sec

SECTION-I (ii)

1)

For the equation x = AC sin (Bt) + D e(BCt), where x and t represent position and time respectively,
which of the following is/are CORRECT?

(A) Dimension of AC is LT–1.

(B) Dimension of B is T–1.
(C) Dimension of AC and D are same.
(D) Dimension of C is T–1.

2) Which of the following quantities cannot enter into the list of fundamental quantities in any
system of units?

(A) Mass, Time and Acceleration

(B) Length, Volume and Linear momentum
(C) Mass, Velocity and Linear momentum
(D) Length, Force and Time

3)

The four pairs of force vectors are given, which pairs of force vectors cannot be added to give a
resultant vector of magnitude 10 N?

(A) 2N, 13 N
(B) 5N, 16 N
(C) 7N, 8N
(D) 100N, 105 N
4) Consider and . Choose correct options.

(A)
(B)
(C)

(D)

5) A particle position is given as x = 6t2 – 12t. Choose correct options. Where t is in seconds and x is
in meter.

(A) Particle stop at t = 2s.

(B) Particle stop at t = 1s.
(C) Acceleration of particle is 12t
(D) Acceleration of particle is 12 m/s2

6) A ball is projected from top of the tower with 10 m/s. Finally ball falls on the ground. Height of

tower is 40m. Then,

(A) max height attained by ball is 45 m from the ground.

(B) time taken by ball to reach same initial position is 2 sec.
(C) total time taken by particle to reach ground is 6 sec.
(D) ball will have 15 m/s at certain instant of time

SECTION-II

1) If mass is expressed as vx dy az where v is velocity; d is density and a is acceleration then the value
of x + y + z is

2) In a new system of units, mass, acceleration & frequency are taken as fundamental units. If unit of
mass is 100 g, unit of acceleration is 2 m/s2 and unit of frequency is 4 sec–1, in this new system of
units, then the value of 10 J in this new system is K × 100. Fill K .

3) The resultant of two forces 3F and 2F is R. If the first force is doubled then the resultant is also
doubled. What is the angle between two forces (in degree) ?
4) Vector and are shown in figure find magnitude of .

5) A body undergoing uniformly accelerated motion starts moving along +x-axis with a velocity of 5
m/s and after 5 seconds its velocity becomes 20 m/s in the same direction. The velocity of the body
10 seconds after the start of the motion is (5 x n)m/s. Find n?

6) The maximum and minimum magnitudes of the resultant of two forces are 35 N and 5 N
respectively. Find the magnitude of resultant force when act perpendicular to each other.

PART-2 : CHEMISTRY

SECTION-I (i)

1) Which of the following statement is NOT CORRECT for an electron that has the quantum number
n = 4 and mℓ = 2.

(A)
The electron may have quantum number ms =
(B) The electron may have quantum number ℓ = 2
(C) The electron may have quantum number ℓ = 3
(D) The electron may have quantum number ℓ = 0, 1, 2, 3

2) Which of the following pair of elements have same value of azimuthal quantum number for outer
most unpaired electron.

(A) Na, Cl
(B) O, Sc
(C) Cu, Li
(D) All of these

3) Which of the following statement is correct?

(A) Total number of electrons in a subshell is (2 + 1)

(B) and orbitals are non-axial
 Only s-orbitals has directional orientation while pz, d, and f-orbitals have non-directional
(C)
properties
(D) Spin multiplicity of N-atom is 4

4) Which of the following sets of quantum numbers represent an impossible arrangement :-

(A)
n = 3 , ℓ = 2 , m = –2 , s =

(B)
n=4,ℓ=0,m=0,s=

(C)
n = 3 , ℓ = 2 , m = –3 , s =

(D)
n=5,ℓ=3,m=0,s=

5) The correct order of increasing atomic size of element N,F, Si & P.

(A) N < F < Si < P

(B) F > N < P < Si
(C) F < N < P < Si
(D) F < N < Si < P

6) The ionization energy will be maximum for which process?

(A) Ba → Ba+
(B) Be → Be+
(C) Cs → Cs+
(D) Li → Li+

SECTION-I (ii)

1) Select correct order of size :

(A) Ti2+ < Ti < Zr

(B) Ti2+ < Ti < Hf
(C) Zr2+ < Zr ≈ Hf
(D) Hf2+ < Hf ≈ Zr

2) Which of the following orders of atomic / Ionic radius is/are correct ?

(A) B < Ga < Aℓ

(B) Sc > Cu < Zn
(C) C < O < N
(D) Al+3 < Al+2 < Al+1

3) Which of the following is correct order of EA.

(A) N < C < O < F
(B) F > Cl > Br > I
(C) Cl > F > Br > I
(D) C < N < O < F

4) Which is/are the correct order/s of atomic radius ?

(A) Li < B < Be

(B) Be < B < Li
(C) Li > Be > B
(D) N > O > F

5) Choose the correct statement(s) if internuclear distance between two atoms in molecule (A2) is 90
pm.

(A) covalent radius is 45 pm

(B) metallic radius of A is greater than 45 pm
(C) actual size of Atom A is more than 45 pm
(D) actual size of atom A is lesser than 45 pm

6) The statement that is not correct for periodic classification of elements is.

(A) The properties of elements are the periodic functions of their atomic numbers
(B) Nonmetallic elements are less in number than metallic elements.
For transition elements, the 3d-orbitals are filled with electrons after 3p-orbitals and before 4s-
(C)
orbitals.
The first ionisation enthalpies of elements generally increases with an increase in atomic
(D)
number as we go along a period.

SECTION-II

1) From the following list, how many elements occupy the ascending position of the Lother Meyer
curve?
Li, Ca, Sr, Br, Rb, Ba, Cl, Fe, K, F

2)

Period number of Sc in modern periodic table is = x

Group number of Tℓ in modern periodic table is = (according to 1 to 18 convention). Find the
value of y – x

3) If the successive ionisation energy values for an element 'X' (belongs to 2nd period) are given
below :
IE1 = 1086 kJ / mol. ; IE2 = 2352 kJ / mol.
IE3 = 4625 kJ / mol. ; IE4 = 6222 kJ / mol.
IE5 = 37830 kJ / mol.
then the atomic number of element 'X' is :

4) Total number of elements which have less I.E1 than N.

Be, B, C, F, P, He

5) How many of the following elements have less than 8 electrons in s-subshell.
Fe, Ga, Ca, Cr, Zn, K, Ar, Cu

6) How many orbital will have the quantum numbers ; n = 3, ℓ = 2, mℓ = +2.

PART-3 : MATHEMATICS

SECTION-I (i)

1) In a city, three daily newspaper A, B, C are published, 42% of the people in that city read A, 51%
read B and 68% read C. 30% read A and B; 28% read B and C; 36% read A and C; 8% do not read
any of three newspapers. The percentage of persons who read all the three papers is

(A) 25%
(B) 18%
(C) 20%
(D) None of these

2) A survey shows that 61% of Indian like cheese where as 72% like mangoes. If µ% of the Indian
like both cheese and mangoes then

(A) µ < 61
(B) µ < 33
(C) µ > 61
(D) 33 ≤ µ ≤ 61

3)

Value of is :

(A)
(B)
(C) 3
(D) 6

4) Let N = {x : 32x + 2 – 13 × 6x + 4x + 1 = 0 & x ∈ R}. If S is sum of distinct elements of set N, then S2

is

(A) 4
(B) 5
(C) 6
(D) 7

5) Let P(x) be a polynomial of the form P(x) = ax7 + bx3 + cx – 5, where a, b, c are constants. If P(–7)
= 7. Then P(7) is equal to

(A) –17
(B) 17
(C) 7
(D) None of these

6) Identify the incorrect statement ?

(A) If A ⊂ B and A ≠ B, then A is called a proper subset of B

(B) If A ⊂ B, then B is called superset of A.
(C) A = {1, 2, 3} is NOT a proper subset of B = {1, 2, 3, 4}
(D) If a set A has only one element, we call it a singleton set.

SECTION-I (ii)

1) Which one of the following results is not true ?

(A) If value of (21/2 + 1) (21/4 + 1) (21/8 + 1) is expressed as , where a, b, c ∈ Z , then a + b +

c=4

(B)
If , then x = –4

(C)
If a, b > 0 then min value of (a + b) is equal to 2

(D) Greatest among and is

2) Let A be a set of rational numbers of the form p/q, where p, q ∈ {1, 2, 3, 4, 5, 6}. Also B is a
subset of A containing natural numbers only, then

(A) Cardinality of set A is 23

(B) Power set of A contains 223 elements
(C) Cardinality of set B is 11
(D) Number of subsets of set B is 26

3) Let P is a natural number and Q is positive irrational number such that (Amax and
Amin represents maximum and minimum value of A respectively), then

(A) Pmax = 12
(B) Pmin = 1
(C)
(D)

4) There exist some positive real number M such that if you add five M's together you get the same
result as if you were to multiply five M's together. Which of the following is true about M

(A) M15 is rational

(B) M12 is rational
(C) M30 is rational
(D) M20 is rational

5) Which of the following is Incorrect ?

(A)
(B)
(C)
(D)

6) If x2 + 3x + 7 is a factor of x4 + px2 + q then

(A)
(B) p & q are relatively prime
(C) q – p2 = 24
(D) one of p or q is a prime number

SECTION-II

1) In a class of 40 students, 12 enrolled for both English and German. 22 enrolled for German. If the
students of the class enrolled for at least one of the two subjects, then if students enrolled for only
English and not German is equal to λ, then λ/5 equals

2) The sum of all real values of x satisfying the equation

3) If 3x + 3–x = 2, then x is equal to

4) Let P(x) = x4 + ax3 + bx2 + cx + d, where a, b, c, d ∈ R.

Suppose P(0) = 6, P(1) = 7, P(2) = 8 and P(3) = 9, then find the value of P(4).

5) If 8x3 + 1 + 18xy = 27y3 and 2x ≠ 1 then value of 3y – 2x is -

6) In triangle ABC right angled at vertex B, a point O is chosen on the side BC such that the circle γ
centered at O of radius OB touches the side AC. Let AB = 63 and BC = 16 and the radius of γ be the

form where m, n are relatively prime positive integers. Find the value of (m – 7n).
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6
A. C A A D B C

SECTION-I (ii)

Q. 7 8 9 10 11 12
A. B,C B,C A,B A,B,D B,D A,B,D

SECTION-II

Q. 13 14 15 16 17 18
A. 4.00 4.00 120.00 5.00 7.00 25.00

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23 24
A. D C D C C B

SECTION-I (ii)

Q. 25 26 27 28 29 30
A. A,B,C,D A,B,D A,C C,D A,B,C C

SECTION-II

Q. 31 32 33 34 35 36
A. 3.00 9.00 6.00 4.00 4.00 1.00

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40 41 42
A. A D D A A C

SECTION-I (ii)

Q. 43 44 45 46 47 48
A. A,C A,B,D A,B,C,D B,D A,B,D A,B,C,D
 SECTION-II

Q. 49 50 51 52 53 54
A. 3.60 7.50 0.00 34.00 1.00 7.00
 SOLUTIONS

PART-1 : PHYSICS

1)

4) We see that dot product of with is zero

5)

We known that,
So, let the time taken to cover first 30 km is t1

hours = hours
and let the time taken to cover next 30 km is t2

hours = hours

So, the total time = hours

Average speed = =

Average speed = km/hr.

6)

8) For (A) : Mass → M, Time → T, Acceleration → LT–2

For (B) : Length → L, Volume → L3, Linear momentum → MLT–1
For (C) : Mass → M, Velocity → LT–1, Linear momentum → MLT–1
For (D) : Length → L, Force → MLT–2, Time → T

9) ≤ Resultant vector ≤
(1) 11 ≤ ≤ 15
(2) 11 ≤ ≤ 21
(3) 1 ≤ ≤ 15
(4) 5 ≤ ≤ 205

12) max =

= Time of height

= 4 sec.
Umax at instant it strike ground is 30 m/s

13) m = R vx dy az (where k is dimensionless)

[M] = [LT–1]x [ML–3]y [LT–2]z
Solve for x, y and z.

14) [Energy] = ML2T–2 =

n1v1 = n2v2

n2 = 10

= 10 × 10 × × 16
n2 = 400

15)

and
......(2)
Divide eq. (2) by (1)

On squaring and cross multiplication

52 + 48 cos q = 40 + 24 cos q
24 cos q = – 12
 θ =120°

17) u = 5 m/s, v = 20 m/s, t = 5 sec.

a=
v = u + at = 5 + 3´ 10 = 35 m/s

PART-2 : CHEMISTRY

22)

25) All are correct

26) C > N > O

27)

EA ⇒ Cl > F,
N<C

28)

Atomic size gradually decreases as you go from left to right in a period.

29)
Metallic radius = Atomic radius
 33) Explanation : Atomic no. is asked by giving value's of successive values.

Concept : IE

Solution/Explanation/Calculation :
Ace to values 4th jump has max. difference
∴ it should what 4e– in valence shell

from 2nd period

Atomic no. = 6.

35)

Ans : (4)

No. of e–s in s-subshell

26Fe – 1s2 2s2 2p6 3s2 3p6 4s2 3d6 8

31Ga – 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p1 8

20Ca – 1s2 2s2 2p6 3s2 3p6 4s2 8

21Cr – 1s2 2s2 2p6 3s2 3p6 4s1 3d5 7

30Zn – 1s2 2s2 2p6 3s2 3p6 4s2 3d10 8

18Ar – 1s2 2s2 2p6 3s2 3p6 6

29Cu – 1s2 2s2 2p6 3s2 3p6 4s1 3d10 7

No of elements = 3

36) Ans : (1)

, mℓ = +2
Subshell = 3d
⇓
 No. of orbitals = 1

PART-3 : MATHEMATICS

37) Let the no. of persons in the city be 100.

Then we have
n(A) = 42, n(B) = 51, n(C) = 68

Using

Substituting the above values, we have

92 = 42 + 51 + 68 – 30 – 28 – 36 +

Hence, 25% of the people read all the three papers.

38) Let total number of Indians be 100, let X, C, A be the sets of all Indians, Indians liking
cheese, Indian liking mangos respectively.
n(X) = 100 n(C) = 61
n(A) = 72 n(C ∩ A) = µ
n(A ∪ C) = n(A) + n(C) – n(A ∩ C)
n(A ∪ C) = 72 + 61 – µ
n(A ∪ C) = 133 – µ
n(A ∪ C) ≤ 100
133 – µ ≤ 100
µ ≥ 33
Also then n(C ∩ A) ≤ n(A)
µ ≤ 61
∴ 33 ≤ µ ≤ 61

39)

y=
y2 = 24 +

40)
Let where t > 0
2
⇒ 9t – 13t + 4 = 0

⇒ t = 1 or

⇒ or ⇒ x = 0 or –2
⇒ S = 0 + (–2) = –2
⇒ S2 = 4

41) P(x) = ax7 + bx3 +cx – 5

P(–7) = 7
a(–7)7 + b(–7)3 + c(–7) – 5 = 7
a.77 + b.73 + c.7 = –12
P(7) = a.77 + b.73 + c.7 – 5
= –12 – 5 = –17

42) A ⊂ B and A ≠ B

A is called proper subset of B

B is called superset of A
A = {1, 2, 3}
B = {1, 2, 3, 4}
ACB ⇒ A is called proper subset of B
If set A has only are element, then we call it a singleton set.
Option A, B, D are correct

43) (A)
 ⇒ a = 1, b = 8, c = –1
∴a+b+c=8

(B)

x = –4

(C) (a + b)

{∵ a, b > 0}
Min value = 4
(D) Let A = and
Assume A > B
Squaring

which contradicts our assumption

Hence A < B

44)

p q Total elements in A

1 {1, 2, 3, 4, 5, 6} 6

2 {1, 3, 5} 3

3 {1, 2, 4, 5} 4

4 {1, 3, 5} 3

5 {1, 2, 3, 4, 6} 5

6 {1, 5} 2
∴ Cardinality of set A = 6 + 3 + 4 + 3 + 5 + 2 = 23
∴ n(A) = 23
number of subset of set A = 2n(A) = 223
P(A) is a set of subsets of A
∴ n(P(A)) = 223

Clearly, B =
∴ n(B) = 6

45)
Pmax = 12 ,

Pmin = 1

46) 5M = M5 ∴ M4 = 5
Hence M12, M20 are rational

47) (A)
⇒ 34 < 43
⇒ 81 < 64 (False)

48) Let other factor be x2 + bx + c

∴ (x2 + 3x + 7) (x2 + bx + c) = x4 + px2 + q
⇒ x4 + x3(b + 3) + x2(c + 7 + 3b) + x(3c + 7b) + 7c = x4 + px2 + q
∵ coefficient of x3 = 0 ⇒ b = –3
coefficient of x = 0 ⇒ 3c + 7b = 0 ⇒ c = 7
∴ p = coefficient of x2 = c + 7 + 3b
=7+7–9=5
q = product of roots = 7c = 49

49) n (E ∩ G) = 12 n (G) = 22
n (E ∪ G) = 40 n (E) = ?
n (E ∪ G) = n(E) + n(G) – n (E ∩ G)
40 = n(E) + 22 – 12
n(E) = 30

= 30 – 12 = 18

50) 2x2 – 5x + 2 = 0

x2 – 5x + 5 = 1
⇒ x = 1, 4
or x2 – 5x + 5 = –1
x = 2, 3 (Rejected)
As at x = 3,
2(3)2 – 5(3) + 2 = 5
(–1)5 ≠ 1

Sum of solutions = 7 + = 7.50

51)

52) Let P(x) = 6 + x, for x = 0, 1, 2, 3

Let f(x) = P(x) – x – 6
⇒ f(x) is also a polynomial of degree4.
⇒ f (x) = x(x – 1)(x – 2)(x – 3)
As f(x) vanishes at x = 0, 1, 2, 3, so
f(x) = P(x) – x – 6 ≡ (x – 0)(x – 1)(x – 2)(x – 3)
⇒ P(x) = x + 6 + x(x – 1)(x – 2)(x – 3)
Hence P(4) = 10 + (4 · 3 · 2 · 1) = 10 + 24 = 34

53) (2x)3 + (–3y)3 + (1)3 = 3(2x)(–3y)(1)

⇒ 2x – 3y + 1 = 0

54)
AC = 65
Now, ΔABC ~ ΔOPC

⇒ ⇒