Thermodynamics Practice Questions Set 2
Thermodynamics Practice Questions Set 2
To calculate the work done during the polytropic expansion of steam in a piston-cylinder setup, use the equation for polytropic processes: W = (P1V1 - P2V2)/(n-1), where P1 and V1 are initial pressure and volume, P2 and V2 are final pressure and volume, and n is the polytropic index. In the problem, the polytropic index can be determined from temperature and pressure data and involves using the ideal gas law and specific volume correlations.
For a gas showing zero change in enthalpy during expansion (isothermal and reversible), this implies that the internal energy change is offset by work done, satisfying the condition ΔH = Q - W = 0. The process must occur at constant temperature with equal magnitudes of heat transfer into the system and work done by the system (Q=W). This can be seen in isothermal processes where ideal gas laws and parameters indicate no change in specific enthalpy.
For adiabatic processes, the work done by an ideal gas can be calculated using the formula W = (Cv*(T1-T2)), where T1 and T2 are the initial and final temperatures, and Cv is the specific heat at constant volume. The adiabatic relationship PV^γ=constant, where γ is the heat capacity ratio, also enables determining one state variable if others change according to the ideal gas law.
To verify if a device violates the first law of thermodynamics, apply the energy conservation principle: ΔU = Q - W, where ΔU is change in internal energy, Q is heat added, and W is work done by the system. Given the device data such as heat intake, heat rejection, and work output, check if the net energy change aligns with the sum of energy inputs and outputs, confirming conservation or excess indicative of a principle violation.
The heat transfer, Q, during a reversible and isothermal expansion of a perfect gas is equal to the work done, W, due to the first law of thermodynamics stating that for isothermal processes, change in internal energy is zero. Calculation involves Q = W = nRT ln(V2/V1), using the relationship from work done in isothermal expansion and expressions involving initial and final volumes and temperatures derived from ideal gas law.
To calculate the polytropic index (n) for steam expanding reversibly between known temperature and pressure, use the relation PV^n=constant from initial to final states. You need to equate the product of pressure and volume raised to the power n at both states and solve for n, using ideal gas relationships or steam tables to calculate or correlate volumes.
When heat added to a system leads to a decrease in internal energy, the energy transferred as work is the sum of the amounts of heat added and the decrease in internal energy. Using the first law of thermodynamics, W = Q - ΔU, calculate W with the provided values for heat added (Q) and the change in internal energy (ΔU) to find the work output, ensuring sign adherence depending on convention for energy direction.
In a reversible and isothermal compression, the change in internal energy (ΔU) is zero for an ideal gas because temperature remains constant. Change in entropy (ΔS) is calculated using ΔS = nR ln(V2/V1), where V1 and V2 are the initial and final volumes, R is the specific gas constant, and n is the amount of substance.
To determine the final temperature of steam after cooling in a closed vessel, start with the initial state data: pressure, temperature, and volume. Use steam tables or equations of state to find the specific enthalpy or entropy. Since the volume is constant, apply the steam properties at the initial and final pressures to solve for the final temperature ensuring consistency with energy balance considerations.
To calculate specific heat capacities Cp and Cv after adiabatic expansion, use the adiabatic relationship between initial and final temperatures and volumes, along with the definition of specific heat. Knowing the work done (W), the formula is W = Cv (T1 - T2). Use the definition Cp = Cv + R and ideal gas relations, substituting calculated Cv to find Cp, ensuring calculations fit the provided state changes and variables.