Tutorial : 2
Questions:
1. Consider the following chemical reactions below. Balance the chemical equations and
classify them according to the type of reaction they represent.
a) Na + I2 → NaI
b) KClO3 → KCl + O2
c) C3H8 + O2 → CO2 + H2O
d) Mg(NO3)2 + K3PO4 → Mg3(PO4)2 + KNO3
e) Al + H2SO4 → Al2(SO4)3 + H2
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2. Silver becomes tarnished in houses because of the presence of small amounts of hydrogen
sulphide. The reaction that takes place is the following:
4Ag(s) + 2H2S(g) + O2(g) → 2Ag2S(s) + 2H2O(l)
If 18.5 g of Ag is in contact with 4.55 g of H2S, determine the mass of Ag2S formed.
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3. Let’s consider the following reaction:
Na2CO3(aq) + HNO3(aq) → NaNO3(s) + H2O(l)
For this reaction, the rate of disappearance of Na2CO3 is 3.86 x10-3 M/s. This means the
rate for other species are: 4
4. Write equilibrium constant expressions for the following reactions. For gases, use both
pressures and concentrations.
(a) Fe (s) + 5 CO (g) ⇌ Fe(CO)5 (g)
(b) (NH4)2CO3 (s) ⇌ 2 NH3 (g) + CO2 (g) + H2O (g)
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5. At 250C, an equilibrium mixture contains 0,096 [Link]–3 CO, 0,191 [Link]–3 H2, and
0,015 [Link]–3 CH3OH.
(a) What is the value of Kc at 250C for the following reaction?
CO (g) + 2 H2 (g) ⇌ CH3OH (g)
(b) What is the value of Kc for the following reaction?
CH3OH (g) ⇌ CO (g) + H2 (g)
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6. Dinitrogen trioxide decomposes to NO and NO2 in an endothermic process (H = +
40,5 kJ/mol).
N2O3 (g) ⇄ NO (g) + NO2 (g)
Predict the effect of the following changes on the position of the equilibrium; that is,
state which way the equilibrium will shift (left, right, or no change) when each of the
following changes is made. Motivate each prediction fully.
(a) Adding more N2O3 (g)
(b) Adding more NO2 (g)
(c) Decreasing the temperature
(d) Increasing the container volume
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[30 marks]