OXYGEN CONTAINING

COMPOUND
1. The major products formed when the following ether is heated with conc. HI are :-
CH3CH2CH2–O–C(CH3)2CH2CH3
(1) CH3CH2CH2I + HO–C(CH3)2CH2CH3 (2) CH3CH2CH2OH + I–C(CH3)2CH2CH3
(3) CH3CH2CH2I + I–C(CH3)2CH2CH3 (4) CH3CH2CH2OH + (CH3)2C=CHCH3
fuEu bZFkj dks lkaæ HI ds lkFk xeZ djus ij eq[; mRikn cusxk \
(1) CH3CH2CH2I + HO–C(CH3)2CH2CH3 (2) CH3CH2CH2OH + I–C(CH3)2CH2CH3
(3) CH3CH2CH2I + I–C(CH3)2CH2CH3 (4) CH3CH2CH2OH + (CH3)2C=CHCH3
2. Correct column match :-

N
Name of reaction Reagent
Reimer-Tiemann
(1) (P) CO2+NaOH
reaction
(2) Kolbe-schmitt reaction (Q) CHCl3 + KOH

(3)
E
Hoffmann Bromamide
reaction
(4) Lucas reagent
(R) Anhydrous ZnCl2 + Conc. HCl

(S) NaOH + Br2

LL
(1) 1→Q, 2→P, 3→S, 4→R (2) 1→P, 2→Q, 3→S, 4→R
(3) 1→Q, 2→P, 3→R, 4→S (4) 1→P, 2→Q, 3→R, 4→S
fuEu LrEHkksa dk feyku fdft,

(1) jhej&Vheku vfHkfØ;k (P) CO2+NaOH

(2) dksYcs&f'eV vfHkfØ;k (Q) CHCl3 + KOH
(3) gkWQeku czke
s sekbM vfHkfØ;k (R) Anhydrous ZnCl2 + Conc. HCl
A

(4) Y;qdkl vfHkdeZd (S) NaOH + Br2

(1) 1→Q, 2→P, 3→S, 4→R
(2) 1→P, 2→Q, 3→S, 4→R
(3) 1→Q, 2→P, 3→R, 4→S
(4) 1→P, 2→Q, 3→R, 4→S
3. The compound which reacts fastest with Lucas reagent at room temperature is :-
(1) butan-1-ol (2) butan-2-ol
(3) 2-methyl propan-1-ol (4) 2-methyl propan-2-ol
dejs ds rki ij Y;qdkl vfHkdeZd ls rhoz vfHkfØ;k djus okyk ;kSfxd gS :-
(1) C;qVsu-1-vkWy (2) C;qVsu-2-vkWy
(3) 2-esfFky çksisu-1-vkWy (4) 2-esfFky çksisu-2-vkWy
1
 OH

4. 
SOCl2
 P 
KCN
 Q 
H3O
 R, R is (gS) :-
CHO COOH NH2
COOH
(1) (2) (3) (4)
CH3
CH3–CH OH
O
5. O2 H
(A) +
H2O

A is (gS):-
CH3 CH3 CH2OH OH
CH3–C–O–O–H H3C–C–OH CH –C–H
(1) (2) (3) 3 (4)

6. Which of the following will not give racemic mixture with HCN?

N
(1) CH3CHO (2) PhCHO (3) PhCOCH3 (4) PhCOPh
fuEu esa ls dkSu HCN ds lkFk jslsfed feJ.k ugh nsrk gS\
(1) CH3CHO (2) PhCHO (3) PhCOCH3 (4) PhCOPh
O

7. H2N–NH2
E H
The above reaction completes with the mechanism :-
(1) Nucleoplilic substitution followed by elimination mechanism
(2) Electrophilic addition followed by elimination mechanism
(3) Electrophilic substitution followed by elimination mechanism
LL
(4) Nucleophilic addition followed by elimination mechanism
mijksä vfHkfØ;k dkSulh fØ;kfof/k ds lkFk [Link] gksrh gS :-
(1) ukfHkdLusgh çfrLFkkiu rn~mijkUr foyksiu fØ;kfof/k
(2) bysDVªkWuLusgh ;kSxkRed rn~mijkUr foyksiu fØ;kfof/k
(3) bysDVªkWuLusgh çfrLFkkiu rn~mijkUr foyksiu fØ;kfof/k
(4) ukfHkdLusgh ;ksxkRed rn~mijkUr foyksiu fØ;kfof/k
8. When acetone reacts with Grignard reagent followed by hydrolysis, it gives :-
(1) 1°- alcohol (2) 2°- alcohol (3) 3° - alcohol (4) Methyl alcohol
A

tc ,flVksu dh vfHkfØ;k fxzU;kj vfHkdeZd ls djk dj ,oa ty vi?kVu ij çkIr mRikn gksxk :-
(1) 1°- ,YdksgkWy (2) 2°- ,YdksgkWy (3) 3° - ,YdksgkWy (4) esfFky ,YdksgkWy
9. A mixture of benzaldehyde and formaldehyde on heating with NaOH solution gives :-
(1) Ph –CH2OH and HCOONa (2) PhCOONa and CH3OH
(3) PhCOONa and HCOONa (4) PhCH2OH and CH3OH
csUtsfYMgkbM rFkk QkWesZfYMgkbM ds feJ.k dks NaOH foy;u ds lkFk xeZ djus ij curk gS :-
(1) Ph –CH2OH rFkk HCOONa (2) PhCOONa rFkk CH3OH
(3) PhCOONa rFkk HCOONa (4) PhCH2OH rFkk CH3OH
10. Aldol condensation between acetaldehyde and propionaldehyde will give how many products [Structural] :-
(1) 2 (2) 3 (3) 4 (4) 1
,flVSfYMgkbM rFkk çksfivksu,fYMgkbM ds e/; ,YMkWy la?kuu ls fdrus mRikn cusxs ¼lajpukRed½ :-
(1) 2 (2) 3 (3) 4 (4) 1
2
11. Match List-I with List-II :-
List-I
List-II
(Reaction of carbonyl
(Product formed)
compound with)
(a) HCN (i) Ketal/Acetal
(b) Alcohol (ii) Hydrazone
(c) R-NH2 (iii) Cyanohydrin
(d) NH2-NH2 (iv) Schiff's base
(1) (a)-(iii), (b)-(i), (c)-(iv), (d)-(ii) (2) (a)-(ii), (b)-(iii), (c)-(i), (d)-(iv)
(3) (a)-(iii), (b)-(iv), (c)-(ii), (d)-(i) (4) (a)-(i), (b)-(iii), (c)-(iv), (d)-(ii)
lwph-I dks lwph-II ds lkFk feykbZ;s :-
-I
-II

N
(a) HCN (i) dhVsy@,flVy
(b) ,sYdksgkWy (ii) gkbMªktksu
(c) R-NH2 (iii) lk;uksgkbfMªu

(d) NH2-NH2 E (iv) f'kQ {kkjd

(1) (a)-(iii), (b)-(i), (c)-(iv), (d)-(ii) (2) (a)-(ii), (b)-(iii), (c)-(i), (d)-(iv)
(3) (a)-(iii), (b)-(iv), (c)-(ii), (d)-(i) (4) (a)-(i), (b)-(iii), (c)-(iv), (d)-(ii)
O
LL
C–Cl H2
12. Product :-
Pd-BaSO4
OH
COOH CHO CH2OH
(1) (2) (3) (4)

O
C–Cl H2
A

Pd-BaSO4
mRikn :-

OH
COOH CHO CH2OH
(1) (2) (3) (4)

13. Which of the following reaction can not be used to prepare benzaldehyde ?
CH3
(i) CrO2Cl2 CO + HCl
(1) (2)
(ii) H2O/H AlCl3
MgBr
(i) HCHO HCN+HCl+AlCl3
(3) (4)
(ii) H2O H3O+
3
 fuEu esa ls dkSulh vfHkfØ;k dk mi;ksx csUtsfYMgkbM+ cukus esa ugh gksrk \
CH3
(i) CrO2Cl2 CO + HCl
(1) (2)
(ii) H2O/H AlCl3
MgBr
(i) HCHO HCN+HCl+AlCl3
(3) (4)
(ii) H2O H3O+
14. The product (D) of the following reaction is :-


CH3Cl 
KCN
 A 
H3O

 B 
NH3
 C   D
(1) CH3CH2NH2 (2) CH3CN (3) CH3CH2CONH2 (4) CH3CONH2
fuEu vfHkfØ;k esa ;kSfxd (D) gS :-
(1) CH3CH2NH2 (2) CH3CN (3) CH3CH2CONH2 (4) CH3CONH2
MgBr
(i) CO2
15. P, in the reaction product 'P' is :-
(ii) H3O
MgBr

N
(i) CO2 P, nh xbZ vfHkfØ;k esa mRikn 'P' gS :-
(ii) H3O
O
CHO COOH OH C

16.
(1)

O
E
CH3–C–OH+H–OC2H5
18
(2)

Conc.(lkanz-)H2SO4
con
(3)

Product (mRikn) :-
(4)
LL
O O
18 18
(1) CH3–C–OC2H5+H2O (2) CH3–C–OC2H5+H2O
O O
18 18
(3) CH3–C–OC2H5+H2O (4) CH3–C–OC2H5+H2O
17. Reactivity order of acid derivatives is - (towards SN reaction) :-
(1) Acid chloride > Anhydride > Ester > Amide
(2) Acid chloride > Ester > Anhydride > Amide
(3) Anhydride > Acid chloride > Ester > Amide
A

(4) Acid chloride > Amide > Ester > Anhydride

vEy O;qRiUuksa dh fØ;k'khyrk Øe gS & ¼ukfHkd Lusgh vfHkfØ;k ds çfr½ :-
(1) ,flM DyksjkbM > ,ugkbMªkbM > bZLVj > ,ekbM
(2) ,flM DyksjkbM > bZLVj > ,ugkbMªkbM > ,ekbZM
(3) ,ugkbZMªkbM > ,flM DyksjkbM > bZLVj > ,ekbM
(4) ,flM DyksjkbZM > ,ekbZM > bZLVj > ,ugkbZMªkbM

4
18. An organic compound with the molecular formula C3H6O does not respond positively to the silver mirror test
with Tollens reagent but produces an oxime. The compound is :-
(1) CH2= CHCH2OH (2) CH3CH2CHO (3) CH2= CHOCH3 (4) CH3COCH3
,d dkcZfud ;kSfxd ftldk [Link]= C3H6O gS] jtr niZ.k ifj{k.k ds çfr /kukRed ugh gS ijarq vkWfDle dk fuekZ.k
djrk gSA ;kSfxd gksxk :-
(1) CH2= CHCH2OH (2) CH3CH2CHO (3) CH2= CHOCH3 (4) CH3COCH3
19. CH3–CHO & CH3–CH2–CHO can be differentiated by :-
(1) Tollen's Reagent (2) Fehling solution (3) 2,4 - DNP Test (4) Iodoform Test
CH3–CHO & CH3–CH2–CHO foHksfnr fd, tk ldrs gS :-
(1) VkWyus vfedeZd (2) Qsfyax foy;u (3) 2,4 – DNP ijh{k.k (4) vk;MksQkeZ ijh{k.k
20. Which of the following compounds give the positive bicarbonate test?
(1) Acetic acid (2) Phenol (3) Ethanol (4) Dimethyl ether
fuEu esa ls dkSulk ;kSfxd /kukRed ckbdkcksZusV ijh{k.k nsrk gS :-
(1) ,lhfVd vEy (2) QhukWy (3) ,sFksukWy (4) MkbZ,fFky bZFkj

N
ANSWER KEY : (OXYGEN CONTAINING COMPOUND)
Que. 1 E 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Ans. 2 1 4 3 1 4 4 3 1 3 1 2 3 4 2 2 1 4 4 1
LL
A