SOLUTIONS
1. 4.1 gm H3PO3 is dissolved to form one litre of an aqueous solution. Its normality is :-
4.1 gm H3PO3 dks 1 yhVj foy;u esa ?kksyk tkrk gS] bldh ukWeZyrk gksrh gS :-
(1) 0.05 N (2) 0.1 N (3) 0.5 N (4) 5 N
2. 1L, 10–2 M H2SO4 solution is diluted to produce 10–4 M H2SO4 solution. How much amount of water was added
into the solution ?
1L, 10–2 M H2SO4 dk ruqdj.k djus ij 10–4 M H2SO4 foy;u feyrk gS] rks foy;u esa tksMs x;s ty dh ek=k
D;k gksxh ?
N
(1) 9L (2) 999L (3) 99L (4) 100L
3. In two molal solution that contains 1 mole of solute, there is :-
(1) 500 mL of solution (2) 100 mL of solution
(3) 500 g of solvent (4) 1000 g of solvent
2 eksyy foy;u ftlesa 1 eksy foys; ?kqyu'khy gS] mlesa :-
E
(1) 500 mL foy;u gksrk gS (2) 100 mL foy;u gksrk gS
(3) 500 g foyk;d gksrk gS (4) 1000 g foyk;d gksrk gS
4. An H2O2 solution is labelled as 5V. Which is correct for the solution?
LL
(1) 5L O2(g) is produced by 1L H2O2 at 10°C, 1 atm
(2) 1L O2(g) is produced by 5L H2O2 at STP
(3) 10L O2(g) is produced by 5L H2O2 at STP
(4) 10L O2(g) is produced by 2L H2O2 solution at STP
fdlh H2O2 foy;u ij 5V ukekafdr fd;k x;k gSA bl foy;u ds fy, D;k lgh gS ?
(1) 5L O2¼g½ çkIr gksrh gS 10°C rFkk 1 atm ij 1L H2O2 foy;u ls
(2) 1L O2(g) çkIr gksrh gS STP ij 5L H2O2 ls
(3) 10L O2(g) çkIr gksrh gS STP ij 5L H2O2 ls
A
(4) 10L O2(g) çkIr gksrh gS STP ij 2L H2O2 ls
5. If the total vapour pressure of the ideal liquid mixture A and B is given by the equation: P = 180XA + 90 mm
Hg. The ratio of the vapour pressure of the pure liquids A and B is given by :-
A rFkk B ds vkn'kZ æo feJ.k dk dqy ok"i nkc P = 180XA + 90 mm Hg lehdj.k ds }kjk fn;k tkrk gSA æo A
rFkk B dk 'kq) voLFkk esa ok"inkc dk vuqikr gS %&
(1) 3 : 2 (2) 4 : 1 (3) 3 : 1 (4) 6 : 2
6. Lowering of vapour pressure due to solute in 1 molal aqueous solution at 100°C is (in mm of Hg) :-
,d foys; ds 1 eksyy tyh; foy;u dk 100°C rki ij ok"inkc esa voueu gS (mm Hg ds in es)a :-
(1) 13.44 (2) 14.12 (3) 35.20 (4) 1.76 × 10–2
1
7. Which condition(s) is/are true for both ideal and non ideal solutions ?
fuEu esa ls dkSulh fLFkfr@fLFkfr;k¡ vkn'kZ rFkk vukn'kZ foy;u nksuks ds fy, lgh gS ?
(1) ΔHmixing = 0 (2) ΔSmixing > 0 (3) ΔGmixing < 0 (4) Both 2 & 3
8. An azeotropic solution of two liquids has a boiling point lower than both of them, then it :-
(1) Shows a negative deviation from Raoult's law
(2) Shows no deviation from Raoult's law
(3) Shows a positive deviation from Raoult's law
(4) Is saturated
nks æoksa ls cus fLFkj&DoFkukadh foy;u dk DoFkukad nksuksa æoksa ds DoFkukadksa ls de gS] rc ;g foy;u :-
(1) jkmYV fu;e ls _.kkRed fopyu n'kkZrk gSA
(2) jkmYV fu;e ls fopyu ugh n'kkZrk gSA
(3) jkmYV fu;e ls /kukRed fopyu n'kkZrk gSA
(4) lar`Ir gksrk gSA
9. Which of the following mixtures do not form an ideal solution ?
(1) C2H5Br and C2H5I (2) C6H5Cl and C6H5Br (3) C6H6 and C6H5CH3 (4) H2O and C2H5OH
N
fuEu esa ls dkSulk feJ.k ,d vkn'kZ foy;u ugh cukrk gS\
(1) C2H5Br rFkk C2H5I (2) C6H5Cl rFkk C6H5Br (3) C6H6 rFkk C6H5CH3 (4) H2O rFkk C2H5OH
10. Which of the following gases is not filled in tanks of scuba divers ?
(1) Hydrogen
E (2) Oxygen (3) Helium (4) Nitrogen
xgjs leqæ esa tkus okys xksrk[kksjksa }kjk mi;ksx fd;s tkus okys VSadksa esa fuEu esa ls dkSulh xSl ugh Hkjh gksrh gS \
(1) gkbMªkstu (2) vkWDlhtu (3) ghfy;e (4) ukbVªkstu
11. Read the following statements and choose the correct option.
LL
(i) Different gases have different KH values at the same temperature.
(ii) Higher the value of KH at a given temperature, lower is the solubility of the gas in the liquid.
(iii) KH is a function of the nature of the gas.
(iv) Solubility of gases in water increases with increase of temperature.
(1) (i), (ii) and (iv) are correct (2) (ii) and (iv) are correct
(3) (i), (ii) and (iii) are correct (4) (i) and (iv) are correct
fuEu dFkuks dks if<;s rFkk lgh fodYi p;u dhft;s
(i) vyx vyx xSlks ds fy, leku rkieku ij KH ds eku vyx vyx gksrs gS
(ii) fn;s x;s rkieku ij KH dk eku vf/kd gksus ij xSl dh æo esa foys;rk de gksxh
A
(iii) KH, xSl dh ç—fr dk Qyu gksrk gS
(iv) rkieku c<kus ij xSlks dh foys;rk ty esa c<+rh gS :-
(1) (i), (ii) rFkk (iv) lgh gS (2) (ii) rFkk (iv) lgh gS
(3) (i), (ii) rFkk (iii) lgh gS (4) (i) rFkk (iv) lgh gS
12. An aqueous solution of a non-volatile solute boils at 100.17°C. At what temperature will the solution freeze ?
(Given : Kb = 0.51 and Kf = 1.86 °C kgmol–1) :-
,d vok"i'khy foys; dk tyh; foy;u 100.17°C rki ij mcyrk gSA fdl rkieku ij ;g foy;u te tk;sxk \
(fn;k x;k gS Kb = 0.51 rFkk Kf = 1.86 °C kgmol–1)
(1) 0.31°C (2) –0.31°C (3) 0.62°C (4) –0.62°C
2
13. Van’t Hoff factor of aqueous solutions of X, Y and Z are 2.8, 1.8 and 3.5 respectively.
Which of the following statements is/are correct ?
(a) BP : X < Y < Z
(b) FP : Z < X < Y
(c) Osmotic pressure : X = Y = Z
(d) VP : Y < X < Z
(1) only b (2) b, d (3) a, c, d (4) b, c
X, Y o Z foy;uksa ds okW.V gkWQ [Link] dk eku Øe'k% 2.8, 1.8 o 3.5 fn;k gSA
buesa ls dkSulk@dkSuls dFku lgh gS@gSa ?
(a) DoFkukad : X < Y < Z
(b) fgekad : Z < X < Y
(c) ijklj.k nkc : X = Y = Z
(d) ok"i nkc : Y < X < Z
(1) dsoy b (2) b, d (3) a, c, d (4) b, c
14. 0.1 molal aqueous solution of an electrolyte AB3 is 90% ionised. The boiling point of solution at 1 atm is :-
,d 0.1 eksyy tyh; foy;u esa AB3 oS|qrvi?kV~; dk 90% vk;uu gksrk gSA 1 ok;[Link]; nkc ij foy;u dk
N
DoFkukad gSA
(1) 273.19 K (2) 374.92 K (3) 376.4 K (4) 373.19 K
15. The concentration of solutions A, B, C and D are respectively 0.1M glucose, 0.05 M KCl, 0.05M MgCl2, 0.1 M
AlCl3. Which pair amongst these solutions is isotonic ?
(1) A and B
E (2) B and C (3) A and D (4) A and C
foy;u A, B, C rFkk D dh lkUærk Øe'k% gS] 0.1M Xywdksl] 0.05M KCl, 0.05M MgCl2 rFkk 0.1 M AlCl3
buesa ls dkSulk ;qXe leijkljh gS \
(1) A rFkk B (2) B rFkk C (3) A rFkk D (4) A rFkk C
LL
16. Abnormal molar mass of CH3COOH in benzene solvent is found to be 90 g/mol, then percentage association of
CH3COOH in benzene is :-
CH3COOH dk csathu foyk;d esa vlkekU; eksyj æO;eku 90 g/mol ik;k x;k gS] rks CH3COOH dk csUthu esa
çfr'kr [Link] gqvk gS-
(1) 33.3% (2) 66.6% (3) 50% (4) 90%
17. Assertion : The depression in freezing point depends on the amount of the solute and nature of solvent.
Reason : For aqueous solutions of different electrolytes, molal depression constant will have different value.
(1) If both assertion and reason are true and reason is the correct explanation of assertion.
(2) If both assertion and reason are true but reason is not the correct explanation of assertion.
A
(3) If Assertion is true but reason is false.
(4) If both assertion and reason are false.
dFku : fgekad esa voueu] foys; dh ek=k rFkk foyk;d dh ç—fr ij fuHkZj djrk gSA
dkj.k : fofHkUu oS|qr vi?kVî ds tyh; foy;u ds fy, eksyy voueu fu;rkad ds eku fHkUu gksrs gSA
(1) ;fn dFku rFkk dkj.k nksuksa lgh gSa rFkk dkj.k dFku dh lgh O;k[;k djrk gSA
(2) ;fn dFku rFkk dkj.k nksuks lgh gSa ysfdu dkj.k dFku dh lgh O;k[;k ugh djrk gSA
(3) ;fn dFku lgh gS rFkk dkj.k xyr gSa
(4) ;fn dFku rFkk dkj.k nksuksa xyr gSaA
18. The osmotic pressure of a 0.1 N solution of BaCl2 at 27°C showing 80% dissociation, is :-
27°C rki ij BaCl2 ds 0.1 N foy;u esa blds 80% fo;kstu fn[kykuss ij ijklj.k nkc gksrk gSA
(1) 3.2 atm (2) 1.6 atm (3) 0.8 atm (4) 6.4 atm
3
19. The vapour pressure of a solvent decreased by 10 mm Hg when a non-volatile solute was added to the solvent.
The mole fraction of solute in solution is 0.2. What would be the mole fraction of the solvent if decrease in
vapour pressure is 20 mm of Hg ?
,d foyk;d esa vok"i'khy foys; feykus ij mldk ok’i nkc 10 mm Hg ls ?kV tkrk gSA foys; dk foy;u esa eksy
çHkkt 0.2 gSA foyk;d dk eksy çHkkt D;k gksxk ;fn ok"i nkc esa fxjkoV 20 mm Hg gks tk;s?
(1) 0.8 (2) 0.6 (3) 0.4 (4) 0.2
20. If liquid components R and S form an ideal solution at 27°C, then for point P (0.1,0) vapour pressure of this
solution is (in mm of Hg) :-
27°C rki ij nzo ?kVd R o S ,d vkn'kZ foy;u cukrs gS] rks fcUnq P (0.1,0) ds laxr bl foy;u dk ok"inkc gksrk
gS:- (mm Hg es)a
P(mm of Hg)
P(mm of Hg)
70
20
N
0 P 1
XR
(1) 90 E (2) 88 (3) 120 (4) 25
ANSWER KEY : (SOLUTIONS)
Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
LL
Ans. 2 3 3 4 3 1 4 3 4 1 3 4 1 4 1 2 3 1 2 4
A