Eston
EA a d catalyzed
EA
strong and
major
Cresonance)
At least 2 steps
Step 1 : HO transfer (open shell forms) NMR
Rds (step that goes
through highest t .
5) detects symmetry
&
Step 2 Complexation :
less
symmetry , more
signals
2-sided
<
attacks identical C and As
groups
·
C stability indistinguishable/equivalent
If a
signal is shared ,
they a re
enhanced by substitution
#I signalX
byhas/pealsCust
He boa
1: 2 :2: 2 : 3
3 0 2010
an
,
open shell
#11.
#che-
resonance can
partially close a shell
more stable CE , faster reaction and selective
more
Naming
·
EA
strong acid var latiers systematic / step-by-step
straight and (H -x) 1. define main
chain-longest continuous a chain
And otalyst
catalyzed if
·
ring , include
Cyclo-
variations in a bonds · Carbons ? 1 : meth 2 : eth 3 : prop U : but S :
pent 6 : nex L : hept 8 : Oct
Identical Ls .
9 non 18 : dec
differentI s but 20
equally stable
ending -
no l bonds : a re I Abond : ene 2A bonds :
gue
·
different Cs and different 28 stability ad distil , tetra etc if there are more
,
groups
- ol
Example ending
-
2 substituents
.
identify n am e and
group
Anything not an H
"Chloro"
X - C
halogen
>
-
mechanism
Che
· R carbon
CHa-Cec-CH3 -
regeneratne
groups "yl" ending
T
>
-
and neutralize
· Carbons +
(meth , eth . )
product y1 ...
etc
CH3--H andCyl
s
·
sopropyl phenyl
Lett .
3 location
number m a i n chain
variationsI n M bonds
"endings" get lowest possible
give lowest at first point of difference
ONE Cresonance)
·
4) final construction
alphabetically list substituents
ScumRSignaa .
3
3-dibromocyclopent-1-ene
signals
1.*
·
Real and
#
Ch High Duch
it
chiral
diff attatched
C with U .
things
higher priority higher atomic
=
↑ R
⑭
③
S
can be R
(right) or Scleft)
view with 4th behind
priority
right if 1 , 2 , 3
go
clockwise , otherwise , S
·
0
S-methyl-hept
6
yn 3 -
-
- -