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Organic Chemistry Reaction Mechanisms

The document discusses the steps involved in a chemical reaction, particularly focusing on HO transfer and complexation, highlighting the significance of symmetry and stability in the process. It also outlines systematic naming conventions for organic compounds, including the identification of main chains and substituents. Additionally, it touches on chirality and the importance of priority in determining the configuration of chiral centers.

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0% found this document useful (0 votes)
22 views3 pages

Organic Chemistry Reaction Mechanisms

The document discusses the steps involved in a chemical reaction, particularly focusing on HO transfer and complexation, highlighting the significance of symmetry and stability in the process. It also outlines systematic naming conventions for organic compounds, including the identification of main chains and substituents. Additionally, it touches on chirality and the importance of priority in determining the configuration of chiral centers.

Uploaded by

piperssza
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Eston

EA a d catalyzed

EA
strong and
major
Cresonance)
At least 2 steps

Step 1 : HO transfer (open shell forms) NMR

Rds (step that goes


through highest t .
5) detects symmetry
&

Step 2 Complexation :
less
symmetry , more
signals

2-sided
<

attacks identical C and As


groups
·

C stability indistinguishable/equivalent
If a
signal is shared ,
they a re

enhanced by substitution

#I signalX
byhas/pealsCust
He boa
1: 2 :2: 2 : 3
3 0 2010

an
,
open shell
#11.

#che-
resonance can
partially close a shell

more stable CE , faster reaction and selective


more
Naming
·

EA
strong acid var latiers systematic / step-by-step

straight and (H -x) 1. define main


chain-longest continuous a chain

And otalyst
catalyzed if
·

ring , include
Cyclo-

variations in a bonds · Carbons ? 1 : meth 2 : eth 3 : prop U : but S :


pent 6 : nex L : hept 8 : Oct

Identical Ls .
9 non 18 : dec

differentI s but 20
equally stable
ending -
no l bonds : a re I Abond : ene 2A bonds :
gue
·

different Cs and different 28 stability ad distil , tetra etc if there are more
,
groups
- ol
Example ending

-
2 substituents
.

identify n am e and
group

Anything not an H

"Chloro"
X - C
halogen
>
-

mechanism

Che
· R carbon
CHa-Cec-CH3 -
regeneratne
groups "yl" ending
T
>
-

and neutralize
· Carbons +
(meth , eth . )
product y1 ...
etc

CH3--H andCyl
s
·
sopropyl phenyl
Lett .
3 location

number m a i n chain

variationsI n M bonds
"endings" get lowest possible

give lowest at first point of difference

ONE Cresonance)
·
4) final construction

alphabetically list substituents


ScumRSignaa .
3
3-dibromocyclopent-1-ene
signals

1.*
·
Real and

#
Ch High Duch
it

chiral

diff attatched
C with U .

things

higher priority higher atomic


=

↑ R


S
can be R
(right) or Scleft)

view with 4th behind


priority

right if 1 , 2 , 3
go
clockwise , otherwise , S

·
0
S-methyl-hept
6
yn 3 -
-
- -

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