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Molar Relationships in Chemistry and Physics

The document contains a series of physics, chemistry, and mathematics questions divided into two sections each. Each question presents multiple-choice answers related to various concepts in these subjects. The document also includes answer keys for the questions in the physics and chemistry sections.

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0% found this document useful (0 votes)
15 views24 pages

Molar Relationships in Chemistry and Physics

The document contains a series of physics, chemistry, and mathematics questions divided into two sections each. Each question presents multiple-choice answers related to various concepts in these subjects. The document also includes answer keys for the questions in the physics and chemistry sections.

Uploaded by

namankansal535
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

27-04-2025

2001CJA101001250001 JA

PHYSICS

SECTION-I

1) If and are unit vectors along X, Y & Z axis respectively, then tick the wrong statement:

(A)
(B)
(C)
(D)

2) Given : and . The unit vector in the direction of is :

(A)

(B)

(C)

(D)

3) The resultant of two forces 10N and 15N can never be

(A) 5 N
(B) 25 N
(C) 150 N
(D) 12.5 N

4) In the figure what is the angle between and ? (Given : )


(A) 30°
(B) 60°
(C) 120°
(D) 150°

5) Given and . Which of the following statements is INCORRECT ?

(A)

(B)

(C)

(D)

6) Which of the following is correct for ?

(A)

(B)

(C)
(D)

7) The vector joining the points A (1, 1, –1) and B (2, –3, 4) and pointing from A to B is

(A)
(B)
(C)
(D)

8) The angle between two vectors and is :–

(A) 0°
(B) 45°
(C) 60°
(D) 90°

9) Given that is a unit vector. What is the value of a ?

(A)
(B)
(C)
(D)

10) If and find value of α so that is perpendicular to the :

(A)

(B)

(C)

(D)

11) In the given diagram and is perpendicular to . Find value of


(A) 2

(B)

(C)

(D)

12) What displacement must be added to the displacement m to produce net displacement
of 6 m pointing in the negative x–direction?

(A)
(B)
(C)
(D)

13) The magnitude of the resultant of two equal vectors is equal to the magnitude of either vector.
The angle between the two vectors is

(A) 60°
(B) 90°
(C) 120°
(D) 150°

14) Find the area of a parallelogram find by vectors , ?

(A) 2
(B)
(C) 10
(D) 6

15) If the resultant of two forces of magnitudes P and Q acting at a point at an angle of 60° is ,

then is

(A) 1
(B)

(C) 2
(D) 4

16)

The resultant of and makes an angle α with A and β with B, then :

(A) α = β if A > B
(B) α < β if A < B
(C) α < β if A > B
(D) α < β if A = B

17)

If y = x3 + 2x2 + 6x - 1 then is :

(A) 3x2 + 2x
(B) 3x2 + 4x
(C) 3x2 + 4x + 6
(D) 3x2 + 4x + 5

18) For , at x = 0 is

(A) 1
(B) –1
(C) 0
(D) 2

19) A vector having magnitude 10 units is shown in diagram. is unit vector along x axis and is

unit vector along y axis. In terms of and , can be written as .

(A)
(B)

(C)
(D)

20) If . then find INCORRECT statment

(A)

(B)

(C)

(D)

SECTION-II

1) , . Find value of 3a, if .

2) If and , then is equal to

3) If and , find the magnitude of component of along .

4) If . Find .

5) Find the value of 8(sin100° cos50° + sin50° cos100°)

CHEMISTRY

SECTION-I

1) Which of the following is NOT homogeneous mixture ?

(A) NaCl + Water solution


(B) Alloy
(C) Sugar solution in water
(D) Sand + Water

2) Which one of the following pairs of compounds illustrate the law of multiple proportions ?

(A) H2O, Na2O


(B) MgO, Na2O
(C) Na2O, BaO
(D) SnCl2, SnCl4

3) What is the mass of 10 nitrogen atoms in amu ?

(A) 14 amu
(B) 280 amu
(C) 140 amu
(D) 70 amu

4) The mass of 1 molecule of O2 is : (O = 16 amu)

(A) 32 g
(B) 16 g
(C) 5.314 × 10–23 g
(D) 2.65 × 10–23 g

5) In the reaction N2(g) + 3H2(g) ——→ 2NH3(g), ratio by volume of N2, H2 and NH3 is 1 : 3 : 2 at
same condition of temperature and pressure. This illustrates law of -

(A) Definite proportion


(B) Multiple proportion
(C) Conservation of mass
(D) Gaseous volumes

6) Find average atomic weight of a mixture containing 25% by mol 35Cl & 75% by mol 37Cl.

(A) 36.55
(B) 36.60
(C) 36.58
(D) 36.50

7) 0.5 mole of H2SO4 is mixed with 0.2 mole of Ca (OH)2. The maximum number of moles of CaSO4
formed is -
H2SO4 + Ca(OH)2 CaSO4 + 2H2O

(A) 0.2
(B) 0.5
(C) 0.4
(D) 1.5

8) Number of molecules in 100 ml of each of O2, NH3 and CO2 at STP are :

(A) In the order CO2 < O2 < NH3


(B) In the order NH3<O2<CO2
(C) O2 = NH3 = CO2
(D) NH3 = CO2 < O2

9) Which of the following contains the largest number of atoms - (C = 12 amu, S = 32 amu, N = 14
amu, H = 1 amu)

(A) 11g of CO2


(B) 4 g-molecule of H2
(C) 5g of NH3
(D) 8g-molecule of SO2

10) One litre of mixture of CO and CO2 is passed through red hot charcoal in a tube. The new volume
become 1.4 L. Find out composition of mixture by volume.

(A) CO=60% and CO2 = 40%


(B) CO=50% and CO2 = 30%
(C) CO= 40% and CO2 = 20%
(D) CO=30% and CO2 = 70%

11) The empirical formula of a compound having molecular mass 180 is CH2O. Find molecular
formula.

(A) CH2O
(B) C2H4O2
(C) C6H12O6
(D) C3H6O3

12) Mass of 12 × 1023 molecules of NH3 in gms -


[Given : NA = 6 × 1023 , Atomic mass of N = 14 amu, H = 1 amu ]

(A) 17
(B) 34
(C) 51
(D) 68

13) Insulin contains 4 % sulphur. The minimum molecular weight of insulin is –

(A) 800
(B) 1200
(C) 1600
(D) 2000

14) A person adds 1.71 gram of sugar (C12H22O11) in order to sweeten his tea. The number of carbon
atoms added are :
[Given : Molar mass of sugar = 342, NA = 6 × 1023]
(A) 3.6 × 1022
(B) 7.2 × 1021
(C) 0.05
(D) 6.6 × 1022

15) The law of conservation of mass holds good for all of the following except -

(A) All chemical reactions


(B) Nuclear reactions
(C) Endothermic reactions.
(D) Exothermic reactions.

16) What mass of CO2 gas can be produced by decomposition of 1000g of CaCO3. The yield of the
reaction is 50%.
[Given : Atomic mass of Ca = 40 ]

CaCO3 CaO + CO2

(A) 420 g
(B) 450 g
(C) 220 g
(D) 400 g

17) Calculate the volume of 20 g of H2 gas at STP

(A) 22.4 L
(B) 112 L
(C) 227 L
(D) 11.2 L

18) For the reaction : A + 2B → C


5 mole of A and 8 mole of B will produce -

(A) 5 mole of C
(B) 4 mole of C
(C) 8 mole of C
(D) 13 mole of C

19) The chloride of a metal contains 71% chlorine by weight and the vapour density of it is 50. The
atomic weight of the metal will be - (Cl = 35.5 amu)

(A) 29
(B) 58
(C) 35.5
(D) 71
20) 1 mol of iron (Fe = 56) reacts completely with 0.65 mol O2 to give a mixture of only FeO and
Fe2O3. Mole ratio of ferrous oxide to ferric oxide is

(A) 3 : 2
(B) 4 : 3
(C) 20 : 13
(D) 3 : 4

SECTION-II

1) Calculate % of carbon by mass in C6H12O6.

2) Total number of atoms present in 3 molecules of NH3 is x . The value of is

3) Given the following reaction

If 140gm impure sample of N2 react with excess of H2 (pure) to produced 34gm NH3, then find the %
purity of N2 considering yield to be 100%.

4) 16 g H2 is reacted with 16 g O2 to produce H2O. Calculate moles of H2O produced.2H2 + O2 →


2H2O

5) The volume of O2 required (in L) for complete combustion of 1 L of C3H8 (g) is :

MATHEMATICS

SECTION-I

1) Sum of integral value(s) of x which satisfy is/are

(A) 0
(B) 2
(C) 6
(D) None of these

2) Number of positive integers satisfying is

(A) 0
(B) 1
(C) 2
(D) 3

3) Number of positive integral value(s) of x satisfying is/are

(A) 0
(B) 1
(C) 2
(D) infinite

4) The L.C.M. of the fractions is

(A)

(B)

(C)

(D) None of these

5) Solution set of is given by

(A) (–∞, –4) ∪ [–2, –1]


(B) (–∞, –4) ∪ (–2, –1)
(C) (–4, –3) ∪ (–3, –2] ∪ [–1, ]
(D) (–4, –3) ∪ (–3, –2) ∪ (–1, )

6) Two finite sets have m and n elements respectively. The total number of subsets of first set is 248
more than the total number of subsets of the second set. The values of m and n respectively are.

(A) 7, 6
(B) 5, 1
(C) 6, 3
(D) 8, 3

7) A survey shows that 63% of the Indian like Mangoes where as 76% like Oranges. If x % of the
Indians like both Mangoes and Oranges then

(A) x = 39
(B) x = 63
(C) 39 ≤ x ≤ 63
(D) None of these
8) The number of positive integral solutions of x4 – y4 = 1572 is -

(A) 0
(B) 1
(C) 2
(D) 4

9) If x – y = a and x2 + y2 = b, then the value of x3 – y3 is :

(A)

(B)

(C)

(D) a2 + b

10) If x2 + y2 + z2 = 11 and x + y + z = 11, then value of xy + yz + zx is -

(A) 120
(B) 110
(C) 55
(D) 22

11) If then value of is

(A) 3541
(B) 2481
(C) 3121
(D) 2207

12)

Number of natural number 'n' for which is a natural number, is

(A) 2
(B) 3
(C) 4
(D) 6

13) The expression simplifies to

(A) 4
(B)
(C)
(D) 6

14) The value of , (where x > 0) is

(A) 0
(B) 1
(C) 2
(D) 3

15) The value of is

(A) 9
(B) 10
(C) 11
(D) 12

16)

Given that 'x' is a real number satisfying then

(A)

(B)

(C)

(D)

17) The solution set of is :

(A) [1, 5]

(B)

(C)

(D)

18) If A = {1,2,3,4,5,8},
B = {3,4,5,10,11,12},
C = {4,5,8,14,15},
Then (A ∩ B) ∪ (A ∩ C) is equal to
(A) {3,4,5}
(B) {3,5,8}
(C) {3,4,8}
(D) {3,4,5,8}

19) The complete solution of , is

(A) [–2, ∞)
(B) [0, ∞)
(C) (–∞, 0) ∪ (2, ∞)
(D) (–∞, 0) ∪ [2, ∞)

20) Suppose a, b, c, d ∈ N, satisfying the relation then the value of (ab + cd) is

(A) 19
(B) 23
(C) 29
(D) 33

SECTION-II

1) Given n(U) = 20, n(A) = 12, n(B) = 9, n(A ∩ B) = 4, where U is the universal set, A and B are
subsets of U, then n((A ∪ B)C) =

2) If and then the value of is equal to where


a, b, c are coprime numbers then a + b + c is equal to (where 'c' is an odd integer)

3) If N = 2 3 4 P 5 Q where P = 3 then number of values of single digit number Q such that N is


completely divisible by 6 is

4) If , find value of
cubing both sides

5) If a, b, c ∈ R and (a –1)2 + (b + 1)2 + (c + 1)2 = 0 then value of 2a – 3b + 4c is


ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D A C D D B C D C A B B C A C C C C A D

SECTION-II

Q. 21 22 23 24 25
A. 4.00 1.00 5.00 2.00 4.00

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. D D C C D D A C D A C B A A B C C B A B

SECTION-II

Q. 46 47 48 49 50
A. 40.00 4.00 20.00 1.00 5.00

MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B D B C C D C A B C D D B B A D D D D B

SECTION-II

Q. 71 72 73 74 75
A. 3.00 36.00 1.00 18.00 1.00
SOLUTIONS

PHYSICS

2)

Unit vector =

3) Rmax = 10 + 15 = 25
Rmin = 15 – 10 = 5
Resultant cannot lie beyond this range.

5)

= 18 + 32 = 50

6) 1. Asking About: Resultant of two vector


2. Concept: Δ low
3. Soln/Explanation:
According to Δ law Q should kept on head of P than the vector going tail of P &
heard of Q is resultant.

7) A(1,1,–1); B(2, –3 , 4)
= (2, –3, 4) – (1, – 1, 1) = (1, –4, 5)

8)

9)
11)

12) Let unknown displacement be then

16)
α<β A<B
The resultant bend towards the vector of which is higher in magnitude.

18)

19)

21)

22) &

23)

Component of along

=
24)


= 12 + 4 – 14 = 2

CHEMISTRY

26) Homogeneous mixture : NaCl + Water solution, alloy, sugar solution


Heterogeneous mixture : sea water, Sand + Water

28)

29)

Mass of one molecule of O2 = 32 amu

=
= 5.314 × 10–23 g

30) Concept Law of In gaseous Volume-In the gaseous reaction, the reactants are always
combined in a simple ratio by volume anf form Products, which is simple ratio by volume at
same temp. and pressure

Final Answer Gaseous Volumes


Correcti option 4

36)

Molecular formula = (Empirical formula)n

=
M.F = (CH2O) = C6H12O6

37)

mass of NH3 =
42)

43)

A Question: For the reaction: A + 2B → C, 5 moles of A and 8 moles of B will produce how
many moles of C?

B Given Data:

A. Balanced chemical equation: A + 2B → C

B. Initial moles of A: 5 moles

C. Initial moles of B: 8 moles

C Concept:

A. Stoichiometry: This branch of chemistry deals with the quantitative relationships


between reactants and products in a chemical reaction.

B. Limiting Reactant: The reactant that is completely consumed first in a chemical reaction,
thereby limiting the amount of product formed.

C. Mole Ratio: The ratio of the coefficients of the reactants and products in a balanced
chemical equation.

D Mathematical Calculation:

A. Determine the limiting reactant:

A. From the balanced equation, 1 mole of A reacts with 2 moles of B.

B. To react with 5 moles of A, we would need 5 moles of A × (2 moles of B / 1 mole of


A) = 10 moles of B.

C. However, we only have 8 moles of B available.

D. Therefore, B is the limiting reactant.


B. Calculate the moles of C produced:

A. From the balanced equation, 2 moles of B produce 1 mole of C.

B. So, 8 moles of B will produce 8 moles of B × (1 mole of C / 2 moles of B) = 4 moles


of C.

E Final Answer: 5 moles of A and 8 moles of B will produce 4 moles of C.

45)

46)

% of carbon (by mass) =

=
% C = 40%

47)

1 molecule = 4 atoms
3 molecule = 12 atoms

MATHEMATICS
51)

53)

x ≠ 0, – 1, 1

55)
(–4, –3) ∪ (–3, –2] ∪ [–1, ∞)

56)

Since, let A and B be such sets, i.e., n(A) = m, n(B) = n


So n(P(A)) = 2m, n(P(B)) = 2n
Thus n(P(A)) – n(P(B)) = 248, i.e., 2m – 2n = 248
⇒ 2n(2m–n – 1) = 23 × 31 ⇒ n = 3, 2m–n –1 = 7 ⇒ m = 8

57)

n(C) = 63, n(A) = 76, n(A ∩ C) ≤ 100


⇒ n(A ∪ C) = n(A) + n(C) – n(A ∩ C)
⇒ n(A ∪ C) = 76 + 63 – n(A ∩ C) ⇒ 100 ≥ 139 – n(A ∩ C)
⇒ n(A ∩ C) ≥ 39
But A ∩ B ⊆ A and A ∩ B ⊆ B
⇒ n(A ∩ B) ≤ n(A) and A ∩ B ≤ B
⇒ n(A ∩ B) ≤ 63 and n(A ∩ B) ≤ n(B)
⇒ n(A ∩ B) ≤ 63
from (1) and (2)
39 ≤ n(A ∩ B) ≤ 63.

58) x4 – y4 = 1572
x and y both are either odd or even
(x – y)(x + y)(x2 + y2) = 1572
LHS is divisible by 8
RHS is not divisible by 8
⇒ not possible.

59) x – y = a
∴ x2 + y2 – 2xy = a2
b – a2 = 2xy

...(1)
Now x3 – y3 = (x – y)3 + 3xy(x – y)

60) Use (x + y + z)2


= x2 + y2 + z2 + z(xy + yz + zx)

61)

62)

must be an integer
⇒ n = 1,2,3,4,6,12

63)
64)

65) Rationalise Denomenators

66)

We have

67)

69)

x∈(–∞, 0) ∪ [2, ∞)

70)
⇒ a = 1 and

⇒ b = 3 and
⇒ c = 4 and d = 5
Hence ab + cd = 23

72) ,

=
= 17 –

73)

N is divisible by 6 if it is divisible by 3 and 2


(i) Q must be even
(ii) 17 + Q must be divisible by 3
∴Q=4

74)

75)

(a – 1)2 + (b + 1)2 + (c + 1)2 = 0


a = 1, b = –1, c = –1

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