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Hybridization and CFSE in Transition Complexes

The tutorial covers various questions related to valence bond theory and crystal field theory, including predicting hybridization and geometry for specific complexes, drawing crystal field diagrams, calculating crystal field stabilization energy (CFSE) for certain oxides, and determining unpaired electrons in octahedral complexes based on the strength of the crystal field splitting. It addresses both paramagnetic and diamagnetic complexes involving transition metals. The focus is on understanding the electronic structure and properties of these complexes.

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0% found this document useful (0 votes)
8 views1 page

Hybridization and CFSE in Transition Complexes

The tutorial covers various questions related to valence bond theory and crystal field theory, including predicting hybridization and geometry for specific complexes, drawing crystal field diagrams, calculating crystal field stabilization energy (CFSE) for certain oxides, and determining unpaired electrons in octahedral complexes based on the strength of the crystal field splitting. It addresses both paramagnetic and diamagnetic complexes involving transition metals. The focus is on understanding the electronic structure and properties of these complexes.

Uploaded by

Aditya Raj
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd

Tutorial 3 (CH1201, Module 2)

Question 1. Using valence bond theory, predict the hybridization and geometry of paramagnetic [NiCl 4]2-,
diamagnetic [Ni(CN)4]2-, diamagnetic [Co(NH3)6]3+, paramagnetic [CoF6]3-, and paramagnetic [FeBr4]2-

Question 2. Draw the crystal field diagrams of [Mn(CN)6]3-, [Fe(H2O)6]2+ and [Fe(CN)6]4-

Question 3. Calculate the CFSE of MnO, Mn2O3, and FeO

Question 4. Determine the number of unpaired electrons in octahedral complexes of d 9, d5, d4 and d3 ions when
o > P and o < P

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