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Gases Evolved in Reactions with HCl

The document contains a series of solved chemistry questions from 2012 to 2024, focusing on the properties and reactions of hydrochloric acid (HCl) and related compounds. It includes balanced equations, observations from experiments, and reasons for certain chemical behaviors. Key topics include the preparation of HCl gas, its reactions with various substances, and safety precautions.

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0% found this document useful (0 votes)
5 views8 pages

Gases Evolved in Reactions with HCl

The document contains a series of solved chemistry questions from 2012 to 2024, focusing on the properties and reactions of hydrochloric acid (HCl) and related compounds. It includes balanced equations, observations from experiments, and reasons for certain chemical behaviors. Key topics include the preparation of HCl gas, its reactions with various substances, and safety precautions.

Uploaded by

rkumarnhpc1
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Chemistry Previous Questions – Solved

(From Dr. Viraf J. Dalal’s Objective Workbook – Page 159)

2012

I. Give the correct statement – with the missing words:​


Aqua regia contains one part by volume of nitric acid and three parts by volume of
hydrochloric acid.​
Answer: Aqua regia = 1 part HNO₃ + 3 parts HCl.

II. Give reason – Hydrogen chloride gas cannot be dried over quick lime.​
Answer: Because quick lime (CaO) is alkaline and reacts with acidic HCl gas.

III. Give balanced equation – Concentrated hydrochloric acid & potassium permanganate
solution.​
Answer: 2KMnO₄ + 16HCl → 2MnCl₂ + 5Cl₂ + 8H₂O + 2KCl

IV. Give balanced equations – for the following conversions:​


A: Hydrogen chloride → Hydrogen​
B: Hydrogen chloride → Lead chloride​
Answers:​
A: Zn + 2HCl → ZnCl₂ + H₂​
B: Pb(NO₃)₂ + 2HCl → PbCl₂ + 2HNO₃

2013

V. Name the gas evolved when:​


i) Potassium sulphite is treated with dil. HCl – SO₂ (sulphur dioxide)​
ii) Concentrated hydrochloric acid is made to react with manganese dioxide – Cl₂ (chlorine)​
iii) A few drops of HCl are added to AgNO₃ soln., followed by addition of NH₄OH soln. – White
ppt of AgCl dissolves in NH₄OH.

2014

VI. Fill in the blank from the choices:​


Quicklime is used to dry HCl gas → CaO is alkaline
VII. Write balanced equation – Action of dilute HCl on sodium sulphite:​
Answer: Na₂SO₃ + 2HCl → 2NaCl + SO₂ + H₂O

VIII. State your observation – Dilute HCl is added to sodium carbonate crystals:​
Answer: Effervescence is observed due to the evolution of CO₂ gas.

IX. State the figure alongside demonstrates:​


Answer: HCl gas turns moist blue litmus paper red – proving it is acidic.

X. Name the gas which turns moist blue litmus paper red:​
Answer: Hydrogen chloride (HCl)

2015

XI. Select from the gases – Ammonia, ethane, hydrogen chloride, hydrogen sulphide, ethyne:​
i) The gas which produces white dense fumes with ammonia – Hydrogen chloride​
ii) The gas that gives white precipitate with AgNO₃ – Hydrogen chloride

XII. Write the equation – for its lab preparation – from sodium chloride and concentrated sulfuric
acid:​
Answer: NaCl + H₂SO₄ → NaHSO₄ + HCl ↑

2016

XIII. State a safety precaution – in the preparation of hydrogen chloride gas:​


Answer: The apparatus must be completely dry; moisture can cause the gas to dissolve
prematurely.

XIV. Fill in the blank – HCl turns blue litmus...​


Answer: Red

XV. State one relevant observation – Action of dilute hydrochloric acid on iron(II) sulphide:​
Answer: Rotten egg smell is observed due to release of hydrogen sulphide gas (H₂S).

XVI. Write a balanced chemical equation – Action of HCl on lead nitrate solution:​
Answer: Pb(NO₃)₂ + 2HCl → PbCl₂ + 2HNO₃

XVII. State your observations:​


i) Lead nitrate solution + dilute HCl + heat – White precipitate of PbCl₂ forms​
ii) Copper carbonate + dilute HCl – Effervescence due to CO₂ gas​
iii) Sodium sulphite + dilute HCl – Pungent smelling SO₂ gas is evolved
2017

XVIII. Fill in the blanks – Potassium sulphite reacting with dilute HCl releases...​
Answer: SO₂ gas

XIX. Identify the substance underlined – a solid formed by the reaction of two gases – one
acidic, one basic:​
Answer: Ammonium chloride (NH₄Cl)

XX. State one relevant observation – Action of dilute HCl on iron(II) sulphide:​
Answer: Evolution of rotten egg smelling hydrogen sulphide gas.

XXI. Identify A & B in the table:

Lab Reactants Used Products Drying Agent Method of


Preparation of Formed Collection
HCl gas

NaCl + H₂SO₄ HCl + NaHSO₄ Conc. H₂SO₄ Upward


displacement of
air

2018

XXII. Write a balanced chemical equation – Action of dilute HCl on magnesium sulphite:​
Answer: MgSO₃ + 2HCl → MgCl₂ + SO₂ + H₂O

XXIII. State one observation – Lead nitrate + dilute HCl + heat:​


Answer: White precipitate of lead(II) chloride forms.

XXIV. Name the gas produced during the action of dilute HCl on sodium sulphide:​
Answer: Hydrogen sulphide (H₂S)

XXV. Fill in the blank – Hydrogen chloride gas is collected by...​


Answer: Upward displacement of air

XXVI. Answer the following – in preparation of hydrogen chloride gas:​


i) Name the acid used – Concentrated sulphuric acid​
ii) Why this acid? – It is non-volatile and has high affinity for water.

XXVII. Write a balanced chemical equation – Laboratory preparation of HCl gas:​


Answer: NaCl + H₂SO₄ → NaHSO₄ + HCl

XXVIII. State the following:​


i) Why direct absorption of HCl gas in water is not feasible – It forms a fog of acid mist and
gets absorbed rapidly.​
ii) What arrangement is used – A funnel with the stem just above water surface (inverted
funnel method).

Great! Here are the **new solved questions** from the page you just sent, continuing with
**Roman numeral numbering** starting from **XXIX**, and **excluding** questions that
were already answered before.

**Years: 2019–2024**

#### **2019**

**XXIX.** *Choose the correct answer – The drying agent used to dry HCl gas is:*

**Answer:** D: CaO (Calcium oxide)

**XXX.** *Fill in the blanks – when sodium chloride is heated with conc. sulfuric acid
below 200°C, one of the products formed is:*

**Answer:** Hydrogen chloride

**XXXI.** *State one observation – A small piece of zinc is added to dilute hydrochloric
acid:*

**Answer:** Effervescence is observed due to the evolution of hydrogen gas.

---
#### **2020**

**XXXII.** *State one relevant reason for – Hydrogen chloride gas fumes in moist air:*

**Answer:** Because it is highly soluble in water and forms tiny droplets of hydrochloric
acid with moisture in air.

**XXXIII.** *Select the correct answer – The indicator which does not change colour on
passage of HCl gas is:*

**Answer:** Methyl orange

**XXXIV.** *The acid which cannot act as an oxidising agent in the lab using conc. H₂SO₄
and NaCl:*

**Answer:** Hydrochloric acid (HCl)

**XXXV.** *Answer the questions – HCl gas is prepared in the lab:*

i) *Give the balanced chemical equation:*

**Answer:** NaCl + H₂SO₄ → NaHSO₄ + HCl ↑

ii) *State why – concentrated sulphuric acid is used instead of nitric acid:*

**Answer:** Because nitric acid is volatile and would evaporate, whereas H₂SO₄ is
non-volatile.

iii) *How is the gas collected?*

**Answer:** By upward displacement of air (since it is denser than air).

iv) *Name the drying agent:*

**Answer:** Concentrated sulphuric acid.

---
#### **2021–22**

**XXXVI.** *Choose the correct answer – Hydrogen chloride gas is not collected over
water as it is:*

**Answer:** A: Highly soluble in water.

**XXXVII.** *The metallic oxide which reacts with HCl and forms salt & water:*

**Answer:** B: Zinc oxide

**XXXVIII.** *Identify the term – the experiment used to demonstrate the high solubility of
HCl gas:*

**Answer:** Fountain experiment

**XXXIX.** *Write the balanced chemical equation – Action of heat on manganese dioxide
& conc. HCl:*

**Answer:** MnO₂ + 4HCl → MnCl₂ + Cl₂ + 2H₂O

**XL.** *Zinc reacts with dilute hydrochloric acid to form zinc chloride:*

**Answer:** Zn + 2HCl → ZnCl₂ + H₂

---

#### **2023**
**XLI.** *Choose the correct answer – In lab preparation, HCl gas is dried by passing
through:*

**Answer:** ii) Conc. sulphuric acid

**XLII.** *Fill in the blank – Silver chloride / Lead chloride gives a white precipitate that is
soluble in excess of ammonium hydroxide solution:*

**Answer:** Silver chloride

**XLIII.** *State a relevant reason – Hydrogen chloride gas cannot be dried over quick
lime:*

**Answer:** Because quick lime is alkaline and reacts with acidic HCl gas.

**XLIV.** *Choose the correct answer – The compound that will produce SO₂ gas on
reaction with dil. HCl is:*

**Answer:** Sodium sulphite

**XLV.** *Write a balanced chemical equation – Ferrous sulphide + HCl → Hydrogen


sulphide:*

**Answer:** FeS + 2HCl → FeCl₂ + H₂S

---

#### **2024**

**XLVI.** *Identify the gas evolved in the following reaction – MnO₂ reacts with conc. HCl:*

**Answer:** Chlorine gas (Cl₂)


**XLVII.** *Hydrogen chloride gas is prepared in the laboratory:*

a) *Give a balanced chemical equation:*

**Answer:** NaCl + H₂SO₄ → NaHSO₄ + HCl

b) *State the method of collection:*

**Answer:** Upward displacement of air

c) *What is the property of sulphuric acid that makes it a suitable reagent?*

**Answer:** It is non-volatile and acts as a dehydrating agent.

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