DATA SHEET
Equations Physical constants
E h fc = nve (unshared e + ½ shared e) NA = 6.022 1023 mol–1 me = 9.109 10–31 kg
c bo = ½(bonding e antibonding e) R = 0.08206 L·atm·mol–1·K–1 e = 1.602 10–19 C
h R = 8.314 J·mol–1·K–1 mp = 1.672 10–27 kg
Hrxn BE(broken) BE(formed)
mu h = 6.626 10–34 J·s mn = 1.675 10–27 kg
Z2 c = 2.998 108 m·s–1 ao = 52.9 pm = 0.529 Å
En RH (where RH = 2.179 10–18 J = 13.60 eV)
n2
n p 3RT Conversion factors
xi i i u rms 0.0 °C = 273.15 K
ntot ptot M
1 nm = 10–9 m; 1 Å = 10–10 m = 10–8 cm ; 1 pm = 10–12 m
an 2
pV nRT p
nRT
2 KE avg 32 RT 1 cal = 4.184 J
V nb V 1 atm = 760 torr = 101.3 kPa
1 eV = 1.602 10–19 J = 96.5 kJ mol–1
Average bond energies (kJ/mol)
Bond Energy Bond Energy Visible spectrum
C–C 347 C–O 358 Wavelength (nm) Colour
C=C 614 C=O 745 (799 in CO2) 400 violet
CC 839 N–O 201 450 blue
N–N 160 N=O 607 490 blue-green
N=N 418 C–H 413 570 yellow-green
NN 945 N–H 391 580 yellow
O–O 204 O–H 467 600 orange
O=O 498 H–H 432 650 red