1. What would be the expected product(s) of the following reactions? 2.
2. What would be the MAJOR organic product of the following reaction?
A)
B)
C)
D)
E)
3. What product would you expect from the reaction shown below?
A)
B)
A)
C)
B)
D)
C)
E)
D)
E)
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7. What product, if any, would result from the reaction shown below?
4. Which of the following are E isomers?
A)
A) III and V
B) II and IV
C) I, III and V
B)
D) II and III
E) I, II and IV
5. Which reagent(s) would you expect to give the highest yield of the product shown? C)
D) both A and B
E) no reaction occurs
A) K+-OtBu
B) CH3S- Na+
C) H2SO4
D) CH3O- Na+
E) K+ -CN
6. What reagent would give the highest yield of the product shown below?
A) K+-OtBu
B) NaCN
C) CH3S-Na+
D) NaOH
E) CH3O-Na+
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8. Predict the product of the following reaction: 9. Predict the MAJOR product of the following reaction:
A)
A)
B) B)
C) C)
D)
D)
E)
E)
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10. What would be the major organic product of the following reaction? 11. Predict the MAJOR product of the following reaction:
A)
A)
B)
B)
C)
C)
D)
D)
E)
E)
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12. Predict the MAJOR product of the following reaction: 13. Predict the MAJOR product of the following reaction
2,3-dimethylcyclohexanol + H2SO4
A)
B)
A)
B)
C)
C)
D) A and B in equal proportions
E) B and C in equal proportions
D)
14. Which of the following is true of thiols?
A) They are more acidic than alcohols.
B) They have lower boiling points than the corresponding alcohol.
C) Thiol oxidations proceed very differently than alcohol oxidations.
E) D) All of these.
E) Two of these.
15. Which of the following reactions would produce diethyl ether?
A)
B)
C)
D) All of these.
E) Two of these.
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16. Saytzev's Rule has to do with the following: 18. What would be the major organic product expected from the following reaction?
A) Free-radical substitutions
B) Hydration of double bonds
C) Bromination of double bonds
D) Products of elimination reactions
E) Hydrogenation of double bonds
17. What is the MAJOR product of the following reaction?
A)
B)
A)
C)
B)
D)
C)
E)
D)
E)
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19. What is the MAJOR product of the following reaction? 20. What is the MAJOR product of the following reaction:
A)
A)
B)
C) B)
D)
C)
E)
D)
E) none of these
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21. What is the product of the following reaction? 22. What would be the product of the following reaction?
A)
A)
B)
B)
C)
D) C)
E)
D)
E)
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23. What would be the product of the following reaction? 24. Which of the following reactions would be the best for the preparation of anisole
(methoxybenzene)?
A)
A)
B)
B)
C)
C)
D)
E) None of these would work.
D)
E)
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25. What would be the product of the following reaction? 26. What would be the expected product for the following reaction?
A)
A)
B)
B)
C)
D)
C)
E)
D)
E)
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27. Which alcohol could be prepared by the greatest number of different combinations of 28. What would be the expected organic product of the following reaction?
Grignard reagents and carbonyl compounds (aldehydes, ketones and/or esters)? (no
multi-step reactions are intended here)
A)
B)
A)
C)
B)
D)
C)
E)
D)
E)
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29. What is the MAJOR product of the following reaction? 30. Which of the following reactions would produce the alcohol shown below?
A)
A)
B)
B)
C)
C)
D) All of these
D)
E) Two of these
31. What is the MAJOR product of the following reaction?
E)
A)
B)
C)
D)
E) no net reaction occurs
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32. What is the major product of the following reaction? 33. What is the expected product of the following reaction?
A)
A)
B)
B)
C)
D)
C)
E)
D)
E)
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34. Predict the product of the following reaction: 35. Which of the sequences below would accomplish the following transformation?
A)
A)
B) B)
C)
C)
D)
D)
E) E)
36. Which of the following reagents would accomplish the reaction shown?
A) H2SO4, H2O
B) H 2CrO4
C) O2 (slow)
D) HO-, H2O
E) None of these.
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37. Which of the following reactions would produce the alcohol shown? Answer Key - Ferret:Exam:chem 109a 2003:quiz [Link]
1. B
2. B
3. C
4. B
5. D
6. A
7. A
8. D
A) 9. B
10. C
11. D
12. D
13. C
14. D
B) 15. E
16. D
17. D
18. C
C)
19. A
D) All of these.
20. B
E) None of these
21. D
22. A
23. A
24. C
25. A
26. B
27. A
28. C
29. A
30. D
31. E
32. A
33. A
34. D
35. B
36. E
37. D
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