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NOx and SO₂ Absorption and Sampling Methods

The document outlines various methods for absorbing reagents and analyzing pollutants such as NOx and SO₂, including the use of sodium hydroxide and hydrogen peroxide, respectively. It also details sampling guidelines for these gases and non-methane hydrocarbons (NMHC), emphasizing the importance of location and timing for accurate measurements. Additionally, it describes procedures for sampling ambient weather parameters like wind speed, solar radiation, humidity, and temperature.

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3 views2 pages

NOx and SO₂ Absorption and Sampling Methods

The document outlines various methods for absorbing reagents and analyzing pollutants such as NOx and SO₂, including the use of sodium hydroxide and hydrogen peroxide, respectively. It also details sampling guidelines for these gases and non-methane hydrocarbons (NMHC), emphasizing the importance of location and timing for accurate measurements. Additionally, it describes procedures for sampling ambient weather parameters like wind speed, solar radiation, humidity, and temperature.

Uploaded by

ibrahimdulaedy818
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd

Absorbing reagents for NOx and SO₂:

For NOx, the absorbing reagent used is sodium hydroxide (NaOH) or potassium permanganate (KMnO₄)
in acidic solutions.

For SO₂, hydrogen peroxide (H₂O₂) or tetrachloromercurate (TCM) is commonly used.

Wavelengths for calorimetry analysis:

NO₂ is analyzed at 540 nm using the Griess-Saltzman reaction.

SO₂ is analyzed at 560 nm using pararosaniline methods.

Basic sampling location guidelines for NOx and SO₂:

Sampling should be done away from direct emission sources to get ambient levels.

Height should be 1.5 to 3 meters above the ground level.

Avoid obstructions like buildings that can affect air circulation.

Position should be in open areas with good air mixing.

Gravimetric method for particulates analysis:

Air is drawn through a pre-weighed filter (e.g., Teflon or quartz fiber filter).

Particulates are collected on the filter.

The filter is dried and weighed again.

The difference in weight determines the concentration of particulates in the sampled air.

Method for sampling of NMHC (Non-Methane Hydrocarbons):

Canister sampling: Air is collected in a stainless steel canister.

Adsorption tubes: NMHCs are trapped in sorbent materials like Tenax or activated charcoal.

Gas chromatography analysis is then used for measurement.

Recommended time for NMHC sampling:

Usually in the morning (6 AM – 9 AM) and evening (6 PM – 9 PM) when traffic and industrial activities
are high.

Avoid midday when photochemical reactions might alter NMHC composition.

Procedures for sampling hydrocarbons:


Use passive samplers (diffusion-based) or active samplers (pumps).

Air is drawn through adsorption media (e.g., activated charcoal).

Sample is later analyzed using Gas Chromatography-Mass Spectrometry (GC-MS).

Sampling of ambient weather parameters:

Wind speed and direction: Measured using an anemometer and wind vane.

Solar radiation: Measured using a pyranometer.

Relative humidity: Measured using a hygrometer or psychrometer.

Temperature: Measured using a thermometer or thermocouple sensor.

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