CALCULATION COVER SHEET Honeywell-UOPFHR

PROCESS ENGINEERING Merox Module

DATE: 12 Jan 2015 Hargrove Job No.:
REVISION: B 0333.141311.20

Extractor Blocked Outlet Scenario:

13. The required relieving rate was taken as 74.1 gpm of subcooled liquid entering the PSV and flashing at the PSV throat.
a. Calculation based on flow through control valve LV-1534 and bypass. Combined Cv assumed to be 12.0 (per client).
b. The required relief rate was calculated assuming negligible friction losses in piping and downstream equipment
between the source pressure and the PSV.
c. The source pressure was taken as 198.4 psig, which was calculated assuming 180 psig normal operating pressure in
the Treater Extractor and an elevation head of 75.5’ between the control valve and the extractor pressure transmitter.
d. The downstream pressure was taken as 176.9 psig, which was calculated from the PSV set pressure + 10%
overpressure and 49’ elevation head between the pump and the PSV.
14. Relief device orifice sizing calculations for blocked outlet performed based on the method outlined in API 520 8th Ed. Section
C.2.3. This method assumes a subcooled or saturated liquid entering the relief valve and flashing. No condensable vapor or non-
condensable gas enters the relief valve.
15. Two-phase flow pressure drop calculations were performed using the “Beggs-Brill-Moody” method in Pro/II.
16. Physical property data for relieving fluid was taken from Pro/II, with composition the same as the inlet stream to the C4 Treater
Extractor (Stream 102 on PFD):
Molar
Component
Composition
H2S 0.000
PROPANE 0.020
PROPENE 0.012
IBUTANE 0.311
BUTANE 0.090
1BUTENE 0.140
IBUTENE 0.121
C2BUTENE 0.109
T2BUTENE 0.153
IPENTANE 0.029
PENTANE 0.001
1PENTENE 0.013
HEXANE 0.001

17. Inlet relief fluid properties generated from Pro/II:

a. Relieving pressure = 179.7 psia
b. Temperature = 102˚F
c. Molecular weight = 57.2 lb/lb-mole
d. Critical temperature = 295.9˚F
e. Critical pressure = 566.7 psia
f. Vapor pressure = 65.0 psia
g. Density at 90% of saturation pressure = 15.5 lb/ft3

Revision History
Rev. No. Description of Revision
A Issued for Approval
B Issued for Approval

2 of 4
 CALCULATION COVER SHEET Honeywell-UOPFHR
PROCESS ENGINEERING Merox Module
DATE: 12 Jan 2015 Hargrove Job No.:
REVISION: B 0333.141311.20

h. Liquid density = 35.1 lb/ft3

i. Liquid viscosity = 0.15 cP
Fire Scenario:
18. The following Caustic physical properties were calculated using PRO II at 10% vaporization point and the relieving pressure:
a. Molecular Weight = 19.66.
b. Compressibility = 1.
c. Latent Heat = 859.4 BTU/lb.
d. Relieving Temperature = 387.6 °F.
e. Viscosity = 0.016 cP.
f. k = 1.372.
19. No additional surface area was included for piping.
20. Heat absorption calculations are based on the assumption that there is inadequate firefighting and drainage.
21. There is no insulation on the Caustic Heater.
22. The environmental factor, F=1.
23. Latent heat was calculated based on vaporizing 10% by mass of the normal liquid (caustic solution, stream 181 in the mass
balance) composition. Also, the vapor relieving stream is based on the 10% vaporization point.
24. The vessel length is 24.33 feet. This accounts for two 4 inch pipes 12 ft 2inches long.

10. Use of Computer Software and Models

Excel Spreadsheets for orifice sizing and single-phase flow pressure drop calculations.
Pro/II for physical property information and two-phase flow pressure drop calculations.
11. Calculation
See Attachments.

12. References
MFD: CW005F05006 & CW005F05005
Standards:
a. API-520 – Sizing, Selection, and Installation of Pressure-relieving Devices in Refineries – Part 1, Dec 2008.
b. API-521 – Pressure-relieving and Depressuring Systems, 6th Ed., Jan 2014.

13. Determining Scenario

1. Determining - Wash oil control valve failure. Required orifice area = 0.234 in2 (see Attachment 3 for calculations).
2. Other - Extractor blocked outlet. Required orifice area = 0.209 in2 (see Attachment 4 for calculations).
3. Other – Fire. Required area = 0.055 in2 (see Attachment 10 for calculations).

14. Orifice Determination

The calculated required orifice size is 0.234 in2 for the wash oil control valve failure case. A balance bellows relief valve with an “F” orifice
(0.307 in2) was selected.

15. Piping Considerations – Inlet

See Attachment 12 for PSV piping isometric. The PSV inlet piping is currently 1-½”, but will need to be increased to 2” diameter.

Based on the control valve failure rated relief rate (40,615.9 lb/hr liquid), the inlet pressure drop is 2.79 psi, which is 1.86% of the set
pressure. This is less than the 3% of set pressure allowed for inlet piping, and thus is acceptable for the fire scenario (see Attachments 5
and 6 for inlet pipe pressure drop calculations for control valve failure scenario).

Revision History
Rev. No. Description of Revision
A Issued for Approval
B Issued for Approval

3 of 4
 CALCULATION COVER SHEET Honeywell-UOPFHR
PROCESS ENGINEERING Merox Module
DATE: 12 Jan 2015 Hargrove Job No.:
REVISION: B 0333.141311.20

Based on the blocked outlet scenario rated relief rate (30,595 lb/hr subcooled liquid), the inlet pressure drop is 1.5 psi, which is 1.0% of the
set pressure. This is less than the 3% of set pressure allowed for inlet piping, and thus is acceptable for both the fire and blocked outlet
scenarios (see Attachment 10 for discharge pipe pressure drop calculations for blocked outlet scenario).
16. Piping Considerations – Outlet
See Attachment 12 for PSV piping isometric. The PSV discharge piping is currently 2”, but will need to be increased to 3” diameter.

Based on the control valve failure rated relief rate (40,615.9 lb/hr liquid), the outlet pressure drop is 1.0 psi, which gives a total back
pressure of 3.0 psig. This is 2.0% of the set pressure, which is less than 50% of the set pressure. The discharge piping is therefore
acceptable for the fire scenario (see Attachments 7 and 8 for discharge pipe pressure drop calculations for control valve failure scenario).

Based on the blocked outlet scenario rated relief rate (30,595 lb/hr liquid/vapor two-phase), the outlet pressure drop is 20.8 psi, which
gives a total back pressure of 22.8 psig. This is 15.2% of the set pressure, which is less than 50% of the set pressure. The discharge
piping is therefore acceptable for both fire and blocked outlet scenarios (see Attachment 10 for discharge pipe pressure drop calculations
for blocked outlet scenario).
17. Conclusion
PSV-0550 is required to protect the Scrubbing Oxidizer and the Caustic Heater from overpressure in the event that there is control valve
failure, fire or blocked outlet on the extractor. A balanced bellows valve with an “F” size orifice (0.307 in2) is selected. The inlet and outlet
piping pressure drops are acceptable with the inlet line size increased to 2” diameter and the outlet line size increased to 3” diameter.

18. Attachments
Item Description Rev. Pages
1. ISA Data Sheet A 1
2. Potential Sizing Scenarios B 1
3. Control Valve Failure - Relieving Rate and Orifice Sizing Calculations A 3
4. Extractor Blocked Outlet - Relieving Rate and Orifice Sizing Calculations A 4
5. Control Valve Failure - Inlet Pipe Pressure Drop Summary A 1
6. Control Valve Failure - Inlet Pipe Pressure Drop Calculations A 3
7. Control Valve Failure - Discharge Pipe Pressure Drop Summary A 1
8. Control Valve Failure - Discharge Pipe Pressure Drop Calculations A 6
9. Extractor Blocked Outlet - Pro/II Workspace - Physical Properties and Inlet/Discharge Pressure Drop
A 1
Calculations
10. Fire - Relieving Rate and Orifice Sizing Calculations A 4
11. P&ID CW005F05006 (Preliminary Mark-up – Not Issued) & CW005F05005 12/24/14 2
/2
12. FA-551 Equipment Datasheet 3 1
13. Isometric for PSV-0550 (Preliminary Mark-up – Not Issued) 12/24/14 3
14. Wash Oil Composition Provided by UOP - 3
15. FV-0570 Datasheet 10/9/14 3
16. EA-503 Vendor Drawing 0 6

Revision History
Rev. No. Description of Revision
A Issued for Approval
B Issued for Approval

4 of 4
 Attachment 1

SHEET 1 OF 1
PRESSURE RELIEF VALVES
SPEC. NO. REV.
NO BY DATE REVISION A
A ABW 12/29/14 IFA CONTRACT DATE
0333.141311.20
REQ. - P.O.

BY CHK'D APPR.
ABW DL
1 Tag Number PSV-0550
2 Service
Wash Oil/ BB from West Plant FCCU
3 Line Number / Vessel Number 05-FA-551
GENERAL
4 Full Nozzle/Semi Nozzle Semi
5 Safety or Relief Safety Relief
6 Conv., Bellows, Pilot Op. Bellows
7 Bonnet Type Closed
8 Size: Inlet Size: Outlet 1.5 2
CONN. 9 Flange Rating or Screwed 150 150
10 Type of Facing RF RF
11 Body and Bonnet Carbon Steel
12 Seat and Disc 316 SST
13 Resilient Seat Seal N/A
MATERIALS 14 Guide and Rings 316 SST
15 Spring Carbon Steel
16 Bellows Inconel
17 Nozzle 316 SST
18 Cap: Screwed or Bolted Screwed
19 Lever: Plain or Packed N/A
20 Test Gage N/A
OPTIONS
21
22
23
24 Code ASME Section VIII
25 Fire No
BASIS
26 Other Control Valve Failure
27
28 Fluid and State Wash Oil/ LPG
29 Required Capacity 31016.35 lb/hr
30 Mol. Wt. Oper. Sp. Gr. - 0.720
31 Oper. Press. Set. Press. 50.00 150.00
32 Oper. Temp. Rel. Temp. 113.00 100.00
33 Back Pressure: Constant 2.00
34 Back Pressure: Variable 1.00
35 Back Pressure: Total 3.00
FLUID DATA 36 % Allowable Overpressure 10.00%
37 Overpressure Factor 1.10
38 Compressibility Factor -
39 Latent Heat of Vaporization -
40 Ratio of Specific Heats -
41 Operating Viscosity 0.408
42 Barometric Pressure (PSIA)
43
44
45 Calc. Area sq. in. 0.234
46 Selected Area 0.307
47 Orifice Designation F
48 Manufacturer
49 Model No.
NOTES: Valve requires liquid capacity certification

© 1981 ISA ISA FORM S20.53

 Attachment 2
Client: Honeywell UOP - FHR Valve No.: PSV-0550
Project: Merox Module Description: Scrubbing Oxidizer & Caustic Heater
Location: FHR Corpus Christi, TX Calc By: ABW Date: 1/12/2015
Project No.: 0333.141311.20 Checked By: DL Date: 1/12/2015
P&ID No.: CW005F05006 Rev: B
ITEM POTENTIAL SIZING CASES COMMENTS
Adapted from API 520/521
1 BLOCK VALVE MISOPERATION Applicable - Blocked exit on Extractor will cause relief through LV-1534.

2 CHECK VALVE FAILURE Not applicable - There are no check valve overpressure scenarios.

Applicable - Wash oil control valve failure can cause overpressurization of

3 CONTROL VALVE MISOPERATION
downstream equipment.

4 EXCHANGER TUBE RUPTURE Not applicable - LP Steam on the tube side of the Caustic Heater cannot overpressure
EA-503.
5 BLOCKED EXITS Applicable - See "Block Valve Misoperation" comment.

6 FIRE Applicable - The Caustic Heater can be overpressured due to a fire

scenario.
7 INSTRUMENT AIR FAILURE Not applicable - Loss of instrument air will not cause a relief scenario.

8 INSTRUMENT POWER FAILURE Not applicable - Instrument power failure will not cause a relief scenario.

9 ELECTRIC POWER FAILURE Not applicable - No electric power overpressure scenarios.

10 STEAM FAILURE Not applicable - Loss of steam will not cause a relief scenario.

11 COOLING WATER FAILURE Not applicable - Cooling water failure will not cause a relief.

12 AIRFAN COOLER FAILURE Not applicable - No airfan cooler in this system.

13 CONDENSING DUTY FAILURE Not applicable - No condenser in this system.

14 REFLUX FAILURE Not applicable - No reflux involved.

15 ABSORBANT FLOW FAILURE Not applicable -- No absorbant in system.

16 LOSS OF REBOILER HEAT Not applicable -- No reboiler involved.

17 ACCUMULATION OF Not applicable - There is no accumulation of non-condensibles.

NON-CONDENSIBLES

18 ABNORMAL HEAT INPUT Not applicable - No source of abnormal heat input.

19 ABNORMAL VAPOR INPUT Not applicable - There are no scenarios for abnormally high vapor input rate.

20 ABNORMAL CHEMICAL REACTION Not applicable - No chemical reaction in this system.

21 EQUIPMENT SHUTDOWN Not applicable - Shutdown of equipment will not cause a relief.

22 HYDRAULIC EXPANSION Not applicable - There is no heat source to cause hydraulic expansion.

23 ENTRANCE OF VOLATILE LIQUID Not applicable - There is no source of volatile liquid in the system.

24 COMBINATION OF CAUSES Not applicable - There is no combination of causes that could cause relief.

HAR-CAL-EN-PR-005 Rev1
Company Confidential Control Valve Failure - Liquid Rate and Sizing Calcs
 Attachment 3

Client: Honeywell UOP - FHR Valve No.: PSV-0550

Project: Merox Module Description: Scrubbing Oxidizer
Location: FHR Corpus Christi, TX Calc By: ABW Date: 12/24/2014
Project No.: 0333.141311.20 Checked By: JO Date: 12/24/2014
P&ID No.: CW005F05006 Rev: A

Relieving Flow Rate through a Failed Open Control Valve

Liquid Wash Oil

Control Valve Tag No. 05-FV-0570
Source Pressure P1 285.0 PSIG From client

Set Pressure Pset 150.0 PSIG

Overpressure OP 10 %
Elevation H 0.0 FT Assume PRD at same elevation as PV

Downstream Pressure P2 165.00 PSIG

Relieving Temperature T1 100 °F
Specific Gravity G1 0.720 client

Valve Sizing Coefficient CV 6.67 Control valve + bypass valve

Volumetric Flow Rate Q 86.11 GPM

Q = C V * SQRT[(P 1 - P 2 )/G 1 ] Fisher Control Valve Handbook, 4th Ed., Pg. 114.

Mass Flow Rate Wm 31016.35 LB/HR

Notes:
1.
2.
3.
4.
5.
6.

HAR-CAL-EN-PR-005 Rev1
Company Confidential Control Valve Failure - Liquid Rate and Sizing Calcs
 Attachment 3
Client: Honeywell UOP - FHR Valve No.: PSV-0550
Project: Merox Module Description: Scrubbing Oxidizer
Location: FHR Corpus Christi, TX Calc By: ABW Date: 12/24/2014
Project No.: 0333.141311.20 Checked By: JO Date: 12/24/2014
P&ID No.: CW005F05006 Rev: A

Relieving Device Orifice Area -- Sizing for Liquid Relief

Equipment Name 05-FA-551
Fluid Wash Oil
Flow Rate Q 86.11 GPM Wm 31,016.35 LB/HR

Specific Gravity G1 0.720  44.91 LB/FT

3

Equipment MAWP MAWP 150.00 PSI

Set Pressure Pset 150.00 PSIG

Valve Type (B = Balanced / C = Conv.) B

Cold Differential Test Pressure CDTP 150.00 PSI

Overpressure OP 10.00 %
Allowable Back Pressure 10.00 %
Abs. Upstream Relieving Pressure P1 179.70 PSIA

Inlet Line Pressure Loss PIN 2.79 PSI From inlet line pressure drop calcs 2.79

Stagnation Pressure at PRD Inlet P1 INS 176.91 PSIA

Allow. Built-Up Back Pressure Pallow 15.00 PSIG

Superimposed Back Pressure PSBP 2.00 PSIG

Calc. Built-Up Back Pressure Pcalc 1.00 PSI From outlet pipe P calcs 1.00

Total Back Pressure P2 17.70 PSIA

% of Gauge Back Pressure 2.00 % For balanced bellows valves only.

Coefficient of Discharge Kd 0.650 API estimate

Back Pressure Correction Factor Kw 1.000 API RP 520, Part 1 - Figure 31

Viscosity Correction Factor Kv 1.000 See Reynold's Number Calculation Below

Combination Capacity Factor Kc 1.00 0.9 with rupture disk, 1.0 w/o rupture disk

2
Ac 0.234 in

API 520 8th Ed, Section [Link] (Eq. 28)

Reynold's Number Calculation

Fluid Viscosity μ= 0.408 cP
2
Orifice Area A= 0.307 IN F API

Q2800G1   2 . 878 342 . 75 

 1 .0

Re  767,912 K v   0 . 9935   
 A  Re 0 .5
Re 1 . 5 

Source: API 520, 8th Ed. Sect. 5.8 Eq. 30

1
K  0 . 975
If Nre < 76 → v
170
 0 . 98
N RE
Kv = 1.000
API 520 8th Ed, Section 5.8 (Eq. 31) Source: Darby and Molavi, Process Safety Progress, 16(2), 80 (1997)

HAR-CAL-EN-PR-005 Rev1
Company Confidential Control Valve Failure - Liquid Rate and Sizing Calcs
 Attachment 3
Client: Honeywell UOP - FHR Valve No.: PSV-0550
Project: Merox Module Description: Scrubbing Oxidizer
Location: FHR Corpus Christi, TX Calc By: ABW Date: 12/24/2014
Project No.: 0333.141311.20 Checked By: JO Date: 12/24/2014
P&ID No.: CW005F05006 Rev: A

Estimate Rated Capacity of Valve Selection

To complete Pressure Drop calculations it may be necessary to estimate the Rated Capacity (Qrated) of the valve that would be selected. The
Rated Capacity may be estimated below.
2
Aselected 0.307 in

Qrated 113.74 GPM

Wrated 40615.90 lb/hr

Notes:
1. calculate viscosity in pro II
2.
3.
4.
5.
6.
7.
8.
9.
10.

HAR-CAL-EN-PR-005 Rev1
Company Confidential Control Valve Failure - Liquid Rate and Sizing Calcs
 Attachment 4

Client: Honeywell UOP - FHR Valve No.: PSV-0550

Project: PSV Sizing Description: Scrubbing Oxidizer
Location: FHR Corpus Christi, TX Calc By: MB Date: 12/24/2014
Project No.: 0333.141311.20 Checked By: DL Date: 12/24/2014
P&ID No.: CW005F05008 Rev: A

Relieving Flow Rate through a Failed Open Control Valve

Liquid C4 Treater Extractor Inlet

Control Valve Tag No. 05-LV-1534
Source Pressure P1 198.4 PSIG See Note 1.

Set Pressure Pset 150.0 PSIG

Overpressure OP 10 %
Elevation H 49.0 FT Positive value because PSV is above LV - Note 4.

Downstream Pressure P2 176.92 PSIG See Note 3.

Relieving Temperature T1 102 °F

Specific Gravity G1 0.562 See Note 2.

Valve Sizing Coefficient CV 12.00 Preliminary. Combined Cv for LV + bypass valve

Volumetric Flow Rate Q 74.13 GPM

Q = C V * SQRT[(P 1 - P 2 )/G 1 ] Fisher Control Valve Handbook, 4th Ed., Pg. 114.

Mass Flow Rate Wm 20842.15 LB/HR

Notes:
1. Based on 180 psig (Op. Press. of C4 Treater Extractor) + liquid head. Elevation difference between extractor PT and LV is approx. 75.5'

2. Specific gravity from Pro/II model of fluid entering 05DA506 C4 Treater Extractor.

3. CV downstream pressure (P2) assumed to be equal to relief valve Pset + 10%. This neglects the pressure drop of any downstream in-line equipment.

4. 05-LV-1534 located on bottom floor (el. = 101' - 6") and PSV located one level above the top of Scrubbing-Oxidizer (el. = 150' - 6").

Page 1 of 4 HAR-CAL-EN-PR-005 Rev1

Company Confidential Extractor Blocked Outlet - PRD Fail Control Valve - Liquid
 Attachment 4

Client: Honeywell UOP - FHR Valve No.: PSV-0550

Project: Merox Module Description: Scrubbing Oxidizer
Location: FHS Corpus Chrisi, TX Calc By: MB Date: 12/24/2014
Project No.: 0333.141311.20 Checked By: DL Date: 12/24/2014
P&ID No.: CW005F05008 Rev: A

Relieving Flowrate for Subcooled Liquid at Inlet of Pressure Relief Valve (API Section C.2.3)
Fluid Hydrocarbon

Set Pressure Pset 150.0 PSIG

Upstream Relieving Press. Po=Pset * 1.10 165.0 PSIG Allowing for 10.0% Accumulation
Inlet Pressure P0 179.7 PSIA
Temperature at PRV Inlet T0 102.0 ˚F From Client - "Extractor Blocked Outlet" scenario

Valve Type (B = Balanced / C = Conv.) B

Super Imposed Back Pressure PSBP 2.0 PSIG Discharges to closed discharge system.
16.7 PSIA
Total Allow. Back Pressure Ptotalallow 45.0 PSIG = 0.30 * Set Pressure
59.7 PSIA
Allow. Built Up Back Pressure Pallow 43.0 PSI
Calc. Built Up Back Pressure Pcalc 20.8 PSI See Pro II Pressure Drop Calculations
Total Calc. Back Pressure Pa 37.5 PSIA

Critical Temperature Tc 295.9 ˚F See Pro II Flash Calculations

Critical Pressure Pc 566.7 PSIA See Pro II Flash Calculations
Vapor Pressure Ps 65.01 PSIA See Pro II Flash Calculations
Liquid Density rlo 35.07 lb/ft3 See Pro II Flash Calculations

Density at 90% of Sat. Press. r9 15.45 lb/ft3 See Pro II Flash Calculations

Relieving Flowrate for Blocked Outlet

Relieving Rate Qrequired 74.1 gpm See calculations for Required Relief Rate through Control Valve.
20,844.08 lb/hr

1. Calculate the Saturated Omega Parameter

 ρ 
ω s = 9  lo − 1 
 ρ9 
ws 11.43
API 520 9th Ed., Section C.2.3 (Eq. C.30)

Page 2 of 4
Page 1 of 3
 Attachment 4

Client: Honeywell UOP - FHR Valve No.: PSV-0550

Project: Merox Module Description: Scrubbing Oxidizer
Location: FHS Corpus Chrisi, TX Calc By: MB Date: 12/24/2014
Project No.: 0333.141311.20 Checked By: DL Date: 12/24/2014
P&ID No.: CW005F05008 Rev: A

2. Determine Subcooling Region

Ps ≥ hstPo Low Subcooling Region (Flashing occurs upstream of throat)

Ps < hstPo High Subcooling Region (Flashing occurs at throat)
API 520 9th Ed., Section C.2.3 (Eq. C.31)
2ω s
η st
=
1 + 2ω s hst 0.96
API 520 9th Ed., Section C.2.3 (Eq. C.32) hstP0 172.16 High Subcooling Region Use C.42

3. Determine Critical or Subcritical Flow

Low Subcooling Region: High Subcooling Region:

Pc ≥ Pa Critical Flow Ps ≥ Pa
Pc < Pa Subcritical Flow Ps < Pa
API 520 9th Ed., Section C.2.3 (Eq. C.33) API 520 9th Ed., Section C.2.3 (Eq. C.34)
Critical Flow use Psat for P

4. Calculate the Mass Flux

Equation C.41
Saturation Pressure Ratio hs=Ps/P0 NA API 520 9th Ed., Section C.2.3 (Eq. C.39)

Critical Pressure Ratio hc NA

NA
2 1 21

 
   1 1 
21
 2
API 520 9th Ed., Section C.2.3 (Eq. C.38)

Subcritical Pressure Ratio ha=Pa/Po NA API 520 9th Ed., Section C.2.3 (Eq. C.40)

Omega Parameter ws NA
Liquid Density rlo NA lb/ft3

Upstream Relieving Press. P0 NA PSIA

 η   2

68 .09 2(1 − η c ) + 2 ω sη s ln  s  − (ω s − 1)(η s − η )

G NA lb/s-ft2
 η  
G= Po ρ lo
 ηs 
ω s  − 1 + 1
η 
API 520 9th Ed., Section C.2.3 (Eq. C.41)

Equation C.42
Liquid Density rlo 35.07 lb/ft3

Upstream Relieving Press. P0 179.70 PSIA

Pressure P 65.01 PSIA Critical Flow Psat = P
1
G = 96.3[ρlo (Po − P)]2 G 6107.7 lb/s-ft2

API 520 9th Ed., Section C.2.3 (Eq. C.42)

Page 3 of 4
Page 2 of 3
 Attachment 4

Client: Honeywell UOP - FHR Valve No.: PSV-0550

Project: Merox Module Description: Scrubbing Oxidizer
Location: FHS Corpus Chrisi, TX Calc By: MB Date: 12/24/2014
Project No.: 0333.141311.20 Checked By: DL Date: 12/24/2014
P&ID No.: CW005F05008 Rev: A

5. Calculate Relieving Device Orifice Required Area

Relieving Rate Qrequired 74.1 GPM

Liquid Density rlo 35.07 lb/ft3

Effective Coefficient of Discharge Kd 0.65

Back Pressure Correction Factor Kb 1.0 Conventional = 1.0, Bellows See Figure D.4 or Manuf. Data
Viscocity Correction Factor Kv 1.0
Mass Flux G 6107.7 lb/s-ft2

Qρ lo
A = 0.3208 in2
K d K b K vG Arequired 0.2092
API 520 9th Ed., Section C.2.3 (Eq. C.45)

Reynold's Number Calculation

Fluid Viscosity µ 0.15 cP See Pro II Flash Calculations
Area (Select API Std Orifice Area) A 0.307 in2 Kv 1.004 lb/ft-sec
where
Q(2800G1 ) − 1 .0
Re = 1,403,150  2 . 878 342 . 75 
µ A K v =  0 . 9935 + 0 .5
+ 
 Re Re 1 .5 
API 520 9th Ed, Section 5.8 (Eq. 31) API 520 9th Ed, Section 5.8 (Eq. 30)

Optional - Estimate Rated Capacity of Valve Selection

To complete Pressure Drop calculations it may be necessary to estimate the Rated Capacity (Qrated) of the valve that would be selected. Using API
Standard orifice sizes, the Rated capacity may be estimated below. Use data from the Vendor Supplied Data Sheet when available.

Preliminary Estimation Vendor Data Sheet

Aselected 0.307 in2 Avendor in2 ASME

Qrated 108.77 GPM Qvendorated GPM

W rated 30595 lb/hr Wvendorrated lb/hr

Page 4 of 4
Page 3 of 3
 Attachment 5
Customer: Honeywell UOP - FHR
Device: Scrubbing Oxidizer Project: Merox Module
Tag No: PSV-0550 Project No.: 0333.141311.20
Associated Equip. No.: Calculated by: ABW
Date: 12/24/2014

Equip. Name: 05-FA-551 Pressure Relief Valve Checked by: JO

P&ID No: CW005F05006 Inlet Pipe Pressure Drop Date: 12/24/2014

Single Phase - Liquid Revision: A

DETERMINATION OF MAXIMUM RATED FLOW: SINGLE PHASE LIQUID

Pressure Drop Flow Rate 40,613.19 LBS/HR

Pressure loss estimate from alternate source 0.00 PSI

Calculated Pressure Drop Inlet to PRD 2.79 PSI From segment pressure loss calculations
PRESSURE DROP VS. ALLOWED 3%: SINGLE PHASE LIQUID
Set Pressure of PRD 150.00 PSIG
Allowable Pressure Drop @ 3% of Pset 4.50 PSI Pressure Drop IS Acceptable
Total Pressure Drop for Inlet Line 2.79 PSI
Total Pressure Drop as Percentage of Pset 1.86 %

Notes:
1.
2.
3.
4.
5.
6.

HAR-CAL-EN-PR-005 Rev1
Company Confidential Control Valve Failure - Liquid Rate and Sizing Calcs
 Attachment 6
Customer: Honeywell UOP - FHR
Device: Scrubbing Oxidizer Project: Merox Module
Tag No: PSV-0550 Project No.: 0333.141311.20
Associated Equip. No.: Calculated by: ABW
Date: 12/24/2014
Equip. Name: 05-FA-551 Pressure Relief Valve Checked by: JO

P&ID No: CW005F05006 Inlet Pipe Pressure Drop Date: 12/24/2014

Segment 1 Liquid Revision: A

DETERMINATION OF MAXIMUM RATED FLOW: SINGLE PHASE LIQUID

Valve Set Pressure, PSIG: PSET 150.00
Calculated Required Valve Flow Rate, LB/HR: Wreq 31,014.28
Rated Valve Flow Rate, LB/HR: Wrate 40,613.19 Estimated: Wrate = Wreq * Area Selected / Area Calculated
Flow Rate Factor FRF 1.00
Derated Flow Rate, LB/HR: WFRF 40,613.19
Pressure Drop Flow Rate, LB/HR: W 40,613.19

WFRF = FRF * Wrate Blank cells >> Input

Shaded cells >>Calculated

PIPE SECTION DATA

Variables
Pressure Drop Flow Rate, GPM QGPM 112.76
Fluid Specific Gravity s.g. 0.720
Fluid Density, LB/FT3 r 44.91
Pressure Drop Flow Rate, LB/HR W 40,613.19
3
Volumetric Flow Rate, FT /MIN Q 15.07
Pipe Internal Diameter, IN d1 1.939 2" Sch 80
Fluid Viscosity, cP m 0.41

9 .6  Q
V  = 12.25 = Pipe velocity, ft/s
  d 12

124.01Vd1 
N Re  = 324,232 = Reynolds number

Flow Result >> Flow is TURBULENT. Use Moody friction factor

Exit Pipe Internal Diameter, IN d2 1.500 For reducers or enlargers only -- 1.5" sch 80
Total Straight Pipe Length, FT L 11.80
Pipe Section Elevation Change, FT hL 0.00 Recoverable Friction/Pressure losses are not included in PRD ∆P Calculations
Absolute Pipe Roughness, FT  0.00015
Relative Pipe Roughness /D 0.00093
1.324
f  2
  / D  7 
0 .9
 = 0.020 Moody friction factor [Churchill correlation (1976)]
 Ln     
  3.7  N Re  



0.020 Friction factor to use

L  12
K p  f = 1.49 = K for straight pipe
d1

HAR-CAL-EN-PR-005 Rev1
Company Confidential Control Valve Failure - Liquid Rate and Sizing Calcs
 Attachment 6
Customer: Honeywell UOP - FHR
Device: Scrubbing Oxidizer Project: Merox Module
Tag No: PSV-0550 Project No.: 0333.141311.20
Associated Equip. No.: Calculated by: ABW
Date: 12/24/2014
Equip. Name: 05-FA-551 Pressure Relief Valve Checked by: JO

P&ID No: CW005F05006 Inlet Pipe Pressure Drop Date: 12/24/2014

Segment 1 Liquid Revision: A

TWO-K PRESSURE DROP CALCULATION Chemical Engineering, August 1981

Fittings Number K1 Number x K1 Kinf Number x Kinf

Elbow 90 deg, screwed 800 0.4 Standard Short radius, R/D=1

Elbow 90 deg, flanged/welded 2 800 1600 0.25 0.5 Standard Short radius, R/D=1
Elbow 90 deg, all long radius 800 0.2 Long radius, R/D=1.5
Elbow 45 deg, std all types 500 0.2 Standard Short radius, R/D=1
Elbow 45 deg, all long radius 500 0.15 Long radius, R/D=1.5
Elbow 180 deg, screwed 1000 0.6 Standard Short radius, R/D=1
Elbow 180 deg, flanged/weld 1000 0.35 Standard Short radius, R/D=1
Elbow 180 deg, all long radius 1000 0.3 Long radius, R/D=1.5
Tee branch, screwed 500 0.7 Standard
Tee branch, scwd long radius 800 0.4
Tee branch, flanged/welded 800 0.8 Standard
Tee branch, stub-in type 1000 1.0
Tee run-thru, screwed 200 0.1
Tee run-thru, flanged/welded 1 150 150 0.5 0.5
Tee run-thru, stub-in 100 0
Valves
Gate 1 300 300 0.1 0.1 Full line size, B=1.0
Ball 500 0.15 Reduced trim, B=0.9
Plug 1000 0.25 Reduced trim, B=0.8
Globe 1500 4.00 Standard
Globe, angle or Y-type 1000 2.00
Butterfly 800 0.25
Lift Check 2000 10.00
Swing Check 1500 1.50
Tilting Disk Check 1000 0.50
Diaphragm 1000 2.00
K1 Total 2050 Kinf Total 1.1

Entrance & Exit, Kin/out

Pipe entrance, "Normal" 1 160 160 0.5 0.5 Square-edged entrance
Pipe entrance, "Borda" 160 1 Inward-projecting entrance
Pipe exit 0 0 1.00
K1 Total 160 Kinf Total 0.5

Misc. Items, Kother

Rupture disc (blown) Manufacturer's K for blown rupture disk.
Pipe reducer 1
Pipe enlarger

HAR-CAL-EN-PR-005 Rev1
Company Confidential Control Valve Failure - Liquid Rate and Sizing Calcs
 Attachment 6
Customer: Honeywell UOP - FHR
Device: Scrubbing Oxidizer Project: Merox Module
Tag No: PSV-0550 Project No.: 0333.141311.20
Associated Equip. No.: Calculated by: ABW
Date: 12/24/2014
Equip. Name: 05-FA-551 Pressure Relief Valve Checked by: JO

P&ID No: CW005F05006 Inlet Pipe Pressure Drop Date: 12/24/2014

Segment 1 Liquid Revision: A

KR = 0.00 = K for Rupture disc

50   d1 
4
 
K pr  0.1      1 = 0.18 = K for Pipe reducer
 N Re  
 2
d  

 2 2
 d   
K pe  1  0.8 f   1   1    = 0.00 = K for Pipe enlarger
   d2   
 
0.18 = Kother (Sum of Misc. Items)

K1  1 
K vf   K inf 1   = 1.67 = Kvf for valves and fittings per Two-K method
N Re  d 1 

K1
K in / out   K = 0.50 = Kin/out for entrance & exit per Two-K method
N Re

Kt = Kvf + Kp + Kin/out + Kother = 3.84 = Kt for resistance coefficient total

hL  
PhL  = 0.00 = Elevation change pressure drop, psi
144
2
K tW
P  0.00000028  PhL = 2.79 = Pressure Drop for Section Pipe, Valves,
  d1 4 Fittings & Elevation Change; psi

INLINE EQUIPMENT AND INSTRUMENTATION

Inline equipment total, psi Manufacturer's literature, calculation aids or other spreadsheets
Inline instrumentation total, psi Manufacturer's literature, calculation aids or other spreadsheets

2.79 Total Section Pressure Drop, psi

HAR-CAL-EN-PR-005 Rev1
Company Confidential Control Valve Failure - Liquid Rate and Sizing Calcs
 Attachment 7
Customer: Honeywell UOP - FHR
Device: Scrubbing Oxidizer Project: Merox Module
Tag No: PSV-0550 Project No.: 0333.141311.20
Associated Equip. No.: Calculated by: ABW
Date: 12/24/2014

Equip. Name: 05-FA-551 Pressure Relief Device Checked by: JO

P&ID No: CW005F05006 Discharge Pipe P Date: 12/24/2014

Single Phase - Liquid Revision: A

RATED FLOW:

Rated Flow Through Discharge Pipe 40,613.19 LBS/HR

Pressure loss estimate from alternate source 0.00 PSI
Calculated Variable Back Pressure on PRD 1.00 PSI From pipe segment pressure drop calculations
PRESSURE DROP VS. SET PRESSURE OF VALVE
Variables
Is the valve conventional or balanced? B Entered on PRD Orifice Sizing Liq spreadsheet.
Set Pressure of Valve, psig Ps 150.00 PSIG
Permissible Back Pressure as % of Set Pressure 10.00 % Typically 10% for Conventional and 40% for Balanced
Permissible Back Pressure 15.00 PSIG
Superimposed Back Pressure 2.00 PSIG
Calculated Built-up Back Pressure 1.00 PSI
Calculated Total Back Pressure 3.00 PSIG
Built-up Back Pressure Ratio 0.67 %
Total Back Pressure Ratio 2.00 % Back pressure is acceptable for a Balanced PRD

Notes:
1.
2.
3.
4.
5.
6.
7.
8.

HAR-CAL-EN-PR-005 Rev1
Company Confidential Control Valve Failure - Liquid Rate and Sizing Calcs
 Attachment 8
Customer: Honeywell UOP - FHR
Device: Scrubbing Oxidizer Project: Merox Module
Tag No: PSV-0550 Project No.: 0333.141311.20
Associated Equip. No.: Calculated by: ABW
Date: 12/24/2014
Equip. Name: 05-FA-551 Pressure Relief Valve Checked by: JO

P&ID No: CW005F05006 Discharge Pipe Pressure Drop Date: 12/24/2014

Segment 1 Liquid Revision: A

DETERMINATION OF MAXIMUM RATED FLOW: SINGLE PHASE LIQUID

Valve Set Pressure, PSIG: PSET 150.00
Calculation Basis 2 Input 1 for Wreq and 2 for Wrate
Calculated Required Valve Flow Rate, LB/HR: Wreq 31,014.28 See Scenario Calculation
Rated Valve Flow Rate, LB/HR: Wrate 40,613.19 Estimated: Wrate = Wreq * Area Selected / Area Calculated
Flow Rate Factor FRF 1.00
Derated Flow Rate, LB/HR: WFRF 40,613.19
Additional Flow, LB/HR: WADD 0.00
Pressure Drop Flow Rate, LB/HR W 40,613.19

WFRF = FRF * Wrate Blank cells >> Input

Shaded cells >>Calculated

PIPE SECTION DATA

Variables
Pressure Drop Flow Rate, GPM QGPM 112.76
Fluid Specific Gravity s.g. 0.720 Fluid properties
Fluid Density, LB/FT3  44.91
Mass Flow Rate, LB/HR W 40,613.19
Volumetric Flow Rate, FT3/MIN Q 15.07
Pipe Internal Diameter, IN d1 2.067 2" Sch 40
Fluid Viscosity, cP  0.41 Fluid properties

9 .6  Q
V  = 10.78 = Pipe velocity, ft/s
  d 12

124.01Vd1 
N Re  = 304,154 = Reynolds number

Flow Result >> Flow is TURBULENT. Use Moody friction factor

Exit Pipe Internal Diameter, IN d2 3.068 For reducers or enlargers only -- 3" Sch 40
Total Straight Pipe Length, FT L
Pipe Section Elevation Change, FT hL 0.00
Absolute Pipe Roughness, FT  0.00015
Relative Pipe Roughness D 0.00087

1.324
f  2 = 0.020 Moody friction factor [Churchill correlation (1976)]
  / D  7 
0.9

 Ln    
  3.7  N Re  


0.020 Friction factor to use
L  12
K p  f = 0 = K for straight pipe
d1

HAR-CAL-EN-PR-005 Rev1
Company Confidential Control Valve Failure - Liquid Rate and Sizing Calcs
 Attachment 8
Customer: Honeywell UOP - FHR
Device: Scrubbing Oxidizer Project: Merox Module
Tag No: PSV-0550 Project No.: 0333.141311.20
Associated Equip. No.: Calculated by: ABW
Date: 12/24/2014
Equip. Name: 05-FA-551 Pressure Relief Valve Checked by: JO

P&ID No: CW005F05006 Discharge Pipe Pressure Drop Date: 12/24/2014

Segment 1 Liquid Revision: A

TWO- K PRESSURE DROP CALCULATION Chemical Engineering, August 1981

Fittings Number K1 Number x K1 Kinf Number x Kinf

Elbow 90 deg, screwed 800 0.4 Standard Short radius, R/D=1

Elbow 90 deg, flanged/welded 800 0.25 Standard Short radius, R/D=1
Elbow 90 deg, all long radius 800 0.2 Long radius, R/D=1.5
Elbow 45 deg, std all types 500 0.2 Standard Short radius, R/D=1
Elbow 45 deg, all long radius 500 0.15 Long radius, R/D=1.5
Elbow 180 deg, screwed 1000 0.6 Standard Short radius, R/D=1
Elbow 180 deg, flanged/weld 1000 0.35 Standard Short radius, R/D=1
Elbow 180 deg, all long radius 1000 0.3 Long radius, R/D=1.5
Tee branch, screwed 500 0.7 Standard
Tee branch, scwd long radius 800 0.4
Tee branch, flanged/welded 800 0.8 Standard
Tee branch, stub-in type 1000 1.0
Tee run-thru, screwed 200 0.1
Tee run-thru, flanged/welded 150 0.5
Tee run-thru, stub-in 100 0
Valves
Gate 300 0.1 Full line size, B=1.0
Ball 500 0.15 Reduced trim, B=0.9
Plug 1000 0.25 Reduced trim, B=0.8
Globe 1500 4.00 Standard
Globe, angle or Y-type 1000 2.00
Butterfly 800 0.25
Lift Check 2000 10.00
Swing Check 1500 1.50
Tilting Disk Check 1000 0.50
Diaphragm 1000 2.00
K1 Total 0 Kinf Total 0

Entrance & Exit, Kin/out

Pipe entrance, "Normal" 160 0.5 Square-edged entrance
Pipe entrance, "Borda" 160 1 Inward-projecting entrance
Pipe exit 0 0 1.00
K1 Total 0 Kinf Total 0

Misc. Items, Kother

Rupture disc (blown) Manufacturer's K for blown rupture disk.
Pipe reducer
Pipe enlarger 1

HAR-CAL-EN-PR-005 Rev1
Company Confidential Control Valve Failure - Liquid Rate and Sizing Calcs
 Attachment 8
Customer: Honeywell UOP - FHR
Device: Scrubbing Oxidizer Project: Merox Module
Tag No: PSV-0550 Project No.: 0333.141311.20
Associated Equip. No.: Calculated by: ABW
Date: 12/24/2014
Equip. Name: 05-FA-551 Pressure Relief Valve Checked by: JO

P&ID No: CW005F05006 Discharge Pipe Pressure Drop Date: 12/24/2014

Segment 1 Liquid Revision: A

KR = 0.00 = K for Rupture disc

50   d1 
4
 
K pr  0.1      1 =
N Re   d 2
0.00 = K for Pipe reducer
   

 2

2

 d  
K pe  1  0.8 f  1   1    = 0.30 = K for Pipe enlarger
   d2   
 
0.30 = Kother (Sum of Misc. Items)

K1  1  =
K vf   K inf 1   0.00 = Kvf for valves and fittings per Two-K method
N Re  d 1 

K1
K in / out   K = 0.00 = Kin/out for entrance & exit per Two-K method
N Re

Kt = Kvf + Kp + Kin/out + Kother = 0.30 = Kt for resistance coefficient total

hL  
PhL  = 0.00 = Elevation change pressure drop, psi
144
2
K tW
P  0.00000028  PhL = 0.17 = Pressure Drop for Section Pipe, Valves,
  d1 4 Fittings & Elevation Change; psi

INLINE EQUIPMENT AND INSTRUMENTATION

Inline equipment total, psi Manufacturer's literature, calculation aids or other spreadsheets
Inline instrumentation total, psi Manufacturer's literature, calculation aids or other spreadsheets

0.17 Total Section Pressure Drop, psi

HAR-CAL-EN-PR-005 Rev1
Company Confidential Control Valve Failure - Liquid Rate and Sizing Calcs
 Attachment 8
Customer: Honeywell UOP - FHR
Device: Scrubbing Oxidizer Project: Merox Module
Tag No: PSV-0550 Project No.: 0333.141311.20
Associated Equip. No.: Calculated by: ABW
Date: 12/24/2014
Equip. Name: 05-FA-551 Pressure Relief Valve Checked by: JO

P&ID No: CW005F05006 Discharge Pipe Pressure Drop Date: 12/24/2014

Segment 2 Liquid Revision: A

DETERMINATION OF MAXIMUM RATED FLOW: SINGLE PHASE LIQUID

Valve Set Pressure, PSIG: PSET 150.00
Calculation Basis 2 Input 1 for Wreq and 2 for Wrate
Calculated Required Valve Flow Rate, LB/HR: Wreq 31,014.28 See Scenario Calculation
Rated Valve Flow Rate, LB/HR: Wrate 40,613.19 Estimated: Wrate = Wreq * Area Selected / Area Calculated
Flow Rate Factor FRF 1.00
Derated Flow Rate, LB/HR: WFRF 40,613.19
Additional Flow, LB/HR: WADD 0.00
Pressure Drop Flow Rate, LB/HR W 40,613.19

WFRF = FRF * Wrate Blank cells >> Input

Shaded cells >>Calculated

PIPE SECTION DATA

Variables
Pressure Drop Flow Rate, GPM QGPM 112.76
Fluid Specific Gravity s.g. 0.720 Fluid properties
Fluid Density, LB/FT3  44.91
Mass Flow Rate, LB/HR W 40,613.19
Volumetric Flow Rate, FT3/MIN Q 15.07
Pipe Internal Diameter, IN d1 3.068 3" Sch 40
Fluid Viscosity, cP  0.41 Fluid properties

9 .6  Q
V  = 4.89 = Pipe velocity, ft/s
  d 12

124.01Vd1 
N Re  = 204,917 = Reynolds number

Flow Result >> Flow is TURBULENT. Use Moody friction factor

Exit Pipe Internal Diameter, IN d2 For reducers or enlargers only

Total Straight Pipe Length, FT L 45.92
Pipe Section Elevation Change, FT hL 0.00
Absolute Pipe Roughness, FT  0.00015
Relative Pipe Roughness D 0.00059

1.324
f  2 = 0.019 Moody friction factor [Churchill correlation (1976)]
  / D  7 
0.9

 Ln    
  3.7  N Re  


0.019 Friction factor to use
L  12
K p  f = 3 = K for straight pipe
d1

HAR-CAL-EN-PR-005 Rev1
Company Confidential Control Valve Failure - Liquid Rate and Sizing Calcs
 Attachment 8
Customer: Honeywell UOP - FHR
Device: Scrubbing Oxidizer Project: Merox Module
Tag No: PSV-0550 Project No.: 0333.141311.20
Associated Equip. No.: Calculated by: ABW
Date: 12/24/2014
Equip. Name: 05-FA-551 Pressure Relief Valve Checked by: JO

P&ID No: CW005F05006 Discharge Pipe Pressure Drop Date: 12/24/2014

Segment 2 Liquid Revision: A

TWO- K PRESSURE DROP CALCULATION Chemical Engineering, August 1981

Fittings Number K1 Number x K1 Kinf Number x Kinf

Elbow 90 deg, screwed 800 0.4 Standard Short radius, R/D=1

Elbow 90 deg, flanged/welded 4 800 3200 0.25 1 Standard Short radius, R/D=1
Elbow 90 deg, all long radius 800 0.2 Long radius, R/D=1.5
Elbow 45 deg, std all types 2 500 1000 0.2 0.4 Standard Short radius, R/D=1
Elbow 45 deg, all long radius 500 0.15 Long radius, R/D=1.5
Elbow 180 deg, screwed 1000 0.6 Standard Short radius, R/D=1
Elbow 180 deg, flanged/weld 1000 0.35 Standard Short radius, R/D=1
Elbow 180 deg, all long radius 1000 0.3 Long radius, R/D=1.5
Tee branch, screwed 500 0.7 Standard
Tee branch, scwd long radius 800 0.4
Tee branch, flanged/welded 800 0.8 Standard
Tee branch, stub-in type 1000 1.0
Tee run-thru, screwed 200 0.1
Tee run-thru, flanged/welded 1 150 150 0.5 0.5
Tee run-thru, stub-in 100 0
Valves
Gate 1 300 300 0.1 0.1 Full line size, B=1.0
Ball 500 0.15 Reduced trim, B=0.9
Plug 1000 0.25 Reduced trim, B=0.8
Globe 1500 4.00 Standard
Globe, angle or Y-type 1000 2.00
Butterfly 800 0.25
Lift Check 2000 10.00
Swing Check 1500 1.50
Tilting Disk Check 1000 0.50
Diaphragm 1000 2.00
K1 Total 4650 Kinf Total 2

Entrance & Exit, Kin/out

Pipe entrance, "Normal" 160 0.5 Square-edged entrance
Pipe entrance, "Borda" 160 1 Inward-projecting entrance
Pipe exit 1 0 0 1.00 1
K1 Total 0 Kinf Total 1

Misc. Items, Kother

Rupture disc (blown) Manufacturer's K for blown rupture disk.
Pipe reducer
Pipe enlarger

HAR-CAL-EN-PR-005 Rev1
Company Confidential Control Valve Failure - Liquid Rate and Sizing Calcs
 Attachment 8
Customer: Honeywell UOP - FHR
Device: Scrubbing Oxidizer Project: Merox Module
Tag No: PSV-0550 Project No.: 0333.141311.20
Associated Equip. No.: Calculated by: ABW
Date: 12/24/2014
Equip. Name: 05-FA-551 Pressure Relief Valve Checked by: JO

P&ID No: CW005F05006 Discharge Pipe Pressure Drop Date: 12/24/2014

Segment 2 Liquid Revision: A

KR = 0.00 = K for Rupture disc

50   d1 
4
 
K pr  0.1      1 =
N Re   d 2
0.00 = K for Pipe reducer
   

 2

2

 d  
K pe  1  0.8 f  1   1    = 0.00 = K for Pipe enlarger
   d2   
 
0.00 = Kother (Sum of Misc. Items)

K1  1  =
K vf   K inf 1   2.67 = Kvf for valves and fittings per Two-K method
N Re  d 1 

K1
K in / out   K = 1.00 = Kin/out for entrance & exit per Two-K method
N Re

Kt = Kvf + Kp + Kin/out + Kother = 7.14 = Kt for resistance coefficient total

hL  
PhL  = 0.00 = Elevation change pressure drop, psi
144
2
K tW
P  0.00000028  PhL = 0.83 = Pressure Drop for Section Pipe, Valves,
  d1 4 Fittings & Elevation Change; psi

INLINE EQUIPMENT AND INSTRUMENTATION

Inline equipment total, psi Manufacturer's literature, calculation aids or other spreadsheets
Inline instrumentation total, psi Manufacturer's literature, calculation aids or other spreadsheets

0.83 Total Section Pressure Drop, psi

HAR-CAL-EN-PR-005 Rev1
Company Confidential Control Valve Failure - Liquid Rate and Sizing Calcs
 Attachment 9

Flash Calculation at 90% of Psat:

90_VAP Flash Name 90_FLASH

Flash Description
90_PSAT
INLET Temperature F 95.2856
90_LIQ
Pressure PSIA 58.5060
90_MIX DP PSI 121.1940
90_FLASH Duty MM BTU/HR -0.0138

Stream Name INLET 90_VAP 90_LIQ 90_PSAT

Stream Phase Liquid Vapor Liquid Mixed
Temperature F 102.000 95.286 95.286 95.286
Pressure PSIA 179.700 58.506 58.506 58.506
Boiling Point Pressure at Stream T PSIA 65.0067 67.3748 58.5059 58.7095
Boiling Point Temperature at Stream P F 179.3212 85.9937 95.2857 95.0597
Total Crit. Temperature (Kay's Rule) F 295.868 286.478 296.090 295.868
Total Crit. Pressure (Kay's Rule) PSIA 566.718 569.372 566.655 566.718
Total Mass Rate LB/HR 21904.107 495.396 21408.711 21904.107
Total Actual Density LB/FT3 35.073 0.611 35.293 15.455
Total Molecular Weight 57.194 56.119 57.219 57.194
Total Sp. Enthalpy BTU/LB 40.166 185.145 36.169 39.539
Vapor Mass Rate LB/HR n/a 495.396 n/a 495.396
Vapor Act. Vol. Rate FT3/HR n/a 810.6602 n/a 810.6602
Vapor Mole Fraction 0.0000 1.0000 0.0000 0.0230
Vapor Molecular Weight n/a 56.119 n/a 56.119
Vapor Act. Density LB/FT3 n/a 0.611 n/a 0.611
Vapor Std. Density LB/FT3 n/a 0.148 n/a 0.148
Vapor Viscosity CP n/a 0.00803 n/a 0.00803
Vapor Sp. Enthalpy BTU/LB n/a 185.145 n/a 185.145
Vapor Z (from k) n/a 0.90214 n/a 0.90214
Vapor Z (from density) n/a 0.9021 n/a 0.9021
Vapor CP/CV Ratio n/a 1.1382 n/a 1.1382
Liquid Mass Rate LB/HR 21904.107 n/a 21408.711 21408.711
Liquid Act. Rate (vol) FT3/HR 624.5332 n/a 606.5945 606.5945
Total Liquid Mole Fraction 1.0000 0.0000 1.0000 0.9770
Liquid Molecular Weight 57.194 n/a 57.219 57.219
Liquid Act. Density LB/FT3 35.073 n/a 35.293 35.293
Liquid Std. Density LB/FT3 36.839 n/a 36.851 36.851
Liquid Viscosity CP 0.14779 n/a 0.15201 0.15201
Liquid Sp. Enthalpy BTU/LB 40.166 n/a 36.169 36.169

Two-Phase Pressure Drop Calculations:

PSV_VAP
PSV_OUT_1 TO_FLARE
PSV_IN_1 PSV_IN_2
PSV_OUT_DP1
Calculation Steps:
PSV_LIQ PSV_MIX
PSV_IN_DP1 1) Modify stream PSV_IN_1 pressure until stream
PSV_FLASH
PSV_IN_2 (PSV inlet) pressure = P0, Inlet Pressure

Stream Name PSV_IN_1 PSV_IN_2 PSV_VAP PSV_LIQ PSV_OUT_1 TO_FLARE INLET_PRESS

Stream Phase Liquid Liquid Vapor Liquid Mixed Mixed 2) Modify stream PSV_IN_1 temperature until stream
Temperature F 102.000 102.002 68.824 68.824 68.824 27.020
Pressure PSIA 180.396 178.939 37.518 37.518 37.518 16.696 PSV_IN_2 (PSV inlet) temperature = T0, Inlet Temperature
Boiling Point Pressure at Stream T PSIA 65.0067 65.0087 44.0491 37.5176 38.2722 17.6001 INLET_TEMP
Boiling Point Temperature at Stream P F 179.6553 178.9548 59.3089 68.8238 67.6567 24.4368
Total Crit. Temperature (Kay's Rule) F 295.868 295.868 286.847 297.048 295.868 295.868
Total Crit. Pressure (Kay's Rule) PSIA 566.718 566.718 568.826 566.442 566.718 566.718 3) Modify unit PSV_FLASH pressure until stream

Total Mass Rate LB/HR 30595.000 30595.000 3476.372 27118.628 30595.000 30595.000 TO_FLARE pressure = Psbp, Super Imposed Back Pressure
Total Actual Density LB/FT3 35.073 35.072 0.400 36.534 3.242 0.759
BACK_PRESS
Total Molecular Weight 57.194 57.194 56.190 57.325 57.194 57.194
Total Sp. Enthalpy BTU/LB 40.167 40.167 176.648 21.242 38.900 38.899
Pipe Name PSV_IN_DP1PSV_OUT_DP1
Vapor Mass Rate LB/HR n/a n/a 3476.372 n/a 3476.373 7423.085 Pipe Description
Vapor Act. Vol. Rate FT3/HR n/a n/a 8695.7210 n/a 8695.7213 39679.0915
Total Pressure Drop PSI 1.4562 20.8216
Vapor Mole Fraction 0.0000 0.0000 1.0000 0.0000 0.1157 0.2465
Line Inside Diameter IN 2.0670 3.0680
Vapor Molecular Weight n/a n/a 56.190 n/a 56.190 56.297 Absolute Line Roughness ft 0.0002 0.0002
Vapor Act. Density LB/FT3 n/a n/a 0.400 n/a 0.400 0.187 Fitting Resistance Coefficient n/a n/a
Vapor Std. Density LB/FT3 n/a n/a 0.148 n/a 0.148 0.148 Line Length FT 31.4000 112.6000
Vapor Viscosity CP n/a n/a 0.00765 n/a 0.00765 0.00704 Average Velocity FT/SEC 10.3986 92.4041
Vapor Sp. Enthalpy BTU/LB n/a n/a 176.648 n/a 176.648 163.165 Average Line Friction Factor 0.0195 0.0286
Vapor Z (from k) n/a n/a 0.92975 n/a 0.92975 0.96196
Vapor Z (from density) n/a n/a 0.9298 n/a 0.9298 0.9620
Vapor CP/CV Ratio n/a n/a 1.1298 n/a 1.1298 1.1241 Flash Name PSV_FLASH
Flash Description
Liquid Mass Rate LB/HR 30595.000 30595.000 n/a 27118.628 27118.627 23171.915
Liquid Act. Rate (vol) FT3/HR 872.3132 872.3493 n/a 742.2829 742.2829 604.5819 Temperature F 68.8238
Total Liquid Mole Fraction 1.0000 1.0000 0.0000 1.0000 0.8843 0.7535 Pressure PSIA 37.5176
Liquid Molecular Weight 57.194 57.194 n/a 57.325 57.325 57.487 DP PSI 141.4218
Liquid Act. Density LB/FT3 35.073 35.072 n/a 36.534 36.534 38.327 Duty MM BTU/HR -0.0388
Liquid Std. Density LB/FT3 36.839 36.839 n/a 36.900 36.900 36.983
Liquid Viscosity CP 0.14779 0.14779 n/a 0.17058 0.17058 0.20840
Liquid Sp. Enthalpy BTU/LB 40.167 40.167 n/a 21.242 21.242 -0.909

Page 1 of 1
 Attachment 10
Customer: Honeywell UOP - FHR
Device: PSV-0550 Project: Merox Module
Tag No: PSV-0550 Project No.: 0333.141311.20
Associated Equip. No.: EA-503 Calculated by: ABW
Equip. Name: Caustic Heater Date: 1/12/15
Checked by: DL

P&ID No: CW005F05008 Fire Relief Load Date: 1/12/15

Revision: A

Pressure Relief Device Calculation: External Fire

Determination of Exposed Surface Area -- Horizontal Cylindrical Vessels Only

Vessel Name or ID Caustic Heater, EA-503

Liquid in Vessel Caustic
Is Vessel Full? Yes YES / NO

Is Vessel a Heat Exchanger? Yes YES / NO Area of shell only in calculations.

Vessel Diameter D 0.3 FT

Vessel T/T Length L 24.33 FT

Vessel Head Type Flat(Flanged

Flat (Flanged Only)
Only)

Vertical Height Limit for Fire Input 25 FT

Vessel Elevation from Solid Surface h₁ 0 FT at grade

Eccentricity  For 2:1 elliptical head only.

Liquid Level L1 0.333333333 FT

Height for Calculation E 0.33 FT

Fraction of Vessel Height = E/D FV 1.00 FT

Fire Coverage FULL

Determine Surface Area of Heads Only

FULL PARTIAL

Flat Heads Full: A F = πD 2 /2 FT2 FT2

Partial: A F = D 2 /2 * [π/2 - arcsin(1 - 2E/D)] -(D/2 - E) * sqrt[E * (D - E)]

Elliptical 2:1 Heads FT2 FT2

Ref: Chemical & Processing Technology website, "Calculate Wetted Surface Area of Horizontal Vessel with Elliptical Head"

Hemispherical Heads AHEM = π•D•E FT2 FT2

Ref: Hellemans, M., The Safety Relief Valve Handbook , 2009, Pg. 10.

HAR-CAL-EN-PR-011 Rev3
Company Confidential PRD Fire Horizontal Vessel
 Attachment 10
Determine Surface Area of Shell and Total Area

Horizontal Vessel Surface Area (shell only) ASHELL = LD*cos-1(1-2•E/D) 25.48 FT2

Additional Surface Area Aadd = 0.00 FT2

Allowances for Piping 0.0 %

Total wetted Area (inc. piping & heads) Awt = 25.48 FT2

Comment:
Note: For horizontal tanks, the wetted surface is at least that surface area included within the vertical height limit indicated above.
Source: API 521, Section 4.4.13 Ref: Hellemans, M., The Safety Relief Valve Handbook , 2009, Pg. 10.

Determine Relieving Mass Flow Rate

MAWP of vessel MAWP 654 PSIG

Overpressure OP 21 %

Set Pressure Pset 150 PSIG

Relieving Pressure P1 196.2 PSIA, (set pressure or MAWP)+

+allowable overpressure(21%)+ atmospheric pressure

Relieving Temperature T1 387.6 °F

Is relieving fluid steam? NO YES / NO

Fluid Caustic
Molecular Weight M 19.66 LB/LB-MOLE

Compressibility Z 1
Latent Heat at Relieving Temperature  859.4 BTU/LB

Viscosity at Relieving Temperature  0.016 cP

Adequate Drainage and Fire Protection? no YES / NO

Environmental Factors F 1.0 Bare tank

Heat of Absorption
Q  21 , 000 FA
0 . 82 Q BTU/HR Adequate drainage
wt

Q 490,771.2 BTU/HR Poor drainage

Required Mass Flow Rate

Q
W  W 571.1 LB/HR


Source: API 521, Section [Link].4.2 Equations 6 & 7

HAR-CAL-EN-PR-011 Rev3
Company Confidential PRD Fire Horizontal Vessel
 Attachment 10
Client: Honeywell UOP - FHR Valve No.: PSV-0550

Project: Merox Module Description: EA-503

Location: FHR Corpus Christi, TX Calc By: ABW Date: 1/12/2015

Project No.: 0333.141311.20 Checked By: DL Date: 1/12/2015
P&ID No.: CW005F05008 Rev. A

Sizing for Gas / Vapor Relief

Equipment Name EA-503
Fluid Caustic
Equipment MAWP MAWP 654 PSI
Set Pressure Pset 150.00 PSIG
Overpressure OP 21.0 %
Upstream Relieving Pressure Pset * OP 181.50 PSIG
Abs. Upstream Relieving Pres. P1 196.20 PSIA
Valve Type (B = Balanced / C = Conv.) B
Cold Dif. Test Pressure CDTP 150.00 PSI
Allowable Back Pressure 40.00 %
Molecular Weight M 19.66 LB/LB-MOLE

Compressibility Z 1.00
Relieving Temperature T1 387.60 °F
Absolute Relieving Temp. T'1 847.60 °R
Required Flow Rate Wm 571.06 LB/HR

Required Flow Rate Wscfm 183.71 SCFM

Required Flow Rate Wacfm 22.44 ACFM
Calculation Flow Rate W 571.06 LB/HR

Superimposed Back Pressure PSBP 2.00 PSIG relieve to flare header

Abs. Superimposed Back Pres. P'SBP 16.70 PSIA

Inlet Line Pressure Loss PIN 0.07 From inlet pipe pressure drop calcs 0.07

Total Allowable Back Pressure 60.00 PSI

Abs. Total Allowable Back Pressure P2A 74.70 PSIA Allow. Built up Back Pressure + Superimposed Back Pressure

Calc. Built-Up Back Pressure 0.15 PSI From outlet pipe pressure drop calcs 0.15

Total Calc. Back Pressure P2C 16.85 PSIA Calc Built Up Back Pressure + Superimposed Back Pressure

Ratio of Specific Heats k 1.37

k ( k 1)
Pcf  2 
  
P1
 k 1 
Critical Flow Pressure Pcf 104.55 PSIA Critical Flow Condition Exists
API 520 Part 1 8th Ed., Section 5.6.2 (Eq. 1)

HAR-CAL-EN-PR-011 Rev3
Company Confidential PRD Fire Horizontal Vessel
 Attachment 10
Relieving Device Orifice Area for Gas / Vapor Service -- Critical Flow Conditions
Required Flow Rate W 571.1 LB/HR

Coefficient C 353.6 Per API 520 -- use Figure 32 or Eq. 8 from Section 5.6.3.

Stagnation Pressure at PRD Inlet P1 INS 196.1 PSIA

Effective Coefficient of Discharge Kd 0.975 Preliminary value from API 520

Back Pressure Correction Factor Kb 1.0 1.0 unless B. Bellows see Fig. 30

Combination Capacity Factor Kc 1.0 0.9 with rupture disk, 1.0 w/o rupture disk
Compressibility Factor Z 1.00 ( k 1) ( k 1)

Molecular Weight  2 
k
M 19.66 LB/LB-MOLE C  520 
 k 1 
W TZ
A 0.055 IN
2

CK d P1 K b K c M
API 520 Part 1, 8th Ed., Section 5.6.3 (Eq. 2) API 520 Part 1, 8th Ed., Section 5.6.3 (Eq. 8)

Relieving Device Orifice Area for Gas / Vapor Service -- Subcritical Flow Conditions
Required Flow Rate W 0.00 LB/HR

Stagnation Pressure at PRD Inlet P1 INS 196.1 PSIA

Effective Coefficient of Discharge Kd 0.975 Preliminary value from API 520

Combination Capacity Factor Kc 1.0 0.9 with rupture disk, 1.0 w/o rupture disk

Molecular Weight M 19.7 LB/LB-MOLE

Compressibility Factor Z 1.00

Back Pressure Ratio r 0.0859 P2C/P1

Coefficient of Subcritical Flow F2 0.23

0.0000 IN2

API 520 Part 1, 8th Ed., Section [Link] (Eq. 12) API 520 Part 1, 8th Ed., Section [Link] (Eq. 18)

Estimate Rated Capacity of Valve Selection

To complete Pressure Drop calculations it may be necessary to estimate the Rated Capacity (Wrated) of the valve that would be selected. The
rated capacity based on the selected orifice size (API or ASME) is shown below:

Wrated = (Aselected/A)*W Aselected 0.307 IN2 API F orifice

Wrated 3,161.3 lb/hr From vendor

HAR-CAL-EN-PR-011 Rev3
Company Confidential PRD Fire Horizontal Vessel
Attachment 11

3"
3" x 2"

2" x 1 1/2"

2"

CORPUS CHRISTI COMPLEX

Page 1 of 21
Attachment 11

CORPUS CHRISTI COMPLEX

Page 2 of 2
 UOP LLC PROJECT
PROJECT SPECIFICATION
SPECIFICATION
25 East Algonquin Road
NOTES:
Des Plaines, Illinois 60017-5017, USA 985953 - 301 SHEET 5
A Honeywell Company 1) FOR PACKED BED INTERNALS REQUIREMENTS SEE PROJECT SPECIFICATION 307.
REV DATE BY APVD REV DATE BY APVD
2) THE CONTRACTOR IS TO CONSULT WITH THE PACKING SUPPLIER TO DETERMINE
0 08AUG14 JG PDH
THE NUMBER AND LOCATION OF BODY FLANGES.
R VESSELS 1 19AUG14 JG PDH
3) CONTRACTOR TO VERIFY LOCATION AND NOZZLE "I01" SIZE AFTER
Note : The information in this document is confidential and the property of UOP LLC and must not be disclosed to others or reproduced in any manner or used for any purpose whatsoever without its written permission

E 2 18SEP14 TS PDH
V CONSULTATION WITH PACKED BED SUPPLIER. 3 26SEP14 TS PDH
301-802,804-V20-0 (REV A).dgn

4) VESSEL TOP HEAD AND UPPER SHELL PORTION DOWN TO 1’-0" BELOW ACCUMULATOR TO BE
SERVICE
SERVICE SCRUBBING OXIDIZER ITEM
ITEM NO
NO 05FA551
LINED WITH 1/8 " THICK TYPE 316L.
IN LINED PORTION: LINING IS CORROSION ALLOWANCE. INTERNALS TO BE STAINLESS STEEL
Design INT 150 psig @ 212 %%dF (#) BY CONTRACTOR
AND NOZZLES TO BE STAINLESS STEEL LINED AND FACED.
Conditions EXT FULL VACUUM @ 300 %%dF
at Top Metal Temperature(Min) 10 %%dF
Operating VESSEL 113 %%dF
Conditions
Radiograph FULL RT
Postweld Heat Treat YES
Material Corrosion
2’-0"

11’-6"
Allowance

S06
O05

D07
O01

I01

3 VESSEL KILLED CARBON STEEL 0.25

MR
STACK TYPE 316L 0.0625

MR
This Vessel is in the Following Service(s):

1" STAINLESS STEEL

1" STAINLESS STEEL

Hydrogen NO

VERTICAL CL AND

3/5" DIA. HOLES

EITHER SIDE OF
* RASCHIG RINGS

* RASCHIG RINGS
ON VERTICAL CL
EQUALLY SPACED

EQUALLY SPACED

OF DISTRIBUTOR
1/8 " DIA. HOLES

HORIZONTAL CL
Hydrofluoric (HF) Acid NO

STAGGERED ON

AND 27 TOTAL
DISTRIBUTOR

67.5%%d ABOVE
(BY OTHERS)

(BY OTHERS)
BY PACKING SUPPLIER

PACKING SUPPORT
Hydrofluoric (HF) Acid (with Resid. Elem. Control) NO

IN BOTTOM
DWG3-312
50 TOTAL
(1" 316 SS IMTP)
RF BOTH SIDES
FILLER FLANGE
Wet Hydrogen Sulfide (H2S) NO
MIST ELIMINATOR

Cyclic NO

LINING
AND LR ELBOW

SUPPORT PER
(BY OTHERS)
SCH MR PIPE

SPEC 3-35)

Caustic YES
FEED PIPE
DWG 3-264
9" THICK

(SEE STD
TYPE 304

PACKING
STYLE A

Carbonate NO
MR

Amine NO
Vessel Heads
VESSEL 2:1 ELLIPTICAL
V01

STACK - TOP FLANGED-FLAT

BAR GRATING
BED NO. 1
DISTRIBUTOR

DWG 3-276
Accessories Applied by Fabricator
Attachment 12

12" PIPE

DETAIL-2
4’-0" ID
Ladders & Platform Clips AS REQUIRED (#)

O07
Insulation Clips and Rings YES

DWG 3-115
Vessel Support YES

BAFFLE

TYPE I
Nozzles and Manways

DETAIL-1
Mark No Size Service
inches
B01 1 STACK ID BODY FLANGE
[Link]

F01 1 STACK ID FLANGED HEAD

FLANGE FACE

FLANGE FACE

BED MATERIAL, SEE PROJECT SPEC 308

I01 1 2 INLET WASH OIL (2)

TANGENT
O01 1 2 OUTLET AIR (2)

TANGENT
V01 1 2 VENT (2)
C02 (#) (#) RELIEF (#) SEE NOTE
M03 1 24 MANWAY
L04 2 2 LEVEL (2)
O05 1 3 OUTLET LIQUID (2)
B06 1 24 MANWAY

1’-2"

1’-9"

1’-0"
J06 1 3 INLET (2)

MR

MR

6"
S06 1 2 UTILITY (2)
D07 1 6 DROPOUT

J06
B06
C02

M03

L04

L04

T08
F01

B01
O07 1 2 DRAIN (2)

1’-9"

3’-3"

8’-0"

4’-0"

2’-6"
T08 1 2 THERMOWELL (2)

*
MR
15’-0" 15’-6"
4- 1/4 " WIDE X 6" LONG
SLOTS @ 90^ SPACING
1/4 " PLATE
D07
Class - ASME CL150 TWO 1/4 " DIA BAR(S) WELD
REDUCING TO VESSEL SHELL
(2) ASME CL300 SCH MR PIPE (SPACING 3/4 " CENTERS)
SLIP-ON
Facing - RAISED FACE FLANGE
DETAIL-2
Normal Liquid Level = 13’-10"
O07
Specific Gravity = 1.1
Delta-P Vessel (Total) = N/A Drawings Referred to in this Specification
DETAIL-1
NOZZLES MUST NOT BE LOCATED IN DOWNCOMERS 3-115 3-264 3-276 3-312
) THE NUMBER, FLANGE RATING, AND SIZE OF NOZZLES AT
THIS LOCATION SHALL BE DETERMINED BY THE CONTRACTOR
 Attachment 13

2" x 1-1/2"

2" SCH 80

2" Nozzle
 Attachment 13

3" SCH 40

3" x 2"
 Attachment 13

3" SCH 40
 Attachment 14

Sample ID 2784252 2783644 2783226 2782795 2782261 2781758 2781120

Sample Date 04/15/14 04/14/14 04/13/14 04/12/14 04/11/14 04/10/14 04/09/14
Code 02DBB1:#1 De02DBB1:#1 De02DBB1:#102DBB1:#102DBB1:#102DBB1:#102DBB1:#1 DeButBtm
Comment
ES%XRY: Sulfur, wt%,XR 0.0378 0.0352 0.0328 0.0376 0.0407 0.0506 0.0502
RSH‐: Mercaptan, wt% 0.0084 0.008 0.0074 0.0081 0.0052 0.006 0.0062
H2SCOU: HydrogenSulfide 2.2 0 0 0 2.7 1.9 0
GRVAPI: API Gravity 59.4 58.7 6.6
VPREID: Reid VP 6.57 6.89 6.65
*C2: Ethane 0 0 0
*C3: Propane 0 0 0 Composition of
*C3=: Propylene 0 0 0 Wash Oil
*IC4:iso‐Butane,vol% 0.0019 0.0017 0.0851
*IC4=:iso‐Butene,vol% 0 0 0
*C4=1:1‐Butene,vol% 0.006 0.005 0.2137
*C4==:1,3‐Butadiene,vol% 0 0 0
*NC4:n‐Butane,vol% 0.0121 0.0098 0.1768
*TC4=:trans‐2‐Butene vol% 0.0232 0.0187 0.4383
*CC4=:cis‐2‐Butene,vol% 0.0357 0.0288 0.4915
*IC5:iso‐Pentane,vol% 7.2895 7.0303 7.1712
*NC5:normal‐Pentane,vol% 1.3953 1.4043 1.0138
*C5=:Amalines,vol% 10.7885 10.9948 9.7556
*C6+:Hexane plus,vol% 80.4478 80.5066 80.6539
ES RSH: Mercaptn,ppm 60.1 61.6
Doctor Test Positive

Sample ID 2784249 2783641 2783688 2784144 2782792 2782258 2782293 2781755 2782098
Sample Date 4/15/14 4/14/14 4/14/14 4/13/14 4/12/14 4/11/14 4/11/14 4/10/14 4/9/14
Code 01GSI:Gasolin 01GSI:Gasolin01GSI:Gaso01GSI:Gaso01GSI:Gaso01GSI:Gaso01GSI:Gaso01GSI:Gaso01GSI:GasolineT In
Comment SPECIAL SPECIAL

Page 1 of 3
 Attachment 14

DSEN00: IBP 102.9 103.7 104 102.7 102 106 103.6

DSEN02: 2%Recoverd 121.9 122.5 122.3 122 121.3 123.3 120.2
DSEN05: 5% Recovered 130.3 130.6 130.3 130.2 129.6 131.7 128.7
DSEN10: 10% Recovered 138.2 138.1 137.1 138 137.2 139.1 136.9
DSEN20: 20% Rec 150.3 150.3 149.8 150 149.3 151.5 148.8
DSEN30: 30% Rec 165 164.6 164.5 164.3 163.7 166 163.8
DSEN40: 40% Rec 184.8 184.1 184.6 183.8 183.7 184.8 183.8
DSEN50: 50% Rec 210.2 209.7 210.3 208.5 209.7 209.2 210.2
DSEN60: 60% Rec 240.5 239.7 240.2 238.1 240.7 240.1 242.1
DSEN70: 70% Recovered 274.2 273.5 274 271.5 275.5 275.1 277.7
DSEN80: 80% Rec 310.3 310.7 310.1 307.4 313.3 311.1 316.4
DSEN90: 90% Rec 352.3 354.1 352.7 348.6 356.3 355.3 363.4
DSEN95: 95% Rec 380.6 384.2 382.4 376.5 391.2 388.1 397.9
DSENMX: Max Boiling Point 412 411.6 408.7 405.9 420.9 420.2 421.6
ES%XRY: Sulfur, wt%,XR 0.0541 0.0514 0.0545 0.0373 0.0479 0.0517
Doctor Test Positive Positive Positive Positive Positive Positive
DSSI00:(TBP) IBP 61 58 59 62 46 46
DSSI05:(TBP) 5% 80 81 81 81 80 80
DSSI10:(TBP)10% 89 89 89 90 88 88
DSSI20:(TBP)20% 105 106 106 106 105 105
DSSI30:(TBP)30% 141 142 142 142 141 141
DSSI40:(TBP)40% 163 165 164 164 163 163
DSSI50:(TBP)50% 194 195 195 194 194 194
DSSI60:(TBP)60% 221 225 221 220 224 223
DSSI70:(TBP)70% 270 273 270 269 276 276
DSSI80:(TBP)80% 321 322 321 321 324 324
DSSI90:(TBP)90% 369 370 368 365 373 373
DSSI95:(TBP)95% 403 405 402 401 411 412
DSSIEP: SD FBP 456 457 456 454 475 472
DSSI99:(TBP)99% 449 450 448 446 456 455
VPREID: Reid VP 6.93 6.8 7.05 6.56 7.08 6.85
RSH WT%: Mercaptan Sulfur 0.007 0.007 0.007 0.007 0.005 0.002
MON: Motor Octane No 80.6 80.6
RON: Res Octane No 91.6 92.4

Page 2 of 3
 Attachment 14

(R+M)/2: Octane Index 86.1 86.5

GRVAPI: API Gravity 80.5

Page 3 of 3
 Attachment 15

Control Valves Specification Sheet

Customer: UOP LLC Novaspect
Contact: Contact: Beth Girardi
Customer Reference: 985953 R616 Flint Hills Sales Office Reference: BJH-186976 Lead Time: 15 Weeks
Control Valves ARO
Item: 90 Rev: Qty: 1
Tags: 05FV0570 Date Last Modified: 10/9/2014
Description: Fisher NPS 1 667-EZ-DVC6200 Globe Control Valve

Service Description: Wash Oil to Oxidizer

1 Fluid: Hydrocarbon Crit. Pres. PC: 442.000 psia
SERVICE CONDITIONS Units: Maximum Normal
2 Liquid Flow Rate (Ql) gpm(US) 2.000 2.000
3 Inlet Pressure (P1) psig 143.000 144.000
4 Outlet Pressure (P2) psig 69.000 69.000
5 Temperature (T1) deg F 100.0000 100.0000
6 SG 0.720 0.720
7 Kinematic Viscosity (Nu) cSt 0.423 0.423
8 Vapor Pressure (Pv) psia 6.000 6.000
9 Sizing Coefficient (Cv) 0.197 0.196
10 % Open 47.29 47.14
11 (Allowed / Calculated) dB(A) /< 50 /< 50 / /
12
PIPE LINE 53 ACTUATOR Type: Spring & Diaphragm
13 Size, Schedule In: 1 in, SCH 160 54 Mfg/Model: Fisher/667
14 Size, Schedule Out: 1 in, SCH 160 55 Size: 34 Eff Area: 69 in2
15 Insulation: 56 On/Off: Modulating: X
16 VALVE BODY/BONNET Type: Globe 57 Spring Action: Down,Close
17 Size: NPS 1 ANSI CL300 58 Max Allow Press: 70 psig
18 Max Press/Temp: 193 psig/100 deg F 59 Min Req'd Press: 33 psig
19 Mfg/Model: Fisher/EZ 60 Available Air Supply Pressure
20 Body/Bonnet Matl: WCC Steel 61 Max: 125 psig Min: 80 psig
21 Liner Matl/ID: 62 Bench Range: 6-30 psi
22 End Connection In: CL300 RF Flg 63 Act Orientation:
23 End Connection Out: CL300 RF Flg 64 Handwheel Type: None
24 Flg Face Finish: 65 Air Failure Valve: Close Set at:
25 End Ext/Matl: 66
26 Flow Direction: Up 67 Input Signal: 4 to 20 mA dc
27 BONNET Type: Plain 68 POSITIONER Type: I/P
28 Lub-Iso Valve: No Lube: No 69 Mfg/Model: Fisher/DVC6200/Advanced-AD
29 Packing Material: Enviro-Seal PTFE/Carbon 70 Incr Signal Output:
30 Packing Type: 71 Gauges: 0-60 psig/0-4 bar By-Pass:
31 72 Cam Characteristic:
32 TRIM Type: Metal 154 73
33 Size: 1/4 Inch Travel: 3/4 Inch SWITCHES
34 Characteristic: Micro-Flute 3 Flute (Eq Pct) 74 Type: None Qty:
35 Balanced/Unbalanced: Unbalanced 75 Mfg/Model:
36 Rated Cv: 1.07 Fl: 0.9 Xt: 0.692 76 Contacts/Rating:
37 Material: S31600 SST/CoCr-A Tip 77 Actuation Points:
38 Seat Material: S31600 SST/CoCr-A 78
Seat/Bore
39 Cage Material: AIRSET
40 Stem Material: S31600 SST 79 Mfg/Model: Fisher/67CFR Filter/Regulator
41 80 Set Pressure: 40 psig
42 81 Filter: 5 micron Gauges: On DVC
SPECIAL ACCESS. 82
43 NEC Class: 1 Group: C&D Div: 2 83 TESTS Hydro Press:
44 3/8" SS Tubing w/ Parker A-Lok Fittings 84 ANSI/FCI Leak Class: ANSI CL IV
45 85
46 86
47 Rev Date Revision Orig App
48
49
50
51
52

Page 1 of 3
 Attachment 15

Valve/Regulator Sizing Calculation

Customer: UOP LLC Novaspect
Contact: Contact: Beth Girardi
Customer Reference: 985953 R616 Flint Hills Sales Office Reference: BJH-186976 Lead Time: 15 Weeks
Control Valves ARO
Item: 90 Rev: Qty: 1
Tags: 05FV0570 Date Last Modified: 10/9/2014
Description: Fisher NPS 1 667-EZ-DVC6200 Globe Control Valve

Service Description: Wash Oil to Oxidizer

Sizing Type: Liquid Flow is Turbulent Solving for: Cv Noise is Hydrodynamic Flow is Volumetric
Variable Name Units Minimum Normal Maximum Other
SERVICE & SIZING
Liquid Hydrocarbon
Specific Gravity (SG) 0.720 0.720
Inlet Pressure (P1) psig 144.000 143.000
Outlet Pressure (P2) psig 69.000 69.000
Temperature (T1) deg F 100.0000 100.0000
Volumetric Flow Rate Liquid (Ql) gpm(US) 2.000 2.000
Pressure Recovery Factor (Fl) 0.900 0.900
Valve Style Modifier (Fd) 0.170 0.170
Cavitation Coefficient (Kc) 0.643 0.643
Kinematic Viscosity (Nu) cSt 0.423 0.423
Vapor Pressure (Pv) psia 6.000 6.000
Critical Pressure (Pc) psia 442.000 442.000
Atmospheric Pressure psi 14.692 14.692

Pipe Size Up in 1 1
Pipe Schedule Up 160 160
Pipe Size Down in 1 1
Pipe Schedule Down 160 160
Nominal Valve Diameter (dv) in 1.000 1.000

Sizing Coefficient (Cv) 0.196 0.197

Application Ratio (Ar) 0.491 0.488
dP Cavitation psi 98.181 97.538
dP Choked psi 124.033 123.223

NOISE CALCULATION
Hydrodynamic_Trim Standard Trim Standard Trim
Valve Lpa (LpAe1m) dB(A) < 50 < 50

VELOCITY OUTPUTS
V1 Pipe ft/s 1.229 1.229
V2 Pipe ft/s 1.229 1.229
Item Notes:

Page 2 of 3
 Attachment 15

Flow Coefficient Graph

Customer: UOP LLC Novaspect
Contact: Contact: Beth Girardi
Customer Reference: 985953 R616 Flint Hills Sales Office Reference: BJH-186976 Lead Time: 15 Weeks
Control Valves ARO
Item: 90 Rev: Qty: 1
Tags: 05FV0570 Date Last Modified: 10/9/2014
Description: Fisher NPS 1 667-EZ-DVC6200 Globe Control Valve

Service Description: Wash Oil to Oxidizer

Page 3 of 3
 Attachment 16

CUSTOMER DATA SPECIAL DATA TUBE BUNDLE DATA

CUSTOMER HONEYWELL INTERNATIONAL SURFACE PREP. SSPC SP10 SIZE 2" STD WT PIPE
PAINT SPEC. SEE BELOW COUNT (1) WELDED U-TUBE
4500610374
10"
P.O. NUMBER MATERIAL SA-106 B
05EA503 HEAT TREAT SEE BELOW HE-79A 20 Be CAUSTIC
TAG ITEM NO. WELD PROCEDURE 
SHELL OUTLET
SERVICE CAUSTIC HEATER
CUSTOMER INSP. YES, SEE BELOW
(1) MOD. #S4J1-12-00-SR-2/3B1.5/1B - PAINT SPEC.
NAT'L. BRD. NO. YES (ASSIGNED LATER)
NON-SILICA ABRASIVES TO BE USED: BLACK BEAUTY,
MISC. A.S.M.E. SECTION VIII, GARNET, OR EQ UP
- FHR-CC: STD 0.13 ACCEPT. ORIGINS OF MATLS: A
S
SALT TEST TO BE PERFORMED.
PURCHASING TO FOLLOW AML ACCEPT ORIGINS:
CODE STAMP ME DIV. 1, 2013
PAINT MUST BE NEW & UNOPENED.
AUSTRIA, BELGIUM, CANADA, DENMARK,FINLAND, RT 100% PER CUST/ASME D.1. ADHESION TEST REQ'D.
FRANCE, VENEZUELA, GERMANY, ITALLY, JAPAN, NACE INSPECTOR REQUIRED, MIN. OF LEVEL II.
UT NON RT-ABLE PRESS. RETAIN. WELDS
NETHERLANDS, NORWAY, S. AFRICA, S. KOREA, 1ST COAT: (4-5 MILS) SHERWIN WILLIAMS EPO-PHEN
SPAIN, SWEDEN, SWITZERLAND, UNITED KINGDOM, PT PER ASME/RWH REQT'S, ATTACHMENT WELDS 2ND COAT: (4-5 MILS) SHERWIN WILLIAMS EPO-PHEN
USA. (COLOR: MFG STD)
"ORIGIN" MEANS SMELTING OF THE RAW MATLS INTO - PWHT PARTS IN CONTACT W/S'SIDE FLUID (SHELL & BUNDLE).
THE STEEL BILLET. PWHT: 1175°F±25°F  LP STEAM
- INSULATION: 1.5" SHELL, 2" TUBE (BY OTHERS) - FOR INSPECTION: 10 WORK DAY ADVANCE NOTICE FOR: H, W, SW.
- SEALWELD NAMEPLATE TO BRACKET TUBE INLET
- PT CAN BE USED FOR MAGNETIC MATERIALS.
- TWO (2) SETS OF SPARE GASKETS PLUS 10% SPARE - BRINELL HARDNESS TEST AFTER PWHT: (1) READING IN WELD & (1)
BOLTING. READING IN HAZ.
- STUDS & NUTS TO BE COATED W/FLUOROKOTE #1.
- CAUSTIC SERVICE SHELLSIDE.
- WIND, SEISMIC, & NOZZLE LOADS REQ'D.
SECTION DATA DESIGN CONDITIONS LP COND.
- GASKET SURFACES TO BE COATED W/RUST PREVEN- 
TATIVE GREASE. TUBE OUTLET
- MARKINGS: "POST WELD HEAT TREATED. NO WELDING WEIGHT PER SECTION: SHELL TUBE
OR BURNING PERMITTED ON THIS VESSEL".
- CENTER OF GRAVITY REQ'D. DRY 920 LBS WET 1046 LBS
DESIGN PSIG FV/170 FV/135
- NITROGEN PURGE EXCHANGER.
- DOMESTIC CRATE FOR SHIPMENT.
TOTAL UNIT WEIGHTS:
DRY WET TEST PSIG 981 979
SHELL SUPPORT BASE
SHELL ASSY. DATA SURFACE AREA:
METAL TEMP. 115/300°F 250/310°F
PER SECTION 15 [Link].
SIZE 4" SCH 120 PIPE SEE EX
TOTAL CORROSION .250" .125"
MATERIAL SA-106 B BELOW TUBES
- S'SIDE MAWP(H&C): 654 PSIG
 20 Be CAUSTIC
CONNECTIONS 2" & 3"-300# RF FLG (LIMITED BY RBH CLOSURE)
MDMT/PSIG -20 °F/ 185 -20 °F/ 150 SHELL OUTLET
WELD PROCEDURE HE-79A T'SIDE MAWP(H&C): 653 PSIG - HYDROTEST IS 1.5*MAWP(H&C)
(LIMITED BY ANSI FLANGE) - HYDROSTATIC TEST SHALL BE HELD FOR 1 HOUR MIN. RECOMMENDED ARRANGEMENT
- HYDROCHART REQ'D. END VIEW SCHEMATIC
- 1/16" C.A. ON SUPPORT BRACKETS.

THIS DRAWING IS THE PROPERTY OF SER. NO. 14-8228A-1

SECTION ARRANGEMENT
[Link],INC. REF. NO.
NO. OF SHELL TUBE PETROFINHairpin Heat Exchangers

ITEM NO. TULSA, OKLAHOMA DRAWN BY DATE

SECTIONS PARALLEL SERIES PARALLEL SERIES FOR SPECIFIED USE ONLY−NOT TO BE LOANED/COPIED
JJM 1/5/2014
05EA503 1 1 1 1 1 APPROVED FOR CONST. BY DATE

GENERAL DATA
DRAWING NO. rev

14-8228 0
SHT 1 OF 6
 Attachment 16
PARTS LIST PARTS LIST
ITEM QTY DESCRIPTION MATERIAL ITEM QTY DESCRIPTION MATERIAL
15 1 NAMEPLATE, 300 SERIES S.S. 30 8 SHELL STUDS & NUTS, 3/4"-10UNC w/(2) HEX NUTS EA. SA-193 B7/ SA-194 2H
21 1 TUBE FLANGE W/HUB, SA-105 31 8 TUBE STUDS & NUTS, 3/4"-10UNC w/(2) HEX NUTS EA. SA-193 B7/ SA-194 2H
22 1 TUBE FLANGE W/HUB, SA-105 32 2 COMPRESSION FLANGE, SA-516 70 NORM
23 2 SPLIT RING (SHELL), SA-106 B 33 2 TUBEFITTING FLANGE, SA-516 70 NORM
24 2 SPLIT RING (TUBE), SA-106 B 34 1 CHANNEL NOZZLE FLANGE, 1 1/2"-300# RFWN FLG W/XXS BORE SA-105
25 2 SEAL RING, SA-106 B D.S.A. 35 1 CHANNEL NOZZLE FLANGE, 1"-300# RFWN FLG W/XXS BORE SA-105
26 2 TUBE GASKET, S.W.S.S./COMP NON-ASB 36 1 CHANNEL NOZZLE TEE, 1 1/2" X 3/4" XXS WELD REDUCING TEE SA-234 WPB
27 1 RETURN BEND HOUSING GASKET, COMP NON-ASB 37 1 CHANNEL NOZZLE PIPE, 1" XXS PIPE SA-106 B
28 1 RETURN BEND HOUSING, SA-216 WCB 38 1 CHANNEL NOZZLE VENT FLANGE, 3/4"-150# RFWN FLG W/XXS BORE SA-105
29 8 R.B.H STUDS & NUTS, 3/4"-10UNC w/(2) HEX NUTS EA. SA-193 B7/ SA-194 2H

10"
14'-1 1/16" 1/2" 1 1/4"
OVERALL ASSEMBLY 1/4"

(ACTUAL C.O.G. WILL BE PROVIDED AS A REVISION TO FINAL CERTIFIED DWGS) 2 3/4"

1'-6" 1/8"
24 1/2 1/8 1 1/2" 7" 1 1/2"
(RECOMMENDED)
WELDED U-TUBE 5" 1/16"
2" STD WT
SHELL OUTLET
(SA-106B/SA-234 WPB)
3"-300# RFWN FLG
W/SCH 120 BORE 32 21 34
24
SHELL PIPE (SA-105) 23 5 1/8"
27 29 4" SCH 120 30 26 38
31
(SA-106 B) 25 33
28 10 1/8" 1/16"
3"
36

37 6" 1/32" 25 1/2 1/8 10" 16"

3"
15 FIXED SUPPORT GROUNDING LUG 9 3/8" 1/16"
(SEE NOTE 3.) SLOTTED HOLES (1) REQ'D (SA-36) (1) REQ'D (304 S.S.) 22
3/4" X 1" LG 35 4 3/8"
(8) EA SUPPORT MOVABLE SUPPORT SHELL INLET
(18")
(1) REQ'D (SA-36) 2"-300# RFWN FLG
12'-10" W/XXS BORE (9 3/16") G
TO REMOVE (SA-105) HE-79
BUNDLE (16 5/64") 75
8'-0" 1'-6 1/8" 1/8"
22 7/8 1/8
END VIEW
(RECOMMENDED) (RECOMMENDED)

ELEVATION
(1) HAIRPIN ASSY REQ'D
THIS DRAWING IS THE PROPERTY OF SER. NO. 14-8228A-1
NOZZLE LOADS
_ Fx (lbf) Fy (lbf) Fz (lbf) Mx (lbf-ft) My (lbf-ft) MZ (lbf-ft)
[Link],INC. REF. NO.
SHELL IN/OUT 60 60 60 85 85 85 PETROFINHairpin Heat Exchangers
TUBE IN/OUT 42 42 42 59 59 59
NOTES: TULSA, OKLAHOMA DRAWN BY DATE
1. NOZZLE FLANGE BOLT HOLES STRADDLE NORMAL CENTERLINES. FOR SPECIFIED USE ONLY−NOT TO BE LOANED/COPIED
MDG 12/30/14
2. "PT" TUBE FLANGE NOZZLE BORE I.D. PER UG-93(d)(4)(d) AFTER WELDING. APPROVED FOR CONST. BY DATE
3. SEALWELD NAMEPLATE TO BRACKET. GENERAL OUTLINE & ASSEMBLY
4. REF. DWG. SHT. 1 FOR ADDITIONAL INFORMATION & Q.C. DRAWING NO. rev
MODEL NO.
S4J1-12-00-SR-2/3B1.5/1B 14-8228 0
P.O. NO. ITEM NO. SHT. 2 OF 6
4500610374 05EA503
 Attachment 16
PARTS LIST PARTS LIST
ITEM QTY DESCRIPTION MATERIAL ITEM QTY DESCRIPTION MATERIAL
1 2 SHELL PIPES, 4" SCH 120 PIPE SA-106 B 10 2 SHELL END FLANGE, SA-105/SA-350 LF2
2 1 SHELL INLET TEE, 4" X 3" SCH 160 WELD REDUCING TEE SA-234 WPB 11 1 SHELL NOZZLE FLANGE, 3"-300# RFWN FLG W/SCH 160 BORE SA-105
(CHECK & BORE STRAIGHT RUN ID OF TEE TO 3.624" +.110/-0.) 12 1 SHELL NOZZLE FLANGE, 2"-300# RFWN FLG W/XXS BORE SA-105
3 1 SHELL OUTLET TEE, 4" X 2" XXS WELD REDUCING TEE SA-234 WPB 13 1 SHELL NOZZLE PIPE, 3" SCH 160 PIPE SA-106 B
(CHECK & BORE STRAIGHT RUN ID OF TEE TO 3.624" +.110/-0). 14 1 SHELL NOZZLE PIPE, 2" XXS PIPE SA-106 B
4 1 MOVABLE SHELL SUPPORT, SA-36 16 1 NAMEPLATE BRACKET, 2 1/2" PROJ. SA-36
5 1 FIXED SHELL SUPPORT, SA-36
8 1 GROUNDING LUG, 304 S.S.
9 1 COVER FLANGE, SA-516 70 NORM

12'-2" 1/8"
SHELL ASSEMBLY LENGTH

8'-0" 18 1/8" 6 15/16" 1/16"

11

1/4"
9 HE-79A
1/4"
13
10
1 10 1/8" 1/16"
2

25 1/2"1/8"

6" 1/32"

2 1/4"
3 9 3/8" 1/16"
B 16
4 8 14 12
5 1 1/2"
10 1/2" 1/16"
WELD GAP A

6 13/16" 1/16"
1/16"
1/16"
WELD GAP
WELD GAP
G
HE-79A

11/16"

NOTES: DETAIL "B"

WELD DETAL FOR COVER FLANGE G
1. SPECIAL REQUIREMENTS.
A. FULL "RT" PRESS. RETAIN. WELDS. REF. ASME CODE SECTION VIII, DIV. 1,
G
1/16"
WELD GAP
HE-79A (1) SHELL ASSEMBLY REQ'D AS SHOWN
B. "UT" NON RT-ABLE PRESS. RETAIN. WELDS. FIG UW-13.2(m) HE-79A 75 THIS DRAWING IS THE PROPERTY OF SER. NO.
C. PWHT PER UCS-56, TABLE UCS-56 FOR P-NO. 1 14-8228A-1
MATL'S IN CONTACT W/S'SIDE FLUID (CAUSTIC). 75
1/16" [Link],INC. REF. NO.
D. AFTER PWHT, HARDNESS TEST (1) READING IN PETROFINHairpin Heat Exchangers

WELD & (1) READING IN HAZ. 200 BHN MAX. WELD GAP
TULSA, OKLAHOMA DRAWN BY DATE
E. BASELINE THICKNESS REQ'D. FOR SPECIFIED USE ONLY−NOT TO BE LOANED/COPIED
MDG 12/30/14
2. USE WELD PROCEDURE(S): HE-79A.
3. "PT" PER UG-93(d)(4)(d) AFTER WELDING. DETAIL "A" APPROVED FOR CONST. BY DATE
4. ALL GASKET SURFACES TO BE PROTECTED FROM WELD SPLATTER PRIOR TO FIT-UP. WELD DETAIL FOR SHELL TEE, NOZZLE & END FLANGES SHELL ASSEMBLY
REF ASME CODE SECTION VIII, DIV. 1, DRAWING NO. rev
5. NOZZLE FLANGE BOLT HOLES TO STRADDLE NORMAL CENTERLINES. MODEL NO.
6. SEE DWG. SHT. 1 FOR ADDITIONAL INFORMATION & Q.C. FIG UW-13.2(n) & FIG UW-16.1(a)
S4J1-12-00-SR-2/3B1.5/1B 14-8228 0
P.O. NO. ITEM NO. SHT. 3 OF 6
4500610374 05EA503
 Attachment 16
PARTS LIST PARTS LIST
ITEM QTY DESCRIPTION MATERIAL ITEM QTY DESCRIPTION MATERIAL
17 2 STRAIGHT TUBES, 2" STD WT PIPE SA-106 B 19 2 TUBEFITTINGS, SA-350 LF2
18 1 RETURN BEND, 2" STD WT L.R. 180DEG WELD RETURN BEND SA-234 WPB 20 18 TUBE SUPPORT, 9/16" DIA ROD C. STL.

13'-1 11/16" 1/8"

TUBE ELELMENT ASSEMBLY

1/16" 12'-1" 1/16"

WELD GAP STRAIGHT TUBE LENGTH WELD GAP
G 19
HE-79A
17
A 3/8"

G
HE-79A THESE FACES MUST BE 6" 1/32"
IN THE SAME PLANE C-C
75

18
TACKWELD TO TUBES
(7/16")
20
2" (2) SPA. @ 3'-0" = 6'-0" 3'-0" (8 3/8")

9/16" ROD

120°

(1) TUBE BUNDLE ASSEMBLY REQ'D AS SHOWN

NOTES: B THIS DRAWING IS THE PROPERTY OF SER. NO. 14-8228A-1
1. PROTECT GASKET SURFACE FROM SCARRING PRIOR TO INSTALLATION. DETAIL "A" VIEW "B-B"
2. USE WELD PROCEDURE : HE-79A. [Link],INC. REF. NO.
PETROFINHairpin Heat Exchangers
3. PWHT PER UCS-56, TABLE UCS-56 FOR P-1 MATLS IN CONTACT W/S'SIDE FLUID (CAUSTIC).
4. AFTER PWHT, HARDNESS TEST (1) READING IN WELD & (1) READING IN HAZ. 200 BHN MAX. TULSA, OKLAHOMA DRAWN BY DATE
5. FULL "RT" PRESSURE RETAINING WELDS PER CUST./ASME D.1.
FOR SPECIFIED USE ONLY−NOT TO BE LOANED/COPIED
MDG 12/30/14
6. "UT" NON-RT ABLE PRESSURE RETAINING WELDS. APPROVED FOR CONST. BY DATE
7. BASELINE THICKNESS REQ'D. TUBE ELELMENT ASSEMBLY
8. SEE DWG. SHT. 1 FOR ADDITIONAL INFORMATION & Q.C. DRAWING NO. rev
MODEL NO.
S4J1-12-00-SR-2/3B1.5/1B 14-8228 0
P.O. NO. ITEM NO. SHT. 4 OF 6
4500610374 05EA503
 Attachment 16

R. W. H O L L A N D, I N C.
EXCHANGER SPECIFICATION SHEET (ENGLISH UNITS)
--------------------------------------------------------------------------
CUSTOMER: UOP/HONEYWELL INQ. NO: 985953 R401
LOCATION: DATE: DEC. 15, 2014 QUOTE NO: 14-377-3 NB (ASSIGNED LATER)
SERVICE: CAUSTIC HEATER ITEM: 05EA503
MODEL: S4J1-12-00-SR-2B1.5/1B PAR SHL/TUBE 1/ 1 CERTIFIED BY R.W. HOLLAND, INC. TULSA, OK
TOT. SURF.: 15 [Link]. SEC./UNIT: 1 SURF./SEC.: 15 [Link]. SHELL TUBE
--------------------------------------------------------------------------
PERFORMANCE OF ONE UNIT
A
S
M
MAWP PSI 654 653
-------------------------------------------------------------------------- E
SHELLSIDE TUBESIDE TEMP °F 300 310
FLUID CIRCULATED 20 Be CAUSTIC LP STEAM U
TOTAL FLOW
VAPOR IN
LB/HR
LB/HR
14595.
0.
222.
222. W MDMT °F -20 -20
LIQUID IN LB/HR 14595. 0.
FLUID VAP OR COND LB/HR 0. 222. AT PSI 654 653
TEMP. IN DEG F 100.0 212.2
TEMP. OUT
CP-LIQUID
DEG F
BTU/LB/F
115.0
.960
212.2
.000
MAEP PSI 15 15
115 250
CP-VAPOR BTU/LB/F .000 .000
S.G. IN OR AVG 1.148 .000 TEMP °F
S.G. OUT 1.144 .958 YEAR
VISC. IN OR AVG CP 1.661 .100 SERIAL NO. 14-8228A-1 BUILT
2015
VISC. OUT CP 1.355 .000
K-LIQUID
VISC. GAS
BTU/HR/FT/DEG F
CP
.352
.000
.000
.000
CUST.: HONEYWELL INTERNATIONAL
K-GAS BTU/HR/FT/DEG F .000 .000 P.O.: 4500610374
MW-IN OR AVG.
MW-OUT
.00
.00
18.02
.00
ITEM: 05EA503
OPER. PRESS. PSIG 82.10 .10 SERVICE: CAUSTIC HEATER
VELOCITY FT/SEC 1.400 35.200
PRESS. DROP ALLOW/CALC PSI 5.00/.23 .10/.07
FOULING HR-FT-DEG F/BTU .0020 .0005
--------------------------------------------------------------------------
DUTY - BTU/HR 218,900. MTD - DEG F 104.5
SERVICE TRANSFER RATE - BTU/HR/FT2/DEG F 139.6
--------------------------------------------------------------------------
CONSTRUCTION

NAMEPLATE FACSIMILE
--------------------------------------------------------------------------
CORROSION ALLOWANCE IN. .2500 .1250 EX. TUBES
DESIGN/TEST PRESSURE PSIG FV/170./CODE FV/135./CODE MATERIAL: 300 SERIES S.S.
DESIGN TEMPERATURE DEG F 115./300./-20. 250./310./-20.
-------------------------------------------------------------------------- ( 1 ) NAMEPLATE(S) REQ'D.
TUBES - MAT'L: SA-106 B 2.0" NPS THK: STD. WT NO.: 1 U-TUBE (APPROX. FULL SCALE)
SHELL - MAT'L: SA-106 B 4.0" NPS THK: SCH. 120 NOM. LG.: 12'
RETURN BEND HOUSING -- MAT'L: SA-216 WCB TYPE: C.J.
SHELL FLANGES -------- MAT'L: SA-516 70
TUBESHEET/TUBEFITTING- MAT'L: SA-516 70
CHANNEL -------------- MAT'L: SA-105/SA-106 B/SA-516 70
THIS DRAWING IS THE PROPERTY OF SER. NO. 14-8228A-1
GASKETS -------------- SHELL: COMP. NON-ASB TUBE: S.W. SS/NON-ASB
CONNECTIONS (SIZE-RATING)- SHELL: 2"-300# RFWN TUBE: 1.5"/1"-300# RFWN
[Link],INC. REF. NO.
DESIGN CODE: ASME SEC. VIII, DIV. 1, W/STAMP & NATL. BD. REGIST. PETROFINHairpin Heat Exchangers

REMARKS: SSPC-SP10 & PAINT w/ TWO (2) COATS S.W. EPO-PHEN. NACE INSPECTOR.
TULSA, OKLAHOMA DRAWN BY DATE
SEPARATED HEAD CLOSURE. (1) 3/4"-150# RF VENT ON T'SIDE. FOR SPECIFIED USE ONLY−NOT TO BE LOANED/COPIED
JJM 12/31/2014
DOMESTIC CRATE. NITROGEN PURGE. (1) GROUND LUG. APPROVED BY DATE
TWO (2) SETS OF SPARE GASKETS + 10% SPARE BOLTING.
PWHT PARTS IN CONTACT w/ S'SIDE FLUID. BRINELL-200 BHN MAX
WIND/SEISMIC CALCULATIONS PROVIDED.
EXCHANGER SPECIFICATION SHEET AND DRAWING NO. rev
NAMEPLATE FACSIMILE 14-8228
0
SHT 5 OF 6
 R.W. HOLLAND, INC.
Attachment 16
VENT BRANCH OF TEE
A.S.M.E. CODE CALCULATION SHEET Material : SA-234 WPB Nom. Wall Thk. : .308 "
(See Section VIII, Div. 1, 2013 for Nomenclature)
Stress, S : 17100 psi Min. Wall, t Min. : .27 "
(ENGLISH UNITS)
Nozzle Size : 0.75 " nom. Joint Eff., E (1) : .85
Serial No. : 14-8228A-1 Schedule : XXS Inside Radius, R
Date: 12/31/14 By : JJM Nozzle O.D. : 1.05 " (corroded) : .562 "
Customer: HONEYWELL INTERNATIONAL P.O. No.: 4500610374
Item No.: 05EA503 Exchanger Mod.: S4J1-12-00-SR-2/3B1.5/1B (2) trn = PR/SE-.6P = .026 " trn + C.A. = .151 "
Comments: None
SHELL TUBE
MAWP, (psig) : 654 /FV 653 TUBEFITTING (INTERNAL)
Temperature, (Deg. F) : 300 310 Material : SA-350 LF2 Nom. Wall Thk. : .467 "
Corrosion Allowance, (in.) : 0.25 0.125 ([Link]) Stress, S : 20000 psi @ 300 Deg. F. (@ Split Ring Groove)
Radiographic Requirement: Full Per Cust Shell Size : 4 " nom. Joint Eff., E (1) : 1.0
Comments: The Following Matls. Are Exempt From I. T. Per UG-20(f) & UCS-66(a) & (b). Schedule : XXS Inside Radius, R
SHELL/STRAIGHT RUN OF TEE Sleeve O.D. : 3 " (@ Split Ring Groove) (corroded) : 1.283 "
(2) trn = PR/SE-.6P = .043 " trn + C.A. = .339 "
Material : SA-106 B/SA-234 WPB Nom. Wall Thk. : .438 "
Comments: NONE
Stress, S : 17100 psi Min. Wall, t min : .383 "
Shell Size : 4 " nom. Joint Eff., E (1) : .85 TUBEFITTING (BENDING)
Schedule : 120 Inside Radius, R T/S Material: SA-350 LF2 U-Tubes? (Y/N) : Y F = 1.25
Shell O.D. : 4.5 " (corroded) : 2.062 " Stress, S : 20000 psi G (mean dia.) : 3.13 "
(2) tr = PR/SE-.6P = .095 " tr + C.A. = .345 " Pressure, P : 654 C.A.(shellside + tubeside) = .375 "
(5) T = FG/2 x SQRT(P/S) = .354 " T + C.A. = .729 "
Comments: None USE T = 8.375 " Nom. Thk.
BRANCH OF TEE/SHELLSIDE INLET NOZZLE TUBE/RETURN BEND
Material : SA-106 B Nom. Wall Thk. : .436 " Material: SA-106 B/SA-234 WPB Stress, S (psi) : 17100
Stress, S : 17100 psi Min. Wall, t min : .382 " Outside Dia., Do : 2.375 " Joint Eff., E (1) : .85
Nozzle Size : 2 " nom. Joint Eff., E (1) : .85 Wall Thk, t : .154 " Inside Radius, R : 1.034 "
Schedule : XXS Inside Radius, R Min. or Avg. Wall (M/A) : A Mill Tolerance, mt : 0.125
Nozzle O.D. : 2.375 " (corroded) : 1.002 " Mean Radius Smallest Bend, Rb : 3 " Thin. Factor , f(6) : 1.198
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -
(2) trn = PR/SE-.6P = .046 " * trn + C.A. = .296 " FOR INTERNAL PRESSURE (2) @ 310 Deg. F.
Comments: * .0625" Min. Allow. Thk. Per Ref. (10) & (8). tr = PR/SE-.6P = .048 " tr x f = .057 "
REINFORCEMENT CALCULATION (3) [Exempt Per Tee in Shell] Use t = t(1-mt) = .135 " Min. Wall
BRANCH OF TEE/SHELLSIDE OUTLET NOZZLE FOR EXTERNAL PRESSURE (7) @ 300 Deg. F.
Material : SA-106 B Nom. Wall Thk. : .438 " Tube Length, L : 144 " L/Do = 60.6316
Stress, S : 17100 psi Min. Wall, t min : .383 " Do/t = 21.9743 (*)
Nozzle Size : 3 " nom. Joint Eff., E (1) : .85
Schedule : 160 Inside Radius, R Factor A : .00231 [Table G]
Nozzle O.D. : 3.5 " (corroded) : 1.562 " Factor B : 15410.4 [Table CS-2]
(2) trn = PR/SE-.6P = .072 " trn + C.A. = .322 " if Do/t is >= 10 if Do/t is < 10
Comments: None. Pa = 4B/3(Do/t) = 935. Pa is the smaller of:
REINFORCEMENT CALCULATION (3) [Exempt Per Tee in Shell]
Pa1 = (2.167/(Do/t)-.0833)B = 236.013
TUBESIDE INLET NOZZLE/STRAIGHT RUN OF TEE or
Pa2 = 2S/(Do/t)(1-1/(Do/t)) = 2409.76
Material : SA-106 B/SA-234 WPB Nom. Wall Thk. : .400 "
Stress, S : 17100 psi Min. Wall, t Min. : .35 " Where S = 27739 , as defined in
Nozzle Size : 1.5 " nom. Joint Eff., E (1) : .85 UG-28(c)(2)(a)(b).
Schedule : XXS Inside Radius, R Comments: None
Nozzle O.D. : 1.9 " (corroded) : 0.675 "
(*) t is reduced by the U-bend thinning factor (6).
(2) trn = PR/SE-.6P = .031 " trn + C.A. = .156 "
REFERENCES:
Comments: None (1) UW-12(d) (2) UG-27(C)(1) (3) Fig. UG-37.1
TUBESIDE OUTLET NOZZLE (4) Appendix 1-7 [Link] not required when nom. nozzle I.D. (not to exceed 20")
is < or = to the shell O.D./2, refer to UG-36(b)(1).
Material : SA-106 B Nom. Wall Thk. : .358 " (5) Appendix A, Para A131 (6) TEMA RCB-2.31 [1 + Do/4Rb]
Stress, S : 17100 psi Min. Wall, t Min. : .313 " (7) UG-28 (8) UG-16(b) (9) UG-16(b)(4)
Nozzle Size : 1 " nom. Joint Eff., E (1) : .85 (10) UG-45
Schedule : XXS Inside Radius, R
Nozzle O.D. : 1.315 " (corroded) : .425 " DRAWING No.
(2) trn = PR/SE-.6P = .02 " trn + C.A. = .145 " 14-8228
Comments: None SHT. 6 OF 6 REV. 0