Uls
colored in nature due to
most of d block compounds are unpane
A compound is coloured in nature it absorbs radiation
if
in Visible region
ft exhibits complementary color of absorbed light
cc white light Abs light
transmitted
Electron transition
Rules of
Laporte's selection rule
Electron transition is possible if sl
P d d d s I d s
S P S S P P
I 0 Z Z
Bl o o
z x x x
x x
transition bw same symmetry Goradelungerade
ie electron
orbitals is forbidden
orbitals transition are Laporte forbidden
d d
00 eg
laporte forbidden
humour tag
spin
selection rule ss o s It
5 1 zor lz SS O
00
I
2
d d transition allowed
are spin
00 ear Laporte forbidden
TI 1
St spin forbidden
Ako
colorless palecolor
spin forbidden is not great contributor as compared to
colors
Laporte forbidden
Hence we may get pale
PR V d d Transition cases
r i
B
0
BG voilet absorbs Ya
Y ya g l e Haas
3 13
gt3 µn2t µn3t ye
Sc yet's j3
Palepink violet Yellowpale
colorless Violet Green Violet
Tet2 Cot2 Ne cuz1 zn2t
colorless
Pink Green blue
Green
Voilet
3
Te13 Crt3 Mnt Pink Mn co12
Tet Ni12 Tet yellow
Green Vt
2
31
hydrolysis H2OyOHJ g Ht
CtfH2O
Green
violet
colour change due to change transfer
charge transfer Lmu
1 Ligand to Metal
ie transition takes
are colored in nature e
some compounds
place from ligand to vacant orbital of metal in VR
Lmct usually seen in high 0s
7 no d d transition
Eg kMn04 H
Mh Intense Purple color
of Foo
O_0 K
IF e
TE
O Mn laporte's rule se I
excitation
d as selection rule
P spin
Intense color
Powder
Kzorzoy Orange KzMn0y Green
Kacroy Yellow ftelson Blood Red
i cm Nos Violet sohn
Croy Red Nag
2
Te Hao no Brown ring complex
6
3e
2 Mice Metal to Ligand charge Transfer
if M is electron rich ligand is an acceptor
D Felbpy d
Red
01ji 48
P
Fete
e
2 Ecco t acceptor
2
3 Bpg
3 MMM metal to Metal charge Transfer
KFefficcano Fe teknDD
1 Prussian blue
Catalystie Properties
D block elements acts as good catalysts due to presence of elections
in d s subshells
Reactant molecule gets attracted
on the surface of metal by
concentration on
electrons increases the
interaction with these
surface of Metal
activation
reactants increasing and
As a result collisions b w
Physisorption
energy decreases I b
0000000000
chemisorption
catalyst due to variable
Transition metal ions can act
as
oxdn states
fet3 t 25042
21 0 52082 a Iz
2
3 z 212
Now gz 0 z
3 25042
2 52082 212
212
tests
Ne
Pd Hydrogenation of unsaturated hydrocarbons
Pt
I
Hydrogenation
PdBasog
walkers Pddal unsaturated Iec to c o
Process
KU Y KI t Oe
Moroz decomposition of KUOz z
Te
Te Haber Process Nat3h2 2MHz
C
Methanol CotHz watergas CHIH
Cruz Prep of
1 Uzo5
I 503
05 contact process 502 20
Ostwald's process NO LaOz NO2
PHkh
unsaturated hydrogy
Tidy Leighan Natta catalyst
Polymerisation of
Et 3
Formation of complexes
due
d block elements form large
no
of complexes
I smaller size
ii High charge density
d subshell orbitals
Iii Presence
of
Formation of interstitial
compounds
fit B c n
D Block elements form interstitial compounds when small non
metallic elements like it B c N are trapped in interstitialsites
Interstitial compounds are usually non stoichiometric
Usefulpropert
hard high MP than their metal i chemically inertness
Very
retain metallic conductivity
f
Magnetic Properties
is due to and
orbital motion
substances spine
Magnetic properties of
electron
of
1 Paramagnetic attracts to magneticfieild
Para att Tetroatt Terriatt Antiferrolaittrep
dialup
Paramagnet attracts to magnetic field 17 9
Oz Koz Kaos Sa No Noa 602 Tet Gt3 Cu
Eg
Hsu pls flu
4s LCLt BMO
1 contribution due to orbitals
1 contribution due to spin of electrons
4th negligible in case of 3d elementslions
µ
due to quencing of orbitals µL o for 3d
o
µ 14 J4x z Wtf BM
5
Iz Total spin
flforzdion
3 Te n z V 8 BM
O
set µ
5313M
test n4 µ
Mggq
cut cut Tet wit Zn't 147
Vt Crt3 Mn
materials
i Diamagnetic weakly repelled in magnetic field
Ln Cut Set3 CO2 Nacl H2o Kzcroce
KMnole Graphite
2mHz 4 Or xxx
i'll Ferromagnetic domain aligns in same direction
Te co Ni Gd Croz 1 99
strong attraction in magnetic feild
D Terrimagnet
yapping you o B
Fezog Mgteaog
D Antiferromagnet
Eg
Mno µpfII You 0
Alloys Last day before eyamGEE
Nichrome German silver Brass Bronze Gun metal
O Invar steel
Belt metal Deverda Duralumin Magnalium solder metal