KYAMBOGO UNIVERSITY
FACULTY OF SCIENCE
DEPARTMENT OF CHEMISTRY
BACHELOR OF SCIENCE IN CHEMICAL
ENGINEERING
YEAR 3, SEMESTER 1
ENVIRONMENTAL AND WASTE MANAGEMENT
ASSIGNMENT AND PRESENTATION (GROUP 10)
NAME [Link]: SIGNATURE
ADENGO PAUL 13/U/7131/CHD/PD
OKELLO ALLAN 13/U/7249/CHE/PE
ATUHAIRE DAN 13/U/7141/CHD/PD
MUKALAZI PATRICK 13/U/7237/CHE/PE
AINEEMBABAZI EDITH 13/U/7133/CHD/PD
KATWESIGYE ADELLAH 13/U/7228/CHE/PE
TURAMYEOMU GLORIA 13/U/7206/CHD/PD
MAGEZI ROBERT 13/U/7233/CHE/PE
1
SOLAR RADIATION
Solar radiation is the radiant energy emitted by the sun inform of electromagnetic energy. Solar
radiation is all the light and the energy that comes from the sun and its energy. Solar radiation is
also sunlight. Electromagnetic energy consists of discrete packets of energy called photons.
Solar radiation or energy of the sun is estimated to be around 5700 kw/km2 which travels to all
direction in planetary system.
THE SUN AND ITS ENERGY
The sun is a star or object located at the center of planetary system. It is composed mainly of
hydrogen and helium.
Hydrogen is converted into helium by thermonuclear fusion thereby releasing huge amount of
energy.
The released energy is converted into thermal (heat) energy, raising the temperature of the sun to
levels that are 20 times the temperature of the earth’s surface.
The heat energy travels through space in terms of electromagnetic waves hence transferring heat
with it. This process is known as solar radiation.
The energy is transferred at the speed of light (2.998×108 m/s in a vacuum) with wave-like
motion. Speed of light, c = ƛv where v is frequency and ƛ is wavelength
Radiation has origins in the absorption and release of energy by electrons. Molecules possess
energy in form of kinetic energy and electrostatic potential energy due to the orbiting of
electrons around the nucleus. Molecules also possess rotational and vibrational energy.
According to quantum mechanics theory, unique electron configurations occur around each
nucleus. The energy level is due to the orbit, and the vibration and rotation of the electrons. A
molecule will transfer to higher energy level by absorbing electromagnet radiation.
Electromagnetic radiation is emitted when electrons drop an energy level. The radiation energy
emitted is in discrete packets called photons. A spectrum of radiation is emitted because the
excitation of electrons differs when they are associated with rotational, vibration and electronic
states of the molecules and atoms.
2
INVERSE SQUARE LAW
It can be used to calculate the radiant energy that reaches the earth’s system (earth’s surface and
atmosphere).
4 πR 2
Inverse square law: I = E
4 πr 2
Where I is radiant energy at the surface of outer sphere
E is the radiant energy at the surface of the object
4πR2 and 4πr2 are the surface areas of the object (sun) and outer surface
Due to losses of the radiant energy to space, reflections, absorption by other planets, not all
reaches the earth.
Only about 1366 w/m2 of energy reaches the earth’s surface and atmosphere. This energy is
called solar constant.
SOLAR CONSTANT (SO)
Solar constant is the amount of energy received at the top of the earth’s atmosphere on a surface
oriented perpendicular to the sun’s rays at a mean distance of the earth from the sun. The solar
constant equation is;
R2
So = E (sun) ×
r2
Where radius of the sun, R = 6.96×105 km and sun-earth distance, r = 1.5×108 km
ASSUMPTIONS OF THE SOLAR CONSTANT EQUATION
i. The equation applies at the top of atmosphere not surface of the earth or below the
atmosphere.
ii. The surface receiving the radiation is perpendicular to the radiation.
iii. The surface receiving the radiation is at a mean sun-earth distance.
iv. Radiation emission from the sun remains constant.
LAWS GOVERNING ENERGY TRANSFER THROUGH RADIATION
3
i. Radioactive heat transfer process is independent of the presence of matter. It can even
move through empty space.
ii. All bodies emit radiation, wavelength and energy characteristics of that radiation are
determined by the body’s temperature.
iii. The energy flux drops as the square distance from the radioactive body.
iv. Radiation goes through a transformation when it encounters other objects.
SOLAR RADIATION AND ITS SPECRTRUM
The sun emits a nearly continuous spectrum of energy, ranging from very short wave length and
high packets of quanta, to low energy and long wave lengths.
On earth, there are four wavebands of electromagnetic radiation that are particular interest and
these are;
Ultraviolet band
Photo-synthetically active band
Near infra-red and infra-red bands (Ross,1980)
Ultraviolet band (0.29-0.38 µm)
This band possesses high energy. It can damage molecular bonds. Its presence leads to the
photochemical formation of ozone is absorbed in the stratosphere. Its flux density is relatively
low since most ozonenis absorbed in the stratosphere. Therefore about 0-4% of incoming solar
radiation is in this band.
Photo-synthetically active band (0.38-0.71 µm)
This spectral band is the visible band. It contains visible energy across the primary colours of
purple, blue, green, yellow, orange, red. It provides the energy for photosynthesis. Between 21-
46% of solar radiation is in this band.
Near infra-red band (0.71-4.0)
This waveband is not visible, but contributes to the heat budget of organisms.
Long wave or terrestrial radiation (3.0-100 µm)
4
This is the radiation emitted by bodies on earth. Its flux density is a function of the surfaces
temperature and emissivity. Anybody warmer than 0K emits radiation.
Distribution of solar energy by waveband
waveband Energy %
0-300 1.2
300-400, ultraviolet 7.8
400-700, visible 39.8
700-1500, near infra-red 38.8
1500 to infinity 12.4
The spectral quality of light incident to the ground is affected by selected absorption by water
vapour gases and aerosols.
Water vapour is a strong absorber of light with wavelengths of 100, 1400, 1600, and 1900 nm.
Ozone absorbs ultraviolet light (ƛ < 300 nm)
Carbon dioxide absorbs strongly in the 2750 and 4250 nm bands and oxygen absorbs 690 and
760 nm sunlight (Bonhomme 1995).
RADIATION LAWS
1) PLANCK’S LAW
It defines the amount of energy emitted as a function of temperature and the wavelength of the
source with units of Jm-3/s.
2) STEFAN-BOLTZMANN LAW
It states that the radiant energy emitted by a surface is proportional to the fourth power of its
temperature.
5
E = ᵷT-4 (Wm-2) where E is the energy, T is the temperature and ᵷ is Stefan-Boltzmann
constant (5.67×10-8 Wm-2K4)
Luminosity equals the solar constant (S O = 1366) measured at the earth’s surface multiplied by
the area of a sphere (4πR2) with radius (R = 1.5×1011) equal to the distance between the earth and
the sun.
L = SO×4πR2 = 3.9×1026W
Knowing that the radius of the sun is 6.69×10 8m, we can form a balance between the black body
radiation law and the emittance of the sun.
3.9× 1026
To calculate its temperature ᵷT = yields a surface temperature of 5770K
4 πR 2
3) WIEN’S LAW
Is derived by examining the maximum of the function. This equation is derived by solving for
wavelength when the partial derivatives of Planck’s law with respect to wavelength equals to
zero.
2897
E = 0, the solution yields ƛmax = (µm)
Tc
SOLAR RADIATION DISTRIBUTION ON THE EARTH’S SURFACE AND
ATMOSPHERE
When the solar radiation reaches the earth, it is partially absorbed in different parts of the climate
system.
However the earth is not a perfect blackbody, it absorbs all the radiation but reflects part of it
back to space.
Since the earth has a spherical shape, incoming solar radiation is unequally distributed over the
planet due to the sun movements.
49% of solar radiation goes through atmosphere and it is absorbed by the hydrosphere, 31% of
solar radiation is reflected back to space, 22% of the radiation is reflected by the clouds, 9%
absorbed by the earth’s surface and 20% is absorbed in the atmosphere.
6
The solar radiation absorbed by the earth and atmosphere warms the earth’s surface and
atmosphere. However the earth’s surface cools in two ways;
i. Radiates heat at a slow rate but not rapidly due greenhouse gases.
ii. The oceans evaporate losing latent heat, also small water bodies on the land hence
cooling.
The atmosphere cools by radiating infra-red radiation to space losing ground heat flux.
SOLAR RADIATION BALANCE OF THE EARTH AND ENERGY BALANCE
RADIATION BALANCE
Net radiation Q* = Total radiation in – Total radiation out
Total radiation in
It involves both short waves (L ) and long waves (K )
Total radiation in = (L ) + (K )
Short wave (K ) = (S + D) where S-direct beam solar, D-diffuse (scattered) solar
Total radiation = (L ) + (S + D)
Total radiation out
It also involves both long waves (L ) and short waves (K )
Total radiation out = (L ) + ( K )
Short wave ( K ) = a ( S + D) where a is albedo, which is the ratio reflected to incoming
energies.
Total radiation out = (L ) + a (S + D)
Q* = (L ) + (S + D) – (L ) - a (S + D)
Q* = (L - L ) + [(S + D) - a (S + D)]
ENERGY BALANCE
7
Net radiation = H + LE + G
Q* = H + LE + G
(L - L ) + [(S + D) - a (S + D)] = H + LE + G
Where H – sensible heat flux (energy used to change temperature of atmosphere), LE –
latent heat flux (energy used to change state of water), G – ground heat flux (energy used to
change temperature of subsurface.
PROPERTIES OF SOLAR RADIATION
The sun is;
Located at the center of the solar system.
A distance of around 150×106 km from the earth.
With a surface temperature of around 5770K.
Energy flux at the surface of the sun is approximately 63×106 W/m2
The earth and other planets are not perfect black bodies since they do not all the incoming solar
radiation but reflect part of it back to space. The ratio between the reflected and incoming
energies is the planetary albedo. The earth’s albedo is about 0.3. This fraction of incoming
radiation is reflected back to space. The other 0.7 part of incoming solar radiation is absorbed by
the planet.
Because of its spherical shape, incoming solar radiation is not equally distributed over the planet.
At each instant, only the sun lights only half of the planet’s surface with maximum radiation
coming in at local moon and less in other times of the day.
The total daily radiation decreases from equator to pole. Thus the earth’s surface should
inherently be warmer at the equator than it is at the pole.
The earth’s axis of rotation tilts at a 23.5˚ away from the plane of rotation around the sun during
solstice time. During solstice, the pole pointing to the sun and surrounding area receive radiation
during all 24 hours of the day while the opposite pole does not receive any solar energy.
This has the potential for making the poles as warmer than the equator in their respective
summer time. If it were not for the large albedo of the Polar Regions.
8
SOLAR RADIATION DISTRIBUTION Outgoing
longwave
radiation 235
Reflected solar Incoming solar
radiation 107 radiation 342W/m2
W/m2 Emitted by
atmosphere Atmospher
165 ic window
40
Reflected by the Absorbed by
clouds, aerosol atmosphere
and atmosphere 67
Green houses
77
gases 324
Latent heat
Black radiation
Reflected by
the surface 30
350 390 324
Absorbed by the surface evapo-tranpiration 78 surface absorption
Thermals 24
SPECTRUM OF SOLAR RADIATION (EARTH)
Irradiance
2.5— U.V Visible Infrared
2.0-- sunlight without electromagnetic absorption
1.5-- ideal blackbody (3230˚C)
1.0-- sunlight at sea level
0.5-- atmospheric absorption bands
0.0--
9
Wavelength (nm)
IMPORTANCE OF SOLAR RADIATION
1) Solar radiation acts as a condition in photosynthesis in plants. It is required in form of
sunlight in plants on terrestrial land. It is also required by water plants like
phytoplankton. The manufactured food like starch, proteins, carbohydrates in turn act as
food for plants and animals.
2) Solar radiation influences the climate system of the earth and its atmosphere due to
movement of the sun. This results into change of seasons for farming. The sun movement
also regulates overheating of the earth since it changes position.
3) Solar radiation is a medium for vision. Therefore human activities can take place due
presence of light from the sun.
4) Solar radiation is a source of vitamin D which is a required body nutrient in animals and
human beings. U.V light reacts with steroids under the skin to form vitamin D hence
promoting proper growth and strong bone development.
5) Solar radiation is a source of solar electricity when captured by special solar panels. Solar
panels convert the captured light into electricity which is used for light, cooking and
other activities.
6) Solar radiation takes part in rainfall formation. It melts the condensed water vapour into
water. Since water is denser than air, it falls back in form of rain water. The rain water
can be used for drinking, cooking, for plants in form of irrigation water.
7) Solar radiation encourages periodism in plants. Since radiation is in form of sun light,
encourages plants to respond to both day and night time.
8) Solar radiation is a source of warmth to the earth and its atmosphere. Since the earth
absorbs part of the incident radiation, stores some radiation which provides warmth for
human activities.
9) Solar radiation acts as a drying agent when drying foods for storage, washed clothes.
10)
10
References
Baldocchi, D. (n.d.). Lecture 5 Solar Radiation Part 1 Principles.
Wikipedia. (2015, November 16). Retrieved from The free encyclopedia: [Link]
11