Understanding Materials and Polymers
Understanding Materials and Polymers
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In this chapter, you will learn about different kinds of materials that are
used to make various objects. You will also learn why these objects are
made of certain materials
CLASSIFYING MATERIALS
A material is a substance or a mixture of a substance that constitutes
an object. Materials can be pure or impure living or non living matter
The materials we have in everyday life have particular properties
which distinguish them from others .How can we classify them? The
materials can be natural or synthetic. They can further be classified in
to four main groups: metals, polymers, ceramics and composites they
may be solids, liquids and gases. Some examples of naturally occurring
materials and their products include sand, wood, grass and metals. The
synthetic products include alloys, plastics and artificial fibres.
Illustration in the book shows matching a material with its
property
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The physical properties of both natural and synthetic materials
determine their uses
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arranged in an orderly manner with strong forces of attraction in
between their particles
Metal have a continuous structure in 3 dimensions.
Polymer is long continuous chains. The long chains are joined
together by weak forces of attraction.
Ceramics are prepared from powdered materials for example
clay mixed with water and hardened by heat.
Composites are made by combining two or more materials that
have different properties that blend into each other. The
combined materials give composites unique properties
CERAMICS
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Ceramic materials such as cups, pots, kettles are made from
clay. The clay used to make ceramics contains compounds of
silica, nitrogen and oxygen. For the production of ceramics, clay
is crushed, grinded and sieved to get fine clay. Then it is mixed
in water to make paste known as slip. The slip formed is moulded
in to different shapes and dried. The hardened shapes heated
strongly in a kiln and little salt is added to make it shiny. The
high temperature expels all the water and causes chemical
changes that make clay stronger and harder. This makes
porcelain non porous, smooth and shiny. Colours may be added
to make the ceramics objects attractive
GLASS
Glass is made from ordinary sand. You can make glass by
heating ordinary sand (which is mostly made of silicon dioxide)
and sodium carbonate until it melts and turns in to a liquid. The
molecular structure of glass makes it rigid, hard and causes it to
shatter easily
CONCRETE MATERIALS
To make concrete, sand is mixed with water, cement and stone
aggregates .A lot of construction work is done using concrete.
Concrete is made using specific ratio of stone aggregates, sand
and cement. The materials are mixed well with water and
allowed to bond with each other .This process of bonding is
called setting
Advantages and disadvantage of some building materials
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Soil Readily available Requires periodic
Cheap Easily weakened
by water
Burnt clay bricks They stay longer It is expensive
They are easy to Requires skilled
construct with labour to make
They are hard
They are strong
Resistant to fire
Wood It is cheap Weak in long run
Readily available Easily catch fire
Easily replaced Attacked by
termites
Glass Strong Can easily break
Resistant to fire Expensive
Enough lighting in
the house
Little material
required
POLYMERS
Protein Polythene
Silk Poly propene
Cellulose Nylon
Rubber Artificial Rubber
The word polymer comes from two Greek words: ‘poly’ meaning many and
‘mer’ meaning part / unit. Polymers are therefore, long chains of small units
joined together. Therefore, a polymer is made of many repeating units called
monomers. Each small unit is actually a chemical substance. Polymers can
be either natural or synthetic. Our bodies are naturally built by large protein
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molecules from small units called amino acids. Our hair, nails etc are made
up of proteins. Other examples of natural polymers are cellulose, which
includes cotton, sisal, wool etc. These are polymers which exist on their own
and man has no influence on their existence. Synthetic polymers include
polythene, synthetic rubber, polyester, nylon etc. These are polymers which
are manufactured in industries.
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cannot be softened or remoulded but instead decompose on heating for
example Bakelite and melamine.
Plastics
Fibres
Fibres, like plastics, are made from polymers. They are extremely long hair
like strands compared to their width. The fibres are strong, flexible and can
be spun in to yearn. They are used to make thread that can be made in to
cloth. Fibres can be classified in to main groups: natural fibres and synthetic
fibers.
Fibre Use
Sisal Ropes, bags
Cotton Clothing
Wool Clothing, warming
Silk Clothing
Nylon Ropes, Garments, Carpets
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When we go to the market, we usually get items wrapped or packed in
plastic or polythene bags .This is one reason why plastic waste keeps
accumulating in our homes. Disposal of plastics is a major problem to the
environment. Some materials decompose through natural processes such as
action by bacteria, these are called biodegradable. However others that
cannot decompose by natural processes are called non biodegradable
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Melamine Partially burns to blacken the surface
Glass Expands and breaks
Plastic place Melts in to a liquid which hardens on cooling
PRPERTIES OF DIFFERENT GBUILDING MATERIALS
Material Property
Iron sheet High tensile Not breakable Not porous
strength
Grass Relatively Breakable porous
durable
Tiles Low tensile Easily Not porous
strength breakable
Durable
Glass Low tensile Easily Not porous
strength breakable
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TEMPORARY AND PERMANENT
CHANGES
By the end of this chapter, you should be able to:
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Temporary and permanent changes may be periodic in some
cases and reversible or irreversible in others.
Change Classify(Permanent or
temporary)
Fermentation of sugar Permanent
Boiling an egg Permanent
Rotting of tomatoes Permanent
Ripening of bananas Permanent
Melting of ice Temporary
Rusting of iron Permanent
Dissolving salt in water Temporary
Temporary changes are the changes which occur only for a short period of
time. Generally, temporary changes are reversible. On the other hand, the
permanent changes which remain for a longer time and are not reversible
All the changes in the world are one of two types namely for a longer time
and are not reversible.
A change which can happen forward and backward both, that is, it can be reversed is called
a reversible
For example, when water is kept in the freezer for some time, it transforms
into ice .But as soon as it is taken out of the freezer, it turns in to water
again. This is a reversible change.
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Changes which cannot be reversed are called irreversible changes. When a
piece of paper is burnt, it turns in to ash. It cannot become paper again. Your
height cannot be decreased. These are irreversible changes and such
changes cannot be reversed at all. For example burning wood in ash and
baking of cake.
CHANGE FACTOR(Answers)
Burning charcoal Heat
Boiling an egg Heat
Rusting of iron Air and water
Setting of cement Water
Chemical changes are changes that occur in the chemical properties of the
substances like it as flammability, reactivity, stability etc. Most of the
chemical changes are irreversible changes. Once the chemical properties of
a substance are changed, it becomes another substance. Thus, it cannot
return to its original state e.g. mixing chemicals, cooking, burning of woods.
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- Changes in mass occur i.e. there is increase or decrease in the mass of the
product formed.
- The reaction is not accompanied by great heat changes (except latent heat
changes accompanying the reaction)
- No changes in mass occurs i.e. the mass of the product is the same as that
of the reactant.
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MIXTURES, ELEMENTS AND
COMPOUNDS
By the end of this chapter, you should be able to:
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Many impurities are harmful but others may be harmless. Some
impurities can be seen but others cannot be easily seen.
When a substance contains an impurity, its melting point decreased
and its boiling point rises. Also, it melts and boils over arrange of
temperatures, not sharply. Higher impurity leads to larger change in
melting and boiling points and sea wider temperature range over
which melting and boiling can occur. Pure water melts at about 0 oC.
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or more substances
Copper (ii) Cannot be separated by Compound
Sulphate physical means
Muddy water Can be separated by Mixture
physical means
Potassium Cannot be separated by Compound
permanganate physical means
Cake Can be separated by Mixture
physical means
But the simplest method used in the laboratory is to test the purity by
determining the melting or boiling of a substance
A pure substance has a definite, sharp, melting point and boiling point.
Melting points and boiling points are different of each substance
which can be compared with data given in the book.
ELEMENTS.
An element is a pure substance that cannot be split or divided in to two
or more simpler forms by any known chemical means
It is made up of atoms of the same kind. Element s is divided into
metals and nonmetals. Metals are elements which are good conductors
of electricity are hard, ductile, lustrous, and malleable. Elements are
used in manufacturing material we cusec in our daily life for example
building, and roofing materials , medicine, jewelry, currency, kitchen
equipment and many others
Elements and their symbols
In chemistry, a symbol of an element is generally a letter (s) that
represents atoms of that element. Atoms of elements are represented
by symbols. The first letter is always capital letter. The second is
always small letter
The symbols originate from the original Greek of Latin names of the
elements. Thus they may not rhyme with the actual name of the
element.
When an element is represented by a single letter, it must be a capital
letter.
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For example
Nitrogen N
Oxygen O
Sulphur S
When a symbol is represented by two letters, the first is capital and the
other is a small letter. For example
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COMPOUNDS
Examples of compounds
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hydroxide Oxygen,
Hydrogen
Potassium Caustic potash KOH Potassium,
hydroxide oxygen and
hydrogen
Calcium Limestone CaCO3 Calcium , Carbon,
carbonate Oxygen
MIXTURES
Most substances are found mixed in nature. The air that surrounds us is a
mixture of gases, the water we use contains dissolved substances, the soil
we grow food on is a mixture of various minerals and the juice we drink and
blood in our bodies are made up of different components which are
physically combined. Such substances are referred to as mixtures. We found
out that a mixture is made up of two or more components which are
physically combined such as ; food , are present in any proportion , can be
easily be separated by physical method and do not require any change in
energy to take place
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How do mixtures differ from Compounds?
When two liquids are mixed together and they dissolve in to each other to
form a uniform layer, such liquids are called miscible liquids. When they
form two distinct layers such liquids are called immiscible liquids.
Immiscible liquids from liquid junctions which separate the two layers and
less dense liquid form the upper layer.
Fractional distillation
When the solution mixture is heated the vapour rises up the fractionating
column, which is packed with beads or glass plates? The vapour condenses
where and trickles down. They continue until the whole fractionating column
gains the temperature of the most component.
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Separation of Immiscible Liquids
When some liquids are mixed, they do not dissolve in one another. They are
completely insoluble in each other. Immiscible liquids are liquids which
separation into layers when they are mixed .An example of this type is a
mixture of oil and water
This method is used to separate two solids where one of them sublimes
when heated. On heating, the component which sublimes / vaporizes and is
deposited on a surface where wit solidifies again
OXIDES
What do you observe when you burn a piece of paper? One of the products
observed is smoke, when substances burn in oxygen; they form products which may
be gases, liquids or solids. The gaseous products may not be visible and disappear
leaving no trace behind. The formation of some other products is accompanied by
changes in appearance, color and texture.
The nature of the oxide formed depends on the element that has been burned in
oxygen.
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Metal + oxygen metallic oxide (most of which are basic)
Metals burn in oxygen forming basic oxides which when dissolved in water forms
basic or alkaline solution i.e. solutions the turn red litmus paper blue and have
effect on blue litmus paper.
Magnesium burns in air (oxygen) with a brilliant white flame forming white ash
(powder) of magnesium oxide.
Sodium burns in excess oxygen with a bright yellow flame to form a yellow powder
of sodium peroxide.
Non-metals burn in air to form acidic oxides (acid andydride). These oxides dissolve
in water to form acidic solutions that turn blue litmus paper red and have no effect
on red litmus paper.
An acid anhydride is an oxide of a non metal that dissolves in water to form an acid.
Examples include:
RUSTING
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This is the process by which iron combines with oxygen in the presence of water to
form brown solids of hydrated iron (III) oxide called rust.
Rust is a brown solid of hydrated iron (III) oxide formed when iron combines with
oxygen in the presence of water. The chemical name of rust is hydrated iron (III)
oxide and its chemical formula is Fe 2O3.xH2O. Conditions necessary for rusting
Air/oxygen
Moisture/water.
Experiment from the book to find out conditions necessary for rusting to
take place
Materials containing irons, such as any kind of steel, will rust if exposed to air and
water. Rust is an iron oxide, which usually takes the form of an orange brown on the
surface of the metal. Other metals form on the surface in a similar way, although we
usually say they corrode.
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pH
Temperature
Humidity
How rusting can be prevented
Rusting has a negative effect on the materials when exposed to the
conditions you have stated before. For this reason methods of
preventing rusting are very important. In order to prevent rusting, we
must prevent these conditions from getting in to contact with iron
containing material. It can be minimized by
Galvanizing the material
Painting the metal
Electroplating
Greasing or oiling the metal
WATER
Water is an important natural resource. All living things need water to remain alive.
For example, water forms about two thirds of the human body and helps it to
function normally. Earth is known as the blue planet because 71% of the earth’s,
surface is covered by water. Water also exists below the surface and as water
vapour in the atmosphere
The earth has an abundance of water, but unfortunately, only a small percentage
(about 0.3%), is available for use by humans. The other 99.7% is in the oceans, soils
icecaps and floating in the atmosphere. Still, much of the 0.3% that is useable is un
attainable
Most of the water used by humans come from rivers and bore halls.
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There are many sources of natural water that we use in our everyday life. The
common sources of natural water include; well, spring water, bore hall water.
However the water from different sources differs in purity. Ordinary water comes
from any sources may contain dissolved mineral salts, suspended solids, plants,
animals of different sizes and sometimes oily materials.
Question
Can you name any other water sources? Name the impurities likely to be present in
the water from different sources
Do living things contain water? Plants take in water through their roots and utilize it
to make their own food. Through transpiration, Plants lose water to the atmosphere.
Animals also need water to keep their cells turgid and also to carry out many body
metabolic activities that require water. Without water all organisms would be dead.
Question
Imagine, you wake up in the morning and there is no water at home. Will your
mother be able to cook, clean utensils, wash clothes or bathe?
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What other activities you would not be in position to-do?
Water cycle play important role in the recycling of water and maintaining the water
balance on earth.
Because of the different conditions and activities on earth, water is always moving
and being converted from one state to another reversibly. This process of water
movement is driven by the sun as the source of energy
When the sun shines, liquid water is converted to vapour. The vapour is easily
blown away by the wind across water bodies towards high mountains. As it rises it
cools and finally condenses again to liquid water droplets which float in the sky to
form clouds. The drops may join together and fall as rain. The rain water passes in
to the springs, rivers and seas. Once again it evaporates and the cycle is repeated.
Water on the earth’s surface is continuously changing in to vapour, going in to the
atmosphere and falling as rain
COMPOSITION OF WATER
PROPERTIES OF WATER
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4. Pure water is neutral to litmus i.e. has no effect on litmus.
The properties of water make it suitable for organisms to survive in during differing
weather conditions. Ice freezes as it expands, which explains why ice is able to float
on liquid water. During the winter when lakes begin to freeze and then moves down
toward deeper water this explains why people can skat5e on or fall through a frozen
lake.
Water undergoes chemical changes when it is added to some other substances .It is
a good solvent and it is often referred to as the universal solvent. Many of
substances such as salts, sugars, acids, alkalis and some gases (especially oxygen,
carbon dioxide) dissolve in water.
Water reacts with some metals and the vigour depends on the position of the metal
in the electrochemical series.
Zinc Iron Tin Lead (Hydrogen) Copper Silver Mercury Platinum Gold do not react
with water in any form
Water has the ability to act as both an acid as well as the base c. It acts as a base. It
acts as a base to acids stronger than itself, and acts as an acid to bases stronger
than itself.
Water reacts with other substances to form products with different chemical
properties. Thus the presence of water can be shown chemically using anhydrous
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copper sulphate or cobalt chloride paper. These chemical substances give specific
changes in colour when water is added to them.
Water is chemically tested for using anhydrous copper (II) sulphate of cobalt
chloride paper. When water is added to anhydrous copper (II) sulphate, it changes
colour from white to blue. Or when water is added to cobalt chloride paper, it
changes color from blue to pink.
Have you ever wondered why you are advised not to drink un boiled water
from natural sources?
Natural sources of water are found in many parts of Uganda as Lakes, Rivers and
springs which never dry up most of the year. This means that almost all the water
that we need for drinking, farming and industry come from the rivers or from
underground water sources.
Underground water usually contains minerals from the rocks it passes through
because water is a good solvent. Thus there is a danger that it can also contain
harmful substances to humans and animals. Natural water may also contains micro
organisms and industrial waste that has not been treated properly, such as the
waste from the factories
Wastewater is generated from many sources. Waste water from shower, bathtub,
washing machines, dishwasher, kitchen sink and toilet is all considered sewage.
Once water is used for any activity, its discharge becomes waste. Most of the water
is discharged as waste water
Sewage is primarily a mixture of organic and inorganic components along with biological
organisms (bacteria and viruses); together, this makes a very complex mixture. Thus
sewage is a mixture of waste materials from the home mixed with water
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There is always requirement of sewage treatment to avoid water pollution. Sewage
treatment is the process of removing contaminants from waste water containing
mainly household sewage plus some industrial waste water
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are formed, their composition ‘physical properties and how they are
weathered to form soil
FORMATION OF ROCKS
The planet earth was formed about 4.5 billion years ago. The force of gravity
pulled the heavier element s together first, forming the core . The lighter
elements then formed the earth’s crust about 3-4 billion years ago. The
mantle developed as a layer between the dense core and the light crust. This
structure still exists today.
Figure showing in the book showing the mantle of the earth
CLASSSIFICATION OF ROCKS
Classification of rocks
Igneous
Igneous Rocks
Metamorphic
Sedimentary
Igneous rocks are formed as a result of the cooling of molten rock from the crust
and upper mantle. The molten rock is called magma when it is still below the
surface and lava when it reaches the surface
Magma is found in the outer mantle; it is hot, liquid rock that is under
pressure from the rocks above it. When it cools it turns to solid rock
When liquid magma rises to the surface from the volcanoes the cooling occurs
quickly and forms lava. Thus igneous rocks are made of material that was once
molten. Their structure usually contains crystals that are formed as the molten
material cools
Rocks form crystals when solutions of minerals cannot absorb any more dissolved
minerals. Some of each mineral type precipitates out of solution to form the centre
of the crystal. This then provides a surface for more mineral ions to precipitate. The
crystal becomes larger until the solution disappears. Examples of indigenous rocks
are granite and basalt
Sedimentary Rocks
Sedimentary rocks are formed by the weathering of existing rocks at the earth’s
surface. They can also be formed when dead plants and animals accumulate and
form fossils or dissolved materials precipitate out of water. Weathering processes
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release small mineral particles that accumulate to form sediment. Over a period of
time, layers of sediment build up to form sedimentary rock.
The smallest particles are clays, followed by silt and then sand, these particles are important
in the formation of soils. Large particles of gravel s and small boulders can also be found in
sediments
The particles are transported by streams and rivers and then deposited as
sediment. Each layer of sediment becomes more com pact and harder because of
the pressure created by the newer deposits above them. Examples of sedimentary
rocks are limestone, Sand stone and shale
Metamorphic Rocks
Metamorphic rocks are formed from existing rocks when the temperature is above
150oC or pressure is above 1480 atmospheres or both. The heat and pressure,
causes changes in the rock crystal structure without melting the existing rock. The
existing rock therefore becomes metamorphic rocks, and a metamorphic rock
becomes another metamorphic rock. Metamorphic rocks are usually harder then
sedimentary rocks
Why the rocks look different? From the origin and process of formation, the different
rocks differ in their characteristics.
Question
All the rocks on earth keep on changing, but these changes normally happen very
slowly. Some changes happen below the earth’s surface. Some changes happen
above the ground .All these changes are part of the rock cycle. The rock cycle
describes each of the main types of rocks, how they form and how they change
Several processes can turn one type of rock. The key processes of the rock cycle
are crystallization, erosion, sedimentation and metamorphism
MINERALS
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Minerals can be defined a ‘homogeneous’ naturally occurring substance with a
definable internal structure. Minerals are building blocks for rocks
‘’All rocks are made of minerals ‘’Minerals are natural substances in which the
particles are arranged in patterns, and often occur in beautiful shapes called
crystals. Metals, gems and industrial materials of many kinds are made of minerals.
Examples of minerals are quartz, mica, and feldspar
Only eight elements oxygen, silicon, aluminum, iron, calcium, sodium, potassium,
and magnesium make up 99%. For example, quartz is made up of silicon and
oxygen, which are the two most common elements that make up the earth
Some minerals are made up of only one metal element, such as gold, silver or platinum, are
called native metals.
Characteristics of Minerals
The scale ranges from 1 -10 points. Ten (10) on the point scale is the hardest, and
one (1) on the scale is the softest. If a mineral is higher on the Mohs scale than
another, it can scratch the one which is lower
How do larger rocks turn in to small rocks? Large rocks are continually turning in to
smaller pieces by the process of weathering. Weathering is the process that
changes solid rock in to sediments. Sediments are small rock particles; with
weathering the rock is disintegrated. It breaks in to pieces. These changes usually
occur where the rock is located but can continue even when the sediments are
transported to another place
Types of weathering
There are two types of weathering: physical (mechanical) weathering and chemical
weathering. Physical (mechanical) weathering happens when rocks are broken into
pieces by physical means. There are many agents, or caused of mechanical
weathering
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PHYSICAL WEATHERING OF ROCKS BY ICE
Ice is an agent of physical weathering. Cycles of freezing and thawing can cause ice
wedging, which can break into pieces. The cycle of ice wedging starts when water
seeps in to cracks in a rock. When the water freezes, it expands. The ice pushes
against the cracks. This causes the cracks to widen. When the ice melts, the water
seeps further in to cracks. As the cycle repeats, the crack get bigger, finally the rock
breaks apart. These changes can be demonstrated in the figure in the
learner as guide
When the large block of chalk is scratched against the board, tiny pieces of the
chalk rub off the aboard. The larger pieces of chalk wear down and become smaller.
The same process happens with rocks
Abrasion is a kind of mechanical weathering that happens when rocks are worn
away by contact with other rocks
Abrasion happens whenever one rock hits another. Water, wind, and gravity can
cause abrasion. Water can cause abrasion by moving rocks and making them hit
each other
Did you know that earthworms cause a lot of weathering? The tunnel through the
soil and move pieces of rocks around. This motion breaks some of the rocks in to
smaller particles. This also exposes more rock particles to the agents of weathering.
Any animal that burrows in the soil causes mechanical weathering .Ants worms ,
mice , coyotes and rabbits are just a few of the animals that can cause weathering.
The mixing and digging by animals can also cause chemical weathering, another
kind of weathering
CHEMICAL WEATHERING
Precipitation such as rain and snow always contains a little bit of acid. However,
sometimes precipitation contains more acid than normal. Rain, sleet or snow that
contains more acid than normal is called precipitation,
Acid precipitation forms when small amounts of certain gases such as sulphur
dioxide and oxides of nitrogen, mix with water in the atmosphere. The gases may
come from natural sources, such as active volcanoes. They are also produced when
people burn fossil fuels such as coal and oil.
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The acids in the atmosphere fall back to the ground in the form of acid rain and
snow. Acids can dissolve materials faster than plain water can. Therefore acids
precipitation can causes rapid weathering of the rock
Have you ever noticed an old rusted car or a building? Rusty metal is an example of
chemical weathering. Metals react with air and moisture to produce rust. What
metal did it react with? In most cases, the answer is air. The oxygen in the air can
react with many metals. These reactions are a kind of chemical weathering called
oxidation. Rust is a common example of oxidation. Rocks can also rust if they have
a lot of iron in them. Many of the people think that rust forms only when water is
present, Oxidation happens more quickly. Oxidation can cause rocks to weaken.
Oxidation changes the metals in rocks in to different chemicals. These chemicals
can be broken down more easily than the metals that were there before
SOIL FORMATION
Where does soil come from? What do you think of when you see soil? Most of the
people relate soil to dirt that makes our clothes and utensils dirty
Soil is a lose mixture of small mineral pieces v, organic material , water and air , All
these materials help to make soil a good place for plants to grow . Do you recall the
process of weathering in the previous chapter?
Soil is made up weathered rocks. The rocks that break down to form soil are called
the parent rocks. Different parent rocks are made up of different chemicals hence
producing different types of soil
LAYERS OF SOIL
Soil comes in many colours and textures; some soils are dense, or packed together
tightly. Other soils are packed loosely. Like rocks, soil can change and. It changes
most near surface. So soil often has different layers .The thin layer on most of the
earth’s land is top soil. It is often soft and reaches in humus. It contains more air
and mater than the deeper layers. The middle layer is subsoil. It is drier and harder
than topsoil. It has more rocks
Bedrock is often below the surface. Here, not much has changed the rock. Bedrock
is soften very hard and dry
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