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Chemistry Basics: Atomic Structure & Metals

The document covers fundamental concepts of atomic structure, including protons, neutrons, and electrons, as well as electronic configurations and the periodic table. It details the properties and reactions of metals, specifically alkali and alkaline earth metals, including their behavior with air and water. Additionally, it outlines the reactivity series of common metals and their reactions with water and acids.

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Mariam Nageh
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0% found this document useful (0 votes)
15 views4 pages

Chemistry Basics: Atomic Structure & Metals

The document covers fundamental concepts of atomic structure, including protons, neutrons, and electrons, as well as electronic configurations and the periodic table. It details the properties and reactions of metals, specifically alkali and alkaline earth metals, including their behavior with air and water. Additionally, it outlines the reactivity series of common metals and their reactions with water and acids.

Uploaded by

Mariam Nageh
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Chemistry Term 1 1

Atomic Structure
Nucleus: 1. Protons (P+), Positive Charged, 1 a.m.u

2. Neutrons (N), Neutral, 1 a.m.u

Energy Shells

Valence Shells: Electrons (E-), Negative charged, 1/2000 a.m.u

Electronic Configuration Noble Gases: Inert gases- Group 0/8

1st shell = 2 electrons 1. Monoatomic

2nd shell = 8 electrons 2. Unreactive

3rd shell... = 8 electrons 3. Full outer shell (Exception Helium has 2e-)

➔ Electrons are always drawn in pairs 4. Argon: Lightbulbs

Atomic Symbol Helium: Party and weather balloons.

11: Atomic Number Transition Metals:

NA: Atomic Symbol Physical Properties:

23: Atomic mass number 1. High melting and boiling Point.

Neutrons = Atomic mass – Atomic Number 2. High Density.

The periodic table 3. High Strength.

Period: Same number of electron shells, 7 Chemical Properties:


horizontal rows.
1. Form coloured compounds.
Group: Same valency electrons, 8 vertical
columns. 2. More than 1 oxidation state.

1. Element are arranged according to their 3. Act as catalysts.


Atomic Number. Isotopes
2. Across the period, the metallic character Atoms of the same element with the same
decreases from left to right. atomic number but different mass number
Chemical properties: Depend on valence due to the difference in number of neutrons.
electrons. Ions: Charged Particle
Physical properties: Depend on mass. 1. Metals lose electrons and become positive
ions.

2. Non-metals gain electrons and become


negative ions.
Chemistry Term 1 13

Metals
Properties along a group Reactions with Air
Elements with similar chemical properties are
Readily tarnish in air as they react with
found in the same group.
oxygen giving a white oxide layer. Therefore,
Group 1: Alkali metals. they are stored under oil. The formed oxide is
soluble in water giving strong alkali solution.
Group 2: Alkaline earth metals.
4Li + O2 → 2Li20
Group 7: Halogens.
Reactions with Water
Group 0/8: Inert gases or Noble gases.
Reacts vigorously with water producing
Alkali Metals
hydrogen gas that burns with the
6 Elements in group 1 → Lithium – Sodium – characteristic flame. The remaining solution
Potassium – Rubidium – Cesium – Francium. is a strong alkali of the metal hydroxide.

They’re very reactive metals. Reactivity of 2Li + 2H2O → 2LiOH + H2


metals is defined by its tendency to lose its
Li2O + H2O → 2LiOH
valence electrons.

Descending the group, number if shells Observations when a piece of Sodium is placed in
increase thus the valence electron is less cold water
firmly held to the nucleus. Therefore, the
reactivity of metals increases on descending 1. Metal floats.
the group.
2. Metal melts since the reaction is
General characteristics exothermic.

3. Metal darts when hydrogen is given out


1. Good conductors of heat and electricity.
from metal in form of jet.
2. Soft metals, Potassium is softer than
4. Gas burns with flame and pop sound.
Lithium.
5. Metal dissolves and solution is clear since
3. Low densities, Lithium is the lightest.
sodium hydroxide is soluble.
4. Shiny silvery surface when cut with a
6. Solution becomes hot.
knife.
→ All common alkali salts are soluble in water.
5. Low melting point, boiling and melting
point decreases as you go down the group.
Chemistry Term 1 14

Metals
Alkaline Earth Metals Reaction With Water:
Metals of group II → Beryllium – Magnesium –
These metals are less reactive and denser
Calcium – Strontium – Barium - Radium
than alkali metals.
General characteristics Ca + 2H2O → Ca (OH)2 + H2

1. Good conductors of electricity and heat. CaO + H2O → Ca (OH)2

2. Generally harder, denser, and of higher


melting points than alkali metals.
Observations when A piece of Calcium is placed
in cold water:
Reaction With Air:
1. The metal sinks in water.
They readily tarnish in air as they react with
2. The metal floats then sinks. This is because
oxygen giving a white oxide layer. They burn
the metal is surrounded with hydrogen
in air with a characteristic flame.
bubbles.
Magnesium burns with bright white light &
3. There is effervescence. This is because
forms a white ash.
Hydrogen gas is evolved.
They react with oxygen according to the
4. The solution becomes turbid after a while.
equation:
This is because the formed Ca (OH), is
2Ca + O2 → 2CaO partially soluble in water.

The formed oxide is partially soluble in water 5. The metal dissolves. Because the solid
giving weak alkali solution. metal changes into aqueous calcium
hydroxide solution.

6. The solution becomes hotter.


Chemistry Term 1 15

Reactivity of Common Metals

K: Potassium
React with everything → React even with cold water
Na: Sodium
to produce alkali + H2
Ca: Calcium

Mg: Magnesium React with cold water ONLY when metal is in


powder form
Al: Aluminium

C: Copper
React with steam only when metal is red hot to
Zn: Zinc produce metal oxide (base) + H2
Fe: Iron

Sn: Tin
React only with acids to give salt & H2. Doesn't react
Pb: Lead with cold/hot water

H+: Hydrogen

Cu: Copper → Doesn't react with water or even acids

Order of reactivity is → 1. Cold water. 2. Hot water (steam). 3. Acids

Reactions of Metals:

Metal + Cold Water → Alkali + Hydrogen

Metal + Steam → Base + Hydrogen

Metal + Acid → Salt + Hydrogen

→ The metals above the carbon, their oxides won't react with carbon.

→ The more reactive the metal, the more stable the compound and requires higher energy to
react

Common questions

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Alkali metals react vigorously with water, producing hydrogen gas and forming strong alkali solutions, as demonstrated by vigorous effervescence and the exothermic heat release. In contrast, alkaline earth metals react with water more slowly and form weaker alkali solutions; for instance, calcium reacts with cold water leading to a less vigorous reaction with effervescence and forming a partially soluble compound .

Both alkali and alkaline earth metals react with oxygen to form oxides; however, their reactions differ in intensity and products. Alkali metals react rapidly and often explosively with oxygen to form white oxides, while alkaline earth metals react with oxygen to form oxides as well, but in a more controlled manner, often resulting in a characteristic flame color and leaving behind a white oxide ash .

Valence electrons are the outermost electrons of an atom, located in the outer electron shell. They play a key role in determining an element's chemical properties, including its reactivity and the types of bonds it can form. Elements with similar valence electron configurations tend to exhibit similar chemical behaviors, which is why elements in the same group of the periodic table have similar chemical properties .

Elements in the same group of the periodic table have similar chemical properties because they have the same number of valence electrons. This similarity in electronic configuration results in comparable reactivity and bonding behavior, as the chemical properties of an element are largely determined by its valence electron arrangement .

The increased reactivity of alkali metals down the group is explained by the increase in the number of electron shells, which results in greater atomic radius and the valence electron being further from the nucleus. Consequently, the valence electron is less strongly attracted to the nucleus, therefore, it is lost more easily, increasing reactivity .

The structure of the periodic table is organized to reflect the electron shell configuration of elements. The horizontal rows, or periods, represent elements with the same number of electron shells, while the vertical columns, or groups, classify elements with the same number of valence electrons, affecting their chemical properties. This arrangement allows for the prediction of element behavior based on their position .

Noble gases are inert because of their full outer electron shells, which make them energetically stable and not prone to reacting with other elements. The exception is helium, which has a full outer shell with only two electrons instead of eight, still providing stable configuration as the first shell can only hold two electrons. This inertness is a result of minimal tendency to gain or lose electrons .

Transition metals can exhibit multiple oxidation states, which enables them to participate in a variety of chemical reactions as they can lose different numbers of electrons. This versatility allows them to form complex ions and colored compounds, and also act as catalysts by providing pathways with lower activation energy for chemical reactions .

Transition metals are distinguished by their physical properties, such as high melting and boiling points, high density, and high strength. Chemically, they form colored compounds, can exhibit multiple oxidation states, and often act as catalysts. These properties derive from the d-electrons that can participate in bonding and electron transitions .

As you move down Group 1 in the periodic table, alkali metals show trends such as decreasing melting and boiling points, and increasing density, although lithium is an exception as the lightest metal. They become softer and more reactive descending the group due to the increasing number of electron shells, resulting in valence electrons being less tightly held and thus easier to lose .

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