EANGH
NTERNArIONA
AKSIPS 41 SMART SCHOOL CHANDIGARH
Annual Examination (2025) M.M:70
Class XI Tirne: 3 Hrs.
Subject: Chemistry
SET-- B
General Instructions:
with internal choice.
)There are 33 questions inthis question paper mark each.
and 4 assertion - reasons carrying 1
i) Section- A consists of 12multiple choice guestions
markseach.
short answer questions carrying 2
1) Section - Bconsists of 5 very
answer questions carrying 3 marks each.
iv) Section -Cconsists of7 short
carrying 4 marks each.
v)Section-D consists of 2case based questions
questions carrying 5 marks each.
vi) Section -E consists of 3long answer
vii) Allquestions are compulsory.
vii) Use of calculator is not allowed. SECTION -A(OBJECTIVE TYPE)
The form
MCQ: respectively, to give a compound having 75.8% of X&24.2% of Y.
mass 75 & 16
Q.1 Two elements X&Yhave atomic
of the compound is:
c) XY d) X,Y;
a) X,Y b) XY;
required toproduce 22g of CO, (g)after combustion?
Q.2 How many moles of methane are c) 44 moles d) 2 moles
a) 11 moles b) 0.5 moles
Q.3The electronic configuration of Cr ion is : c) [Ar]3d4s? d) [Ar]3d4s'
a) [Arj3d'4s b) [Ar]3d°4s0
as two radial nodes is :
Q4 The orbital having two angular as well d) 4d
a) 4f "b) 5d c) 3p
molecules H,0, NHa, CH, & CO, are in the order:
0.5 The bond angles in
a) H,0> NH,> CH, >CO, b) H,0 <NH< CO, < CH,
c) H,0 < NH,< CH, <C0, d) H,0 > NH,< CH, > CO,
temperature of asubstance by 1'C (1K) is called:
Q.6 The quantity of heat needed to raise the d) Specific heat capacity
b) Specific heat c) Molar heat capacity
"a) Heat Capacity
Q7 The [OH] of an aqueous solution is1x 10*.
The pH of the solution is :
" b)9 c) 4.5 d) 11
a) 5
Q.8 The conjugate acid of NH, :
a) NH b) NH c)NH,2 d) NH,
Q.9 In the reaction 6Clo, ’ 4CI0, + 2CI,the chlorine (CI) is:
d) None of these
a) Oxidised b)Reduced -c) Oxidised as well as reduced
0.10 Which of the following hybridisation has maximum s- character?
c) sp d) All have same s- character
a) sp b) sp
0.11 Phenol molecule has :
a) 6 sigma &6 pi bonds b) 16 sigma &6 pi bonds
c) 13 sigma &3 pi bonds " d)14 sigma &3 pi bonds
NaoH, The Yis:
Q.12 In the reaction, CH,COOH X Cao
a) CH,CHO .b) CH, c) C,H, d) CH,COCH,
Assertion and Reason type questions:
(A) Both asse rtion &reason are correct statements, and reason is the correct explanation of the assertion.
(B) Both assertion &reason are correct statements, but reason is not the correct explanation of the assertion.
(C)Assertion is correct, but reason is wrong statement.
correct statement.
Assertion is wrong, but reason is statement.
(D)
wrong and reason is also wrong
(E)Assertion is
bigger than Cl atom.
0.13 Assertion: C is than Cl atom.
has more effective nuclear charge
Reason: Ct NaCl.
more covalent than
Q.14 Assertion: LiCl is polarising power than Na".
smaller in size, has higher mechanism.
Reason: Li" is free radical
Addition of HBr to alkene follows radical mechanism.
Q.15 Assertion: presence of peroxide follows free
in
Reason: Addition of HBr spontaneous.
negative, reaction will be
Q.16 Assertion: If AG is
Reason: If AG =-ve,Keo is +ve. SECTION-B
numbers:
significant figure in each of the following
Q.17 Calculate the number of c) 3.0 x 10 d) 0.0025
a) 500.0 b) 208.
SI units.
Convert 100 miles per hour into its number.
between Azimuthal & Spin quantum
Q,18 Write any two differences
following molecules:
Q.19 Predict and draw the shape of
a) CIF, b)SF4
reaction mixture?
effect of temperature on equilibrium on
Q.20 State Lechatelier's princple. What is the
a) Nucleophiles b) Metamerism
Q.21 Define with example:
SECTION -C
ion has larger bond length (on the basis of molecular orbital
Q.22 a) Which of the two : superoxide (0, ) or peroxide (o,)
theory)? Justify your answer. (2+1)
b) What is dipole moment ?
500 mL of 0.375 molar aqueous solution. Molar mass of
Q.23 Calculate the mass of sodium acetate (CH,COONa) required to make
sodium acetate is 82.0245 g/mol.
Fis less negative than that of Cl.
Q.24 Account for the following : a) Electron gain enthalpy of
b)The decreasing order of metallic character is K> Mg> Al> B.
c) lonisation enthalpy of P is more than that of S.
Q.25 Derive relationship between K, & Ke
Q.26 Balance givenredox reaction in acidic medium:- MnO, + Cz0,’ Mn + CO,
Q.27 Give the mechanism of electrophilic substitution reactions of benzene.
Or
Discuss the stabilityof carbocations in detail.
Q.28 Name the following compounds (IUPAC system):
1 CH3- CH CHcoOH
NHa
2.
3
SECTION-D
Case study based questions:
029 Read the passage given below and answer the following questions:
The extent of disorder or randomness in a system may be expressed by a thermodynamic property known as entropy. sto
change in rearrangement of atons or ions in the reactantS tO
function. ror cemical reactions, entropy change is attributed to the
reactants, there w be iesue
that in the products. If the structure of the products is very much disordered than that of the by tne
accompanving a chemical reaction may be estirmated quantitatively
increase in entrOPy. Tnerefore, change in entropv EntroPy may oe
reactionand the structures of the products formed.
considerationof the. structures of species taking nart in the
also be related to the heat involved in aprocess. procesS at equiltbrium.
thermodynamics & write expression for change in entropy for reversible
a) State second law of Calculate AG and prediCt the re3sloi4y
changes of a reaction are 40.63 kl/mol & 108.8 J/K/mol respectively. (2+2)
D) Ehtnaipy && entropy
of the reaction at 27° C.
answer the following questions: called oletins.
Q.30 Read the passage given below and -carbon double bonds in their molecules. They are aiso
hydrocarbons containing carbon each carbon atoms.
AlKenes are unsaturated trigonal planar shape involving three sp hybrid orbitals in Geometrical isormers
family i.e, ethene has isomerism.
he first member of alkene structural & geometrical
repulsion. The alkene show alkenes. Ihe
Inis arrangement of alkene
reduces electron
similar. There are different methods to prepare
properties are liquids while
different physical properties but their chemical alkenes containing 5 to 18 carbon atoms are
nave temperature. The
alkenes are gases at ordinary
Tirst three members of
the higher members of the family
are liquid.
olefins?
i) Why alkenes are known as (1+1+2)
iü)What is Markovnikov's rule?
double bond.
i) Discuss the structure of SECTION -E
principle? llustrate with an
example. second spectral line in Balmer
e Q.31 a)State Pauli's
exclusion the wavelength of the
spectral line in the Balmer series 6561 A°, Calculate
b) The wavelength of first (2+2+1)
series. electron is quantized?
saying that energy of the A,H =-1662 kJ/mol
c) What doyou mean by reaction : CgHg (e) + 50; (g) ’300, (g) + 4H,0 (g),
Q,32 a) The enthalpy change for the
of various bonds are :
The average bond enthalpies
C-C C-H C=0
347 414 741 464 (kJ/mol)
O, molecule.
Calculate bond enthalpy of O=0bond in having atomic number 25.
of element
b) Predict the group and period Or
+ O (e)> 2H,O () at 298 K,
a) For the equilibrium reaction: 2H, (g)
J/K/mol)
AG° =-474.78 kJ/mol. Calculate Kfor it. (R=8.314 (3+2)
of periodic table.
b) Write any two advantages of the long form
Q.33 a) Write the reaction for following:
a) Kolbe'sreaction b) Pyrolysis c) Friedel craft acylation
effect? (Any two points)
b) How will you differentiate between resonance and inductive
Or
a) Why nitrobenzene is ortho, para directing in nature? (3+2)
substitutions with difficulty?
b) Why does benzene undergo electrophilic substitution reactions easily & nucleophilic
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