Safety Data Sheet

TASKI ROOM CARE R5 - PLUS

Revision: 2019-04-03 Version: 01.0

SECTION 1: Identification of the substance/mixture and supplier

1.1 Product identifier
Product name: TASKI ROOM CARE R5 - PLUS

1.2 Recommended use and restrictions on use

Identified uses:
Air freshener
Restrictions of use:
Uses other than those identified are not recommended

1.3 Details of the supplier

DIVERSEY NEW ZEALAND LTD.
24 Bancroft Crescent, Glendene, Auckland, 0602, New Zealand
Telephone: +64 9 813 9800; 0800 803 615 (toll free)
Fax: + 64 9 813 9801
Website: [Link]

1.4 Emergency telephone number

Seek medical advice (show the label or safety data sheet where possible)
Call 0800 243 622 (24 hrs)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

HSNO Classification
6.4A - Irritating to the eye
6.5B - Contact sensitisers
9.1C - Harmful in the aquatic environment

GHS Equivalent Classification

Serious eye irritation, Category 2
Skin sensitisation, Category 1
Acute aquatic toxicity, Category 3
Chronic aquatic toxicity, Category 3

2.2 Label elements

Signal word: Warning

Hazard statements:
H319 - Causes serious eye irritation.
H317 - May cause an allergic skin reaction.
H402 - Harmful to aquatic life.

Prevention statement(s):
P233 - Keep container tightly closed.
P264 - Wash face, hands and any exposed skin thoroughly after handling.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P280 - Wear protective gloves.

Response statement(s):
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical advice or attention.

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P321 - Specific treatment (see supplemental first aid instructions on this label).
P363 - Wash contaminated clothing before reuse.

Disposal statement(s):
P501 - Dispose of unused content as chemical waste.

2.3 Other hazards

No other hazards known.

2.4 Classification diluted product:

Recommended maximum concentration (%): 9.1

HSNO Classification
Not classified as hazardous

Not classified as hazardous

SECTION 3: Composition/information on ingredients

3.1 Substances / Mixtures

Ingredient(s) CAS number EC number Weight

percent
alkyl alcohol ethoxylate 68439-46-3 [4] 3-10
alkyl alcohol ethoxylate 68439-46-3 [4] 3-10
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthyl)ethan-1-one 54464-57-2 259-174-3 0.1-1
alpha-hexylcinnamaldehyde 101-86-0 202-983-3 0.1-1
ionone, methyl- 1335-46-2 215-635-0 0.1-1
2-(4-tert-Butylbenzyl)propionaldehyde 80-54-6 201-289-8 0.1-1
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one 1506-02-1 216-133-4 0.1-1
1,2-benzisothiazol-3(2H)-one 2634-33-5 220-120-9 0.1-1
sodium hydroxide 1310-73-2 215-185-5 0.01-0.1
tridec-2-enenitrile 22629-49-8 245-142-6 0.01-0.1

[4] Polymer.
Non-hazardous ingredients are the remainder and add up to 100%.

Workplace exposure limit(s), if available, are listed in subsection 8.1.

SECTION 4: First aid measures

4.1 Description of first aid measures
General Information: Symptoms of intoxication may even occur after several hours. It is recommended to continue
medical observation for at least 48 hours after the incident.
Inhalation: Get medical attention or advice if you feel unwell.
Skin contact: Wash skin with plenty of lukewarm, gently flowing water. Take off immediately all contaminated
clothing and wash it before re-use. If skin irritation occurs: Get medical advice or attention.
Eye contact: Hold eyelids apart and flush eyes with plenty of lukewarm water for at least 15 minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If irritation occurs and persists, get
medical attention.
Ingestion: Rinse mouth. Immediately drink 1 glass of water. Never give anything by mouth to an unconscious
person. Get medical attention or advice if you feel unwell.
Self-protection of first aider: Consider personal protective equipment as indicated in subsection 8.2.
First aid facilities: Eyewash facilities should be considered in a workplace where necessary.

4.2 Most important symptoms and effects, both acute and delayed
Inhalation: No known effects or symptoms in normal use.
Skin contact: May cause an allergic skin reaction.
Eye contact: Causes severe irritation.
Ingestion: No known effects or symptoms in normal use.

4.3 Indication of any immediate medical attention and special treatment needed
No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if available, can be found
in section 11.

Poison Information Center: Call 0800 764 766 (0800 POISON)

SECTION 5: Firefighting measures

5.1 Extinguishing media
Carbon dioxide. Dry powder. Water spray jet. Fight larger fires with water spray jet or alcohol-resistant foam.

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5.2 Special hazards arising from the substance or mixture

No special hazards known.

5.3 Advice for firefighters

As in any fire, wear self contained breathing apparatus and suitable protective clothing including gloves and eye/face protection.

5.4 Hazchem code

None allocated

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
Wear suitable gloves.

6.2 Environmental precautions

Do not allow to enter drainage system, surface or ground water. Do not allow to enter the ground/soil. Dilute with plenty of water. Inform
responsible authorities in case undiluted product reaches drainage system, surface or ground water or the ground/soil.

6.3 Methods and material for containment and cleaning up

Absorb with liquid-binding material (sand, diatomite, universal binders, sawdust).

6.4 Reference to other sections

For personal protective equipment see subsection 8.2. For disposal considerations see section 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Measures to prevent fire and explosions:
No special precautions required.

Measures required to protect the environment:

For environmental exposure controls see subsection 8.2.

Advices on general occupational hygiene:

Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not mix with
other products unless adviced by Diversey. Wash hands before breaks and at the end of workday. Take off contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Avoid contact with skin and
eyes. Use only with adequate ventilation. See chapter 8.2, Exposure controls / Personal protection.

7.2 Conditions for safe storage, including any incompatibilities

Store in accordance with local and national regulations. Store in a closed container. Keep only in original packaging.
For conditions to avoid see subsection 10.4. For incompatible materials see subsection 10.5.

7.3 Specific end use(s)

No specific advice for end use available.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
Workplace exposure limits

Air limit values, if available:

Ingredient(s) Long term value(s) Short term value(s) Ceiling value(s)
sodium hydroxide 2 mg/m3

Biological limit values, if available:

8.2 Exposure controls

The following information applies for the uses indicated in subsection 1.2 of the Safety Data Sheet.
If available, please refer to the product information sheet for application and handling instructions.
Normal use conditions are assumed for this section.

Recommended safety measures for handling the undiluted product:

Covering activities such as filling and transfer of product to application equipment, flasks or buckets

Appropriate engineering controls: If the product is diluted by using specific dosing systems with no risk of splashes or direct skin
contact, the personal protection equipment as described in this section is not required.
Appropriate organisational controls: Avoid direct contact and/or splashes where possible. Train personnel.

Personal protective equipment

Eye / face protection: Safety glasses are not normally required. However, their use is recommended in those cases

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where splashes may occur when handling the product (EN 166).
Hand protection: Chemical-resistant protective gloves (EN 374). Verify instructions regarding permeability and
breakthrough time, as provided by the gloves supplier. Consider specific local use conditions, such
as risk of splashes, cuts, contact time and temperature.
Sugges tedgl ovesforpr olongedc ontact:Mat eri
al:butyl rubberPenet rat
iont i
me:≥480mi nMat eri
al
thicknes s :≥0. 7mm
Sugges tedgl ovesforpr otectionagai nsts plas hes:Mat er i
al:nitril
erubberPenet rationt i
me:≥30mi n
Mat erialthick ness:≥0. 4mm
In consultation with the supplier of protective gloves a different type providing similar protection may
be chosen.
Body protection: No special requirements under normal use conditions.
Respiratory protection: No special requirements under normal use conditions.

Environmental exposure controls: No special requirements under normal use conditions.

Recommended safety measures for handling the diluted product:

Recommended maximum concentration (%): 9.1

Appropriate engineering controls: Use only in well ventilated areas.

Appropriate organisational controls: No special requirements under normal use conditions.

Personal protective equipment

Eye / face protection: No special requirements under normal use conditions.
Hand protection: No special requirements under normal use conditions.
Body protection: No special requirements under normal use conditions.
Respiratory protection: No special requirements under normal use conditions.

Environmental exposure controls: No special requirements under normal use conditions.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Method / remark
Physical State: Liquid
Colour: Clear, Dark Red
Odour: Perfumed
Odour threshold: Not applicable
pH: ≈ 7 ( neat ) ISO 4316
Dilution pH: <≈ 7 ( 10%) ISO 4316
Melting point/freezing point (°C): Not determined Not relevant to classification of this product
Initial boiling point and boiling range (°C): Not determined
Flammability (liquid): Not flammable.
Flash point (°C): > 93 closed cup
Sustained combustion: Not applicable.
( UN Manual of Tests and Criteria, section 32, L.2 )
Evaporation rate: Not determined Not relevant to classification of this product
Flammability (solid, gas): Not applicable to liquids
Upper/lower flammability limit (%): Not determined
Vapour pressure: Not determined
Vapour density: Not determined Not relevant to classification of this product
Relative density: ≈ 1. 004 ( 20°C) OECD 109 (EU A.3)
Solubility in / Miscibility with Water: Fully miscible
Partition coefficient: n-octanol/water No information available.
Substance data, partition coefficient n-octanol/water (log Kow): see subsection 12.3
Autoignition temperature: Not determined
Decomposition temperature: Not applicable.
Viscosity: Not determined
Explosive properties: Not explosive.
Oxidising properties: Not oxidising

9.2 Other information

Surface tension (N/m): Not determined
Corrosion to metals: Not corrosive

SECTION 10: Stability and reactivity

10.1 Reactivity
No reactivity hazards known under normal storage and use conditions.

10.2 Chemical stability

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Stable under normal storage and use conditions.

10.3 Possibility of hazardous reactions

No hazardous reactions known under normal storage and use conditions.

10.4 Conditions to avoid

None known under normal storage and use conditions.

10.5 Incompatible materials

None known under normal use conditions.

10.6 Hazardous decomposition products

None known under normal storage and use conditions.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Mixture data:.

Relevant calculated ATE(s):

ATE - Oral (mg/kg): >5000

Skin irritation and corrosivity

Result: Not corrosive or irritant Method: Weight of evidence
Eye irritation and corrosivity
Result: Eye irritant 2 Method: Weight of evidence

Substance data, where relevant and available, are listed below:.

Acute toxicity
Acute oral toxicity
Ingredient(s) Endpoint Value Species Method Exposure
(mg/kg) time (h)
alkyl alcohol ethoxylate LD 50 > 300-2000 Rat Method not given
alkyl alcohol ethoxylate LD 50 300 - 2000 Method not given
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthyl)ethan-1-one No data
available
alpha-hexylcinnamaldehyde No data
available
ionone, methyl- No data
available
2-(4-tert-Butylbenzyl)propionaldehyde LD 50 1390 Method not given
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one LD 50 1000 Method not given
1,2-benzisothiazol-3(2H)-one LD 50 > 2000 Rat
sodium hydroxide No data
available
tridec-2-enenitrile No data
available

Acute dermal toxicity

Ingredient(s) Endpoint Value Species Method Exposure
(mg/kg) time (h)
alkyl alcohol ethoxylate LD 50 > 2000 Rabbit Method not given
alkyl alcohol ethoxylate LD 50 2000 - 5000 Rat Method not given
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthyl)ethan-1-one No data
available
alpha-hexylcinnamaldehyde No data
available
ionone, methyl- No data
available
2-(4-tert-Butylbenzyl)propionaldehyde No data
available
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one No data
available
1,2-benzisothiazol-3(2H)-one LD 50 > 2000 Rat OECD 402 (EU B.3)
sodium hydroxide LD 50 1350 Rabbit Method not given
tridec-2-enenitrile No data
available

Acute inhalative toxicity

Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (h)
alkyl alcohol ethoxylate No data
available

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alkyl alcohol ethoxylate No data

available
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthyl)ethan-1-one No data
available
alpha-hexylcinnamaldehyde No data
available
ionone, methyl- No data
available
2-(4-tert-Butylbenzyl)propionaldehyde No data
available
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one No data
available
1,2-benzisothiazol-3(2H)-one No data
available
sodium hydroxide No data
available
tridec-2-enenitrile No data
available

Irritation and corrosivity

Skin irritation and corrosivity
Ingredient(s) Result Species Method Exposure time
alkyl alcohol ethoxylate Not irritant Rabbit Method not given
alkyl alcohol ethoxylate Not irritant Method not given
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthyl)ethan-1-one No data available
alpha-hexylcinnamaldehyde No data available
ionone, methyl- No data available
2-(4-tert-Butylbenzyl)propionaldehyde No data available
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one No data available
1,2-benzisothiazol-3(2H)-one Corrosive Method not given
sodium hydroxide Corrosive Rabbit Method not given
tridec-2-enenitrile No data available

Eye irritation and corrosivity

Ingredient(s) Result Species Method Exposure time
alkyl alcohol ethoxylate Severe damage Rabbit Method not given
alkyl alcohol ethoxylate Severe damage Rabbit Method not given
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthyl)ethan-1-one No data available
alpha-hexylcinnamaldehyde No data available
ionone, methyl- No data available
2-(4-tert-Butylbenzyl)propionaldehyde No data available
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one No data available
1,2-benzisothiazol-3(2H)-one Severe damage Method not given
sodium hydroxide Corrosive Rabbit Method not given
tridec-2-enenitrile No data available

Respiratory tract irritation and corrosivity

Ingredient(s) Result Species Method Exposure time
alkyl alcohol ethoxylate Not irritating to
respiratory tract
alkyl alcohol ethoxylate No data available
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthyl)ethan-1-one No data available
alpha-hexylcinnamaldehyde No data available
ionone, methyl- No data available
2-(4-tert-Butylbenzyl)propionaldehyde No data available
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one No data available
1,2-benzisothiazol-3(2H)-one No data available
sodium hydroxide No data available
tridec-2-enenitrile No data available

Sensitisation
Sensitisation by skin contact
Ingredient(s) Result Species Method Exposure time (h)
alkyl alcohol ethoxylate Not sensitising Guinea pig Method not given
alkyl alcohol ethoxylate Not sensitising Guinea pig Method not given
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthyl)ethan-1-one No data available
alpha-hexylcinnamaldehyde No data available
ionone, methyl- No data available
2-(4-tert-Butylbenzyl)propionaldehyde No data available
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one No data available

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1,2-benzisothiazol-3(2H)-one Sensitising Guinea pig

sodium hydroxide Not sensitising Human repeated patch
test
tridec-2-enenitrile No data available

Sensitisation by inhalation
Ingredient(s) Result Species Method Exposure time
alkyl alcohol ethoxylate No data available
alkyl alcohol ethoxylate No data available
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthyl)ethan-1-one No data available
alpha-hexylcinnamaldehyde No data available
ionone, methyl- No data available
2-(4-tert-Butylbenzyl)propionaldehyde No data available
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one No data available
1,2-benzisothiazol-3(2H)-one No data available
sodium hydroxide No data available
tridec-2-enenitrile No data available

CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction)

Mutagenicity
Ingredient(s) Result (in-vitro) Method Result (in-vivo) Method
(in-vitro) (in-vivo)
alkyl alcohol ethoxylate No evidence for mutagenicity, negative Method not No data available
test results given
alkyl alcohol ethoxylate No evidence for mutagenicity, negative OECD 473 No data available
test results
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl- No data available No data available
2-naphthyl)ethan-1-one
alpha-hexylcinnamaldehyde No data available No data available
ionone, methyl- No data available No data available
2-(4-tert-Butylbenzyl)propionaldehyde No data available No data available
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-n No data available No data available
aphthyl)ethan-1-one
1,2-benzisothiazol-3(2H)-one No evidence for mutagenicity, negative OECD 471 (EU No data available
test results B.12/13)
sodium hydroxide No evidence for mutagenicity, negative DNA repair test No evidence for mutagenicity, negative OECD 474 (EU
test results on rat test results B.12) OECD
hepatocytes 475 (EU B.11)
OECD 473
tridec-2-enenitrile No data available No data available

Carcinogenicity
Ingredient(s) Effect
alkyl alcohol ethoxylate No evidence for carcinogenicity, negative test results
alkyl alcohol ethoxylate No evidence for carcinogenicity, negative test results
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthyl)ethan-1-one No data available
alpha-hexylcinnamaldehyde No data available
ionone, methyl- No data available
2-(4-tert-Butylbenzyl)propionaldehyde No data available
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one No data available
1,2-benzisothiazol-3(2H)-one No data available
sodium hydroxide No evidence for carcinogenicity, weight-of-evidence
tridec-2-enenitrile No data available

Toxicity for reproduction

Ingredient(s) Endpoint Specific effect Value Species Method Exposure Remarks and other effects
(mg/kg bw/d) time reported
alkyl alcohol ethoxylate NOAEL > 250 Rat No known significant effects or
critical hazards
alkyl alcohol ethoxylate NOAEL > 250 Rat Not known No effects on fertility No
developmental toxicity
1-(1,2,3,4,5,6,7,8-octah No data
ydro-2,3,8,8-tetramethyl available
-2-naphthyl)ethan-1-on
e
alpha-hexylcinnamalde No data
hyde available
ionone, methyl- No data
available
2-(4-tert-Butylbenzyl)pr No data
opionaldehyde available
1-(5,6,7,8-tetrahydro-3, No data
5,5,6,8,8-hexamethyl-2- available
naphthyl)ethan-1-one
1,2-benzisothiazol-3(2H No data

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)-one available
sodium hydroxide No data No evidence for developmental
available toxicity No evidence for
reproductive toxicity
tridec-2-enenitrile No data
available

Repeated dose toxicity

Sub-acute or sub-chronic oral toxicity
Ingredient(s) Endpoint Value Species Method Exposure Specific effects and organs
(mg/kg bw/d) time (days) affected
alkyl alcohol ethoxylate No data
available
alkyl alcohol ethoxylate NOAEL 80 - 400 Method not
given
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-napht No data
hyl)ethan-1-one available
alpha-hexylcinnamaldehyde No data
available
ionone, methyl- No data
available
2-(4-tert-Butylbenzyl)propionaldehyde No data
available
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl) No data
ethan-1-one available
1,2-benzisothiazol-3(2H)-one No data
available
sodium hydroxide No data
available
tridec-2-enenitrile No data
available

Sub-chronic dermal toxicity

Ingredient(s) Endpoint Value Species Method Exposure Specific effects and organs
(mg/kg bw/d) time (days) affected
alkyl alcohol ethoxylate NOAEL 80 OECD 411 (EU
B.28)
alkyl alcohol ethoxylate NOAEL 80 OECD 411 (EU 90
B.28)
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-napht No data
hyl)ethan-1-one available
alpha-hexylcinnamaldehyde No data
available
ionone, methyl- No data
available
2-(4-tert-Butylbenzyl)propionaldehyde No data
available
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl) No data
ethan-1-one available
1,2-benzisothiazol-3(2H)-one No data
available
sodium hydroxide No data
available
tridec-2-enenitrile No data
available

Sub-chronic inhalation toxicity

Ingredient(s) Endpoint Value Species Method Exposure Specific effects and organs
(mg/kg bw/d) time (days) affected
alkyl alcohol ethoxylate No data
available
alkyl alcohol ethoxylate No data
available
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-napht No data
hyl)ethan-1-one available
alpha-hexylcinnamaldehyde No data
available
ionone, methyl- No data
available
2-(4-tert-Butylbenzyl)propionaldehyde No data
available
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl) No data
ethan-1-one available
1,2-benzisothiazol-3(2H)-one No data
available
sodium hydroxide No data
available
tridec-2-enenitrile No data
available

Chronic toxicity
Ingredient(s) Exposure Endpoint Value Species Method Exposure Specific effects and Remark

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route (mg/kg bw/d) time organs affected

alkyl alcohol ethoxylate NOAEL 80 Method not
given
alkyl alcohol ethoxylate No data
available
1-(1,2,3,4,5,6,7,8-octah No data
ydro-2,3,8,8-tetramethyl available
-2-naphthyl)ethan-1-on
e
alpha-hexylcinnamalde No data
hyde available
ionone, methyl- No data
available
2-(4-tert-Butylbenzyl)pr No data
opionaldehyde available
1-(5,6,7,8-tetrahydro-3, No data
5,5,6,8,8-hexamethyl-2- available
naphthyl)ethan-1-one
1,2-benzisothiazol-3(2H No data
)-one available
sodium hydroxide No data
available
tridec-2-enenitrile No data
available

STOT-single exposure
Ingredient(s) Affected organ(s)
alkyl alcohol ethoxylate Not applicable
alkyl alcohol ethoxylate No data available
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthyl)ethan-1-one No data available
alpha-hexylcinnamaldehyde No data available
ionone, methyl- No data available
2-(4-tert-Butylbenzyl)propionaldehyde No data available
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one No data available
1,2-benzisothiazol-3(2H)-one No data available
sodium hydroxide No data available
tridec-2-enenitrile No data available

STOT-repeated exposure
Ingredient(s) Affected organ(s)
alkyl alcohol ethoxylate Not applicable
alkyl alcohol ethoxylate No data available
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthyl)ethan-1-one No data available
alpha-hexylcinnamaldehyde No data available
ionone, methyl- No data available
2-(4-tert-Butylbenzyl)propionaldehyde No data available
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one No data available
1,2-benzisothiazol-3(2H)-one No data available
sodium hydroxide No data available
tridec-2-enenitrile No data available

Aspiration hazard
Substances with an aspiration hazard (H304), if any, are listed in section 3. If relevant, see section 9 for dynamic viscosity and relative density
of the product.

Potential adverse health effects and symptoms

Effects and symptoms related to the product, if any, are listed in subsection 4.2.

SECTION 12: Ecological information

12.1 Toxicity

No data is available on the mixture.

Substance data, where relevant and available, are listed below:

Aquatic short-term toxicity

Aquatic short-term toxicity - fish
Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (h)
alkyl alcohol ethoxylate LC 50 5-7 Fish OECD 203 (EU C.1) 96
alkyl alcohol ethoxylate LC 50 5-7 Fish 92/69/EEC, C1, 96
semi-static
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthyl)ethan-1-one No data
available

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alpha-hexylcinnamaldehyde No data
available
ionone, methyl- No data
available
2-(4-tert-Butylbenzyl)propionaldehyde No data
available
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one No data
available
1,2-benzisothiazol-3(2H)-one LC 50 2.18 Oncorhynchus OECD 203 (EU C.1)
mykiss
sodium hydroxide LC 50 35 Various Method not given 96
species
tridec-2-enenitrile No data
available

Aquatic short-term toxicity - crustacea

Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (h)
alkyl alcohol ethoxylate EC 50 5.3 Daphnia 92/69/EEC 48
magna Straus
alkyl alcohol ethoxylate EC 50 5.3 Daphnia 92/69/EEC 48
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthyl)ethan-1-one No data
available
alpha-hexylcinnamaldehyde No data
available
ionone, methyl- No data
available
2-(4-tert-Butylbenzyl)propionaldehyde No data
available
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one No data
available
1,2-benzisothiazol-3(2H)-one EC 50 2.94 Daphnia OECD 202 (EU C.2) 48
sodium hydroxide EC 50 40.4 Ceriodaphnia Method not given 48
sp.
tridec-2-enenitrile No data
available

Aquatic short-term toxicity - algae

Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (h)
alkyl alcohol ethoxylate EC 50 1.4 - 47 Not specified 92/69/EEC 72
alkyl alcohol ethoxylate EC 50 1.4 - 47 Not specified 92/69/EEC 72
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthyl)ethan-1-one No data
available
alpha-hexylcinnamaldehyde No data
available
ionone, methyl- No data
available
2-(4-tert-Butylbenzyl)propionaldehyde No data
available
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one No data
available
1,2-benzisothiazol-3(2H)-one E r C 50 0.11 OECD 201 (EU C.3) 72
sodium hydroxide EC 50 22 Photobacteriu Method not given 0.25
m
phosphoreum
tridec-2-enenitrile No data
available

Aquatic short-term toxicity - marine species

Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (days)
alkyl alcohol ethoxylate No data -
available
alkyl alcohol ethoxylate No data -
available
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthyl)ethan-1-one No data
available
alpha-hexylcinnamaldehyde No data
available
ionone, methyl- No data
available
2-(4-tert-Butylbenzyl)propionaldehyde No data
available
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one No data
available
1,2-benzisothiazol-3(2H)-one No data
available
sodium hydroxide No data -
available
tridec-2-enenitrile No data

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available

Impact on sewage plants - toxicity to bacteria

Ingredient(s) Endpoint Value Inoculum Method Exposure
(mg/l) time
alkyl alcohol ethoxylate EC 50 > 140 Bacteria Method not given
alkyl alcohol ethoxylate EC 50 > 140 Bacteria Method not given 3 hour(s)
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthyl)ethan-1-one No data
available
alpha-hexylcinnamaldehyde No data
available
ionone, methyl- No data
available
2-(4-tert-Butylbenzyl)propionaldehyde No data
available
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-1-one No data
available
1,2-benzisothiazol-3(2H)-one EC 20 3.3 Activated OECD 209 3 hour(s)
sludge
sodium hydroxide No data
available
tridec-2-enenitrile No data
available

Aquatic long-term toxicity

Aquatic long-term toxicity - fish
Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/l) time
alkyl alcohol ethoxylate EC 10 8983 Not specified Method not 21 day(s)
given
alkyl alcohol ethoxylate EC 10 8.983 Not specified Method not 21 day(s)
given
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-napht No data
hyl)ethan-1-one available
alpha-hexylcinnamaldehyde No data
available
ionone, methyl- No data
available
2-(4-tert-Butylbenzyl)propionaldehyde No data
available
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl) No data
ethan-1-one available
1,2-benzisothiazol-3(2H)-one No data
available
sodium hydroxide No data
available
tridec-2-enenitrile No data
available

Aquatic long-term toxicity - crustacea

Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/l) time
alkyl alcohol ethoxylate 2579 Daphnia Method not 21 day(s)
magna given
alkyl alcohol ethoxylate EC 10 2.579 Daphnia sp. Method not 21 day(s)
given
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-napht No data
hyl)ethan-1-one available
alpha-hexylcinnamaldehyde No data
available
ionone, methyl- No data
available
2-(4-tert-Butylbenzyl)propionaldehyde No data
available
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl) No data
ethan-1-one available
1,2-benzisothiazol-3(2H)-one No data
available
sodium hydroxide No data
available
tridec-2-enenitrile No data
available

Aquatic toxicity to other aquatic benthic organisms, including sediment-dwelling organisms, if available:
Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/kg dw time (days)
sediment)
alkyl alcohol ethoxylate No data -
available
alkyl alcohol ethoxylate No data -
available

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1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-napht No data
hyl)ethan-1-one available
alpha-hexylcinnamaldehyde No data
available
ionone, methyl- No data
available
2-(4-tert-Butylbenzyl)propionaldehyde No data
available
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl) No data
ethan-1-one available
1,2-benzisothiazol-3(2H)-one No data
available
sodium hydroxide No data -
available
tridec-2-enenitrile No data
available

Terrestrial toxicity
Terrestrial toxicity - soil invertebrates, including earthworms, if available:
Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/kg dw time (days)
soil)
alkyl alcohol ethoxylate No data -
available
alkyl alcohol ethoxylate No data -
available
sodium hydroxide No data -
available

Terrestrial toxicity - plants, if available:

Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/kg dw time (days)
soil)
alkyl alcohol ethoxylate No data -
available
alkyl alcohol ethoxylate No data -
available
sodium hydroxide No data -
available

Terrestrial toxicity - birds, if available:

Ingredient(s) Endpoint Value Species Method Exposure Effects observed
time (days)
alkyl alcohol ethoxylate No data -
available
alkyl alcohol ethoxylate No data -
available
sodium hydroxide No data -
available

Terrestrial toxicity - beneficial insects, if available:

Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/kg dw time (days)
soil)
alkyl alcohol ethoxylate No data -
available
alkyl alcohol ethoxylate No data -
available
sodium hydroxide No data -
available

Terrestrial toxicity - soil bacteria, if available:

Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/kg dw time (days)
soil)
alkyl alcohol ethoxylate No data -
available
alkyl alcohol ethoxylate No data -
available
sodium hydroxide No data -
available

12.2 Persistence and degradability

Abiotic degradation
Abiotic degradation - photodegradation in air, if available:
Ingredient(s) Half-life time Method Evaluation Remark
sodium hydroxide 13 second(s) Method not given Rapidly photodegradable

Abiotic degradation - hydrolysis, if available:

Abiotic degradation - other processes, if available:

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Biodegradation
Ready biodegradability - aerobic conditions
Ingredient(s) Inoculum Analytical DT 50 Method Evaluation
method
alkyl alcohol ethoxylate 80% Method not given Readily biodegradable
alkyl alcohol ethoxylate 60 % in 28 day(s) Read across Readily biodegradable
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-nap Not readily biodegradable.
hthyl)ethan-1-one
alpha-hexylcinnamaldehyde Not readily biodegradable.
ionone, methyl- OECD 301F Readily biodegradable
2-(4-tert-Butylbenzyl)propionaldehyde OECD 301B Readily biodegradable
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphth Not readily biodegradable.
yl)ethan-1-one
1,2-benzisothiazol-3(2H)-one Weight of Not readily biodegradable.
evidence
sodium hydroxide Not applicable (inorganic
substance)
tridec-2-enenitrile Not readily biodegradable.

Ready biodegradability - anaerobic and marine conditions, if available:

Degradation in relevant environmental compartments, if available:

Ingredient(s) Medium & Type Analytical DT 50 Method Evaluation
method
1,2-benzisothiazol-3(2H)-one Sewage treatment Primary > 90% OECD 303A Biodegradable
plant simulation degradation

12.3 Bioaccumulative potential

Partition coefficient n-octanol/water (log Kow)
Ingredient(s) Value Method Evaluation Remark
alkyl alcohol ethoxylate 3.11 - 4.19
alkyl alcohol ethoxylate 3.11 - 4.19 Method not given High potential for bioaccumulation
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetr No data available
amethyl-2-naphthyl)ethan-1-one
alpha-hexylcinnamaldehyde No data available
ionone, methyl- No data available
2-(4-tert-Butylbenzyl)propionaldehyde No data available
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexam No data available
ethyl-2-naphthyl)ethan-1-one
1,2-benzisothiazol-3(2H)-one 0.7 OECD 107 No bioaccumulation expected
sodium hydroxide No data available Not relevant, does not
bioaccumulate
tridec-2-enenitrile No data available

Bioconcentration factor (BCF)

Ingredient(s) Value Species Method Evaluation Remark
alkyl alcohol ethoxylate < 500
alkyl alcohol ethoxylate < 500 Method not given High potential for bioaccumulation
1-(1,2,3,4,5,6,7,8-octah No data available
ydro-2,3,8,8-tetramethyl
-2-naphthyl)ethan-1-on
e
alpha-hexylcinnamalde No data available
hyde
ionone, methyl- No data available
2-(4-tert-Butylbenzyl)pr No data available
opionaldehyde
1-(5,6,7,8-tetrahydro-3, No data available
5,5,6,8,8-hexamethyl-2-
naphthyl)ethan-1-one
1,2-benzisothiazol-3(2H 6.95 OECD 305
)-one
sodium hydroxide No data available
tridec-2-enenitrile No data available

12.4 Mobility in soil

Adsorption/Desorption to soil or sediment
Ingredient(s) Adsorption Desorption Method Soil/sediment Evaluation
coefficient coefficient type
Log Koc Log Koc(des)
alkyl alcohol ethoxylate No data available High potential for mobility in
soil
alkyl alcohol ethoxylate No data available Potential for mobility in soil,
soluble in water
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-nap No data available

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hthyl)ethan-1-one
alpha-hexylcinnamaldehyde No data available
ionone, methyl- No data available
2-(4-tert-Butylbenzyl)propionaldehyde No data available
1-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphth No data available
yl)ethan-1-one
1,2-benzisothiazol-3(2H)-one No data available
sodium hydroxide No data available Mobile in soil
tridec-2-enenitrile No data available

12.5 Other adverse effects

No other adverse effects known.

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Waste from residues / unused The concentrated contents or contaminated packaging should be disposed of by a certified handler
products: or according to the site permit. Release of waste to sewers is discouraged. The cleaned packaging
material is suitable for energy recovery or recycling in line with local legislation.

Empty packaging
Recommendation: Dispose of observing national or local regulations.
Suitable cleaning agents: Water, if necessary with cleaning agent.

SECTION 14: Transport information

ADG, IMO/IMDG, ICAO/IATA
14.1 UN number: Non-dangerous goods
14.2 UN proper shipping name: Non-dangerous goods
14.3 Transport hazard class(es): Non-dangerous goods
14.4 Packing group: Non-dangerous goods
14.5 Environmental hazards: Non-dangerous goods
14.6 Special precautions for user: Non-dangerous goods
14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code: Non-dangerous goods
Other relevant information:
Hazchem code: None allocated

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

HSNO Approval Number HSR002530.

Group standard Cleaning Products (Subsidiary Hazard) Group Standard 2017
Inventory Listing(s) New Zealand: NZIoC (New Zealand Inventory of Chemicals)
All components are listed on the NZIoC inventory, or are exempt

SECTION 16: Other information

The information in this document is based on our best present knowledge. However, it does not constitute a guarantee for any specific product
features and does not establish a legally binding contract

SDS code: MS32000581 Version: 01.0 Revision: 2019-04-03

•H410-Ver
ytoxict
oaquati
cli
fewi
thlonglast
ingeff
ects.
•H411-Toxi
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icl
if
ewithl
onglast
ingeffect
s.
•H412-Har
mf ul
toaquat
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if
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s.
Abbreviations and acronyms:
•DNEL-Der i
vedNoEf fec tLimi t
•AUH-GHSSpec if
ichaz ar ds t
atement
•PNEC-Predi ct
edNoEf f
ec tConc entration
•ATE-AcuteTox ici
tyEs timat e
•LD50-Let
hal Dos e,50% /Medi anLet hal dose
•LC50-Let
hal Conc entration,50% /Medi anLethalConcent
rat
ion
•EC50-eff
ectiveconc entrat i
on,50%
•NOEL-Noobs ervedef fec tl
evel
•NOAEL-Noobs ervedadver seeffectlevel
•STOT-RE-Spec i
fi
ctargetor gantoxicity( r
epeatedexposur
e)
•STOT-SE-Spec ifi
ctargetor gantoxi
c it
y( singl
eex posur
e)
•ECNo.-Eur opeanCommuni t
yNumber
•OECD-Or ganizati
onf orEc onomicCooper ati
onandDevelopment

End of Safety Data Sheet

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