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Solution

The document contains multiple-choice questions (MCQs) related to colligative properties and solutions, referencing specific pages from the NCERT textbook. It covers topics such as boiling point elevation, freezing point depression, osmotic pressure, and various solution behaviors under different conditions. The questions assess knowledge on the relationships between solute concentration, vapor pressure, and the physical properties of solutions.

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11 views14 pages

Solution

The document contains multiple-choice questions (MCQs) related to colligative properties and solutions, referencing specific pages from the NCERT textbook. It covers topics such as boiling point elevation, freezing point depression, osmotic pressure, and various solution behaviors under different conditions. The questions assess knowledge on the relationships between solute concentration, vapor pressure, and the physical properties of solutions.

Uploaded by

swatipr2612
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF or read online on Scribd
'6. Which of the following is/are coligative : NCERT Based MCQs ieee ee ee Pee fo : @) Weter - Nitric acia Renan (4) Benzene - Acetone ae wate E solution that could be used in the blood steam se Gon boiling point of a solution of INCERT Fo. 291 9 (mol vit. = 100) in 100 9 of water is (1) 0.48 mol (2) 032 moll. (4) 0.45 mol. 'ATy: then the ebullioscopic constant of water is INCERT Pg. 16] 8, (1), Lowering in vapour pressure @) Freezing point @) Boiling point (4) Both (2) & (3) ‘The average osmotic pr 8) 0.30 mot AS molar solution of 1,50, property? [NCERT Pg. 15) cessure of human blood i678 sntration of aqueous NaC} is diluted from 1 litre to 'e normality of the resulting solution is (1) 10047, @ at, 40 litres. Th aT 0 (4) 1047, bees (1) 0.25N @ 10N 3 The order of Ky values of A, B and C gases is @) 20N @ 05N Ky,> Ku. Kg. Then, the Jer of 5 correct order of their 9, Which of the followin ee worrcrnre ich of the following with respect to negative solubility in a liquid at given temperature is deviation is correct? INCERT Pa. 13) INCERT Pg. 71 4) AGeq <0 Ege) <0, AHsa < { Mee css ) se ie ? Bae Oe AS gy <0 ‘ @ B>A>c 7 se oa Bie-c>A | 2) AG gq, < 0; AHsy <0: 8857 © a (= (@) AGga > 0: Bes 0: AS =O (4) A>B>Cc 4, The effect of increase in aqueous solution of a substan the temperature of an 10. INCERT Pg. 4] (1) Decrease in its molality (4) AGgg > 0, Hg > 0: ASgas? © The total vapour pressures Prorat two volatile component (in tort) for @ mixture of ts, A and Bis given by: Pi, = 220 - 110 Xp sion of component, B is (2) Increase in its molality {@) Increase in its mole fraction where, Xz is mole frac tu (4) Decrease in its molarity ie i an a ressure (in torr) of pure components, By the molarity of a solution of sod chloride in jence, Pt 500 ml of syaver containing 5.85.9 0rsodu™ chloride and B are respectively INCERT Pg. is [NCERT Pg. 4] (a) 110, 220 oa (1) 0.25M (2) 220, 110 - \ ie 0M (@) 220, 320 a (3) 20M (4) 220, 10 (4) 02M 8, Puse Road, New Delhi-110008. Phone : 011-47623456 Tower, (RNCaiporate Orrico : have ee EEN ee ae following mixtures se at 30°C is INCERT Pg. 20] () HD and HNO, @) 002M (@) H,0 and CoHs 9 (4) 008M pias oo a HCl, and CH,— © — CH, ¢ ofthe folowing aqueous solution wil have th @ CHE), s eee? Meer Ce I (4) n-hexane and n-heatane 4 @ !) 0.1 NaCl solution (2) 0.1 m Sugar solution (ech oto fotoning wll riot chey af sa: Man 10:1 m MgCl, solution (4) 0.1 m AICI, solution 0 Qk, “4 tenmatessscononstien tenia OS ae : Ty courvenone @) Leceenene” 6 Whkthoneof he fotlwng 92008 vl have mi value ofK, (kbar) at same temperature in aquagy @) Equal to one (@) Zer0 fare ® is 25% in 2) CO, 15, If degree of dissociation of Al(SO,), is 25% in a oH @) ©0, : solvent, then INCERT Pg, 24] are #0 14. Ani oe ana pOon= expermment| Polina Point 7 in the case of osmosis, solvent molecules move ig the (@) Normal osmotic pressure = 2 « experimental is ‘osmotic pressure (1) Higher vapour pressure to lower vapour pressing 8) Normal molecular weight = 2 « experimental (2) Higher concentration to lower concentration a ‘molecular weight (@) Lower vapour pressure to higher vapour pressulg ® 15, Th 1 igher osmotic pressure 1) Normal tezig pont = 2 = experiments! Haher osmotic pressure to lower osmoig « st lad 8. Assuming salts to be 90% dissociated, which of a (RSL Section - 5 following will have highest osmotic pressure? 4 Objective Type Questions (1) DecimolarAl,(SO,), @ ‘Which of the following is correct about a solution 2) Decimotar Bac, « showing positive deviation? (3) DecimateeNa,s r (1) Vapour pressure observed will be the less than a . 16. 2 that calculated from Raoult's law (4) Asolution obtainec by mixing equal volumes of iS (2) and (3) and filtering 4 {2) Minimum boiling azeotrope will be formed 9 Whict fol ( Baie. Nich of the following is not a colligative propefy® tnt fs ( (4) AV, < 0 (1) Vapour pressure of pure liquid solvent % (2) Elevation in boiling 2 On mixing 10 mi of ethanol with 10 mi of benzene are the total volume of the solution is 8) Depression in freezing point (1) > 20 mi (4) Osmotic pressure a < 10. ‘ — 2) <20m Which ofthe folowing is correct fora solution shown @) =20m Positive deviation fr om Raoult’s law? 4 Vic > 0, AHpie >0 (2) AV ian <0, AH $0 (3) AVmig = 0, AH, 0 (4) AVyy > 0, AP (4) Can't be predicted (1) a hn Tower, usa Road, New Dethi-t10005 Phone : 011-47623456) pressure of solvent and re the moles of solute and, @ Pam my oe Te . ‘ man, Fg pain of Gt, CH,OH, CH, Baron ave sore, 880, eave ate size Which ofthe follow ing will hav (apour pressure at room temperature? mie (t) Cots (2) CHOH @) PP=Pxn, P= 199% 135 (where xis the mole fraction of meth are the vapour pressures of pure moth alconoh pure ethyl alcohol at 40°C? (1) 195 and 264 torr (2) 119 and 195 torr (8) 119 and 264 tor (4) 384 and 195 torr solvent decreased by 10.” alconok.) What and @) CoH SNH, (4) [Link], 20. The vapour pressure of a! /law> 43. Hany solute’ dimerises in water att atm pre of ig when @non-olatle solute was ced 6 > Hanyehtecmensnwsi sangre «SN ae tn un foozo Bipraaze a caare ciercy | teleeNtetetcareatge | ninimum, ofA " @) 08 @ 06 aqueous (1) 50% 2) 30% Ske Oe 21. Wamofnon-volatie organic substance of 5% % @ 2 (4) 100% mass Mis dissolved in 250 gm benzene. Molal 44, An aqueous solution freezes at-0.36°C. Ky and Ky tlevation constant of benzene is K,, Elevation in 8S procter are 1.8 and 0.52°C -kg mot respectively oo ve from then value of boling point of solution at 1 alm pressure ) aK,W ressure E ey Soe 108" 01" Bs (4) 101.04°C ) 100.1°C » KW (@) 0.104°C (4) 100°C ® “aw ressure 44. Therelationship between osmotic pressure (P)at278 22. The molal elevation constant for water Is smotic Keuihen 10 g glucose (P,), 10.9 urea (P,) and 10.9 Tre reach Calouatethebolingotthescuton fuerose (P,) are dissolved in 250 mi of water's made by dissolving 6.0 gm of urea in : 200 gm of water of the (t) P, > P2>P. Lael > g } (4) 100.28°C @ 108°C @) P,>P.>P. ae : i) 2 (3) 028°C (@) 20028°C @) P7 Ps? Ps 23, The graph plotted vapour pressure vs mole fraction, is the graph for which of the folowing example (4) P,> P2>P we: 16, Arrange the followi aqueous solutionsin the order nes of of their increasing boiling points (i) 10-* M NaC! (i) 10° M Urea erty? 0 pie? (ii) 10° M MgCl, (v) 10° M NaCl @ wcrA (4) A>B>C ure ({1) vs concentration ives a straight line with ature at which SECTION - C Previous Years Questions ce water follow the order re () B>Arc @a>cre 2 The plot of osmotic press’ (mol L~) for a solution gi slope 25.73 L. bar mot". The tempe the osmotic pressure measurement = done © [NEET-2024) (083 L bar mot" K"") (Use R= (2) 310°C (1) 37°c (4) 12.05°C @) 25.73°C 3, Which amongst the electrolytes will have rinimury point? Choose the correct option. [NEET-2023 (Phase?) (2) 1M NaCl (4) 0.4 MKCI es at the same temperature NeeT-2022 (Phase2)] following aqueous SolutONS of elevation in boiling (1) 0.1 M MgSO, (8) 0.05 M NaCl 4, Ky, value for some gas ‘T are given: ERB Coporate Ofte Jo i Aakash Tower g, Pusa Road, (1) HoHO < cH, < 60, < @) Ar< 00, < GH, < HCHO @) Are CH, < CO, < HCHO (@) HCHO < CO, < CH, Py? Pe der of os ots @) Pa> Ps > Po () PL>P,>P, Pe Para 49460 ; @ 27 100 ml of 1 M NaOH is mixed with 60 m! of TN'KOH solution. “Normality of mixture is le traction—+ 1) 1N 2) 0.5N vera e Correct observation fo this solution @) 0.25N 4) 2N ¢ (1), He 9 @) AS pyc: i 28 Mass of NaC! required to prepare 0.01 m aqueous B59 ‘solution in 1 kg water is (3) AV ini 748 (4) All of these m) 0.8859 436, Amixture of two quids A and 8 having boing poe Grais 70°C. and baling point of Bis 100°C, dei 3 4) 5.889 at 101.2°C as single liquid, hence this mistursis ‘The vapour pressures of two iquids Aand Bare 100 Cy eee su tn 16Dior respective, Tho ota vapour pressure Sie nal ton oo {@) Non ideal solution showing —ve deviation 44 on (@) immiscible solution 150,00 torr (4) 199.33 tor 16. Vapour presstre diagram of some iquds pli against temperature are shown below 30. The freezing point of a solution containing 0.4 g of st p aceticacid in 40 g of benzene is lowered by 0.512°C. Pr 7s 8S imal isthe degree of dimerisation of acetic acid? a [Kbenzene) = 5.12 K kg mot") | 4) 60% 2 90% | E (4) 60% 7 4 molar aqueous solution is__ ‘Most volatile liquid nm aqueous solution Ma 4), More & Qe a1 Q) Less ack (@) Equally ane (4) Very less were uring evaporation of iquid {Wnt is he concentration of NO,-ions when equal ° a yolumes of 0.1 MAGNO; and 0.1 MNaClare mixed (1) The temperature of liquid rises together? sii (2) The temperature of liquid falls (1) 0.1N (2) 0. “ (0) The temperature of quid remains une @ 005M @) 02M ‘ (4) The liquid molecules becomes inert memmenncarmeate Once Aakash Tower, 8, Puse Road, New Dai 10008, Phone * 014471 Point 49) Ne* moves from solution Ato solution B S Baw Both Na* and é Wich havi ih a ee Bed we Tn tn a ai ‘ ques sli from solution (A ‘solution (B) ) to (3) Aqueous solution (4) us elation () Ages slton “a t We wc 9 Comect observation a 1 Freezing point of solution is marked a5 Ma ae @c @ 0 O1MUrea 0.1MNaCl 0.1 M CaCl, (1) Vapour pre: pour pressure o' 45, varit Hoff factor for acaic acid in aqueous medium, at infinite dilution is s di - (2 @4 va % 3 46. Correct order o freezing point of gven eaution int is maximum for Il ho 0) Rr O BR is minimum for It ; S02 co ih 0.4 MINA lution of sugar is taken in a beaker hve eee! 40. @ tole v Be cyatais a (y Leneii

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