;,,·
[�� .
Q&o , $ :
. •. ., ' .. ....... 1. . J - -1 . . I_,.,.;]
2023 f 111 IO I I
CNEMIS'l''RY (S!)
(1 PQff) Mas. Marki : '70
T1t< qwstio11 pttpt'r is di\'I� into /011, .'ftclfons.
Q. No. I conrnin.v Ttlf m1Jlt 1JJ/t choiC'e l)'fN ofqu�stions
con:ving O.t mark each.
Q. No. 1 contains E/1,,, vtry short answer t)pe of
questions C'Orryin,f! One mark eaC'h.
,:, StttitHI B: Q. Yo. 3 to Q. No. /,I are Twelt 1t short answer type of
q1«•.,;;im1s can:ni1g TN'O 11wrks each. (Allempr anJ' Eight)
,3, �lion C: {>. .\"o. IS 10 Q..\'o. 16 arc T•rth·e slwrt ansll'er �,pe of
quest io11.�· can:n·ng T/1rec marks· each. (Attempt any
EightJ
(-I) S«tion D: Q. ,\·o. 27 to Q. No. JI are Five long answer type of
questions carrying Four marks each.(Allempt any
Three)
(5) Use oflog table is allowed Use of calculator is not allowed.
(6) Figures lo the right indicate full marks.
(7) For each multiple choice type of question. it is mandatory to write
the correct answer along with its alplwbe! e.g. (a}............. ./ (b) ... .........
· I (c) ............. I (d) ........... etc.
Page 1 P.T.O.
,\'o rnnrkls) _(/101/ be �i\-en. if ONLY the correct an.,;wer or lhe
alphahcr o/ Jhe correct [Link] is wrirten.
On�,· the first attempt will be considered for evaluation.
Given
R = 8.314 J.K '· mol 1
NA = 6.022,. 1023
r-= 96500C
SECTION -A
Q. I. Select and write the correct answer for the following multiple 11 O J
choice type of questions
(i) The relation between radius of sphe_r_e and edge length in
body centered cubic lattice is given by formula
JJ
(b) r=-X4
(a) JJr= 4a , a
JJ
{c) r=-a (d) r=-xa
{i i) The pH of weak monoacidic base i�) 1.2, its OH- i_on
concentration is
\l!), l.585 x 10-3 mol dm-3 (b) 3.010 x 10-11 moldm-3
(c) 3.010 x 10-3 moldm-3 (d) 1.585 x 10-11 moldm-3
(iii) Which of the following correctly represents integrated rate
· law equation for a first order reaction in
gas phase :
k 2.303 X Iog Pi k 2. 3 Pi
(a) (b) = 3t0 x Iog,o
, -- t Pi-P
10
";/ 2Pi-P
2.303 2Pi 2 .3 03 Pi - P
(c) k= X 1021
0 Pi - ( d) k= xlog,o 2Pi
� -
t
t -P
(iv) The spin only magnetic moment of Mn2+ ion is ___
(a) 4.901BM ,(b) 5.916BM
(c) 3.873 BM (d) 2.846 BM
1 ° 1 2 !5! 2 1 Page 2
·..�.... ·--- .. ·--- . . -... .,...,..._
_.., .... . . -.,.. .
(v) The formula of_a complex having JUPAC name
correct
Tetraamminedibromoplatinum (IV) bromide is
--
(a) [Pt Br (NH3)4] Br2 (b) [Pt Br (NH ) ] Br
2 3 4
(c) [Pt Br2 (NH )4] Br (d) [Pt Br(Nl-1 3 >.tJ Br
, 3 2
(vi) The allylic halide. among the following is __
(a) R _:_ CH- R (b} Cll 2 = CII -- X
X ..,(d)
(c) Q' CH2=CH-CH2-X
(,ii) The product of followi ng reaction is
--
i)LiAIH4
CH3 -CH =CH-CH 2 -CHO ?
ii)H30+
(a) CH3 -CH2 -CH2 -CH2 -.CH 2 -OH
..(b) CH3 -CH =CH-CH2 -CH2 -0H
(c) CH3 -CH2 -CH 2 -CH 2 -COOH
(d) CH,� -CH=CH-CH.,- -COOH
(viii) Ozonolysis of 2, 3 di�ethyl but-2-ene, followed by
decomposition by Zn dust and water gives __
(a ) acetaldehycle
(b) propionaldehyde and acetone
!c) acetone
( d) acetaldehyde and butyraldehyde
(ix) The glycosidic l!nkage present in maltose is __
(a) a, '3 - I, 2- glycosidic linkage
(J>) a -1, 4 - gJycosidic linkage
(c) P-1.4-glycosidic linkage
(d) a -1,6-glycosidic linkage
(x) The monomer of natural rubber is __
'8-) Isoprene (b) Acrylonitrile
( c) E -Caprolactam ( d) Tetrafluoroethylene
P.T.O.
Page 3
Q. 2. Answer the following que 18\
stions :
y of
(i) Write the nam� ?f the technique used to know geometr
nanopanic les.
(ii) · the name of th · o n of
W rite e product formed by the actt
LiAIH4 / ether on acetamide.
,(iii) Writ e the structure of t he produc t forme d wh en
chlor obenzene is treated with sodium metal in the presence
, of dry ether.
(iv) Write the chemical composition of cryolite.
(v) Write the name of platinum complex used in the treatment
of cancer.
(vi) Write the SI unit of cryoscopic constant.
(vii) Write the correct co'ndition for spontaneity in terms of Gibbs
energy.
(viii) Calculata molar conductivity for 0.5 M BaC12 if its
conductivity at 298K is 0.01 n-1 cm-1.
SECTION - B
Attempt any EIGHT of the following questions: { 161
Q. 3. Distinguish between Janthanides and actinides.
Q. 4. Calculate the mole f action of solute, if the vapour pressure of
r
pure benzene at certain temperature is -?�9 ynmHg and vapour
pressure of solution of a solute in benzene is 600 mmHg.
Q. 5. Define : Green chemistry. Write two advantages of nanoparticle
and nanotechnology.
Q. 6. Explain the following terms:
(a) Substitutional impurity defect
(b) Interstitial impurity defect
IOI 2I �I2I Page 4
chemical reactions for the f0!10,vi11u:
Q. 7. Write the
(a) Chlorobenzene is hcatrd with fuming H 2 S0 4
(b) Ethyl bromide is heated with silver Jcctatc
Q. 8. Define: Acidic butler solution. \Vntc the rcl�tion"hir hctwccn
solubility and solubility product for f > bl ,.
I
Q. 9. What is the action of the following reagents on ethyl amine
(a) Chlorofon11 and caustic potash
( b) itrous acid
Q. JO. Cakulate standard Gibbs energy change at 25 °C for the cell
reaction
Cd ts)+Sn 2�\aq) Cd2�(aq)+Sn (s)
E e,Cd= - 0.403V. E 0Sn=- 0.136V
Q. I I. Write chemical reaction for the preparation of glucose from
sucrose. \Vrite structure of D-ribose.
Q. 12. Define Extensi\'e property. Calculate the work done during the
expansion of 2 moles
.. of an ideal -gas from· IO dm3 to 20. .dm 3 at
"'
298 Kin ,·acuum.
Q. 13. \\.'rite the reactions f0r the formation of nylon 6,6 polymer.
Q. 14. Draw structures of the [Link]:
(a) chloric acid
(b) peroxy disulphuric acid
SECTION - C
Attempt any EIGHT of the following questions : l24l
Q. J 5. Define Osmosis.
How will you determine molar mass of non volatile solute hy
elevation ofboiling point?
r.T.O.
Q. 16. Convert the following :
(i) Ethyl alcohol into ethyl acetate
(ii) Phenol into benzene
(iii) Diethyl ether into ethyl chloride
Q. 17. A \Veak 1nonohasic acid i� I 0°1«> dissociated in 0.05 M soluti on.
What is percent dissociation in 0.15 M solution'.'
Q. 18. Explain dehydroh:1logcnation reaction of 2-chlorobutane. Write
use and environmental effect of CFC.
Q. 19. 2000 mmol of an ideal gas expanded isothermally and reversibly
from 20 L to 30 L at 300 K calculate the work done in the
process (R = [Link]-I mo1-1 ). w:- - )P'"� ,.,v
Q. 20. What are interstitial compounds? Give the classi tication of alloys
with examples. [Link]
Q. 21. Draw labelled diagram ofH -o fuel cell. Write two applications
2 2
offuel cell.
Q. 22. Explain formation of [CoF6 J 39complex with respect to
(i) Hybridisation
(ii) Magnetic properties
(iii) Inner I outer complex
(iv) Geometry
Q. 23. What is Pseudo first order reaction? Derive integrated rate la,.v
equation for zero order reaction.
Q. 24. Explain A Idol condensation ofethanal.
Q. 25. Explain anomalous behaviour of oxygen in group 16 with r�s�ch.
to :
(i) Atomicity
(ii) Magnetic property
(iii) Oxidation state
Page 6
Q. 26. Write chemical reactio ns for the following c nve on
o rsi s :
(a) Acetic acid into acetic anhydride
(b) Acetic acid into ethyl alcohol
Write IUPAC name and structure of mcthylphenylamine.
SECTION-D
Attempt any THREE of the followini questions: 1121
Q. 27. Show that, time required for 99.9o/o completion of a first order
reaction is three times the tim e required for 90% completion.
Give electronic configuration of Gd (Z =64 ). W.,ite the name of
nano structured material used in car tyres to increase the life of
tyres.
Q. 28. Derive relationship between �H and 6U for gaseous reaction.
Define: Vulcanization
What is peptide bond?
Q. 29. Silver crystallizes in fee structure. If edge length of unit cell is
400 pm, calculate density of silver (Atomic mass of Ag= 108).
Write a note on Haloform reaction.
Q. 30. Define : Distereoisomers.
Give cis and trans isomers of [Co(Nl-1 3 )4 Cl 2 ]EB .
What is reference electrode?
Give reason : Bleaching action of ozone is also called dry bleach.
Q. 31. Write Dow process for preparation of Phenol. W hat is the action
of bromine water on phenol?
Give reason: Group 16th elements have lower ionisation enthalpy
compared to group 15th elements.
Write two uses of dioxygen.
•••
Page 7