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Heating Water in a Rigid Container

The document presents a problem involving heating water in a closed, rigid container, detailing the initial and final states of the system. It provides calculations for temperatures, masses of vapor, and pressure when the container holds only saturated vapor. The final results indicate T1 = 99.63°C, T2 = 111.4°C, mg1 = 0.295 kg, mg2 = 0.431 kg, and p = 2.11 bar.

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0% found this document useful (0 votes)
98 views2 pages

Heating Water in a Rigid Container

The document presents a problem involving heating water in a closed, rigid container, detailing the initial and final states of the system. It provides calculations for temperatures, masses of vapor, and pressure when the container holds only saturated vapor. The final results indicate T1 = 99.63°C, T2 = 111.4°C, mg1 = 0.295 kg, mg2 = 0.431 kg, and p = 2.11 bar.

Uploaded by

Latif Ibraheem
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Example 2-1: Heating Water at Constant Volume

Problem Statement:
A closed, rigid container of volume V = 0.5 m3 is placed on a hot plate. Initially, the
container holds a two-phase mixture of saturated liquid water and saturated water vapor
at p1 = 1 bar with a quality of x1 = 0.5. After heating, the pressure in the container is
p2 = 1.5 bar.
Determine:

(a) The temperatures (T1 and T2 ) at states 1 and 2 in ◦ C.

(b) The masses of vapor at states 1 and 2 in kg.

(c) The pressure when the container holds only saturated vapor.

Solution:
Given Data:

• V = 0.5 m3

• p1 = 1 bar, x1 = 0.5

• p2 = 1.5 bar

Step 1: Determine State 1 Properties


From the property table at p1 = 1 bar:

vf = 1.0432 × 10−3 m3 /kg, vg = 1.694 m3 /kg

The specific volume at state 1:

v1 = vf + x1 (vg − vf )

v1 = 1.0432 × 10−3 + 0.5(1.694 − 1.0432 × 10−3 ) = 0.8475 m3 /kg


Step 2: Determine State 2 Properties
At p2 = 1.5 bar, from the property table:

vf = 1.0528 × 10−3 m3 /kg, vg = 1.159 m3 /kg

Since vf < v2 < vg , the system is in the two-phase region. The quality (x2 ) is given by:

v2 − vf 0.8475 − 1.0528 × 10−3


x2 = = = 0.731
vg − vf 1.159 − 1.0528 × 10−3

Step 3: Determine Temperatures


From the property table:
T1 = 99.63◦ C, T2 = 111.4◦ C

1
Step 4: Calculate Mass of Vapor
Total mass (m):
V 0.5
m= = = 0.59 kg
v 0.8475
Mass of vapor at state 1:

mg1 = x1 m = 0.5(0.59) = 0.295 kg

Mass of vapor at state 2:

mg2 = x2 m = 0.731(0.59) = 0.431 kg

Step 5: Pressure for Saturated Vapor


When the container holds only saturated vapor (x = 1), the specific volume equals vg .
Interpolating in the property table at v = 0.8475 m3 /kg:

p = 2.11 bar

Final Answers:

(a) T1 = 99.63◦ C, T2 = 111.4◦ C

(b) mg1 = 0.295 kg, mg2 = 0.431 kg

(c) p = 2.11 bar

Common questions

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The property table is essential for determining state properties by providing standardized reference values for saturated liquids and vapors at various pressures. At 1 bar and 1.5 bar, the table gives the specific volumes of saturated liquid (vf) and vapor (vg), which helps ascertain the mixture quality and set temperature (such as T1 = 99.63°C, T2 = 111.4°C). By comparing the specific volume of the system to vf and vg, the phases present and their proportions can be deduced, aiding in calculations like quality and vapor mass .

The mass of vapor at different states is calculated using the quality and total mass of the system. At state 1, the mass of vapor is determined by multiplying the quality by the total mass: mg1 = x1 * m = 0.5 * 0.59 kg = 0.295 kg. At state 2, mass of vapor is similarly calculated: mg2 = x2 * m = 0.731 * 0.59 kg = 0.431 kg. This change reflects an increase in vapor mass corresponding to the increase in quality due to heating .

The initial quality and state impact subsequent temperature and mass changes by dictating the starting composition and energy requirements for phase transitions. With an initial quality of 0.5, the process begins halfway between saturated liquid and vapor, requiring less energy to reach fully vaporized states than if starting nearer to the liquid side. This facilitates a more substantial increase in vapor mass with relatively moderate temperature hikes as heating progresses from a balanced state, optimizing the thermodynamic advantages of latent heat absorption .

In a rigid container, the specific volume remains constant when transitioning from state 1 to state 2. This constraint implies that the volume of the container does not change and must equal the product of the specific volume and total mass. As pressure changes and the substance is heated, the quality changes, altering the proportions of liquid and vapor but maintaining the system's total volume. It dictates the state of the substance during phase change ensuring it remains within liquid-vapor mixtures until saturation .

The example provides insights that phase transitions in engineering systems require careful consideration of pressure, temperature, and specific volume to control system states effectively. Understanding the relationship between these properties allows engineers to predict how a system behaves under heat input, particularly in designing containers and heating processes. It underscores the importance of accurate property tables for engineering calculations involving phase change management to ensure safe and efficient operation .

As the two-phase mixture is heated from 1 bar to 1.5 bar, the quality increases from 0.5 to 0.731. This increase in quality indicates that a greater proportion of the mixture becomes vapor while the total mass remains constant. It shows that the mixture transitions further towards the vapor region while remaining in a two-phase system because the specific volume stays between the specific volumes of the liquid and vapor phases .

The process illustrates how energy input affects phase change in a closed, rigid thermodynamic system by demonstrating a pressure rise due to heating. Initially, the mixture at 1 bar is partly liquid and vapor. As energy is added, the pressure increases to 1.5 bar, shifting the state further towards vapor as evidenced by the increase in quality. At each step, the specific volume remains constant, reflecting that the added energy alters the phases' distribution rather than the system's volume, consistent with phase change fundamentals .

A rigid container influences the thermodynamics during heating by preserving constant volume, which restricts changes to pressure and temperature rather than volume alterations. This constraint forces the mixture to evolve within fixed volumetric confines, exclusively modifying its thermodynamic state through pressure and quality shifts as heat is added. Consequently, the system's specific volume remains steady, concentrating energy inputs on facilitating phase transitions rather than expansion, affecting how and when saturation conditions are reached .

The quality at state 2 is greater than at state 1 because heating increases the pressure from 1 bar to 1.5 bar in a closed, rigid container while maintaining the specific volume. As temperature and pressure rise, more energy is provided to the system, converting more liquid into vapor and thus increasing the quality despite the specific volume remaining unchanged. The specific volume at state 2 lies between the specific volumes of saturated liquid and vapor at the new pressure, supporting a higher quality in the mixture .

The pressure increases to 2.11 bar when the container holds only saturated vapor because this state corresponds to the specific volume of the system matching the specific volume of saturated vapor at this pressure. Since the container is rigid, only heating can cause such a transition, and it occurs when the mixture reaches the saturation point where remaining liquid has completely vaporized. At this point, the temperature and pressure align with the saturation properties at a specific volume of 0.8475 m³/kg, indicating 2.11 bar from the property table .

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