HEATING CURVE
EXPLAINING THE HEATING CURVE
When a solid is heated the particles gain kinetic energy and vibrate faster. This makes them ‘push’
their neighbouring particles further away from themselves. This causes an increase in the volume of
the solid, and the solid expands. As the particles gain kinetic energy, the temperature increases
During melting, the temperature remains constant, because, the heat energy is used to weaken the
forces of attraction between particles. The regular pattern of the structure breaks down, changing
into a liquid i.e the particles can now move around each other.
Continued heating causes the liquid particles to move around even faster as their kinetic energy
increases. Some particles at the surface of the liquid have enough energy to overcome the forces of
attraction between themselves and the other particles in the liquid and they escape to form a gas.
The liquid begins to evaporate as a gas is formed
Eventually, a temperature is reached at which the particles are trying to escape from the liquid so
quickly that bubbles of gas actually start to form inside the bulk of the liquid. This temperature is
called the boiling point of the substance. At the boiling point the pressure of the gas created above
the liquid equals that in the air – atmospheric pressure.
COOLING CURVE
The reverse processes of condensing and freezing occur on cooling .
When a gas is cooled, the kinetic energy of the particles decreases, and the particles move closer
together. The forces of attraction between the particles now become significant and cause the gas
to condense into a liquid. When a liquid is cooled it freezes to form a solid. In each of these changes
energy is given out
NOTE:
Whenever a change of state occurs, the temperature remains constant during the
change
Solids which have high melting points have stronger forces of attraction between
their particles than those which have low melting points.
Liquids with high boiling points have stronger forces between their particles than
liquids with low boiling points
A pure substance has a fixed boiling and melting points eg. Pure water boils at
1000C and melts at 00C.
Solids and liquids can be identified from their characteristic melting and boiling
points
Evaporation occurs at the surface of a liquid. It takes places at any temperature,
even below of the liquid.