Chemistry 𝑆= √

3 𝐾𝑠𝑝
4
3
=√
1.0×10−6
4
= 0.629 × 10−2 ≈
6.3 × 10−3

101. (1) 108. (4)

(𝐶𝐻3 )3 B is electron deficient. So, acts as a
Lewis acid. 109. (1)
𝐹𝑒(𝑂𝐻)3 ⇌ 𝐹𝑒 3+ + 3𝑂𝐻 −
102. (2) S 3S
𝐶𝐻3 𝐶𝑂𝑂𝐻 ⇌ 𝐶𝐻3 𝐶𝑂𝑂− + 𝐻 + 𝐾𝑠𝑝 = (𝑆)(3𝑆) = 27𝑆 4
3
C 0 0
𝐶(1 − 𝛼) 𝐶𝛼 𝐶𝛼
𝐶𝛼2
We know, 𝐾𝑎 = (where, 1 − 𝛼 ≈ 1 ) 110. (2)
1−𝛼
𝐾 1.7×10−5
Or 𝛼 = √ 𝐶𝑎 = √ =1 111. (3)
0.0002
+
𝛼 = 0.29, 𝐻 = 𝐶𝛼 = 0.0002 × 0.29
[𝐻 + ] = 5.8 × 10−5 M
𝑝𝐻 = − log[𝐻 + ] = − log(5.8 × 10−5 )
= − log 5.8 + 5 log 10 = −0.76 + 5 = 4.24

103. (2) 112. (1)

IUPAC name is
104. (3)
𝑀2+ + 𝑆 2− → 𝑀𝑆
Lower the value of 𝐾𝑠𝑝′ lower will be
solubility. Hence, HgS will precipitate first.

105. (4)
2𝐻2 𝑂(𝑔) ⇌ 2𝐻2(𝑔) + 𝑂2(𝑔) , 𝐾1
1 1
113. (3)
𝐻2(𝑔) + 2 𝑂2 ⇌ 𝐻2 𝑂(𝑔) , 𝐾 =
√𝐾1
1 ′ 114. (2)
𝐶𝑂2(𝑔) ⇌ 𝐶𝑂(𝑔) + 2 𝑂2(𝑔) , 𝐾 = √𝐾2
As s-character increases electronegativity
If equilibrium constant for the reaction
increases and stability of carbanion increases.
𝐶𝑂2(𝑔) + 𝐻2(𝑔) ⇌ 𝐶𝑂(𝑔) + 𝐻2 𝑂(𝑔) 𝑖𝑠 𝐾 " , then − − −
𝐶𝐻 ≡ 𝐶 > 𝐶𝐻2 = 𝐶 𝐻 > 𝐶𝐻3 − 𝐶 𝐻2
𝐾
𝐾 " = 𝐾 × 𝐾 ′ = √𝐾2 𝑠𝑝 𝑠𝑝2 𝑠𝑝3
1
Among 𝐶𝐻3 − 𝐶𝐻2− and 𝐶𝐻3− , 𝐶𝐻3− is more
106. (2) stable because +𝐼 effect of 𝐶𝐻3 destabilises
Base on accepting a proton gives its conjugate the carbanion. Thus, correct order of stability
acid. is
− − − −
𝐶𝐻 ≡ 𝐶 > 𝐶𝐻2 = 𝐶 𝐻 > 𝐶 𝐻3 > 𝐶𝐻3 — 𝐶 𝐻2
(A) (B) (D) (C)
107. (1)
𝐾𝑠𝑝 = 4𝑆 3
115. (3)

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116. (3) Due to poor screening effect, Al and Ga have
Hyperconjugation effect is also known as no nearly same atomic radii.
bond resonance and Baker-Nathan effect.
127. (2)
117. (3) 𝑛2
Radius of Bohr’s orbit (𝑟) = 0.529 × 𝑍
𝑟 ∝ 𝑛2

Thus, geometrical isomers are differ in spatial 128. (2)

ℎ𝑐 ℎ𝑐
arrangement of atoms only. 𝐸1 = 𝜆 = 8000×10−10 𝑚
1
118. (4) ℎ𝑐 ℎ𝑐
𝐸2 = = 16000×10−10 𝑚
𝜆2
𝐸2 8000×10−10 1
In this reaction −𝑁𝐻2 acts as nucleophilic = 16000×10−10 = 2
𝐸1
species which adds on carbon. Therefore, this
𝐸1 = 2𝐸2
is the case of nucleophilic addition reaction.
Simultaneously, a mole of 𝐻2 𝑂 is eliminated. 129. (2)
Therefore, overall this reaction is nucleophilic 130. (4)
addition elimination reaction.
131. (2)
119. (2) Energy of orbitals increases in the order:
120. (4)
6𝑠, 4𝑓, 5𝑑, 6𝑝
121. (3)
132. (3)
Higher the (𝑛 + 𝑙) value, higher will be the
energy. If value of (𝑛 + 𝑙) is same, higher
122. (3)
the value of 𝑛, higher will be the energy.
Ionic radii of isoelectronic ions decrease with
So, energy order : 4𝑠 < 3𝑑 < 4𝑝
increase of nuclear charge thus it shows a
(𝑛 + 𝑙) : 4 5 5
decrease from 𝑂2− to 𝐴𝑙 3+ .
(𝑛) : 4 3 4
123. (3)
133. (3)
Ionisation energy increases from left to right
in a period. But oxygen after removal of first Element Moles Least ratio
22 0.6875
electron gets stable half-filled electronic S = 0.6875 =1
32 0.6875
configuration and thus its second ionisation 4.10
78 =
energy is higher than that of fluorine. Thus, F = 4.10 0.6875
19
5.97 = 6
order of 2nd ionisation energy is 𝐶 < 𝑁 < 𝐹 <
𝑂.
Empirical formula = 𝑆𝐹6
124. (2)
134. (4)
Acidic strength order:
Haber’s process, 𝑁2 + 3𝐻2 → 2𝑁𝐻3
H2 O < H2 S < H2 Se < H2 Te
2 moles of 𝑁𝐻3 are formed by 3 moles of 𝐻2 .
pK a order : H2 O > H2 S > H2 Se > H2 Te
∴20 moles of 𝑁𝐻3 will be formed by 30 moles
of 𝐻2
125. (4)

126. (1) 135. (3)

Millimoles of 𝐴 = 100 × 0.1 = 10

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 Millimoles of 𝐵 = 25 × 0.2 = 5 some energy, so the energy released is less
Total millimoles = 10 + 5 = 15 than the expected.
15 15
∴ 𝑀 = 100+25 = 125 = 0.12
142. (2)
Radial nodes 𝑛 − 𝑙 − 1 = 1; Total nodes =
136. (4)
𝑛−1=3
For acid, [𝐻 + ] = 10−8 M, From 𝐻2 𝑂, [𝐻 + ] =
Hence, 𝑛 = 4
10−7 M
4−𝑙−1= 1
Total [H + ] = 10−8 + 10−7 = (1 +
𝑙=2
10)10−8 = 11 × 10−8 M
Orbital angular momentum
pH= log[𝐻 + ] = − log(11 × 10−8 ) ⇒ ℎ ℎ ℎ
6.9586 ≈ 6.96 = √𝑙(𝑙 + 1) = √2(2 + 1) = √6
2𝜋 2𝜋 2𝜋

137. (3) 143. (4)

𝑝𝑂𝐻 = − log[𝑂𝐻 − ] For first excited state
⇒ 𝑝𝑂𝐻 = − log(1) 𝑟𝑛 = 𝑟0 (𝑛)2 = 0.53(2)2 = 2.12 Å
∴ 𝑝𝑂𝐻 = 0
Also, pH + pOH = 14 ∴ 𝑝𝐻 = 14 144. (4)
1
𝐾. 𝐸 = 𝑚𝑣 2
2
138. (4) ∴ 𝐾. 𝐸 ∝ 𝑣 (accelerating potential)
A salt of strong acid and strong base cannot be
hydrolysed. In this case the equilibrium
145. (3)
cannot shifted towards backward. Visible range of hydrogen spectrum contains
Balmer series.
139. (2)
Electronic configuration of element with
146. (3)
atomic number 101: [𝑅𝑛] 5𝑓 13 6𝑑0 7𝑠 2 88
𝐶𝑂2 = 44 = 2 mole of 𝐶𝑂2 = 2 mole of C
As electrons are being filled in 5𝑓 thus it
36
represents actinoid. Electronic configuration 𝐻2 𝑂 = 18 = 2 mole of 𝐻2 𝑂 = 4 mole of H
of element with atomic number Mass of C + Mass of H + Mass of O = 44
14 2 2
104: [𝑅𝑛] 5𝑓 6𝑑 7𝑠 , thus, group number is ⇒ 24 + 4 + 𝑥 = 44; 𝑥 = 16
4 for this element. That means it contains one O-atom.
Molecular formula is 𝐶2 𝐻4 𝑂.
140. (1)
1 + 0 + 9 = 109 147. (3)
Un + nil + enn + ium = unnilennium 60 12
𝑋 × 0.6 × 100 = 200 × 0.9 × 100 ⇒ 𝑥 = 60

141. (1)
In general, electron affinity decreases down 148. (4)
Let volume of solution be 1000 mL.
the group but electron affinity for chlorine
Moles of 𝐻2 𝑆𝑂4 = 18
is more than fluorine, and similarly electron
Mass of 𝐻2 𝑆𝑂4 = 18 × 98 = 1764 g
affinity for Sulphur is more than oxygen,
Mass of solution = 1000 × 1.8 = 1800 g
because in F and O, due to small size of the
Mass of solvent = 1800 − 1764 = 36 g
atom, the electrons are already crowded. 18
Entry of one more electron results in more Molality = 36 × 1000 = 500
repulsions, which leads to absorption of

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149. (3)
22.4 L of 𝐶𝑂2 at STP = 1 mole = 6.023 ×
1023 molecules.
Hence, number of atoms = 3 × 6.023 × 1023

150. (1)
1 L of gas weights = 1.16 𝑔
22.4 L of gas weights = 1.16 × 22.4 = 26 g
Molecular weight of gas = 26 g
It can be possibly 𝐶2 𝐻2 .

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