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Carbocation Stability and Rearrangements Guide

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10 views4 pages

Carbocation Stability and Rearrangements Guide

Notes

Uploaded by

chaukeprecious027
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

2024_NCHE 322 Study unit 3 Tutorial

1. Give a clear explanation of how the following carbocation is stabilized

Me CH2
+
+
C
Me CH2CH3

2. Define rearrangement reactions and give the different types found.


3. Name and illustrate the 3 types of carbocation rearrangements (3)
4. Provide the carbocation rearrangement of the following:
+
CH3 CH2
+ +
CH2

+
+
+
5. Complete the following reactions.

Cl
EtOH

OH H2SO 4

O
1. NH2OH
2. H2SO4
OH H2SO 4
OH

Cl CH N
2 2
Heat
MeOH

O
NH2
NaOH (aq)
Br2
Heat

PhCO3H

Cl
N CH3 HCl(aq)
O

6. Propose the mechanism for the following rearrangements.


NO
N +
H

O
1. NaN3
Ph Cl 2. heat, H2O

N N
NH HCl

O O
AlCl3
heat
MeO

O O

1. -OH
2. H+

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