Solutions JEE Main 2024 - 2019 PYQs

Chapter Priority: Priority A MathonGo

Q1. The vapour pressure of pure benzene and methyl benzene at 27 ∘

C is given as 80 Torr and 24 Torr, respectively.
The mole fraction of methyl benzene in vapour phase, in equilibrium with an equimolar mixture of those two
liquids (ideal solution) at the same temperature is _______ ×10 −2
(nearest integer) 09 Apr 2024 (E)

Q2. 0.05MCuSO when treated with 0.01MK

4 2Cr2O7 gives green colour solution of Cu 2Cr2O7 . The two solutions
are separated as shown below : [SPM : Semi Permeable Membrane]

Due to osmosis : 09 Apr 2024 (M)

(1) Molarity of CuSO solution is lowered.
4 (2) Molarity of K 2Cr2O7 solution is lowered.
(3) Green colour formation observed on side Y. (4) Green colour formation observed on side X.

Q3. A solution is prepared by adding 1 mole ethyl alcohol in 9 mole water. The mass percent of solute in the
solution is ________ (Integer answer) (Given : Molar mass in gmol −1
Ethyl alcohol : 46 water: 18)
08 Apr 2024 (E)

Q4. Molality of an aqueous solution of urea is 4.44 m. Mole fraction of urea in solution is x × 10 . Value of x is −3

_______ - (Integer answer) 08 Apr 2024 (E)

Q5. A solution containing 10 g of an electrolyte AB in 100 g of water boils at 100.52

2
∘
C . The degree of ionization
of the electrolyte (α) is _______ ×10 . (nearest integer) [Given : Molar mass of AB
−1
2 = 200 g mol
−1
, Kb

(molal boiling point elevation const. of water) = 0.52 K kg mol , boiling point of water = 100
−1 ∘
C; AB2 ionises
as AB 2 → A
2+
+ 2 B
−
] 08 Apr 2024 (M)

Q6. Consider the dissociation of the weak acid HX as given below HX(aq) ⇌ H +
(aq) + X
−
(aq), Ka = 1.2 × 10
−5

[Ka : dissociation constant ] The osmotic pressure of 0.03M aqueous solution of HX at 300 K is _______
×10
−2
bar (nearest integer). [Given : R = 0.083 Lbarmol −1
K
−1
] 06 Apr 2024 (M)

Q7. When ' x ' ×10

−2
mL methanol (molar mass = 32 g ; density = 0.792 g/cm ) is
3

added to 100 mL water (density = 1 g/cm

3
), the following diagram is obtained.
x = ______ (nearest integer). [Given : Molal freezing point depression constant
of water at 273.15 K is 1.86 K kg mol ] −1

06 Apr 2024 (E)

Q8. An artificial cell is made by encapsulating 0.2M glucose solution within a semipermeable membrane. The
osmotic pressure developed when the artificial cell is placed within a 0.05M solution of NaCl at 300 K is
_______ ×10 −1
bar. (nearest integer). [Given : R = 0.083 Lbarmol −1
K
−1
] Assume complete dissociation of
NaCl 05 Apr 2024 (M)

Q9. Considering acetic acid dissociates in water, its dissociation constant is 6.25 × 10 . If 5 mL of acetic acid is −5

dissolved in 1 litre water, the solution will freeze at −x × 10 −2∘

C , provided pure water freezes at 0 ∘
C .x=
______. (Nearest integer)
Given :

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−1 −1
(Kf ) = 1.86 K kg mol , density of acetic acid is 1.2 g mol
water

−1 −1
molar mass of water = 18 g mol , molar mass of acetic acid=60 gmol

−3
density of water = 1 g cm

Acetic acid dissociates as CH 3COOH ⇌ CH3COO

⊖
+ H
⊕
05 Apr 2024 (E)

Q10. The Molarity (M) of an aqueous solution containing 5.85 g of NaCl in 500 mL water is: (Given: Molar Mass
Na : 23 and Cl : 35.5gmol −1
) 04 Apr 2024 (M)
(1) 2 (2) 20
(3) 4 (4) 0.2

Q11. 2.5 g of a non-volatile, non-electrolyte is dissolved in 100 g of water at 25 ∘

C . The solution showed a boiling
point elevation by 2 ∘
C . Assuming the solute concentration is negligible with respect to the solvent
concentration, the vapor pressure of the resulting aqueous solution is ________. mm of Hg (nearest integer)
[Given : Molal boiling point elevation constant of water (K b) = 0.52 K. kgmol
−1
, 1 atm pressure = 760 mm
of Hg, molar mass of water = 18 g mol ] −1
04 Apr 2024 (M)

Q12. 2.7 kg of each of water and acetic acid are mixed. The freezing point of the solution will be −x ∘
C . Consider
the acetic acid does not dimerise in water, nor dissociates in water. x = ______ (nearest integer) [Given: Molar
mass of water = 18 g mol , acetic acid = 60 g mol
−1 −1
Kf H2O : 1.86 K kg mol
−1
Kf acetic acid:
3.90 K kg mol
−1
freezing point: H 2O = 273 K , acetic acid = 290 K] 04 Apr 2024 (E)

Q13. We have three aqueous solutions of NaCl labelled as 'A',' B' and 'C with concentrations 0.1M, 0.01M and
0.001M , respectively. The value of van't Hoff factor for these solutions will be in the order. 01 Feb 2024 (M)
(1) i A < iB < iC (2) i A < iC < iB

(3) i A = iB = iC (4) i A > iB > iC

Q14. Mass of ethylene glycol (antifreeze) to be added to 18. 6 kg of water to protect the freezing point at −24°C is
kg (Molar mass in gmol −1
for ethylene glycol 62, Kf of water = 1. 86 K kg mol )
−1
01 Feb 2024 (E)

Q15. Identify the mixture that shows positive deviations from Raoult's Law 31 Jan 2024 (M)
(1) (CH 3)2CO + C6H5 NH2 (2) CHCl 3 + C6H6

(3) CHCl 3 + (CH3)2 CO (4) (CH 3)2CO + CS2

Q16. If a substance ′A′ dissolves in solution of a mixture of ' B' and ' C ' with their respective number of moles as
nA, nB and n , mole fraction of C in the solution is:
C 30 Jan 2024 (E)
(1) nC

nA×nB×nC
(2) nC

nA+nB+nC

(3) nC

nA−nB−nC
(4) nB

nA+nB

Q17. What happens to freezing point of benzene when small quantity of napthalene is added to benzene?
30 Jan 2024 (M)
(1) Increases (2) Remains unchanged
(3) First decreases and then increases (4) Decreases

Q18. The mass of sodium acetate (CH 3 COONa) required to prepare 250 mL of 0. 35M aqueous solution is _____
g.( Molar mass of CH 3 COONa is 82. 02 g mol
−1
) Round off to the nearest integer. 30 Jan 2024 (M)

Q19. The solution from the following with highest depression in freezing point/lowest freezing point is

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30 Jan 2024 (E)

(1) 180 g of acetic acid dissolved in 1 L of aqueous solution.
(2) 180 g of acetic acid dissolved in benzene
(3) 180 g of benzoic acid dissolved in benzene
(4) 180 g of glucose dissolved in water

Q20. A solution of H 2 SO4 is 31. 4% H 2 SO4 by mass and has a density of 1. 25 g/ mL. The molarity of the H 2 SO4

solution is M (nearest integer) [Given molar mass of H 2 SO4 = 98 g mol

−1
] 29 Jan 2024 (M)

Q21. Molality of 0. 8M H 2 SO4 solution (density 1. 06 g cm

−3
) is _______×10 −3
m .
Round off your answer to the nearest integer.
29 Jan 2024 (E)

Q22. The osmotic pressure of a dilute solution is 7 × 10 5

Pa at 273 K. Osmotic pressure of the same solution at
283 K is _______ × 10 4
Nm
−2
.(Nearest integer) 29 Jan 2024 (M)

Q23. The quantity which changes with temperature is: 27 Jan 2024 (E)
(1) Molarity (2) Mass percentage
(3) Molality (4) Mole fraction

Q24. A solution of two miscible liquids showing negative deviation from Raoult's law will have : 27 Jan 2024 (M)
(1) increased vapour pressure, increased boiling point
(2) increased vapour pressure, decreased boiling point
(3) decreased vapour pressure, decreased boiling point
(4) decreased vapour pressure, increased boiling point

Q25. The vapour pressure of 30% (w/v) , aqueous solution of glucose is ________ mm Hg at ∘
25 C . [Given: The
density of 30% (w/v) , aqueous solution of glucose is 1. 2 g cm
–3
and vapour pressure of pure water is
24 mm Hg .] (Molar mass of glucose is 180 g mol
–1
)
15 Apr 2023 (M)

Q26. Solution of 12 g of non-electrolyte (A) prepared by dissolving it in 1000 mL of water exerts the same osmotic
pressure as that of 0. 05 M glucose solution at the same temperature. The empirical formula of A is CH2 O.

The molecular mass of A is ________g. (Nearest integer)

13 Apr 2023 (M)

Q27. Sea water contains 29. 25% NaCl and 19% MgCl by weight of solution. The normal boiling point of the sea
2

water is ∘
C (Nearest integer) Assume 100% ionization for both NaCl and MgCl Given: 2

Kb(H2O = 0. 52 K kg mol
−1
) Molar mass of NaCl and MgCl is 58. 5 and 95 g mol
2
−1
respectively.
13 Apr 2023 (E)

Q28. 80 mole percent of MgCl

2
is dissociated in aqueous solution. The vapour pressure of 1. 0 molal aqueous
solution of MgCl at 38 2
o
C is _____ mm Hg . (Nearest integer)
Given: Vapour pressure of water at 38 o
C is 50 mm Hg

12 Apr 2023 (M)

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Q29. What weight of glucose must be dissolved in 100 g of water to lower the vapour pressure by 0. 20 mm Hg ?
(Assume dilute solution is being formed) Given: Vapour pressure of pure water is 54. 2 mm Hg at room
[Link] mass of glucose is 180 g mol
−1
11 Apr 2023 (E)
(1) 3. 59 g (2) 3. 69 g
(3) 4. 69 g (4) 2. 59 g

Q30. 0. 004 M K 2 SO4 solution is isotonic with 0. 01 M glucose solution. Percentage dissociation of K 2 SO4 is
_____ (Nearest integer) 11 Apr 2023 (M)

Q31. An aqueous solution of volume 300 cm

3
contains 0. 63 g of protein. The osmotic pressure of the solution at
300 K is 1. 29 mbar . The molar mass of the protein is gmol . Given: R = 0. 083 L
−1
barK
−1
mol
−1

10 Apr 2023 (E)

Q32. If the degree of dissociation of aqueous solution of weak monobasic acid is determined to be 0. 3, then the
observed freezing point will be _____ % higher than the expected/theoretical freezing point. (Nearest integer).
10 Apr 2023 (M)

Q33. The vapour pressure vs. temperature curve for a solution solvent system is shown below.
The boiling point of the solvent is _____°C.

08 Apr 2023 (M)

Q34. If the boiling points of two solvents X and Y (having same molecular weights) are in the ratio 2: 1 and their
enthalpy of vaporizations are in the ratio 1 : 2 , then the boiling point elevation constant of X is m times the
boiling point elevation constant of Y. The value of m is (nearest integer). 08 Apr 2023 (E)

Q35. Mass of Urea (NH2 CONH2) required to be dissolved in 1000 g of water in order to reduce the vapour
pressure of water by 25% is _______ g. (Nearest integer)
Given : Molar mass of N, C, O and H are 14, 12, 16 and 1 g mol
−1
respectively.
06 Apr 2023 (M)

Q36. Consider the following pairs of solution which will be isotonic at the same temperature. The number of pairs
of solutions is/ are _____
A. 1 M aq. NaCl and 2 M aq. urea B. 1 M aq. CaCl2 and 1. 5 M aq. KCl

C. 1. 5 M aq. AlCl3 and 2 M aq. Na2 SO4 D. 2. 5 M aq. KCl and 1 M aq. Al2(SO4)3

06 Apr 2023 (E)

Q37. 20% of acetic acid is dissociated when its 5 g is added to 500 mL of water. The depression in freezing point of
such water is _____ × 10
−3∘
C . Atomic mass of C, H and O are 12, 1 and 16 a.m.u. respectively. [Given :
Molal depression constant and density of water are 1. 86 K kg mol
−1
and 1 g cm
−3
respectively.
01 Feb 2023 (E)

Q38. 25 mL of an aqueous solution of KCl was found to require 20 mL of 1M AgNO3 solution when titrated using
K2 CrO4 as an indicator. What is the depression in freezing point of KCl solution of the given concentration?

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(Nearest integer). (Given : K f = 2. 0 K kg mol

−1
) Assume
1) 100% ionization and
2) density of the aqueous solution as 1 g mL
−1

01 Feb 2023 (M)

Q39. At 27°C, a solution containing 2. 5 g of solute in 250. 0 mL of solution exerts an osmotic pressure of 400 Pa .
The molar mass of the solute is g mol −1
(Nearest integer)
(Given : R = 0. 083 L bar −1
mol
−1
) 31 Jan 2023 (M)

Q40. Evaluate the following statements for their correctness.

A. The elevation in boiling point temperature of water will be same for 0. 1 M NaCl and 0. 1 M urea.
B. Azeotropic mixture boil without change in their composition.
C. Osmosis always takes place from hypertonic to hypotonic solution.
D. The density of 32% H 2 SO4 solution having molarity 4. 09 M is approximately 1. 26 g mL
–1
.
E. A negatively charged sol is obtained when KI solution is added to silver nitrate solution.
Choose the correct answer from the options given below:
31 Jan 2023 (E)
(1) B and D only (2) B, D and E only
(3) A and C only (4) A, B and C only

Q41. A solution containing 2 g of a non-volatile solute in 20 g of water boils at 373. 52 K . The molecular mass of
the solute is _____ gmol . (Nearest integer)
−1

Given, water boils at 373 K, K for water = 0. 52K

b kg mol
−1

30 Jan 2023 (M)

Q42. Lead storage battery contains 38% by weight solution of H2 SO4 . The van't Hoff factor is 2. 67 at this
concentration. The temperature in Kelvin at which the solution in the battery will freeze is _____ (Nearest
integer). Given K f = 1. 8 K kg mol
−1

30 Jan 2023 (E)

Q43. A 300 mL bottle of soft drink has 0. 2 MCO2 dissolved in it. Assuming CO2 behaves as an ideal gas, the
volume of the dissolved CO at STP is _____ mL. (Nearest integer)
2

Given: At STP, molar volume of an ideal gas is 22. 7L mol

−1

30 Jan 2023 (M)

Q44. Some amount of dichloromethane (CH2 Cl2) is added to 671. 141 mL of chloroform (CHCl3) to prepare
2. 6 × 10
−3
M solution of CH 2 Cl2(DCM) . The concentration of DCM is _____ ppm (by mass).
Given: Atomic mass : C = 12; H : 1; Cl = 35. 5 density of CHCl 3 = 1. 49g cm
−3

30 Jan 2023 (M)

Q45. Match List I with List II.

List I List II
van't Hoff
A. I. Cryoscopic constant
factor, i
B. k f II. Isotonic solutions

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Solutions with same

C. III. Normal molar mass

osmotic pressure Abnormal molar mas

Solutions with same composition

D. Azeotropes IV.
of vapour above it
Choose the correct answer from the options given below:
29 Jan 2023 (E)
(1) A-III, B-I, C-II, D-IV (2) A-III, B-II, C-I, D-IV
(3) A-III, B-I, C-IV, D-II (4) A-I, B-III, C-II, D-IV

Q46. Solid Lead nitrate is dissolved in 1 litre of water. The solution was found to boil at 100. 15°C . When 0. 2 mol

of NaCl is added to the resulting solution, it was observed that the solution froze at −0. 8°C . The solutbility
product of PbCl2 formed is _____ ×10
−6
at 298 K . (Nearest integer) Given: Kb = 0. 5K kg mol
−1
and
Kf = 1. 8 kg mol
−1
. Assume molality to be equal to molarity in all cases.
29 Jan 2023 (M)

Q47. What is the mass ratio of ethylene glycol (C 2H6O2 , molar mass = 62 g/ mol) required for making 500 g of
0. 25 molal aqueous solution and 250 mL of 0. 25 molar aqueous solution? 25 Jan 2023 (E)
(1) 1 : 1 (2) 3 : 1
(3) 2 : 1 (4) 1 : 2

Q48. The osmotic pressure of solutions of PVC in cyclohexanone at 300 K are plotted on
the graph. The molar mass of PVC is g mol
−1
(Nearest integer) (Given :
R = 0. 083 L atm K
−1
mol
−1
)

25 Jan 2023 (M)

Q49. The number of pairs of the solution having the same value of the osmotic pressure from the following is
(Assume 100% ionization)
A. 0. 500 M C 2H5 OH(aq) and 0. 25 M KBr(aq)

B. 0. 100 M K 4[Fe(CN)6](aq) and 0. 100 M FeSO 4 (NH4)

2
SO4(aq)

C. 0. 05 M K 4[Fe(CN)6] (aq) and 0. 25 M NaCl (aq)

D. 0. 15 M NaCl(aq) and 0. 1 M BaCl2(aq)

E. 0. 02 M KCl. MgCl2. 6H2O(aq) and 0. 05 M KCl(aq)

25 Jan 2023 (E)

Q50. 5 g of NaOH was dissolved in deionized water to prepare a 450 mL stock solution. What volume (in mL) of
this solution would be required to prepare 500 mL of 0. 1 M solution ? Given : Molar Mass of
Na, O and H is 23, 16 and 1 g mol
–1
respectively 24 Jan 2023 (M)

Q51. The number of units, which are used to express concentration of solutions from the following is _____. (Mass
percent, Mole, Mole fraction, Molarity, ppm, Molality.)
24 Jan 2023 (E)

Q52. In the depression of freezing point experiment

A. Vapour pressure of the solution is less than that of pure solvent

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B. Vapour pressure of the solution is more than that of pure solvent

C. Only solute molecules solidify at the freezing point
D. Only solvent molecules solidify at the freezing point 24 Jan 2023 (M)
(1) A and D only (2) B and C only
(3) A and C only (4) A only

Q53. The Total pressure observed by mixing two liquid A and B is 350 mm Hg when their mole fractions are
0. 7 and 0. 3 respectively. The Total pressure becomes410 mm Hg if the mole fractions are changed to
0. 2 and 0. 8 respectively for A and B. The vapour pressure of pure A is ______ mm Hg . (Nearest integer)
Consider the liquids and solutions behave ideally 24 Jan 2023 (E)

Q54. 1. 80 g of solute A was dissolved in 62. 5 cm

3
of ethanol and freezing point of the solution was found to be
155. 1 K . The molar mass of solute A is gmol . [Given: Freezing point of ethanol is 156. 0 K. Density of
−1

ethanol is 0. 80 g cm
−3
. Freezing point depression constant of ethanol is 2. 00 K kg mol
−1
] 29 Jul 2022 (E)

Q55. If O gas is bubbled through water at 303 K, the number of millimoles of O gas that dissolve in 1 litre of
2 2

water is____(Nearest integer) (Given : Henry's Law constant for O at 303 K is 46. 82k bar and partial
2

pressure of O 2 = 0. 920 bar)

(Assume solubility of O in water is too small, nearly negligible)
2 29 Jul 2022 (M)

Q56. 150 g of acetic acid was contaminated with 10. 2 g ascorbic acid (C 6H8O6) to lower down its freezing point by
(x × 10
−1
)°C . The value of x is____ (Nearest integer). [Given K f = 3. 9 K kg mol
−1
; Molar mass of
ascorbic acid = 176 g mol
−1
] 28 Jul 2022 (M)

Q57. A gaseous mixture of two substances A and B, under a total pressure of 0. 8 atm is in equilibrium with an
ideal liquid solution. The mole fraction of substance A is 0. 5 in the vapour phase and 0. 2 in the liquid phase.
The vapour pressure of pure liquid A is____atm.(Nearest integer) 28 Jul 2022 (E)

Q58. Boiling point of a 2% aqueous solution of a nonvolatile solute A is equal to the boiling point of 8% aqueous
solution of a non-volatile solute B. The relation between molecular weights of A and B is. 27 Jul 2022 (M)
(1) M A = 4MB (2) M B = 4MA

(3) M A = 8MB (4) M B = 8MA

Q59. When a certain amount of solid A is dissolved in 100 g of water at 25 °C to make a dilute solution, the vapour
pressure of the solution is reduced to one-half of that of pure water. The vapour pressure of pure water is
23. 76 mmHg . The number of moles of solute A added is 27 Jul 2022 (E)

Q60. The elevation in boiling point for 1 molal solution of non-volatile solute A is 3 K. The depression in freezing
point for 2 molal solution of A in the same solvent is 6 K. The ratio of K and K i.e., K b f b/Kf is 1 : X. The
value of X is 26 Jul 2022 (E)

Q61. Two solutions A and B are prepared by dissolving 1 g of non-volatile solutes X and Y. respectively in 1 kg of
water. The ratio of depression in freezing points for A and B is found to be 1 : 4. The ratio of molar masses of
X and Y is 25 Jul 2022 (E)
(1) 1 : 4 (2) 1 : 0. 25
(3) 1 : 0. 20 (4) 1 : 5

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Q62. The depression in freezing point observed for a formic acid solution of concentration 0. 5 mL L
−1
is
0. 0405 °C . Density of formic acid is 1. 05 g mL
−1
. The Van't Hoff factor of the formic acid solution is nearly:
(Given for water k f = 1. 86 K kg mol
−1
) 25 Jul 2022 (M)
(1) 0. 8 (2) 1. 1
(3) 1. 9 (4) 2. 4

Q63. Elevation in boiling point for 1. 5 molal solution of glucose in water is 4 K. The depression in freezing point
for 4. 5 molal solution of glucose in water is 4 K. The ratio of molal elevation constant to molal depression
constant (K b/Kf ) is 29 Jun 2022 (E)

Q64. 1. 2 mL of acetic acid is dissolved in water to make 2. 0 L of solution. The depression in freezing point
observed for this strength of acid is 0. 0198 °C. The percentage of dissociation of the acid is (Nearest integer)
[Given : Density of acetic acid is 1. 02 g mL
−1
Molar mass of acetic acid is 60 g mol −1

Kf (H2O) = 1. 85 K kg mol ]
−1
29 Jun 2022 (M)

Q65. The vapour pressures of two volatile liquids A and B at 25 °C are 50 Torr and 100 Torr, respectively. If the
liquid mixture contains 0. 3 mole fraction of A, then the mole fraction of liquid B in the vapour phase is x

17
.
The value of x is 28 Jun 2022 (M)

Q66. 2 g of a non-volatile non-electrolyte solute is disolved in 200 g of two different solvents A and B whose
ebullioscopic constants are in the ratio of 1 : 8. The elevation in boiling points of A and B are in the ratio
x

y
(x : y). The value of y is____(Nearest Integer) 27 Jun 2022 (M)

Q67. Given below are two statements : one is labelled as Assertion and the other is labelled as Reason.
Assertion: At 10 °C , the density of a 5 M solution of KCl [atomic masses of K & Cl are 39 & 35. 5 g mol
−1

respectively], is 'x' gml

−1
. The solution is cooled to −21 °C . The molality of the solution will remain
unchanged.
Reason: The molality of a solution does not change with temperature as mass remains unaffected with
temperature.
In the light of the above statements, choose the correct answer from the options given below.
27 Jun 2022 (M)

(1) Assertion is true but Reason is false.

(2) Assertion is false but Reason is true.
(3) Both Assertion and Reason are true and Reason is the correct explanation of Assertion.
(4) Both Assertion and Reason are true but Reason is not the correct explanation of Assertion.
Q68. A solution containing 2. 5 × 10 −3
kg of a solute dissolved in 75 × 10 −3
kg of water boils at 373. 535 K. The
molar mass of the solute is mol −1
⋅ [nearest integer] (Given : K b(H2O) = 0. 52 K kg mol
−1
and boiling point
of water = 373. 15 K) 27 Jun 2022 (E)

Q69. The osmotic pressure exerted by a solution prepared by dissolving 2. 0 g of protein of molar mass
60 kg mol
−1
in 200 mL of water at 27 °C is____Pa. [integer value] (use R = 0. 083 L bar mol −1
K
−1
)
26 Jun 2022 (E)

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Q70. A 0. 5 percent solution of potassium chloride was found to freeze at −0. 24 °C. The percentage dissociation of
potassium chloride is (Nearest integer) (Molal depression constant for water is 1. 80 K kg mol
−1
and molar
mass of KCl is 74. 6 g mol
−1
) 26 Jun 2022 (M)

Q71. Solute A associates in water. When 0. 7 g of solute A is dissolved in 42. 0 g of water, it depresses the freezing
point by 0. 2 °C. The percentage association of solute A in water, is
[Given: Molar mass of A = 93 g mol
−1
. Molal depression constant of water is 1. 86 K kg mol
−1
]
25 Jun 2022 (E)
(1) 50% (2) 60%
(3) 70% (4) 80%

Q72. The osmotic pressure of blood is 7. 47 bar at 300 K. To inject glucose to a patient intravenously, it has to be
isotonic with blood. The concentration of glucose solution in gL −1
is (Molar mass of glucose = 180 g mol
−1
,
R = 0. 083 Lbar
−1
mol
−1
) (Nearest integer) 24 Jun 2022 (M)

Q73. A company dissolves 'x' amount of CO2 at 298 K in 1 litre of water to prepare soda water. X = ×10
−3
g .
(nearest integer) (Given: partial pressure of CO2 at 298 K = 0. 835 bar. Henry's law constant for CO2 at
298 K = 1. 67 kbar . Atomic mass of H, C and O is 1, 12, and 6 g mol
−1
, respectively)
24 Jun 2022 (E)

Q74. If 80 g of copper sulphate CuSO4 ⋅ 5H2O is dissolved in deionised water to make 5 L of solution. The
concentration of the copper sulphate solution is x × 10
−3
mol L
−1
. The value of x is _____.
[Atomic masses Cu : 63. 54u, S : 32u, O : 16u, H : 1u]

01 Sep 2021 (E)

Q75. The molarity of the solution prepared by dissolving 6. 3 g of oxalic acid (H 2C2O4 ⋅ 2H2O) in 250 mL of water
in mol −1
L is x × 10 −2
. The value of x is _________ . (Nearest integer)
[Atomic mass : H : 1. 0, C : 12. 0, 0 : 16. 0 J ] 31 Aug 2021 (M)

Q76. Sodium oxide reacts with water to produce sodium hydroxide. 20. 0 g of sodium oxide is dissolved in 500 mL

of water. Neglecting the change in volume, the concentration of the resulting NaOH solution is _________
×10
−1
M. (Nearest integer)
[Atomic mass : Na = 23. 0, O = 16. 0, H = 1. 0 ] 31 Aug 2021 (E)

Q77. Which one of the following 0. 10 M aqueous solutions will exhibit the largest freezing point depression?
31 Aug 2021 (M)
(1) glycine (2) hydrazine
(3) KHSO 4 (4) glucose

Q78. 1. 22 g of an organic acid is separately dissolved in 100 g of benzene (K b = 2. 6 K kg mol

−1
) and 100 g of
acetone (K b = 1. 7 K kg mol
−1
). The acid is known to dimerize in benzene but remain as a monomer in
acetone. The boiling point of the solution in acetone increases by 0. 17°C. The increase in boiling point of
solution in benzene in ∘
C is x × 10 −2
. The value of x is (Nearest integer) [Atomic mass:
C = 12. 0, H = 1. 0, O = 16. 0 ] 31 Aug 2021 (E)

Q79. 200 mL of 0. 2 M HCl is mixed with 300 mL of 0. 1 M NaOH. The molar heat of neutralization of this
reaction is −57. 1 kJ. The increase in temperature in ∘
C of the system on mixing is x × 10 −2
. The value of x is

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(Nearest integer) [Given: Specific heat of water = 4. 18 J g

−1
K
−1
Density of water= 1. 00 g cm
−3
] (Assume
no volume change on mixing)
27 Aug 2021 (M)

Q80. 1 kg of 0. 75 molal aqueous solution of sucrose can be cooled up to −4°C before freezing. The amount of ice
(in g) that will be separated out is ___________. (Nearest integer) [Given : K f (H2O) = 1. 86 K kg mol
−1
]
27 Aug 2021 (M)

Q81. 40 g of glucose (Molar mass = 180) is mixed with 200 mL of water. The freezing point of solution is __K.
(Nearest integer) [Given: K f = 1. 86 K kg mol
−1
; Density of water = 1. 00 g cm
−3
; Freezing point of water
= 273. 15 K] 27 Aug 2021 (E)

Q82. Of the following four aqueous solutions, the total number of those solutions whose freezing point is lower than
that of 0. 10 MC 2 H5 OH is (Integer answer)
(i) 0. 10M Ba3 (PO4)
2
(ii) 0. 10M Na2 SO4 (iii) 0. 10M KCl (iv) 0. 10M Li3 PO4 26 Aug 2021 (M)

Q83. 83 g of ethylene glycol dissolved in 625 g of water. The freezing point of the solution is ..... K. (Nearest
integer) [Use : Molal Freezing point depression constant of water = 1. 86 K kg mol
−1
, Freezing point of
water = 273 K, Atomic masses : C : 12. 0u, O : 16. 0u, H : 1. 0u] 26 Aug 2021 (E)

Q84. 1. 46 g of a biopolymer dissolved in a 100 mL water at 300 K exerted an osmotic pressure of 2. 42 × 10 −3

bar .
The molar mass of the biopolymer is − × 10 4
g mol
−1
. (Round off to the Nearest Integer)
[Use: R = 0. 083 L bar mol −1 −1
K ]

27 Jul 2021 (M)

Q85. In a solvent 50% of an acid HA dimerizes and the rest dissociates. The van't Hoff factor of the acid is _____
×10
−2
(Round off to the nearest integer) 27 Jul 2021 (E)

Q86. When 3. 00 g of a substance X' is dissolved in 100 g of CCl , it raises the boiling point by 0. 60 K. The molar
4

mass of the substance 'X is ___ g mol . (Nearest integer). [Given K for CCl is 5. 0 K
′ −1
b 4 kg mol
−1
]

25 Jul 2021 (E)

Q87. CO gas is bubbled through water during a soft drink manufacturing process at
2
298 K . If CO2 exerts a partial
pressure of 0. 835 bar then x m mol of CO2 would dissolve in 0. 9 L of water. The value of x is _______.
(Nearest integer)
(Henry's law constant for CO at 298 K is 1. 67 × 10
2
3
bar )
25 Jul 2021 (M)

Q88. If the concentration of glucose (C H12O6)

6
in blood is 0. 72 gL −1
, the molarity of glucose in blood is
− × 10
−3
M (Nearest integer) [Given : Atomic mass of C = 12, H = 1, O = 16 u] 22 Jul 2021 (M)

Q89. Which one of the following 0. 06 M aqueous solutions has lowest freezing point ? 22 Jul 2021 (M)
(1) Al 2
(SO4)
3
(2) C 6
H12O6

(3) KI (4) K 2
SO4

Q90. At 20°C, the vapour pressure of benzene is 70 torr and that of methyl benzene is 20 torr. The mole fraction of
benzene in the vapour phase at 20°C above an equimolar mixture of benzene and methyl benzene is
__ × 10
−2
. (Nearest integer) 20 Jul 2021 (M)

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Q91. The vapour pressures of A and B at 25°C are 90 mmHg and 15 mm Hg respectively. If A and B are mixed
such that the mole fraction of A in the mixture is 0. 6, then the mole fraction of B in the vapour phase is
x × 10
−1
. The value of x is (Nearest integer) 20 Jul 2021 (E)

Q92. 2 molal solution of a weak acid HA has a freezing point of 3. 885°C. The degree of dissociation of this acid
is ______×10 −3
. (Round off to the Nearest Integer). [Given : Molal depression constant of water
= 1. 85 K kg mol
−1
Freezing point of pure water= 0°C] 18 Mar 2021 (M)

Q93. A solute A dimerizes in water. The boiling point of a 2 molal solution of A is 100. 52 C
∘
. The percentage
association of A is ___. (Round off to the Nearest integer) Use : Kb for water = 0. 52 K kg mol
−1
. Boiling
point of water = 100°C
18 Mar 2021 (E)

Q94. The oxygen dissolved in water exerts a partial pressure of 20 kPa in the vapour above water. The molar
solubility of oxygen in water is ______ ×10
−5
mol dm
−3
. (Round off to the Nearest Integer). [Given :
Henry's law constant = K H = 8. 0 × 10
4
kPa for O . Density of water with dissolved oxygen= 1. 0
2 kg dm
−3

]
17 Mar 2021 (M)

Q95. A 1 molal K 4 Fe(CN)6 solution has a degree of dissociation of 0. 4 . Its boiling point is equal to that of another
solution which contains 18. 1 weight percent of a non electrolytic solute A. The molar mass of A is _____ u.
(Round off to the Nearest Integer). [Density of water = 1. 0 g cm
−3
] 17 Mar 2021 (E)

Q96. At 363 K, the vapour pressure of A is 21 kPa and that of B is 18 kPa. One mole of A and 2 moles of B are
mixed. Assuming that this solution is ideal, the vapour pressure of the mixture is___________ kPa. (Round of
to the Nearest Integer). 16 Mar 2021 (E)

Q97. AB is 10% dissociated in water to A

2
2+
and B . The boiling point of 10. 0 molal aqueous solution of AB is--
−
2

∘
C. (Round off to the Nearest Integer). [Given : Molal elevation constant of water Kb = 0. 5 K kg mol
−1

boiling point of pure water= 100°C]

16 Mar 2021 (M)

Q98. When 12. 2 g of benzoic acid is dissolved in 100 g of water, the freezing point of solution was found to be
−0. 93 °C(Kf (H2O) = 1. 86 K kg mol
−1
) . The number (n) of benzoic acid molecules associated (assuming
100% association) is _____. 26 Feb 2021 (E)

Q99. 224 mL of SO 2(g)

at 298 K and 1 atm is passed through 100 mL of 0. 1 M NaOH solution. The non-volatile
solute produced is dissolved in 36 g of water. The lowering of vapour pressure of solution (assuming the
solution is dilute) (P° (H2O)= 24 mm of Hg) is x × 10 −2
mm of Hg the value of x is (Integer answer)
26 Feb 2021 (M)

Q100. 1 molal aqueous solution of an electrolyte A 2 B3 is 60% ionised. The boiling point of the solution at 1 atm is
_____ K. (Rounded-off to the nearest integer) [Given K for (H b 2O) = 0. 52 K kg mol
−1
] 25 Feb 2021 (M)

Q101. If a compound AB dissociates to the extent of 75% in an aqueous solution, the molality of the solution which
shows a 2. 5 K rise in the boiling point of the solution is ___ molal. (Rounded-off to the nearest integer)
[Kb = 0. 52K kg mol
−1
] . 25 Feb 2021 (E)

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Q102. C 6H6 freezes at 5. 5°C. The temperature at which a solution of 10 g of C 4H10 in 200 g of C 6H6 freeze is
_______ ∘
C. (nearest integer value), (The molal freezing point depression constant of C 6H6 is 5. 12°C/m.)
24 Feb 2021 (E)

Q103. When 9. 45 g of ClCH2 COOH is added to 500 mL of water, its freezing point drops by 0. 5°C. The
dissociation constant of ClCH2 COOH is x × 10
−3
. The value of x is off to the nearest integer)
−1
[Kf (H = 1. 86 K kg mol ]
2O)

24 Feb 2021 (M)

Q104. The elevation of boiling point of 0. 10m aqueous CrCl 3. xNH3 solution is two times that of 0. 05 m aqueous
CaCl2 solution. The value of x is … … … … . .
[Assume 100% ionisation of the complex and CaCl , coordination number of Cr as 6, and that all NH
2 3

molecules are present inside the coordination sphere] 06 Sep 2020 (M)

Q105. A set of solutions is prepared using 180 g of water as a solvent and 10 g of different non-volatile solutes A, B

and C. The relative lowering of vapour pressure in the presence of these solutes are in the order [Given,
molar mass of A = 100 g mol
−1
; B = 200 g mol
−1
; C = 10, 000 g mol
−1
] 06 Sep 2020 (E)
(1) B > C > A (2) C > B > A
(3) A > B > C (4) A > C > B

Q106. The osmotic pressure of a solution of NaCl is 0. 10 atm and that of a glucose solution is 0. 20 atm. The
osmotic pressure of a solution formed by mixing 1 L of the sodium chloride solution with 2 L of the glucose
solution is x × 10 −3
atm. x is ________ (nearest integer) 04 Sep 2020 (E)

Q107. At 300 K, the vapour pressure of a solution containing 1 mole of n -hexane and 3 moles of n -heptane is
550 mm of Hg. At the same temperature, if one more mole of n -heptane is added to this solution, the vapour
pressure of the solution increases by 10 mm of Hg. What is the vapour pressure in mmHg of n - heptane in
its pure state______? 04 Sep 2020 (M)

Q108. If 250 cm of an aqueous solution containing 0. 73g of a protein A is isotonic with one litre of another aqueous
3

solution containing 1. 65g of a protein B, at 298K, the ratio of the molecular masses of A and B is
___________ ×10
−2
(to the nearest integer). 03 Sep 2020 (E)

Q109. Henry's constant (in kbar) for four gases α, β, γ and δ in water at 298 K is given below :
α β γ δ
−5
KH 50 2 2 × 10 0. 5

(density of water = 10 3
k gm
−3
at 298 K ) This table implies that :
03 Sep 2020 (M)
(1) α has the highest solubility in water at a given pressure
(2) solubility of γ at 308K is lower than at 298K
(3) The pressure of a 55. 5 molal solution of δ is 250 bar
(4) The pressure of 55. 5 molal solution of γ is 1 bar .

Q110. The size of a raw mango shrinks to a much smaller size when kept in a concentrated salt solution. Which one
of the following process can explain this? 02 Sep 2020 (E)

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(1) Osmosis (2) Dialysis

(3) Diffusion (4) Reverse osmosis

Q111. How much amount of NaCl should be added to 600 g of water (ρ = 1.00g/mL) to decrease the freezing point
of water to −0.2 o
? ________. (The freezing point depression constant for water = 2 K kgmol
C
−1
)
09 Jan 2020 (M)

Q112. A cylinder containing an ideal gas ( 0.1mol of 1.0dm

3
) is in thermal equilibrium with a
large volume of 0.5 molal aqueous solution of ethylene glycol at its freezing point. If the
stoppers S and S (as shown in the figure) are suddenly withdrawn, the volume of the gas
1 2

in litres after equilibrium is achieved will be ____. (Given,

−1 3 −1 −1
Kf (water) = 2.0Kkgmol , R = 0.08dm atmK mol )

09 Jan 2020 (E)

Q113. Ferrous sulphate heptahydrate is used to fortify foods with iron. The amount (in grams) of the salt required to
achieve 10ppm of iron in 100kg of wheat is ____________.
Atomic weight: Fe = 55.85; S = 32.00; O = 16.00 08 Jan 2020 (M)

Q114. A graph of vapour pressure and temperature for three different liquids X, Y and Z is
shown below:
The following inferences are made:
(A)X has higher intermolecular interactions compared to Y.
(B)X has lower intermolecular interactions compared to Y.
(C)Z has lower intermolecular interactions compared to Y.
The correct inferences is/are:
08 Jan 2020 (M)
(1) (A) and (C) (2) (A)
(3) (B) (4) (C)

Q115. At 35 o
C, the vapour pressure of CS , is 512mm Hg and that of acetone is 144 mmHg. A solution of CS in
2 2

acetone has a total vapour pressure of 600 mmHg . The false statement amongst the following is:
07 Jan 2020 (M)
(1) Raoult's law is not obeyed by this system
(2) a mixture of 100mLCS and 100mL acetone has a volume < 200mL
2

(3) CS and acetone are less attracted to each other than to themselves
2

(4) heat must be absorbed in order to produce the solution at 35 o

C

Q116. Two open beakers one containing a solvent and the other containing a mixture of that solvent with a non
volatile solute are together sealed in a container. Over time: 07 Jan 2020 (E)
(1) the volume of the solution increases and the volume of the solvent decreases
(2) the volume of the solution decreases and the volume of the solvent increases
(3) the volume of the solution and the solvent does not change the volume of the solution does not
(4) change and the volume of the solvent decreases

Q117. The mole fraction of a solvent in aqueous solution of a solute is 0.8. The molality (in mol kg −1
) of the
aqueous solution is: 12 Apr 2019 (M)

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(1) 13.88 × 10 −3
(2) 13.88 × 10 −1

(3) 13.88 (4) 13.88 × 10 −2

Q118. A solution is prepared by dissolving 0.6 g of urea (molar mass = 60 g mol ) and 1.8 g of glucose (molar −1

mass = 180 g mol ) in 100 mL of water at 27

−1 o
C. The osmotic pressure of the solution is:
(R = 0.08206 Latm K −1
mol )
−1
12 Apr 2019 (E)
(1) 8.2 atm (2) 2.46 atm
(3) 4.92 atm (4) 1.64 atm

Q119. At room temperature, a dilute solution of urea is prepared by dissolving 0.60 g of urea in 360 g of water. If
the vapour pressure of pure water at this temperature is 35 mm Hg, lowering of vapour pressure will be:
(molar mass of urea = 60 g mol ) −1
10 Apr 2019 (M)
(1) 0.028 mm Hg (2) 0.027 mm Hg
(3) 0.031 mm Hg (4) 0.017 mm Hg

Q120. 1 g of a non-volatile non-electrolyte solute is dissolved in 100 g of two different solvents A and B whose
ebullioscopic constants are in the ratio of 1 : 5. The ratio of the elevation in their boiling points, , is:
ΔTb(A)

ΔTb(B)

(assuming they have the same molar mass) 10 Apr 2019 (E)
(1) 10 : 1 (2) 1 : 5
(3) 1 : 0.2 (4) 5 : 1

Q121. The osmotic pressure of a dilute solution of an ionic compound XY in water is four times that of a solution
0.01 M BaCl2 in water. Assuming complete dissociation of the given ionic compounds in water, the
concentration of XY ( in mol L −1
) in solution is 09 Apr 2019 (M)
(1) 4 × 10 −2
(2) 16 × 10 −4

(3) 4 × 10 −4
(4) 6 × 10 −2

Q122. Molal depression constant for a solvent is 4.0 K kg mol −1

. The depression in the freezing point of the solvent
for 0.03 mol kg −1
solution of K 2SO4 is:
(Assume complete dissociation of the electrolyte) 09 Apr 2019 (E)
(1) 0.36 K (2) 0.24 K
(3) 0.18 K (4) 0.12 K

Q123. Liquid M and liquid N form an ideal solution. The vapour pressures of pure liquids M and N are 450 and
700 mmHg, respectively, at the same temperature. Then correct statements is:
(x M = Mole f raction of 'M in solution;
' '
xN = Mole f raction of 'N in solution;

'
yM = Mole f raction of 'M in vapour phase;
'
yN = Mole f raction of 'N in vapour phase; )
09 Apr 2019 (M)
(1) (2)
xM yM xM yM
> =
xN yN xN yN

(3) (4) (x
xM yM
< M − yM) < (xN − yN)
xN yN

Q124. The vapour pressures of pure liquids A and Bare 400 and 600 mm Hg respectively at 298 K. On mixing the
two liquids, the sum of their volumes is equal to the volume of the final mixture. The mole fraction of liquid
B is 0.5 in the mixture. The vapour pressure of the final solution, the mole fractions of components A and B
in the vapour phase, respectively are 08 Apr 2019 (M)

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(1) 500 mm Hg, 0.5, 0.5 (2) 450 mm Hg, 0.4, 0.6

(3) 450 mm Hg, 0.5, 0.5 (4) 500 mm Hg, 0.4, 0.6

Q125. For the solution of the gases w, x, y and z in water at 298 K, the Henry's law constants (K H) are 0.5, 2, 35

and 40 kbar, respectively. The correct plot for the given data is: 08 Apr 2019 (E)
(1) (2)

(3) (4)

Q126. The freezing point of a 4% aqueous solution of X is equal to the freezing point of a 12% aqueous solution of
Y . If the molecular weight of X is A, then the molecular weight of Y will be 12 Jan 2019 (M)
(1) 2A (2) A
(3) 4A (4) 3A

Q127. Molecules of benzoic acid (C 6H5 COOH) dimerise in 30 g of benzene. ' w ' g of benzoic acid shows a
depression in freezing point equal to 2 K. If the percentage association of the acid to form dimer in the
solution is 80, then w is: ( Given that K f = 5 Kmol
−1
, molar mass of benzoic acid = 122 gmol
−1
)

12 Jan 2019 (E)

(1) 1.0g (2) 2.4g
(3) 1.8g (4) 1.5g

Q128. The freezing point of a diluted milk sample is found to be −0.2 ∘

C, while it should have been −0.5 ∘
C for pure
milk. How much water has been added to pure milk to make the diluted sample? 11 Jan 2019 (M)
(1) 1 cup of water to 2 cups of pure milk (2) 3 cups of water to 2 cups of pure milk
(3) 1 cup of water to 3 cups of pure milk (4) 2 cups of water to 3 cups of pure milk

Q129. K 2HgI4 is 40% ionised in aqueous solution. The value of its van't Hoff factor (i) is: 11 Jan 2019 (E)
(1) 1.6 (2) 1.8
(3) 20 (4) 22

Q130. The amount of sugar (C 12H22O11) required to prepare 2L of its 0 .1 M aqueous solution is: 10 Jan 2019 (E)
(1) 17 .1 g (2) 136 .8 g

(3) 68 .4 g (4) 34 .2 g

Q131. Liquids A and B form an ideal solution in the entire composition range. At 350K, the vapour pressure of pure
A and pure B are 7 × 10 3
Pa and 12 × 10 3
Pa , respectively. The composition of the vapour in equilibrium
with a solution containing 40 mole percent of A at this temperature is: 10 Jan 2019 (M)
(1) x A = 0.4; xB = 0.6 (2) x A = 0.76; xB = 0.24

(3) x A = 0.28; xB = 0.72 (4) x A = 0.37; xB = 0.63

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Q132. The elevation in boiling point for 1 molal solution of glucose is 2 K. The depression in freezing point for 2
molal solution of glucose in the same solvent is 2 K. The relation between K and K is: b f 10 Jan 2019 (E)
(1) Kb = 2 Kf (2) K b = 1 .5 Kf

(3) Kb = Kf (4) K b = 0 .5 Kf

Q133. A solution of sodium sulphate contains 92 g of Na ions per kilogram of water. The molality of Na ions in
+ +

that solution in mol −1

kg is: 09 Jan 2019 (M)
(1) 16 (2) 4
(3) 12 (4) 8

Q134. Which one of the following statements regarding Henry's law is not correct? 09 Jan 2019 (M)
(1) Different gases have different K (Henry's law constant) values at the same temperature
H

(2) The partial pressure of the gas in vapour phase is proportional to the mole fraction of the gas in the
solution
(3) Higher the value of K at a given pressure, higher is the solubility of the gas in the liquids
H

(4) The value of K increases with increase of temperature and K is function of the nature of the gas
H H

Q135. A solution containing 62 g ethylene glycol in 250 g water is cooled to −10 o

C . If K for water is
f

1.86 K kg mol
−1
, the amount of water (in g ) separated as ice is: 09 Jan 2019 (E)
(1) 48 (2) 64
(3) 16 (4) 32

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ANSWER KEYS
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9. (19) 10. (4) 11. (707) 12. (31) 13. (1) 14. (15) 15. (4) 16. (2)
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121. (4) 122. (1) 123. (1) 124. (4) 125. (1) 126. (4) 127. (2) 128. (2)
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