sn-1

S
Unique Paper Code
217161 22
Name of the Course
[Link](Prog)
Name of the Paper
CHPT-101: Chemistry-I
SemesterT I

Time: 3hrs
Maximum Marks : 75
Instructions for Candidates
1. Write your Roll No. the top immediately on
on
receipt of this question paper.
2 Attempt any three questions from Section-A and
Section-B respectively

Section-A
1. (a) write all the possible orbitals when n=4. Determine maximum number of
electrons which can exist in a completely filled orbital
with, n=4.
(b) Give four possible quantum numbers for a 5f electron of an atom.
(c) Define concept of exchange energy
d) Draw the shapes of 2s , 2p and 3z orbitals
(e) states all the possible values for the quantum numbers n, l and m

(3,3,2, 1 %,3)

2. (a) Give the salient features of molecular orbital theory

(b) PCl5 has trigonal bipyramid shape while IFs has distorted square pyramid. Explain
(C) Bond angle of OF2 is less than that of OCl2
(d) Draw the molecular orbital energy level diagram for N2 , discuss its bond order
and magnetic behaviour. Why is the bond order in Na less then that
in N2
molecule.
(e) Predict which of the following ions is planar,
CIo, Cio, NO (3,3,1 %, 3, 2)
3. (a) ZnClh is soluble in organic solvents while MgCl2 is insoluble
(b) Melting points of NaCl is much higher than that of AIC3
(e) Bea molecules doesn't exist, explain on the basis of molecular orbital theory
(d) Which is more polar and why, CO2 or NO2
e) Gives postulates of VSEPR theory. (3,3,1 , 3 ,2)
4. Write short note
on the folloWing:
(a) Bonding and anti bonding orbitals
(b) Fazan's rule
c) Polarization power
 (d) Quantum number
(e) Dual nature of electron
(3,3,1 %,3, 2)

Section-BB
1. Attempt any five of the following:
(2% x5=12%)
(a) Giving reasons arrange the
following carbocations in increasing order of stability:
(CH)C", CH,CH2, (CH,)>CH', CH*
(b) Classify the following as electrophiles and
nucleophiles:
Br, H0, NH2, NO2, NHA
(c) Benzyl radical is more stable than
allyl radical. Explain
(d) Phenol is more acidic than alcohols but less acidic
than carboxylic acids.
(e) Why alkynes are less reactive than alkenes towards
Explain
electrophilic addition
reactions?
(What is Saytzeff's rule? Explain, giving suitable examples

2. (a) Write structure of 2-bromo-3-chlorobutane and indicate the

number of
stereoisomerspossible for this compound 2
(b) Out of ethylamine and aniline, which one is more basic and
why? 3
(c) The peroxide effect (or Kharasch effect) in alkene is observed only in the addition
o f HBr and not HCl
and HI. Expalin. 3
(d) What is aromaticity? Giving suitable reason explain which of the following
compound is/are aromatic
42
H,

3 (a) Arrange
explanation
the
AOO)
following in increasing
(11)
order of acidic
(iii)
strength with suiatable

2
CICHCOOH, HCOOH, CH,CoOH, CLCHCOOH
( Draw the Newman projection for different conformations possible for

butane. Discuss their stability 3

C) Assign R and S configuration of the folowing 3
 CHO
NH2
HO -SH
CH OH
H CH
(a) (b)

(d) Assign E/Z configuration of the following 42

CH CHCHF HC CHO CI

=N
H
F CHOCH3 OH CH3
(a) b) (c)

4. (a) How will you differentiate between 'eonfiguration' and the 'conformation' 2
(b) Giving mechanism involved write the structure of alcohol formed from CH,CH=CH2,
underfoBlowing conditions: 42
i Hydroboration- Oxidation
11. Oxymercuration- demercuration
ii. Acid eatalysed hydration

(c) Draw all posible conformations of cyclohexane. Which amongst these is most
stable? Give reason for your answer 3

(d) Methane and chlorine react in the presence of light to give chloromethane. Give
mechanism for this reaction 3
 [This question paper contains printed pages]
Your Roll No....o **

Sr. No. of Question Paper (23)

Unique Paper Code :235166
Name of the Paper :MAPT-101 Calculus and Matrices
Name of the Course [Link] (Mathematical Sciences-1
6Seg)I
B-Se-(Physieal-Seieces)-I
Semester :

Maximum Marks: 75
Duration:3 HourTS

Instructions for Candidates

********** ****

1. Write your Roll No. on the top immediately on receipt ofthis question paper
2. Attempt any two questions from each section.

SECTION-I

(a) Let S ={(1,3).(1.-1)}. Show that

(1) S spans R*
(ii) S is linearly independent .
6)
(b) Show that
(i) Wi= {(a, b, 1) :a, be R} is not a subspace ofR°
(i) W2={(a, b): a, b20:a, be R} is a subspace of R (6)

Ta) Find rank of the matrix by reducing

it to triangular form using Elementary
o 12 11
Row Operations |1 2 3 4 (6)
3 11 3
Let T: R R be a Linear Transformation such that T (1.0,1) = (2.-1).
(b) T (0,1,1) =(1,1), T (1,I,0) = (-1,4). Find T (1, 2. 3) and T (1.1.1)
(6)
(a) Using Elementary Row Operations, solve the following system of equations
x+2y+3z=14
3x +y+ 2z =11
2x3y +z =|1 (6)
 (b) Find the eigen values and the
corresponding eigen vectors of the matrix
2107
0 21
o 02 (6)

SECTION II
4. (a) Discuss the convergence of the
sequences
COSH
(1)
(i) -1)> (6)

(b) If y= Show that y, = Cnlsin(n++De ******

where r=V1 +x, 0= tan(*). (6)

(c) Ify=a cos (in x)+ b sin (In x), Show that
xyn+2+(2n+1) x yn+1 + (n*+1) yn = 0 (6)

5. (a) Draw the graph ofy =;x*-3x +

2
Mention the transformations used at every step (6)
(b) f the population of a country doubles itself in 100 years, in how many years
will it become four times under the assumption that the rate of increase is
proportional to the number of inhabitants?
(6)
(c) Find the Taylor Series expansion of e* at the points x = 0 and x = a.
(6)
(a) Draw the level curves of flxy)= y +x* at heights k = 1,2,5
6. 6)
(b) Verify that 0oxOy wherez
oyêr
= (6)
I+x+y
(c) Verify that the function
z = log ( + y ) +2 tan'"(y/x) satisfy the Laplace's Equation (6)

SECTION IHI
7. (a) Find an equation of a straight line joining the points whose affixes are

1 - iand 2-5i (4)

(b) Find an equation of the circle described on the join ofthe points (1+ i)
and (2-i) as the extremities of one ofits diameters
(3
 mw

8. (a Let Zi I*1,Z2=! -V3i. Find their polar representations and interpret

Z-Z2geometrically (4)
(b) Form an equation in lowest degree with real coefficients which has 2-3i
and 3 + 2i as two of its roots.

9 (a) Solve the equation Z" + 1 = 0, where Z is a complex number

(4)
(b) Find moduius and argument of the complex number
(1+ sin o +icoso
1+sino-icoso
 18
This paper contains2 printed pages)
[Link]. of question paper 21) Your Roli No. ...

Inigue paner code: 216/223/151

Name of the Course: [Link].(P)/ [Link]. (H)

Name of the paper: Introduction to Biology LSPT-101

Semester-,
Time: 3 hours Maximum Marks: 75

Instructions for candidates:

1. Write your Roll No. on the top immediately on receipt of this question paper
2. Attempt five questions in all including Question No.1 which is compulsory.

1 (i) Define (any 5) 1X5=5 marks

a) Phylogeny
b) Codon
cAtherosclerosis
d) Derived lipids
e) Saponification number
f) Central dogma

(i) Give one word answer for the following 1X5 5 marks

a) Sugar present in milk.

b) Disease caused due to deposition of fat in blood vessels.
c)Bond between nucleotides in DNA.

d) Molecules that are 'mirror images of each other.

e Tentative answer to a well-framed question.

(ii) Match the following 1X5-5marks

Nucledtide Protein degradation

Sanger Heredity
Collagen DNA

Gene Energy
ATP Connective tissue
2 Differentiate between (any 5) 3X5-15 marks
i Fibrous and globular proteins
i. Saturated and Unsaturated fatty acids
ii. Replication and Transcription
iv. Starch and cellulose
V.
Primary and secondary structure of proteins
vi. Macronutrients and Micronutrients

3. Write short notes on (any5) 3X5-15 marks

a. Phospholipids
b. Speciation
C. Enantiomers
d. Mass extinction
e. Ecosystem
f. Fossils

4. (a) Briefly describe the key features of the Darwin's theory of Natural selection.
8marks
(b) Describe the role of mass extinction and adaptive radiation in
changing life on earth.7marks
5(a) VWhat are model organ+sms Brieflyexplain any two model organisms
widely used in
biological research.(8marks
ww.wwiwwwwi4AmKnwawMVAW **** * ***********www v wwwwwvn
wwwwwv v
**
******
wawow wwwvmawpwwwwwwwwwmawww******
w

(b) Discuss the main features of the domain Archaea.7marks

[Link]

6. (al Mention different types of carbohydrates Witn suitable examples and the
functian oe
of c-

10marks
(b) What is the importance of weak bondsin biological macromolecules?5marke
ww. wwww.w

7. (a) Discuss the key events involved in the conversion of glucose to pyruvatein ohse
pathway. Also mention the enzymes involved at each step.(10marks ****wwwwwa *waimmin

(b) Drawa well labeled diagram ofa typical eukaryotic cell/5marks **** ********** *
 Si. No of Question Paper

Unique Paper Code

5To 25
222-1 6)/ 2221163
Name of the Paper
PhsiesI (eeheics)
Name of the Course
[Link] P
Semester
I
Unique Paper Code: 222161
Duration: 3hrs Maximum Marks: 75
Attempt any ive questions n all. Question number one is Compuisory.
.

AtteMpt any rour Questions from rest of the paper

Q1 Attenpt any ve questions y
. .

The velocity ofais 6iSt4kin rame of reference S moving with velocity 0.8 c along the
..
a

xaxis relative 1o a referenceframe S at rest. What is the velacity of particle in lattertrame?

.

b State Keplers
law
.'
:

Aparticle
executes Simpleharmonicmotionof period 10 sec and anmpitu [Link]
. .

themaximum amplitude ofvelocity.

*

***

dtateihe law o gravitattonai attraction and her detine the graVitational constant G. Aiso

wrte its dimensionsr : i .

eDefinoPoissons ratio Also explain the term Resilience

Sof nmotion how ihat NewlonS Irst iaornmonon is a spectal caseof

What do you utiderstand by inertialand erevitational mass? .

.'
h The lengh of rockership is 100monthe ground when itisin flight its 1ength obseved ar
the grouind is:99 metres Calculate th
;
,
5315)
02 aDefine inertial frame of reference: Showthat all other frames ofreference with
constant
velocity relative tó it are also inertial frames of reference. What are
characteristic
properties and imporíance ofsuch frames

:
b) If centre of mass of three particles
of masses 1, 2 and 3 kg be at the point 3,3,3, Where
should
the fourth mass of 4kg be placed so that the centre of mass of four particles be at the point
1,1,1?

Q3 a) At what velocity will a 10,000 kg tuck have i) same momentumn, ii) the same kinetic

energy as a4,0000 kg car at 30 m/sec ?

b) Define Angular momentum. State and prova law of cORServation of Angular Momentim.

Show that the time rate of changeof aigular motmentum ot a particle is equal to torque

acting onhit 9

c) Show that the torce I yz i t zx

j +ay k is a conservative forece.
Q4 a) What anc central forcey? Show tat angular monientum of particle meving under the
influenee of central forces is always conserved Als show that Areal velocity of radius

vector ronains constant under the intluence of centralforce

b) Why are gravitational and coulombs forces called central forces.

o) Find the masss of suin drom the following data radius of carth orbitis r 5x10°km and
6.66 10 Nu kg
OSa) Dcline Simple Harmonio Motion. What are unportant properties of Simple Harnonic
Oscillato. Why is S.H.M considered to be a fundamental penodic motion? Showthat tinine
N N

Sun
period ofa [Link] is given by
T2 Displaccent sAccoleration
.

b Show iwith the help of a diagram the phase relationi betiveen displacement, velocity a

eeleratian for given displacetnenty Asin (wt + o)

i t is the ratio of Kinetic'energy at displacement one fourth to one third of amplitude

in case ot siunple harmonic motion.

 poStullates of relativity
6 a) St:ile basic

h Show by means of Lorentz transformations equations that

x 2
x *2Ct=

c)Explain in detaii the concept of twin paradox.

7 a) Prove the relation Y= 2n (1.+o); where Y is Youngs modulus, n is modulus of rigidity

and o is poisons ratio.
6
b) Show that in any type of strain the work done per unit volume is equal to
stress x strain6
c) A wire Sni long and 0.3mm in diametér is stretched by a force 800 gm
r
weight. Calculate the
energy storedin it