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JEE Advanced Model A Syllabus & Exam Details

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0% found this document useful (0 votes)
13 views23 pages

JEE Advanced Model A Syllabus & Exam Details

Uploaded by

hydjbhc720a
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

SEC: ISR_*CO-SC(MODEL-A) Date: 23-04-23

Time: 3 Hrs Max. Marks: 180


23-04-23_ISR.IIT_STAR CO-SC(MODEL-A) _JEE ADV_CAT-15_SYLLABUS
PHYSICS: (100% CUMULATIVE)

SYLLABUS COVERED FROM 06-06-22 TO 25-04-23

CHEMISTRY: (100% CUMULATIVE)

SYLLABUS COVERED FROM 06-06-22 TO 25-04-23

MATHEMATICS: (100% CUMULATIVE)

SYLLABUS COVERED FROM 06-06-22 TO 25-04-23


Narayana IIT Academy 23-04-23_ISR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-15_Q’P
TIME: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 180

PHYSICS
+Ve - Ve [Link] Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct Choice
Sec – I (Q.N : 1 – 6) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Comprehension Type With
Sec – II (Q.N : 7 – 12) Numerical value type +2 0 6 12
(3 Comprehensions – 2 + 2 + 2 = 6Q)
Questions with Comprehension Type
Sec – III (Q.N : 13 – 16) +3 –1 4 12
(2 Comprehensions – 2 + 2 = 4Q)
Sec – IV (Q.N : 17 – 19) Questions with Non-Negative Integer type +4 0 3 12
Total 19 60

CHEMISTRY
+Ve - Ve [Link] Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct Choice
Sec – I (Q.N : 20 – 25) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Comprehension Type With
Sec – II (Q.N : 26 – 31) Numerical value type +2 0 6 12
(3 Comprehensions – 2 + 2 + 2 = 6Q)
Questions with Comprehension Type
Sec – III (Q.N : 32 – 35) +3 –1 4 12
(2 Comprehensions – 2 + 2 = 4Q)
Sec – IV (Q.N : 36 – 38) Questions with Non-Negative Integer type +4 0 3 12
Total 19 60
MATHS
+Ve - Ve [Link] Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct Choice
Sec – I (Q.N : 39 – 44) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Comprehension Type With
Sec – II (Q.N : 45 – 50) Numerical value type +2 0 6 12
(3 Comprehensions – 2 + 2 + 2 = 6Q)
Questions with Comprehension Type
Sec – III (Q.N : 51 – 54) +3 –1 4 12
(2 Comprehensions – 2 + 2 = 4Q)
Sec – IV (Q.N : 55 – 57) Questions with Non-Negative Integer type +4 0 3 12
Total 19 60

ISR.IIT_*CO SC Page No: 2


Narayana IIT Academy 23-04-23_ISR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-15_Q’P
PHYSICS [Link]: 60
SECTION - 1 (Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
1. A horizontal force F is applied at the center of mass of a cylindrical object of mass ‘m’
and radius R, perpendicular to its axis as shown in the figure. The coefficient of friction
between the object and the ground is  . The center of mass of the object has an
acceleration a . The acceleration due to gravity is g. Given that the object rolls without
slipping, which

A) For the same F, the value of a does not depend on whether the cylinder is solid or
hollow

B) For a solid cylinder, the maximum possible value of a is 2  g

C) The magnitude of the frictional force on the object due to the ground is always mg

F
D) For a thin-walled hollow cylinder, a 
2m

ISR.IIT_*CO SC Page No: 3


Narayana IIT Academy 23-04-23_ISR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-15_Q’P
02. A cylindrical tube, with its base as shown in the figure, is filled with water. It is
moving down with constant acceleration a along a fixed inclined plane with an angle =
45º. P1 and P2 are pressures at points 1 and 2, respectively, located at the base of the
tube. Let    P1  P2  /  gd  , where  is density of water, d is the inner diameter of the

tube and g is the acceleration due to gravity. Which of the following statement(s) is
(are) correct?

A)   0 when a  g / 2 B)   0 when a  g / 2

2 1 1
C)   when a  g / 2 D)   when a  g / 2
2 2

03. A uniform capillary tube of inner radius ‘r’ is dipped vertically into a beaker filled with
water.. The water rises to a height ‘h’ in the capillary tube above the water surface in
the beaker. The surface tension of water is  . The angle of contact between water and
the wall of the capillary tube is  . Ignore the mass of water in the meniscus. Which of
the following statements is (are) true?

A) For a given material of the capillary tube, h decreases with increase in r

B) For a given material of the capillary tube, h is independent of 

C) If the experiment is performed in a lift going up with a constant acceleration, then h


decreases

D) h is proportional to contact angle 

ISR.IIT_*CO SC Page No: 4


Narayana IIT Academy 23-04-23_ISR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-15_Q’P
04. A student is performing an experiment using a resonance column and a tuning fork of
frequency 244s 1 . He is told that the air in the tube has been replaced by another gas
(assume that the column remains filled with the gas). If the minimum height at which
resonance occurs is  0.350  0.005 m , the gas in the tube is (Useful information

167RT  640J1/2 mole 1/2 ; 140RT  590 J1/2 mol1/2 . The molar mass M grams are

10
given in the options. Take the value of for each gas as given there).
M

 10 7   10 3 
A) Neon  M  20,   B) Nitrogen  M  28,  
 20 10   28 5

 10 9   10 17 
C) Oxygen  M  32,   D) Argon  M  36,  
 32 16   36 32 

05. One end of a taut string of length 3m along the x axis is fixed at x = 0. The speed of the
waves in the string is 100 ms 1 . The other end of the string is vibrating in the y
direction so that stationary waves are set up in the string. The possible waveform(s) of
these stationary waves is (are)

x 50t x 100t
A) y  t   Asin cos B) y  t   Asin cos
6 3 3 3

5x 250 t 5x


C) y  t   Asin cos D) y  t   Asin cos 250t
6 3 2

06. Consider a Vernier callipers in which each 1 cm on the main scale is divided into 8
equal divisions and a screw gauge with 100 divisions on its circular scale. In the
Vernier callipers, 5 divisions of the Vernier scale coincide with 4 divisions on the main
scale and in the screw gauge, one complete rotation of the circular scale moves it by
two divisions on the linear scale. Then:

ISR.IIT_*CO SC Page No: 5


Narayana IIT Academy 23-04-23_ISR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-15_Q’P
A) If the pitch of the screw gauge is twice the least count of the Vernier callipers, the
least count of the screw gauge is 0.01 mm.

B) If the pitch of the screw gauge is twice the least count of the Vernier callipers, the
least count of the screw gauge is 0.005 mm.

C) If the least count of the linear scale of the screw gauge is twice the least count of the
Vernier callipers, the least count of the screw gauge is 0.01 mm.

D) If the least count of the linear scale of the screw gauge is twice the least count of the
Vernier callipers, the least count of the screw gauge is 0.005 mm

SECTION - 2 (Maximum Marks : 12)


This section contains TWO (3) Paragraphs. Based on each paragraph, there are 2 questions.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +2 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
Question Stem for Question Nos. 7 and 8:
A pendulum consists of a bob of mass m = 0.1 kg and a massless inextensible string of
length L = 1.0 m. It is suspended from a fixed point at height H = 0.9 m above a
frictionless horizontal floor. Initially, the bob of the pendulum is lying on the floor at
rest vertically below the point of suspension. A horizontal impulse P = 0.2 kg-m/s is
imparted to the bob at some instant. After the bob slides for some distance, the string
becomes taut and the bob lifts off the floor. The magnitude of the angular momentum
of the pendulum about the point of suspension just before the bob lifts off is J kg-m2/s
The kinetic energy of the pendulum just after the lift-off is K Joules

ISR.IIT_*CO SC Page No: 6


Narayana IIT Academy 23-04-23_ISR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-15_Q’P
7. The value of J is __________.

8. The value of K is __________.

Question Stem for Question Nos. 9 and 10:


A ball of mass m = 1 kg is colliding with a wedge of mass M = 0.9 kg with a velocity
of 15 m/s as shown in the figure. After striking the wedge, the ball rebounds in some
arbitrary direction and due to the impulse, the wedge recoils in backward direction with
a speed of 10 m/s. Assume all the surfaces to be smooth take   370 and g  10 m / s 2

9. The coefficient of restitution between ball and wedge is___

10. Magnitude of impulse (in N-s) on the ball would be___

Question Stem for Question Nos. 11 and 12:


A soft plastic bottle, filled with water of density 1 gm/cc, carries an inverted glass test
tube with some air (ideal gas) trapped as shown in the figure. The test tube has a mass
of 5 gm, and it is made of a thick glass of density 2.5 gm/cc. Initially, the bottle is
sealed at atmospheric pressure p0 = 105 Pa so that the volume of the trapped air is

V0 = 3.3 cc. When the bottle is squeezed from outside at a constant temperature, the
pressure inside rises and the volume of the trapped air reduces. It is found that the test
tube begins to sink at pressure p 0  p without changing its orientation. At this
pressure, the volume of the trapped air is v 0  v

Let v  Xcc and p  Y  103 Pa

ISR.IIT_*CO SC Page No: 7


Narayana IIT Academy 23-04-23_ISR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-15_Q’P

11. The value of X is_______

12. The value of Y is_______

SECTION - 3 (Maximum Marks : 12)


This section contains TWO (2) Paragraphs. Based on each paragraph, there are 2 questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
For each question, choose the option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
Negative Marks: –1 In all other cases.
Question Stem for Question Nos. 13 and 14:
A 3kg block is attached to a spring with a force constant k  900 N / m which is
compressed 2m initially from its equilibrium position. When 3kg mass is released, it
strikes the 6kg mass and they stick together in an inelastic collision.

13. The common velocity of the blocks after collision is

A) 10 m/s B) 30 m/s C) 15 m/s D) 2 m/s

ISR.IIT_*CO SC Page No: 8


Narayana IIT Academy 23-04-23_ISR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-15_Q’P
14. The amplitude of resulting oscillation after the collision is

1 1
A) m B) m C) 2m D) 3m
2 3

Question Stem for Question Nos. 15 and 16: 


A positive point charge q is fixed at origin. A dipole with a dipole moment p is placed

along the x-axis far away from the origin with p pointing along the positive x–axis.

15. Find the kinetic energy of the dipole when it reaches distance ‘d’ from the origin

3 pq 3 pq 1 pq 1 pq
A) B) C) D)
40 d 2 20 d 2 20 d 2 40 d 2

16. Find the force experienced by the dipole at this moment

1 pq 1 pq 1 pq 2 pq
A) B) C) D)
40 d3 20 d3 2 20 d 3 0 d 3

SECTION - 4 (Maximum Marks : 12)


This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE INTEGER
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
17. Heat is generated uniformly per unit volume inside a spherical volume of radius 1m at
1
rate of 20 W/m3. The thermal conductivity of the spherical volume is W / mK , the
6
outer surface temperature of the sphere is 200 C . If the temperature of the centre of the
sphere is x  10 (in degree centigrade) find x.

18. A particle is projected from point A, that is at a distance 4R from the centre of the
earth, with speed V1 in a direction making 300 with the line joining the centre of the
earth and point A, as shown in the figure. Find the speed V1 if particle passes grazing
the surface of the earth. Consider gravitational interaction only between these two.

ISR.IIT_*CO SC Page No: 9


Narayana IIT Academy 23-04-23_ISR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-15_Q’P
 GM E 
 Use   6.4  107 m 2 / S2  . Where M E is mass of the Earth. Express your
 R 
x
answer in the form of km / s and find the value of x.
2

19. A body of mas 3.14 kg is suspended from one end of a wire of length 10m. The radius
of the wire is changing uniformly from 9.8 104 m at one end of 5 104 m at the other
end. Find the change in length of the wire in mm. Young’s modulus of the material of
the wire is 2 1011 N / m2 . Schematic diagram of the suspended wire is given (mass of
wire is negligible) (take g  9.8 ms 2 )

ISR.IIT_*CO SC Page No: 10


Narayana IIT Academy 23-04-23_ISR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-15_Q’P
CHEMISTRY [Link]: 60
SECTION - 1 (Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
20. For the compounds given below

Cl Cl

Cl Cl
X Y

The correct statement(s) is (are)

A) X and Y are enantiomers. B) X and Y are diastereomers.

C) X and Y are geometrical isomers. D) X and Y are optical isomers.

X
base, 
21.
E2
 alkene.

The correct statements for the above reaction is (are)

A) When X  F and base  EtO  , saytzeff alkene is major product.

B) When X  I and base  EtO  , saytzeff alkene is major product.

C) When X  I and base  tBuO , saytzeff alkene is major product.

D) When X  F and base = MeO , hoffman alkene is major product.

ISR.IIT_*CO SC Page No: 11


Narayana IIT Academy 23-04-23_ISR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-15_Q’P
22. Which of the following compounds are more basic than

NH 2 ?

NH

A) CH 3  CH 2  NH 2 B) CH 3  C  NH 2

C) C  NH 2 D ) CH 2  CH  NH 2

23. Select correct statement(s)

A) Stability of peroxides and super oxides of alkali metals increases with increase in
size of the cation.

B) Increase in stability in (option A) is due to stabilization of large anions by larger


cations through lattice energy effects.

C) The low solubility of LiF is due to its high lattice energy whereas low solubility of
CsI is due to smaller hydration energy.

D) NaOH does not form hydrate.

24.  2 B  g  is the equilibrium at 4 atm and 270 C . If the volume of


The reaction: A  s  
system is increased at constant temperature, then at new equilibrium, relative to initial
equilibrium

A) Moles of A(s) decrease

B) Moles of B (g) increases

C) Molar concentration of A(s) decreases

D) Molar concentration of B (g) decreases

ISR.IIT_*CO SC Page No: 12


Narayana IIT Academy 23-04-23_ISR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-15_Q’P
25. In an evacuated vessel of 8.2 L capacity, 0.2 moles of A(g) is taken, vessel is sealed
and heated to 127 0 C , by which the following first order reaction occurred at constant
volume and temperature

A g   2B  g   C  s 

The vapour pressure of C(s) is 0.1 atm at 127 0 C . If the half life of reaction is 20 min,
then the correct information(s) related with reaction is/are: (R = 0.082 L-atm/K-mol)

A) Ptotal  1.7 atm at t  

B) Ptotal  0.98 atm after 10% decomposition of A(g)

C) Ptotal  0.88 atm after 5% decomposition of A(g)

D) Ptotal  1.3 atm at t = 20 min

SECTION - 2 (Maximum Marks : 12)


This section contains TWO (3) Paragraphs. Based on each paragraph, there are 2 questions.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +2 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
Question Stem for Question Nos. 26 and 27:
X  2 6
i B H / THF
CH 3  CH 2  CH 3  Y 
(alkene)

 ii  dil .HCl 

For the reaction above answer the following

26. What mass of B2 H 6 (in g) is consumed by 21g of X?

(Assume complete reaction with 100% yield and no wastage).

(Atomic mass of B = 10.8)

27. What mass of Y (in g) is obtained on complete reaction of 105 g of X?

(Assume complete reaction with 100% yield)

ISR.IIT_*CO SC Page No: 13


Narayana IIT Academy 23-04-23_ISR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-15_Q’P
Question Stem for Question Nos. 28 and 29:
The energy change when one mole of a given acid (base) is neutralized by the required
number of moles of base (acid), is called the enthalpy of neutralization of that acid
(base) by the given base (acid) under the given conditions. It is known that a strong
acid and a strong base reacts effectively as

H   aq   OH   aq   H 2O : H  57.33 kJ / mole

However for weak acids and weak bases some energy gets absorbed by the weak
electrolyte to dissociate into the ions. The energy required by one mole of
undissociated weak electrolyte for the complete ionization is called the enthalpy of
ionization of that weak electrolyte under the given conditions.

28. At 250 C , the enthalpy of ionization of a weak acid HA  K a  102  whose half litre ,7.5

mM solution when treated with the sufficient moles of a strong base, 200 J of heat is
released (ans must be in kj/mole

29. 200 ml of 0.1M NaOH solution is mixed with 200 ml of 0.025M H 2 SO4 solution.
Calculate H of mixing if acid under goes complete ionization (magnitude only, in
terms of joules)

Question Stem for Question Nos. 30 and 31:


For the following electrochemical cell at 250 C

Pt H 2 1atm  H   C1M  H   C2 M  H 2 1atm  Pt

pK a values of some weak acids are given

Acid pKa

HA 4

HB x

H2D 4  Pka1  & 6  Pka 2 

(Use 2.303RT/F value as 0.059)

ISR.IIT_*CO SC Page No: 14


Narayana IIT Academy 23-04-23_ISR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-15_Q’P

30. If H in anodic half cell arises due to titration of H 2 D with strong base NaOH up to first
equivalent point and 0.005 M H 2 SO4 is taken in cathode half-cell, and then Ecell of the
given cell is (in Mv)

31. If H  in anodic half cell is corresponding to the equivalence point in following titration
curve and H  in cathodichalf cell is due to 0.1 M HA & 0.1 M Na  A , the EMF of the
given cell is titration curve of HB(aq) with NaOH(aq (in V)

SECTION - 3 (Maximum Marks : 12)


This section contains TWO (2) Paragraphs. Based on each paragraph, there are 2 questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
For each question, choose the option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
Negative Marks: –1 In all other cases.
Question Stem for Question Nos. 32 and 33:
Carbocation is a group of atoms with positively charged carbon atom having six
electrons in the velence shell after sharing. Carbocations are formed in the heterolysis
of a bond and are planar species. Stability of carbocation is determined by inductive
effect, hyperconjugation and resonance effect. Greater the number of contributing
structures, more is the stability of a carbocation. Electron releasing groups (+1 effect)
increases the stability of a carbocation whereas the electron withdrawing groups (-1
effect) have an opposite effect

ISR.IIT_*CO SC Page No: 15


Narayana IIT Academy 23-04-23_ISR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-15_Q’P
32. The most stable and the least stable carbocation among, respectively are

I   II  CH 2  CH  C H 2

 III  C6 H 5  C H 2  IV  CH 3  C H  CF3
A) II, I B) III, IV C) I, II D) I, IV

33. Most stable carbocation is formed by the heterolysis of

A)  CH 3 3 CBr B)  C6 H 5 3 CBr

C)  C6 H 5  2 CHBr D) C6 H 5CH 2 Br

Question Stem for Question Nos. 34 and 35:

Substance ‘A’ undergoes first order reaction by two parallel paths forming products B
and C in two paths respectively as follows

The percentage yield of B is 10% and that of C is 90%. The rate constant for the
disappearance of A is 1.4  104 sec 1 .

34. The rate constant  k1  for the formation of B is

A) 1.4  10 5 sec1 B) 1.4  10 4 sec 1

C) 1.26  105 sec1 D) 1.26  104 sec 1

ISR.IIT_*CO SC Page No: 16


Narayana IIT Academy 23-04-23_ISR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-15_Q’P
35. the rate constant  k2  for the formation of C is

A) 1.4  10 5 sec1 B) 1.4  10 4 sec 1

C) 1.26  105 sec1 D) 1.26  104 sec 1

SECTION - 4 (Maximum Marks : 12)


This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE INTEGER
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
36. Total number of stereoisomers of compound below is
Br Br

Cl Br

Cl2 / hv Fractional P Q
37.   C4 H 7 Cl 
distillation
 Q . Find the value of
P (isomeric products) (no. of fractions) 2

38. Vander waal’s gas equation may be expressed as

B C
Z 1   ...
Vm Vm2

Where Vm  molar volume of gas. If B = - 0.105 L mol 1 and C  4  104 L2 mol 2 at

127 0 C , the value of vander waal contant ‘a’ (in atm L2 mol 2 ) is

(R = 0.08 L-atm/K-mol)

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Narayana IIT Academy 23-04-23_ISR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-15_Q’P
MATHEMATICS [Link]: 60
SECTION - 1 (Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
39. Let Q  x   0 be a quadratic equation having roots  and  . If Pn   n   n , then
choose the correctoption(s).

P100  2P98
A) If Q  x   x 2  6x  2 then 6
P99

2 P15 P16  P14 P16  P152  P14 P15


B) If Q  x   x  x  4 then  16
P13 P14

P17 P20  5 2P17 P19


C) If Q  x   x 2  5 2x  10  0 then 5
P18 P19  5 2P182

P17 P20  5 2P17 P19


D) If Q  x   x 2  5 2x  10  0 then 1
P18 P19  5 2P182

f n 1
40. Given f 1  2 and f  n  1  n  N, then
f n 1

1 f  2013 
A) f  2015   B)  f  2012   9
2

C) f 1001  2 D) f  2015   3

41. Let f  x  be double differentiable function such that f   x   5  x  0, 4 and f take its

largest value at an interior point of this interval. Then the value of f   0   f   4  can be

A) 18 B) 19 C) 20 D) 21

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Narayana IIT Academy 23-04-23_ISR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-15_Q’P
 
  
    
42. Let a, b and c be three non zero non collinear vectors then a .  b  c  a   is equal to
  
   
A)  a .b    
 a . c    b. c 
    


     
B) b.  a   a  c  
  

   
C)  a  b  . c  a 
  

                             
2 2 2

D) sgn  b.  a   a  c     b  c x a    a    a   b x  c  a    
                
 

43. Let  Tn  be a sequence such that Tn3  2Tn  Tn 1  n  N, and T1  1, then

100 100
A)   Tn3  Tn  1  T101  99
n 1
B) T
n 1
3
n  Tn  1  T101  100

100 100
 Tn 1 
C) T 2
n  2   T100 D) 
n 1  Tn
 Tn2   2100
n 1 

44. If [.] denotes greatest integer function, then choose the correctoption(s).

 sin x   x2  x 
A) Lim  1 B) Lim  2 0
x 0
 x  x  x  x
 

 5x 2  2x  1 
C) Lim  2  5 D) Lim  7x  22  1
x 
 x  x 1  x 

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Narayana IIT Academy 23-04-23_ISR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-15_Q’P
SECTION - 2 (Maximum Marks : 12)
This section contains TWO (3) Paragraphs. Based on each paragraph, there are 2 questions.
The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +2 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
Question Stem for Question Nos. 45 and 46:
For any square matrix A of order n  n, A  xI  0 is known as its characteristic
equation & its roots are called characteristic roots. It can be observed that

1) Sum of characteristic roots = sum of diagonal elements of A.

2) Product of characteristic roots = A (where A denotes determinant value of matrix


A)

Cayley Hamilton theorem states that every square matrix satisfies its characteristic
equation.

 2 10 
45. Let B    ,then find least value of n  N such that Bn  I 2 &   0. ( I 2 is
 1 4 
identity matrix of order 2)
3
tr  AB  BA 
46. If A and B are any 3×3 matrices then find . (Hence tr  A  denotes sum
AB  BA

of diagonal elements of A)

Question Stem for Question Nos. 47 and 48:


There are 2 circles in a parallelogram, one of them of radius 3 touches all its sides &
other circle touches two sides of parallelogram & first circle. The distance between
points of tangents which lie on same side of parallelogram is equal to 3.

47. If r is radius of the other circle. Find the value of 4r.

48. If d1 & d 2 denotes lengths of diagonals of parallelogram, then product d1.d 2 is ______

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Narayana IIT Academy 23-04-23_ISR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-15_Q’P
Question Stem for Question Nos. 49 and 50:
Using derivatives we can find minimum or maximum value of a function in a given
interval.

log e x
49. If the maximum value of is K, then the value of log e K is
x

x2
50. If the maximum value of 2x , x  0 is K, find log e K .
e

SECTION - 3 (Maximum Marks : 12)


This section contains TWO (2) Paragraphs. Based on each paragraph, there are 2 questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
For each question, choose the option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
Negative Marks: –1 In all other cases.
Question Stem for Question Nos. 51 and 52:
Consider a regular tetrahedron of side length ‘a’ units

51. Its volume is given by

a3 a3 2a 3
A) B) C) D) None
6 6 2 6
52. Length of altitude from any vertex to opposite face is

2 3 2 3
A) a B) a C) a D) a
3 2 5 2

Question Stem for Question Nos. 53 and 54:


For function defined piece wise in intervals, we can draw the graph in given intervals
and spot the points of discontinuity or non-differentiability.

 12x 2  3x  7 if x  1


53. The number of points where the function f  x     4x 2  1 if  1  x  1

 x  1  x  2 if x 1

(where[t] denotes the greatest integer x  t ), is discontinuous is _______.

A) 0 B) 7 C) 4 D) 3
ISR.IIT_*CO SC Page No: 21
Narayana IIT Academy 23-04-23_ISR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-15_Q’P
 sin  x   x  
 , x   2, 1
 x  x

54.  
Let f  x    max 2x,3  x  , x 1

 1 , Otherwise

Where [t] denotes greatest integer  t. If m is the number of points where f is not
continuous and n is the number of points where f is not differentiable, then the ordered
pair (m, n) is

A)  3,3 B)  2, 4  C)  2,3 D)  3,4 

SECTION - 4 (Maximum Marks : 12)


This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE INTEGER
For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
55. A is 2  2 matrix with real entries such that A  0 & A  A adjA  0 (WhereadjA

denotes adjoint and A denotes determinant of matrix A). Find A  A adjA .

56. Number of real values of  for which the lines 2x  3y  6 & x  y  3 cut coordinate
axis at concyclic points (consider only points that are at finite distance from origin)

57. Consider two fixed points A  2,0  &B 18,0  P is a point such that APB  90o. Let

the locus of P be C1.

Let S   :   length of segment MN where M is  4,0  and N  C1 

Find number of integers in the set S.

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Narayana IIT Academy 23-04-23_ISR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-15_Q’P

ISR.IIT_*CO SC Page No: 23

Common questions

Powered by AI

The least count of a screw gauge with a circular scale having 100 divisions is determined by the pitch and division adjustments. If the pitch is twice the Vernier callipers' least count, the screw gauge's least count is 0.01 mm .

The acceleration of a cylinder when a force is applied at its center of mass depends on whether the cylinder is solid or hollow. For a solid cylinder, the maximum possible acceleration is 2\(\mu g\).

Stationary waves in a string occur under resonant conditions where the wave speed matches the product of frequency and wavelength, often needing exact calculations of vibrational modes to satisfy node and antinode positioning .

The height \(h\) to which the liquid rises in a capillary tube is independent of the surface tension \(\sigma\) for a given material. However, if the experiment occurs in a lift with constant upward acceleration, \(h\) decreases .

In a cylindrical tube moving down a fixed inclined plane at a 45º angle with constant acceleration, the pressure difference \((P_1 - P_2)\) can become zero when the acceleration \(a\) is equal to \(g/2\).

The coefficient of restitution \(e\) depends on the ratio of relative velocities after and before collision. Given the velocities, \(e\) can be calculated using the absolute velocity changes of the involved masses .

For weak acids and bases, the enthalpy of neutralization is less than the theoretical value \(-57.33 \text{kJ/mol}\) for strong acids and bases, due to additional energy required for ionization of weak electrolytes .

The total pressure \(P_{total}\) in a vessel after a first-order reaction will adjust as \(A(g)\) decomposes. The pressure is evaluated at different decomposition stages or complete reaction, considering vapor pressure and reaction rate .

The minimum height of resonance is determined by the speed of sound in the gas. When air in the tube is replaced by another gas, parameters like molar mass influence the resonance condition, requiring knowledge about the specific gas characteristics .

After an impulse is applied, the angular momentum \(J\) before lift-off can be calculated using the relation \(JL = PL\), and the kinetic energy \(K\) after lift-off is determined by \((P^2)/(2m)\), considering the system's linear properties .

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