9th Atoms and Molecules Ncert Solutions-1
9th Atoms and Molecules Ncert Solutions-1
Atoms and 1
Molecules
18th century marked the recognition of difference between compounds and
elements and scientists started thinking about combining and reactions of elements.
Antoine L Lavoisier laid the foundation of chemical science by establishing two
important laws of chemical combination.
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SCIENCE JSUNIL TUTORIAL CLASS 9
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SCIENCE JSUNIL TUTORIAL CLASS 9
Atomic Masses of Few Elements (iv) Tetraatomic molecules They consist of four
Element Atomic Mass (u)
atoms. e.g., P4 .
Hydrogen
(v) Polyatomic molecules They consist of more than
1
four atoms. e.g., S 8 .
Carbon 12
Nitrogen 14 Atomicity of Some Elements (Non-metal)
Oxygen 16
Name Atomicity Name Atomicity
Sodium 23
Argon Monoatomic Nitrogen Diatomic
Magnesium 24
Sulphur 32 Helium Monoatomic Chlorine Diatomic
Chlorine 35.5 Oxygen Diatomic Phosphorus Tetra-atomic
Calcium 40 Hydrogen Diatomic Sulphur Poly-atomic
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SCIENCE JSUNIL TUTORIAL CLASS 9
The charged species are known as ions. These Copper (II)* Cu2+
can be negatively or positively charged. 3 Aluminium Al 3+ Nitride N3− Phosphate PO 3−
4
Iron (III)* Fe 3+
Ions are of following two types :
* These elements show more than one valency. Here, the Roman
Cations numeral written in brackets shows their valency. These have covalent
The positively charged ions which are attracted bonds.
towards cathode in an electric field are known as ® The compounds which contain molecules are called molecular
cations. e.g., Na + , K + , Ca 2+ , Al3+ , etc. compounds. e.g. H2O , CH4 , etc.
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SCIENCE JSUNIL TUTORIAL CLASS 9
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SCIENCE JSUNIL TUTORIAL CLASS 9
Example 1. Calculate the molar mass of the following Molar mass of atoms is also known as gram atomic
substances. mass. To find the gram molecular mass or molar mass we
(a) Ammonia (b) Hydrochloric acid keep the numerical value same but change the units from
(c) Phosphorus molecule (d) Hydrogen molecule ‘u’ to ‘g’.
(e) Oxygen molecule (f) Sulphur dioxide
Sol. 1 mole of
(a) Molar mass of ammonia carbon atoms
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SCIENCE JSUNIL TUTORIAL CLASS 9
Given mass 48
or, Number of moles =
Molar mass
=
32
= 1.5 mol Percentage Composition
The percentage composition of a component in a
(b) Molar mass of H 2O = 2 × 1 + 16 = 18 g
compound is the percentage of the total mass of the
∴ 18 g of H 2O =1mol
compound that is due to that component. It is obtained by
Given mass 18
or, Number of moles = = = 1mol dividing mass due to component by the total mass of the
Molar mass 18 compound and multiplying by 100, i.e.,
(c) Molar mass of CO 2 = 12 + 2 × 16 = 44 g Percentage composition of component
Q 44 g of CO 2 =1mol Mass due to that component
1 = × 100
∴ 22 g of CO 2 = × 22 = 0.5 mol Total molar mass of compound
44
Given mass 22 Example 5. Calculate the percentage composition of
or, Number of moles = = = 0.5 mol
Molar mass 44 carbon in CO 2 .
(d) Molar mass of NH3 = 14 + 3 × 1 = 17 g Sol. Molar mass of CO 2 =12 + 2 ×16
Q 17g of NH3 = 1 mol = 44 g mol −1
1
∴ 51g of NH3 = × 51 = 3 mol Mass due to carbon (C) = 12 g
17
12
or, Number of moles =
Given mass 51
= = 3 mol Percentage composition of C = ×100
Molar mass 17 44
= 27. 3%
Example 4. Calculate the number of aluminium ions
which are present in 0.0051 g of aluminium oxide.
Sol. Molar mass of 1 mole of aluminium oxide (Al 2O3 )
Check oint 5
1. What is Avogadro number ?
= 2 × 27 + 3 × 16 = 54 + 48 =102 g
Q 102 g of Al 2O3 contains 2. Write the weight of 1 mole of sodium atoms and
= 2 × 6.022 × 10 23 Al 3 + ions 1 mole of oxygen molecules.
3. Calculate the molecular mass of MgO,
∴ 0.0051 g of Al 2O3 will contain
C2H 5OH and C2H2 .
2 × 6.022 × 10 23
× 0.0051ions 4. Calculate the percentage composition of glucose
102
(C6H 12O6 ).
= 6.022 × 1019 Al 3 + ions
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SCIENCE JSUNIL TUTORIAL CLASS 9
According to ‘law of definite proportions’ in the second sample of ammonia, 2. (a) Ammonium carbonate
hydrogen and nitrogen should be in the ratio of 3 : 14. NH4 CO 3
H 3 5 3
Therefore, = ⇒ = +1 –2
N 14 N 14 (NH4 )2 CO 3
5 × 14
N= = 23.3 g (b) Potassium sulphate
3
K SO 4
+1 –2
Check Point 2 K 2SO 4
1. (c) Cupric chloride
Element Atomic Mass ( u) Cu Cl
Oxygen 16 +2 –1
Chlorine 35.5 CuCl 2
Carbon 12 (d) Aluminium nitride
Hydrogen 1 Al N
+3 –3
2. Silver (Ag), Chromium (Cr), Chlorine (Cl), Mercury (Hg), Lead (Pb), Copper AlN
(Cu), Gold (Au), Aluminium (Al).
(e) Calcium phosphate
Ca PO 4
Check Point 3 +2 –3
1. Molecules which contain more than four atoms are called poly-atomic Ca 3 (PO 4 )2
molecules. For example, sulphur (S8 ), ethyl alcohol (C 2H5OH), sugar
(C12H22O11 ), etc. 3. For the formula of metal sulphate, valencies of
metal ion and sulphate ion should be known.
2. 2Cl indicates 2 atoms of chlorine and Cl 2 indicates one molecule of Valency of sulphate ion (SO 2−
4 ) is –2 and that of
chlorine. metal is +3 (because it combines with 3
3. An ‘atom’ is the smallest particle of an element which may or may not have chloride ions forming the formula MCl3 ).
independent existence. For example, helium is an atom and exists as such. Therefore, formula of metal sulphate is
On the other hand, ‘molecule’ is the smallest particle of an element or M 2 (SO 4 )3 .
compound, capable of independent existence. For example, hydrogen
atom (H) cannot exist as such but exists as H2 , which is a molecule. 4. Chemical formulae Chemical names
NaHCO 3 — Sodium bicarbonate
4. CaCO 3 is a heteroatomic molecule which contains three types of atoms,
Ca(OH)2 — Calcium hydroxide
i.e., one atom of calcium, one atom of carbon and three atoms of oxygen.
CaO — Calcium oxide
5. KNO 3 — Potassium nitrate
Compound Combining Ratio by Simple
Mass ratio/Atomic mass
elements mass ratio Check Point 5
H2 O H and O 1:8 1 8 1 2:1
H= = 1, O = = 1. It is 6.022 × 1023
and denoted by the symbol
1 16 2
3 1 8 1 NA .
CO 2 C and O 3:8 C = = ,O = = 1:2
12 4 16 2 2. Weight of 1 mole of sodium atoms = 23 g
NH 3 N and H 14 : 3 14 3 1:3 (atomic mass) and weight of 1 mole of oxygen
N= = 1, H = = 3
14 1 molecules = 32 g (molecular mass).
3. Molecular mass of MgO = 24 + 16 = 40u
Check Point 4 Molecular mass of C 2H5OH
1. = 2 × 12 + 5 × 1 + 16 + 1= 46u
Ion Symbol Valency
Molecular mass of C 2H2 = 24 + 2 = 26u
Hydroxide OH− –1
Carbonate CO 2– –2 4. Molar mass of glucose
3
(C 6H12O 6 ) = 6 × 12 + 12 × 1 + 6 × 16
Sulphate SO 2− –2
4
= 72 + 12 + 96 = 180 g
Bicarbonate HCO −3 –1 Percentage of carbon =
72
× 100 = 40 %
Nitrate NO −3 –1 180
12
Ammonium NH+4 +1 Percentage of hydrogen = × 100 = 6.66 %
3− 180
Nitride N –3 96
Percentage of oxygen = × 100 = 53.33 %
Phosphate PO 3−
4 –3 180
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