JEE (Adv.

)-Chemistry Atomic structure and nuclear chemistry

@ Marked Questions may have for Revision Questions.

This Section is not meant for classroom discussion. It is being given to promote self-study and
self testing amongst the Reliable students.

PART- 1 : PAPER JEE (MAIN) PATTERN

SECTION–I : (Maximum Marks : 80)
˜ This section contains TWENTY questions.
˜ Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
˜ For each question, darken the bubble corresponding to the correct option in the ORS.
˜ For each question, marks will be awarded in one of the following categories :
Full Marks : +4If only the bubble corresponding to the correct option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –1 In all other cases
1. Which of the following ions has the maximum magnetic moment?
(A) Mn+2 (B) Fe+2 (C) Ti+2 (D) Cr+2.
2. Energy of H-atom in the ground state is –13.6 eV, hence energy in the second excited state is :
(A) – 6.8 eV (B) – 3.4 eV (C) – 1.51 eV (D) – 4.53 eV
3. Which of the following set a of quantum numbers is correct for an electron in 4f orbital?
(A) n = 4, l =3, m = +4, s = +1/2 (B) n = 4, l = 4, m = –4, s = –1/2
(C) n = 4, l = 3, m = +1, s = +1/2 (D) n = 3, l=2, m =–2, s = +1/2
4. In a photoelectric experiment, kinetic energy of photoelectrons was plotted against the frequency of incident
radiation (n), as shown in figure. Which of the following statements is correct?

(A) The threshold frequency is n1.

(B) The slope of this line is equal to Plank’s constant.
(C) As the frequency of incident wavelength increases beyond threshold frequency, kinetic energy of
photoelectrons decreases.
(D) It is impossible to obtain such a graph.
5. Calculate the number of photons emitted by a 100 W yellow lamp in 1.0 s. Take the wavelength of yellow light
as 560 nm and assume 100 percent efficiency.
(A) 6.8 × 1020 (B) 4 × 1012 (C) 4 × 1020 (D) 2.8 × 1020
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6. In what region of the electromagnetic spectrum would you look for the spectral line resulting from the electronic
transition from the tenth to the fifth electronic level in the hydrogen atoms? (RH = 1.10 × 105 cm–1)
(A) Microwave (B) Infrared (C) Visible (D) Ultraviolet
7. In a multi-electron atom, which of the following orbitals described by the three quantum numbers will have the
same energy in the absence of magnetic and electric field ?
(i) n = 1, l = 0, m = 0 (ii) n =2, l = 0, m = 0 (iii) n = 2, l = 1, m = 1 (iv) n = 3, l = 2, m =1
(v) n = 3, l = 2, m = 0
(A) (iv) and (v) (B) (iii) and (iv) (C) (ii) and (iii) (D) (i) and (ii)
x
8. An electron in an atom jumps in such a way that its kinetic energy changes from x to . The change in
4
potential energy will be :
3 3 3 3
(A) + x (B) - x (C) + x (D) - x
2 8 4 4

1
9. Select the incorrect graph for velocity of e– in an orbit VS. Z, and n :
n

(A) (B) (C) (D)

10. Which of the following is discreted in Bohr’s theory ?

(A) Potential energy (B) Kinetic energy
(C) Velocity (D) Angular momentum
11. Which quantum number defines the orientation of orbital in the space around the nucleus ?
(A) Principal quantum number (n) (B) Angular momentum quantum number
(C) Magnetic quantum number (m l) (D) Spin quantum number (m s)
12. In any subshell, the maximum number of electrons having same value of spin quantum number is :
(A) l ( l + 1) (B) l + 2 (C) 2l + 1 (D) 4l + 2

13. Maximum number of total nodes is present in :

(A) 5s (B) 5p (C) 5d (D) All have same number of nodes
14. For similar orbitals having different values of n :
(A) the most probable distance increases with increase in n
(B) the most probable distance decreases with increase in n
(C) the most probable distance remains constant with increase in n
(D) none of these
15. Which of the following set of quantum numbers represents the highest energy of an atom ?
1 1
(A) n = 3, l = 0, m = 0, s = + (B) n = 3, l = 1, m =1, s = +
2 2
1 1
(C) n = 3, l = 2, m = 1, s = + (D) n = 4, l = 0, m = 0, s = +
2 2

4E
16. The energy of a I, II and III energy levels of a certain atom are E, and 2E respectively. A photon of
3
wavelength l is emitted during a transition from III to I. What will be the wavelength of emission for transition
II to I ?
l
(A) (B) l (C) 2l (D) 3l
2

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JEE (Adv.)-Chemistry Atomic structure and nuclear chemistry
17. Neutron scattering experiments have shown that the radius of the nucleus of an atom is directly proportional
to the cube root of the number of nucleons in the nucleus. From 73 Li to 189
76 Os , the radius is :
(A) Halved (B) the same (C) Doubled (D) Tripled
18. The angular velocity of an electron occupying the second Bohr orbit of He+ ion is (in sec–):
(A) 2.067 × 1016 (B) 3.067 × 1016 (C) 1.067 × 1018 (D) 2.067 × 1017

19. The nucleus of an atom is located at x = y = z = 0. If the probability of finding an electron in d x 2 - y 2 orbital in
a tiny volume around x=a , y =0 , z = 0 is 1 × 10–5, what is the probablility of finding the electron in the same
size volume around x = 0 ,y = a, z = 0 ?
(A) 1 × 10–5 (B) 1 ×10–5 × a (C) –1 × 10–5 × a (D) zero
20. An excited state of H-atom emits a photon of wavelength l and returns in the ground state, the principal
quantum number of excited state is given by :
lR (lR - 1)
(A) lR(lR - 1) (B) (C) lR(lR - 1) (D)
(lR - 1) lR

SECTION-II : (Maximum Marks: 20)

˜ This section contains FIVE questions.
˜ The answer to each question is a NUMERICAL VALUE.
˜ For each question, enter the correct numerical value (If the numerical value has more than two decimal
places, truncate/round-off the value to TWO decimal places; e.g. 6.25, 7.00, –0.33, –.30, 30.27, –127.30,
if answer is 11.36777..... then both 11.36 and 11.37 will be correct) by darken the corresponding bubbles
in the ORS.
For Example : If answer is –77.25, 5.2 then fill the bubbles as follows.
˜ Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct numerical value is entered as answer.

21.@ An electron beam can undergo diffraction by crystals. Through what potential (in volts) should a beam of
electrons be accelerated so that its wavelength becomes equal to 1.54 Å?
22. If the value of En = – 78.4 kcal/mole, the order of the orbit in hydrogen atom is :
23. The energy required to break one mole of Cl – Cl bonds in Cl2 is 242 kJ mol–1 . The longest wavelength (in nm)
of light capable of breaking a single Cl – Cl bond is
(c = 3 × 108 m s–1 and NA = 6.02 × 1023 mol–1)
24. Calculate the sum of minimum and maximum number of electrons which may have magnetic quantum
1
number, m = +1 and spin quantum number, s = – in cromium (Cr) :-
2
25. The ‘spin-only’ magnetic moment [in units of Bohr magneton (mb)] of Ni2+ in aqueous solution would be
(Atomic number : Ni = 28)

PART 2 : PAPER JEE (ADVANCED) PATTERN

SECTION-I : (Maximum Marks : 12)
˜ This section contains FOUR questions.
˜ Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
˜ For each question, darken the bubble corresponding to the correct option in the ORS.
˜ For each question, marks will be awarded in one of the following categories :
Full Marks : +3 If only the bubble corresponding to the correct option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –1 In all other cases

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JEE (Adv.)-Chemistry Atomic structure and nuclear chemistry
1/ 2
1 æ 1ö
1. For a 3s orbital Y (3s) = ç ÷ (6 – 6s + s2 ) Y -s / 2
9 3 è aº ø
2Zr
Where s = . What is the maximum radial distance of node from nucleus ?
3aº

2 (3 + 3)a0 3 (3 + 3 )a 0 3 (3 – 3 3)a0 3 (3 – 3 )a0

(A) (B) (C) (D)
3 Z 2 Z 2 Z 2 Z
2. Find the quantum number of the excited state of electrons in He+ ion which on transition to first excited state
emit photons of wavelengths 108.5 nm. (RH = 1.09678 × 107 m–1)
(A) 6 (B) 5 (C) 4 (D) 2
3. Calculate the energy required to excited one litre of hydrogen gas at 1 atm and 298 K to the first excited state
of atomic hydrogen. The energy for the disociation of H–H bond is 436 kJ mol–1. Also calculate the minimum
frequency of photon to break this bond.
(A) 98.19 Hz (B) 10.93 × 1014 Hz (C) 1015 Hz (D) 6.22 × 1014 Hz
4. 1 mol of He+ ion is excited. Spectral analysis showed existence of 50% ions in 3rd level, 25% in 2nd level and
remaining 25% in ground state. Ionization energy of He+ is 54.4 eV ; calculate total energy evolved when all
the ions return ground state.
(A) 331.13 × 104 J (B) 400.14 × 104 J
(C) 10 J
4
(D) 6.66 × 104 J

SECTION-II : (Maximum Marks: 32)

˜ This section contains EIGHT questions.
˜ Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s)
is (are) correct option(s).
˜ For each question, choose the correct option(s) to answer the question.
˜ Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen,
both of which are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen
and it is a correct option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –1 In all other cases.
˜ For Example : If first, third and fourth are the ONLY three correct options for a question with second
option being an incorrect option; selecting only all the three correct options will result in +4 marks. Selecting
only two of the three correct options (e.g. the first and fourth options), without selecting any incorrect
option (second option in this case), will result in +2 marks. Selecting only one of the three correct options
(either first or third or fourth option), without selecting any incorrect option (second option in this case),
will result in +1 marks. Selecting any incorrect option(s) (second option in this case), with or without
selection of any correct option(s) will result in –1 marks.
5. Which is true about an electron?
(A) Rest mass of electron is 9.1 × 10–28 g
(B) Mass of electron increases with the increase in velocity
(C) Molar mass of electron is 5.48 × 10–4 g/mole
(D) e/m of electron is 1.7 × 108 coulomb/g
6. Which of the following statement(s) are wrong ?
(A) Photons having energy 400 kJ will break 4 mole bonds of a molecule A2 where A–A bond dissociation
energy is 100kJ/mol.
(B) Two bulbs are emitting light having wavelength 2000Å & 3000Å respectively. If the bulbs A & B are 40 watt
and 30 watt respectively then the ratio of no. of photons emitted by A & B per day is 1 : 2.
(C) When an electron make transition from lower to higher orbit, photon is emitted.
(D) None of the above
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7. d z2 - orbital has :
(A) Two lobes along z-axis (B) Ring along yz-plane
(C) Ring along xy-plane (D) Ring along x axis
8. Consider the following six electronic configurations (remaining inner orbitals are completely filled) and mark
the correct option.

(I) (II) (III)

(IV) (V) (VI)

(A) Stability order : II > I > IV > III

(B) Order of spin multiplicity : IV > III = I > II
(C) V does not violate all the three rules of electronic configuration
(D) If VI represents A and A+ when kept near a magnet, acts as diamagnetic substance.
9. The radial distribution functions [P(r)] is used to determine the most probable radius, which is used to find the
dP(r )
electron in a given orbital for 1s-orbital of hydrogen like atom having atomic number Z, is
dr

4Z 3 æ 2ö
dP ç 2r - 2Zr ÷ e -2Zr / a0
= 3 ç a0 ÷ø :
dr a0 è

dP(r )
(A) At the point of maximum value of radial distribution function = 0; one antinode is present
dr
a0
(B) Most probable radius of Li2+ is pm
3
a0
(C) Most probable radius of He+ is pm
2
(D) Most probable radius of hydrogen atom is a0 pm
10. Which is true about an electron?
(A) Rest mass of electron is 9.1 × 10–28 g
(B) Mass of electron increases with the increase in velocity
(C) Molar mass of electron is 5.48 × 10–4 g/mole
(D) e/m of electron is 1.7 × 108 coulomb/g
11. Many elements have non-integral atomic masses because
(A) they have isotopes
(B) their isotopes have non-integral masses
(C) the constituents, neutrons, protons and electrons combine to give fractional masses
(D) none of these

12. Which of the following statement(s) are wrong ?

(A) Photons having energy 400 kJ will break 4 mole bonds of a molecule A2 where A–A bond dissociation
energy is 100kJ/mol.
(B) Two bulbs are emitting light having wavelength 2000Å & 3000Å respectively. If the bulbs A & B are 40 watt
and 30 watt respectively then the ratio of no. of photons emitted by A & B per day is 1 : 2.
(C) When an electron make transition from lower to higher orbit, photon is emitted.
(D) None of the above

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JEE (Adv.)-Chemistry Atomic structure and nuclear chemistry
SECTION-III : (Maximum Marks: 18)
˜ This section contains SIX questions.
˜ The answer to each question is a NUMERICAL VALUE.
˜ For each question, enter the correct numerical value (in decimal notation, truncated/rounded-off to the
second decimal place; e.g. 6.25, 7.00, –0.33, –.30, 30.27, –127.30, if answer is 11.36777..... then both
11.36 and 11.37 will be correct) by darken the corresponding bubbles in the ORS.
For Example : If answer is –77.25, 5.2 then fill the bubbles as follows.
˜ Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct numerical value is entered as answer.
Zero Marks : 0 In all other cases.

13. Calculate maximum number of possible spectral lines which may be emitted in brackett series in H atom, if
electrons present in 9th excited level return upto ground level in a sample of H-like species.

14. What minimium number of atoms/ions should be present in a sample of H-like species, so that a maximum
of 6 spectral lines can be produced of electronic transition from fifth excited state upto n = 2?
15. When a certain metal was irradiated with light frequency 1.6 × 1016 Hz, the photo electrons emitted had twice
the kinetic energy as did photoelectrons emitted with frequency 1 × 1016 Hz when the same metal was
irradiated with light, then threshold frequency x × 1015 Hz. Find "x".
16. The IE1 of H is 13.6 eV. It is exposed to electromagnetic waves of 1028Å and gives out induced radiation. Find
out orbit of these induced radiation.

17. According to Bohr theory, the electronic energy of a hydrogen atom in the nth Bohr atom is given by

21.76 ´ 10-19
En= – J. Calculate the longest wavelength of light that will be needed to remove an electron
n2
from the third Bohr orbit of the He+ ion (If the wavelength is x × 10–7 (in meter) and x is an integer. Report ‘x’)

7
18. 4 Be captures a K-electron into its nucleus. What will be the sum of mass number and atomic number of the
nuclide formed?

PART - 3 : OLYMPIAD (PREVIOUS YEARS)

STAGE - I (NATION STANDARD EXAMINATION IN CHEMISTRY (NSEC))
1. Which of the following pair of electrons is excluded from an atom ? [NSEC-2000]
(A) n = 2, l = 0, m = 0, s = + ½ and n = 2, l = 0, m = 0, s = + ½
(B) n = 2, l = 1, m = + 1, s = + ½ and n = 2, l = 1, m = – 1, s = + ½
(C) n = 1, l = 0, m = 0, s = + ½ and n = 1, l = 0, m = 0, s = – ½
(D) n = 3, l = 2, m = – 2, s = + ½ and n = 3, l = 0, m = 0, s = + ½

2. The de Broglie wavelength associated with particle is [NSEC-2000]

(A) inversely proportional to its momentum (B) inversely proportional to its energy
(C) directly proportional to its velocity (D) directly proportional to its momentum.
3. The equation E = hn indicates that [NSEC-2000]
(A) photons have both particle and wave nature (B) photons are waves
(C) photons are stream of particles (D) no such inference can be drawn from the given equation
4. Consider a 20 W light source that emits monochromatic light of wavelength 600 nm. The number of photons
ejected per second in terms of Avogadro`s constant (NA) is approximately [NSEC-2003]
(A) NA (B) 10–2 NA (C) 10–4 NA (D) 10–5 NA

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5. The species which has its fifth ionisation potential equal to 340 eV is [NSEC-2003]
(A) B+ (B) C+ (C) B (D) C

6. Isosteres are compounds having similar geometry and isoelectronic species are species having the same
number of electrons. The pair of species CO2 and NO2+ is [NSEC-2003]
(A) isosteric and isoelectronic (B) isosteric, but not isoelectronic
(C) isoelectronic, but not isosteric (D) neither isosteric nor isoelectronic.

7. The ratio of the energy of a photon of wavelength 2000 to that of one with wavelength 4000 is
[NSEC-2004]
(A) 1/4 (B) 4 (C) 1/2 (D) 2.

8. The phenomenon which suggested that light is emitted in packets (quanta) is [NSEC-2004]
(A) electron diffraction (B) photoelectric effect
(C) diffraction of light (D) black body radiation.

9. Wave length associated with electron motion [NSEC-2005]

(A) increases with increase in the speed of electron
(B) remains same irrespective of the speed of electron
(C) decreases with increase of the speed of electron
(D) changes with the atomic number of the atom to which it belong.

10. The metal that shows photoelectric emission at lowest frequency radiation is [NSEC-2005]
(A) beryllium (B) lithium (C) sodium (D) magnesium.

11. The number of unpaired electrons in the scandium atom is [NSEC-2006]

(A) 1 (B) 2 (C) 0 (D) 3.

12. The set of quantum numbers n = 2, l = 2, ml = 0 for an atomic system [NSEC-2006]

(A) is not allowed (B) refers to an electron in 2d orbital
(C) denotes a 2p electron (D) describes one of the 7f orbitals.

13. The three quantum numbers n, l, m corresponding to the valence electron in rubidium (Z=37) are
[NSEC-2006]
(A) 5,0,0 (B) 5,1,0 (C) 5,0,1 (D) 5,1,1

14. The radiation having the highest amount of energy has [NSEC-2006]
(A) l = 3 nm (B) l = 3 pm (C) l = 3 A (D) u = 3 × 10 s-1.
8

15. Mass of a typical star is 1.0 × 1030 kg. Assume that a star is typically 3/4 hydrogen and 1/4 helium by mass.
The estimated number of protons (which are present in H as well as He) in a typical star is approximately
[NSEC-2006]
(A) 0.5 × 1057 (B) 1 × 1056 (C) 1 × 1058 (D) 0.5 × 1055.

16. Element having (4, 0, 0, + 1/2) as a set of four quantum numbers for its valence electron is- [NSEC-2007]
(A) Na (B) Ca (C) K (D) Br

17. The fundamental particle responsible for keeping the nucleus together is, [NSEC-2009]
(A) meson (B) muon (C) positron (D) hyperon

18. The maximum number of electrons in 3dZ2 orbital is – [NSEC-2009]

(A) 2 (B) 4 (C) 5 (D) 10

19. The ion which has 18 electrons in the outermost shell is – [NSEC-2009]
(A) Cu+ (Z = 29) (B) Al3+ (Z = 13) (C) K+ (Z = 19) (D) Th (Z = 90)
4+

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20. The velocity of an electron in the second Bohr orbit of an atom of an element is 1.1 x 106 m sec–1. Its velocity
in the third orbit is [NSEC-2010]
(A) 3.3 x 106 m sec–1 (B) 2.2 x 106 m sec–1 (C) 7.333 x 105 m sec–1 (D) 3.666 x 105 m sec–1
21. The sum of all the quantum numbers of hydrogen atom is [NSEC-2010]
(A) –1 (B) 0 (C) +1/2 (D) 3/2
22. The number of valence electrons in an atom with the configuration 1s2 2s2 2p6 3s2 3p2 is [NSEC-2011]
(A) 6 (B) 5 (C) 4 (D) 2
23. The wavelength of a moving body of mass 0.1 mg is 3.31 × 10–29 m. The kinetic energy of the body in J would
be : [NSEC-2011]
(A) 2.0 × 10–6 (B) 1.0 × 10–3 (C) 4.0 × 10–3 (D) 2.0 × 10–3
24. The widest range over which electronic excitations in organic compounds occur, is [NSEC-2012]
(A) 200 nm - 780 nm (B) 220 nm- 500nm (C) 250 nm- 700 nm (D) 290 nm -1000nm
25. If the radius of the first Bohr orbit is r, then the deBroglie wavelength in the third Bohr orbit is [NSEC-2012]
(A) 2pr (B) 9r (C) r/3 (D) 6pr
26. The quantum numbers for the 19th electron of Cr (Z = 24) are : [NSEC-2012]
(A) n = 3, l = 0, m = 0, s = + ½ (B) n = 4, l = 0, m = 0, s = + ½
(C) n = 3, l = 2, m = 2, s = + ½ (D) n = 4, l = 2, m = 2, s = + ½
27. The number of unpaired electrons in Ni2+ is [NSEC-2013]
(A) 0 (B) 2 (C) 3 (D) 4
28. The electronic level which allows the hydrogen atom to absorb, but not emit a photon is [NSEC-2013]
(A) 1s (B) 2s (C) 2p (D) 3s
29. The number of unpaired electrons in Ni2+ ion is 2, therefore its spin multiplicity is [NSEC-2013]
(A) 2 (B) 1 (C) 3 (D) 4
30. 4s orbital has lesser energy than 3d orbital because it has [NSEC-2013]
(A) Greater value of n (B) Lesser value of l
(C) Lesser value of (n +l) (D) l = 0
31. The magnetic moment of a divalent ion of an element with atomic number 24 in an aqueous solution is
[NSEC-2014]
(A) 4.9BM (B) 2.45BM (C) 2.83BM (D) 1.73BM
32. From the following species that are isoelectronic are [NSEC-2014]
I . NH3 II. CH3+ III. NH2– IV. NH4+
(A) (I), (II), (III) (B) (II), (III), (IV) (C) (I), (II), (IV) (D) (I), (III), (IV)
33. The set of quantum numbers that cannot be allotted to an electron in an atom is [NSEC-2014]
(A) n = 3, l = 2, m l = +2, ms = –1/2 (B) n = 2, l = 0, m l = +1, ms = +1/2
(C) n = 1, l = 0, ml = 0, m s = +1/2 (D) n = 4, l = 3, ml = 0, ms = –1/2
34. If the energy of an electron in the 1st and 2nd energy levels of an H atom are –13.6 eV and –3.4 eV,respectively,
the energy required in eV to excite an electron from the 1st to the 2nd energy level is [NSEC-2014]
(A) 17.0 (B) –17.0 (C) 10.2 (D) –10.2
35. The element X formed in the following nuclear reaction is [NSEC-2014]
53
24 Cr + a ¾¾
4
2 ® n +X 1
0

56 55 56 55
(A) 26 Fe (B) 25 Mn (C) 25 Mn (D) 25 Fe

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JEE (Adv.)-Chemistry Atomic structure and nuclear chemistry
36. If l0 and l are the threshold wavelength and the wavelength of the incident light, respectively on a metal
surface, the velocity of the photoelectron ejected from the metal surface is (m e = mass of electron,
h = Planck’s constant, c = speed of light) [NSEC-2015]

2h(l 0 – l) 2hc(l0 – l) 2hc (l0 – l) 2h æ 1 1ö

(A) (B) (C) (D) ç – ÷
me me m e ll0 me è l0 l ø
37. The energy of an electron in the first Bohr orbit is –13.6 eV. The energy of Be3+ in the first excited state
is [NSEC-2015]
(A) –30.6 eV (B) –40.8 eV (C) –54.4 eV (D) +40.8 eV
38. The de Brogile wavelength of an object of mass 33 g moving with a velocity of 200ms–1 is of the order of :
[NSEC-2015]
(A) 10–31m (B) 10–34m (C) 10–37m (D) 10–41 m
39. Imagine that in any atom about 50% of the space is occupied by the atomic nucleus. If a silver foil is
bombarded with a-particles, majority of the a-particles would [NSEC-2015]
(A) be scattered (B) be absorbed by the nuclei
(C) pass through the foil undeflected (D) get converted into photons
40. For an electron whose x-positional uncertainty is 1.0 x 10-10 m, the uncertainty in the x. Component of the
velocity in m s-1 will be of the order of [NSEC-2015]
(A) 106 (B) 109 (C)102 (D) 1015
41. The ionization energy of a certain element is 412 kJ mol –1. When the atoms of this element are in the first
excited state, however, the ionization energy is only 126 kJ mol–1. The region of the electromagnetic spectrum
in which the wavelenght of light emitted in a transition from the first excited state to the ground state is
[NSEC-2016]
(A) Visible (B) UV (C) IR (D) X-ray
42. The kinetic energy of an electron that has a wavelength of 10 nm is [NSEC-2016]
(A) 2.4 × 10–21 J (B) 4.8 × 10–21 J (C) 2.4 × 10–29 J (D) 4.8 × 10–29 J
43. When a certain metal was irradiated with light of frequency 3.2 × 1016 Hz, the photoelectrons emitted had
twice the kinetic energy as did the photoelectrons emitted when the same metal was irradiated with light
of frequency 2.0 × 1016 Hz. The v 0 of the metal is : [NSEC-2016]
(A) 2.4 × 1016 Hz (B) 8.0 × 1016 Hz (C) 8.0 × 1015 Hz (D) 7.2 × 1016 Hz
44. An electron beam can undergo diffraction by crystals which proves the wave nature of electrons. The
potential required for a beam of electrons to be accelerated so that its wavelength becomes equal to
0.154 nm is : [NSEC-2016]
(A) 63.5 V (B) 31.75 V (C) 635 V (D) 127 V
45. The ratio of the energy of the electron in ground state of hydrogen atom to that of the electron in the
first excited state of Be3+ is [NSEC-2016]
(A) 1 : 4 (B) 1 : 8 (C) 1 : 16 (D) 4 : 1
46. The electrons identified by quantum number n and l, (i) n = 4, l = 1, (ii) n = 4, l = 0, (iii) n = 3, l = 2, (iv)
n = 3, l = 1 can be placed in order of increasing energy from lowest to highest as : [NSEC-2016]
(A) (iv) < (ii) < (iii) < (i) (B) (ii) < (iv) < (i) < (iii) (C) (i) < (iii) < (ii) < (iv) (D) (iii) < (i) < (iv) < (ii)
47. The energy of an electron in Bohr’s orbit of hydrogen atom is –13.6eV. The total electronic energy of a
hypothetical’ He atom is which there are no electron– electron repulsions is [NSEC-2017]
(A) 27.2 eV (B) –27.2 eV (C) –108.8 eV (D) [Link]
48. The energy of an electron in the ground state of H atom is -13 6eV. The negative sign indicates that
[NSEC-2017]
(A) electrons are negatively charged.
(B) H atom is more stable than a free electron.
(C) energy of the electron in the H atom is lower than that of a free electron.
(D) work must be done to make a H atom from a free electron and proton.

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49. Which of the following elements will exhibit photoelectric effect with light of the longest wavelength?
[NSEC-2018]
(A) K (B) Rb (C) Mg (D) Ca
50. If the radius of the hydrogen atom is 53 pm, the radius of the He+ ion is close to [NSEC-2018]
(A) 75 pm (B) 38 pm (C) 106 pm (D) 27 pm
51. An orbital among the following that has two radial nodes and two angular nodes is [NSEC-2018]
(A) 3d (B) 4p (C) 4f (D) 5d

PART - 4 : ADDITIONAL PROBLEMS

SUBJECTIVE PROBLEMS
1. The wave function of 3s electron is given by

3/2 é æ ö æ r ö
2ù
1 æ 1 ö ê27 - 18ç r ÷ + 2ç ÷ ú -r / 3 a
Y3s = ça ÷ ça ÷
81 3P çè a 0 ÷ø ê ú e 0

ë è 0 ø è 0 ø û
It has a node at r = r0, Find out the relation between r0 and a0
2.@ The dissociation energy of H2 is 430.53 kJ mol–1. If H2 is exposed to radiant energy of wavelength 253.7 nm.
What % of radiant energy will be converted into kinetic energy? (Report your answer as nearest integer)
3. A moving particle is associated with wavelength 5 × 10–8m . If its momentum is reduced to half of its value,
compute the new wavelength. If answer is 10–x then find ‘x’.
4. Photon having wavelength 12.4 nm was allowed to strike a metal plate having work function 25 eV. Calculate
the
(a) Maximum kinetic energy (in eV) of photoelectrons emitted in eV.
(b) Wavelength (in Å) of electron with maximum kinetic energy in Å.
5. Why cathode ray tube experiment is not conducted at atmospheric pressure ?
6. The vapours of Hg absorb some electrons accelerated by a potential diff. of 4.5 volt as a result of which light
is emitted. If the full energy of single incident e- is supposed to be converted into light emitted by single Hg
atom, find the wave no. (in m –1) of the light.

7. Calculate the speed of an electron in the ground state of He+ ion. What fraction of speed of light is this value?
How long does it take for the electron to complete one revolution around the nucleus. How many times does
the electron travel around the nucleus in one second ?
8. The diameter of a dust particle of mass 10–3 gm is 2Å. If uncertainity in speed of this particle is
3.31
´ 10–3 m / s , then find minimum uncertaintity in its position
p
9. When an electron falls from (n + 2) state to (n) state in a He + ion the photon emitted has energy
6.172 × 10 –19 joules. What is the value of n.

ONLY ONE OPTION CORRECT TYPE

10. Uncertainity in position of a particle of 25 g in space is 10–15 m. Hence, Uncertainity in velocity (in [Link]–1) is:
(plank’s constant, h = 6.6 ´ 10–34 Js)
(A) 2.1 ´ 10–18 (B) 2.1 ´ 10–34 (C) 0.5 ´ 10–34 (D) 5.0 ´ 10–24
11. The value of Planck’s constant is 6.63 × 10–34 Js. The velocity of light is 3 × 108 m/sec. Which value is closest
to the wavelength of a quantum of light with frequency of 8 × 1015 sec–1 ?
(A) 5 × 10–18 m (B) 4 × 10–8 m (C) 3 × 107 m (D) 2 × 10–25 m

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12. S1 : Bohr model is applicable for Be2+ ion.
S2 : Total energy coming out of any light source is integral multiple of energy of one photon.
S3 : Number of waves present in unit length is wave number.
S4 : e/m ratio in cathode ray experiment is independent of the nature of the gas.
(A) F F T T (B) T T F F (C) F T T T (D) T F F F
13. A photon of frequency n causes photo electric emission from a surface with threshold frequency n0. The de-
Broglies wavelength (l) of the photo electron emitted is given by :

h h é 1 1 ù mc 2
(A) Dn = (B) Dn = (C) ê n – n ú = (D) l = h
2ml l ë 0 û h 2mDn
14. The de-Broglie wavelength of a tennis ball of mass 60 g moving with a velocity of 10 m/s is approximately
(planck’s constant, h = 6.63 ´ 10–34 J-s)
(A) 10–33 m (B) 10–31 m (C) 10–16 m (D) 10–25 m
15. Choose the incorrect statement from among the following :
(A) A node is a point in space where the wave function (y) has zero amplitude.
(B) The number of peaks in radial distribution is n – l.
(C) Radial probability density pn, l(r) = 4pr2R2n,l(r).
(D) y2 represent the atomic orbital.
16. The numbers of d-electrons retained in Fe2+ (atomic number Fe = 26) ion is
(A) 3 (B) 4 (C) 5 (D) 6
17. Which of the following does not characterise X-rays ?
(A) The radiation can ionise the gas (B) It causes fluoresce effect on ZnS
(C) Deflected by electric and magnetic fields (D) Have wavelength shorter than ultraviolet rays
18. In Bohr series of lines of hydrogen spectrum, the third line from the red end corresponds to which one of the
following inner-orbit jumps of the electron for Bohr orbits in an atom of hydrogen ?
(A) 3 ® 2 (B) 5 ® 2 (C) 4 ® 1 (D) 2 ® 5
19. The ratio of slopes of Kmax Vs v and V0 Vs v curves in the photoelectric effect gives (v = frequency,
Kmax = maximum kinetic energy, V0 = stopping potential) :
(A) charge of electron (B) Planck’s constant
(C) work function (D) the ratio of Planck’s constant of electronic charge
20. From the a-particle scattering experiment, Rutherford concluded that
(A) a-particles can come within a distance of the order of 10–14 m of the nucleus
(B) the radius of the nucleus is less than 10–14 m
(C) scattering follows Coulomb’s law
(D) All of these

h
21. The orbital angular momentum for an electron revolving in an orbit is given by l ( l + 1) . This momentum
2p
for an s-electron will be given by
1 h h h
(A) + . (B) Zero (C) (D) 2 . 2p
2 2p 2p

22. An electron in a hydrogen like atom makes transition from a state in which its de-Broglie wavelength is l1 to
a state where its de-Broglie wavelength is l2 then wavelength of photon (l) generated will be

4mc ìï l21 l22 üï l21 l22 2mc ìï l21 l22 üï

(A) l = l1 – l2 (B) l = í 2 ý (C) l = (D) l = í 2 ý
h ïî l1 - l22 ïþ l21 - l22 h ïî l1 - l22 ïþ
where m is mass of the electron, c is speed of light in vaccum.

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23. An electron is continuously accelerated in vacuum tube by applying potenital difference. If its de-broglie
wavelength is decreased by 1 %. The change in kinetic energy of the electron is nearly.
(A) Decreased by 1 % (B) Increased by 2 % (C) Increased by 1 % (D) Decreased by 2 %
24. Which of the given statement (s) is/are false.
I Orbital angular momentum of the electron having n = 5 and having value of the azimuthal quantum
h
number as lowest for this principle quantum number is .
p
II If n = 3, l = 0, m = 0, for the last valence shell electron, then the possible atomic number must be 12 or 13.
7
III Total spin of electrons for the atom 25Mn is ± .
2
IV Spin magnetic moment of inert gas is 0
(A) I, II and III (B) II and III only (C) I and IV only (D) None of these
25. The radial probability is the probability of finding electrons in a small spherical shell around the nucleus at a
particular distance (r). Hence radial probability is :
4 2
(A) 4 pr2 dr y2 (B) pr dr y2 (C) 2 pr2 dr y2 (D) 4 pr dr y
3

MATCH THE COLUMN

26.@ Match each List-I with an appropriate pair of characteristics from List-II and select the correct answer using
the code given below the lists.
List-I List-II
P. Lyman series 1. maximum number of spectral line observed = 6
Q. Balmer series 2. maximum number of spectral line observed = 2
8R
R. In a sample of H-atom for 5 upto 2 transition 3. 2nd line has wave number
9
3R
S. In a single isolated H-atom for 3 upto1 transition. 4. 2nd line has wave number
16
Code :
P Q R S P Q R S
(A) 3 4 1 2 (B) 1 2 4 3
(C) 3 1 2 4 (D) 2 3 1 4

NUMERICAL TYPE QUESTIONS

27.@ A hydrogen like atom (atomic number Z) is in a higher excited state of quantum number n. This excited atom
can make a transition to the first excited state by successively emitting two photons of energies 10.20 eV
and 17.00 eV respectively. Alternatively, the atom from the same excited state can make a transition to the
second excited state by successively emitting two photons of energy 4.25 eV and 5.95 eV respectively.
Determine the values of n and Z (ionisation energy of hydrogen atom = 13.6 eV). Give answer = n + Z.
28. How many of the following statements are true about the cathode rays ?
(i) Path of travelling is straight from the cathode with a very high velocity as it produces shadow of an object
placed in its path.
(ii) rays consist of material particle.
(iii) They deflect towards negative end of the electrode.
(iv) They produce yellow glow when the glass will beyond anode.
(v) Cathode rays penetrate through thin sheets of aluminium and metals.
(vi) They affect the photographic plates
(vii) The ratio of charge(e) to mass(m) i.e. charge/mass is same for all cathode rays irrespective of the gas
used in the tube. e/m = 1.76 × 1011 Ckg–1
(viii) cathode rays are visible at low voltage.

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29. A single electron system has ionization energy 20902.2 kJ/mole. Find the number of protons in the
nucleus of the system.

30. A radio station is broadcasting programme at 100 MHz frequency. If the distance between the radio station
and the receive set is 300 KM. How long the signal would take to reach the set from the radio station in
term of 10–3 sec.

31. There are two samples of H and He+ atom. Both are in some excited state. In hydrogen atom total
number of lines observed in Balmer series is 4 and in He + atom total number of lines observed in
paschen series is 1. Electron in hydrogen sample make transitions to lower states from its excited
state, then the photon corresponding to the line of maximum energy line of Balmer series of H sample
is used to further excite the already excited He+ sample. Then maximum excitation level of He+ sample
will be :

32. An element undergoes a reaction as shown : -

x + e– ® x – energy released = 30.87 eV
If the energy released, is used to dissociate 12 g of H2 molecules, equally into H+ and H*, where H* is an
excited state, in which the electron travels a path length equal to four times it’s debroglie wavelength.
Determine the least amount (in moles) of ‘x’ that would be required.
Given: I.E. of H = 13.6 eV/atom , Bond energy of H2 = 4.526 eV/molecule.

33. In a sample of hydrogen atom in ground state electrons make transition from ground state to a particular
excited state where path length is five times de-broglie wavelength, electrons make back transition to the
ground state producing all possible photons. If photon having 2nd highest energy of this sample can be used
to excite the electron in a particular excited state of Li 2+ atom then find the final excited state of Li 2+ atom.

34. Photons of equal energy were incident on two different gas samples. One sample containing
H-atoms in the ground state and the other sample containing H-atoms in some excited state with a principal
quantum number ‘n’. The photonic beams totally ionise the H-atoms. If the difference in the kinetic energy of
the ejected electrons in the two different cases is 12.75 eV. Then find the principal quantum number ‘n’ of the
excited state.

35. If each orbital can hold a maximum of 3 electrons, the number of elements in 4th periodic table (long form) is.

36. In all how many nodal planes are there in the atomic orbitals for the principal quantum number n = 3

234 206
37. 90 Th disintegrates to give 82 Pb as the final product. How many alpha and beta particles are emitted
during this process ? Express answer as number of a-particle + number of b-particle emitted.

38. The uncertainty in position and velocity of the particle are 0.1 nm and 5.27×10–27 ms–1 respectively. Then the
mass of the particle in grams is : (h = 6.625 × 10–34Js). Represent answer by dividing with 10.

ONE OR MORE THAN ONE OPTIONS CORRECT TYPE

39.@ Choose the correct statement(s) :
(A) The shape of an atomic orbital depends upon azimuthal quantum number
(B) The orientation of an atomic orbital depends upon the magnetic quantum number
(C) The energy of an electron in an atomic orbital of multi-electron atom depends upon principal quantum
number only
(D) The number of degenerate atomic orbitals of one type depends upon the value of azimuthal quantum
number
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40. For radial probability curves, which of the following is/are correct ?
(A) The number of maxima in 2s orbital are two
(B) The number of spherical or radial nodes is equal to n – l – 1
(C) The number of angular nodes are ‘l’
(D) 3dz2 has 3 angular nodes

41.@ dxy orbital has four lobes between x- and y-axes. The wave functions of two lobes are positive and those of
other two are negative. The positive wave function signifies that :
(A) both x and y are positive (B) both x and y are negative
(C) either x or y is negative (D) none of these

42. Many elements have non-integral atomic masses because

(A) they have isotopes
(B) their isotopes have non-integral masses
(C) the constituents, neutrons, protons and electrons combine to give fractional masses
(D) none of these

43. In a hydrogen like sample two different types of photons A and B are produced by electronic transition.
Photon B has it’s wavelength in infrared region. If photon A has more energy than B, then the photon A may
belong to the region
(A) ultraviolet (B) visible (C) infrared (D) None

44. Identify the correct statement(s) :

(A) Wavelength associated with a 1 kg ball moving with the velocity 100 m/s can’t be calculated.
(B) Wave nature of the running train is difficult to observe because wavelength is extremely small.
hc
(C) Wavelength associated with the electron can be calculated using the formulae E =
l
(D) If an electron is accelerated through 20 V potential difference if it has already 5eV kinetic energy then

wavelength of the electron is approximately 6 Å.

45. Choose the incorrect statement(s):

(A) Increasing order of wavelength is
Micro waves > Radio waves > IR waves > visible waves > UV waves
(B) The order of Bohr radius is (rn : where n is orbit number for a given atom) r1 < r2 < r3 < r4
(C) The order of total energy is (En : where n is orbit number for a given atom) E1 > E2 > E3 > E4
(D) The order of velocity of electron in H, He+, Li+, Be3+ species in second Bohr orbit is
Be3+ > Li+2 > He+ > H

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RRP ANSWER KEY

PART- 1

1. (A) 2. (C) 3. (C) 4. (B) 5. (D) 6. (B) 7. (AC)

8. (A) 9. (D) 10. (D) 11. (C) 12. (C) 13. (D) 14. (A)
15. (C) 16. (D) 17. (D) 18. (A) 19. (A) 20. (B) 21. 63.3
22. 2 23. 494 24. 5 (2 + 3) 25. 2.84

PART - 2
1. (B) 2. (B) 3. (B) 4. (A) 5. (ABCD) 6. (ABC) 7. (A)
8. (ABC) 9. (ABCD) 10. (ABCD) 11. (ABC) 12. (ABC)

13. 6 14. 2 15. 4 16. 3 17. 2 18. 10 (7 + 3 = 10)

PART - 3
1. (A) 2. (A) 3. (A) 4. (C) 5. (C) 6. (A) 7. (D)
8. (B) 9. (C) 10. (C) 11. (A) 12. (A) 13. (B) 14. (B)
15. (A) 16. (C) 17. (A) 18. (A) 19. (A) 20. (C) 21. (D)
22. (C) 23. (A) 24. (A) 25. (D) 26. (C) 27. (B) 28. (A)
29. (C) 30. (C) 31. (A) 32. (D) 33. (B) 34. (C) 35. (A)
36. (C) 37. (C) 38. (B) 39. (A) 40. (A) 41. (A) 42. (A)
43. (C) 44. (A) 45. (A) 46. (A) 47. (C) 48. (C) 49. (B)
50. (D) 51. (D)
PART - 4
1. r0 = 7.1a0 and r0 = 1.95 a0 2. 9 (8.68%)
3. 7 4. (a) 75 eV (b) 1.414 Å
5. At atmospheric pressure in the cathode tube the generated cathode rays shall face numerous collisions.
Hence the distance traveled by the rays will be infinitisimally small.
6. 3.63 × 106 m–1 7. 4.36 × 106 m/s, 0.0145, 3.8 × 10–17 sec, 2.63 × 1016 revolution
8. 5 × 10–26 m
9. n=3
10. (A) 11. (B) 12. (C) 13. (D) 14. (A) 15. (D) 16. (4)
17. (C) 18. (B) 19. (A) 20. (D) 21. (B) 22. (D) 23. (B)
24. (A) 25. (A) 26.@ (A) 27.@ 9 28. 5 (i, ii, v, vi, vii) 29. 4
30. 1 31. 12 32. 6 33. 12 34. 4 35. 48 36. 11
37. 13 38. 10 39. (ABD) 40. (ABC) 41. (AB) 42. (ABC) 43. (ABC)
44. (BD) 45. (AC)

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RRP SOLUTIONS
PART- 1
1. Mn2+ has the maximum number of unpaired electrons (5) andtherefore has maximum moment.

13.6 13.6
2. 2nd excited state will be the 3rd energy level. En = 2 eV or E = = 1.51 eV..
n 9
3. For 4¦ orbital electrons, n = 4
l = 3 (because ) m = + 3, + 2, + 1, 0, –1, –2, –3 s = + 1/2.

PDt l PDt
5. The number of photon is N = = =
E
h(c / l ) hc
hn
Substitution of the data gives
(5.60 ´ 10-7 m) ´ (100Js -1) ´ (1.0s)
N= = 2.8 × 1020
(6.626 ´ 10-34 s) ´ (3 ´ 108 ms-1)

1
6. Wave numbers are the reciprocals of wavelengths and are given by the expression v = l .

1 é1 1ù
_= 1.1 × 105 ê n – n ú
n ë 1 2û

7. The electron having same principle quantum number and azimuthal quantum number will be the same energy
in absence of magnetic and electric field.
(iv) n = 3, l = 2, m =1
(v) n = 3, l = 2, m = 0
have same n and l value.
2x 3
8. Change in P.E. = – + (2x) Þ x
4 2
11. It is fact.
12. Maximum number of electrons with same spin is equal to maximum number of orbitals, i.e., (2l +1).
13. Total nodes = n – 1.
14. It is fact.
15. The electron have n + l higher value have hegher energy.
n+l=3+0=3
n+l=3+1=4
n + l = 3 + 2 = 5(highest energy)
n+l=4+0=4

4E hc E hc
16. For II to I transition, DE = –E= l ; = l
3 II ®I 3 II – I
hc hc
For III to I transition, DE = 2E – E = or E =
l l

hc hc
\ = l lII–I = 3l
3´l II – I

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1/ 3
ROs æ 189 ö
17. RLi
= ç ÷ =3
è 7 ø

2pZe2
18. Velocity of an electron in He+ ion in an orbit = .....(i)
nh

n2h2
Radius of He+ ion in an orbit = ....(ii)
4p2me2 Z
By equations (i) and (ii),
u 8p3 Z 2me4
Angular velocity (w) = = ....(iii)
r n3h3

8 ´ (22 / 7)3 ´ (2)2 ´ (9.108 ´ 10-28 ) ´ (4.803 ´ 10 -10 )4

= = 2.067 × 1016 sec–1.
(2)3 ´ (6.626 ´ 10 -26 )3

19. It would be same in x and y axis for d x 2 - y 2 .

æ ö
1 ç 1 1÷
20. = R çç n2 – n2 ÷÷ ; n1 = 1, n2 = ?;
l è 1 2ø

æ ö
1 ç1 1 ÷ Rl lR
–
= R çç 1 n2 ÷÷ Þ n22 = Þ n2 =
l è 2ø R l –1 lR – 1

1 h
21. For an electron mu2 = eV and l=
2 mu

1 h2
Thus, m × 2 2 = eV
2 m l
-34 2
1 h2 1´ (6.62 ´ 10 )
or V= = = 63.3 volt.
2
2 ml e 2 ´ 9.108 ´ 10 (1.54 ´ 10 -10 )2 ´ 1.602 ´ 10-19
-31

22. En = – 78.4 kcal/mole = – 78.4 × 4.2 = – 329.28 kJ/mole

329.28
=– eV = – 3.4 eV. (energy of II orbit of H atom).
96.5

23. Cl–Cl(g) ¾¾® 2Cl(g) ; DH = 242 KJ mol

242 ´ 103
= J molecule–1
6 .02 ´ 10 23
hc
E=
l

242 ´ 10 -23 ´ 103 6.6 ´ 10-34 ´ 3 ´ 108

=
6.02 l

6.6 ´ 10 -34 ´ 3 ´ 108 6 .6 ´ 3 ´ 6.02

l= = ´ 10–6 = 0.494 ´ 10–6 = 494 ´ 10–9 m = 494 nm
242 ´ 10 -23 ´ 103 242

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3d 4s 4p
25. 28
Ni ® [Ar]3d8 4s2
Number of unpaired electrons (n) = 2
m= n(n + 2) = 2( 2 + 2) = 8 » 2.84

PART - 2
1. Radial node occurs where probability of finding of e– is zero.
\ Y 2 = 0 or Y = 0
\ 6 – 6s + s2 = 0 s = 3 ± 3
3 (3 + 3 )a 0
For maximum distance r =
2 Z

1 é1 1ù
2. = RHZ2 ê 2 – 2 ú
l ëê 1 n2 ûú

1 é 1 1ù
= 1.09678 × 107 × 4 ê 2 – 2 ú
-9
108.5 ´ 10 ëê 2 n2 úû
This gives n2 = 5.

PV 1´ 1
3. Mole of H2 present in one litre = = = 0.0409
RT 0.0821´ 298
Thus, energy needed to break H–H bonds in 0.0409 mole of H2 = 0.0409 × 436 = 17.83 kJ.
Also energy needed to excite one H atom from 1st to 2nd energy level
æ 1ö
= 13.6 ç 1– ÷ eV = 10.2 eV = 10.2 × 1.6 × 10–19 J
è 4ø
\ Energy needed to excite 0.0409 × 2 × 6.02 × 1023 atoms of H
= 10.2 × 1.6 × 10–19 × 0.0409 × 2 × 6.02 × 1023 J = 80.36 kJ
Thus, total energy needed = 17.83 + 80.36 = 98.19 kJ
436 ´ 103
Energy required to break (H–H) bond = joule
6.023 ´ 1023

436 ´ 103
E = hn \ = 6.625 × 10–34 n
6.023 ´ 1023
n = 10.93 × 1014 sec–1 or Hz.
4. 25% of He+ ions are already in ground state, hence energy emitted will be from the ions present in 3rd level
and 2nd level.
é 1 1ù
DE = (IP)Z ê 2 – 2 ú per ion or atom
ëê n1 n2 úû

N0 é 1 – 1 ù
(DE)3®1 = (54.4) ê 2 ú
2 ë1 32 û

N0 4 ´ N0
for ions falling to ground state = 54.4 × eV
2 9

N0 é 1 – 1 ù
and (DE)2®1 = (54.4) ê 2 ú
2 ë1 22 û

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N0 3 ´ N0
for ions falling to ground state = 54.4 × eV
4 16

é4 3 ù 91
hence total energy = 54.4 × N0 ê + ú = 54.4 × 602 × 1023 × eV
ë 9 16 û 144

91
= 54.4 × 6.02 × 1023 × × 1.6 × 10–19 J = 331.13 × 104 J.
144

5. me = 9.1 × 10–31 kg = 9.1 × 10–28 g.

m0
m= (m0 : rest mass ; m : dynamic mass).
v2
1–
c2

æ 2ö
ç1 – v ÷ ¯
As v ­, ç \ m­
è c 2 ÷ø
Molar mass of e = 9.1 × 10–28 × 6.023 × 1023 = 5.48 × 10–4 g/mole.

e 1.6 ´ 10 -19
For electron, = = 1.7 × 108 c/g.
m 9.1´ 10 -28

6. (A) Since the number of photons is not specified (it may or may not be equal to 4 NA). So, this statement is
not always true.
(B) [Link] photon emitted per day × Energy of one photon = Energy emitted per day.
12400
For bulb A, ne A × × 1.6 × 10–19 = 40 × 24 × 3600.
2000

12400
For bulb B, neB × × 1.6 × 10–19 = 30 × 24 × 3600.
3000

\ ne A : neB = 8 : 9.
(C) When an electron make transition from lower to higher orbit, a photon is absorbed.

7. d z2 orbital has two lobes along Z axis and a ring along XY plane.

8. A : excitation possible only in d-orbitals

B : Spin multiplicity = 2 |S| + 1; |S|
= total spin
C : V violated Hund`s rule
D : A+ is paramagnrtic due to unpaired e–
\ A, B, C are correct.
9. (A, B, C, D) At the point of maximum value of RDF
dP
=0
dr

æ 2ö
ç 2r – 2Zr ÷ a0
ç a ÷ = 0; r = Z
è 0 ø
where Z = 3 for Li 2+ and Z = 2 for the He+ ;
Z = 1 for hydrogen.

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10. me = 9.1 × 10–31 kg = 9.1 × 10–28 g.
m0
m= (m0 : rest mass ; m : dynamic mass).
v2
1–
c2

æ v 2 ö÷
ç
As v ­, ç1 – 2 ÷ ¯ \ m­
è c ø
Molar mass of e = 9.1 × 10–28 × 6.023 × 1023 = 5.48 × 10–4 g/mole.

e 1.6 ´ 10 -19
For electron, = = 1.7 × 108 c/g.
m 9.1´ 10 -28
11. Non integral atomic masses of elements are due to existence of isotopes of that element which have different
masses.
12. (A) Since the number of photons is not specified (it may or may not be equal to 4 NA). So, this statement is
not always true.
(B) [Link] photon emitted per day × Energy of one photon = Energy emitted per day.
12400
For bulb A, ne A × × 1.6 × 10–19 = 40 × 24 × 3600.
2000
12400
For bulb B, neB × × 1.6 × 10–19 = 30 × 24 × 3600.
3000

\ ne A : neB = 8 : 9.
(C) When an electron make transition from lower to higher orbit, a photon is absorbed.

15. By photoelectric effect. hn = hn0 + KE

\ KE1 = h(n1–n0) .....(A)
KE2 = h(n2–n0)= KE1/2 ......(B)
n2 - n0 1
Dividing equation (B) by (A) we have =
n1 - n0 2

1.0 ´ 1016 1
16
= 2.0 × 1016 –2n0 = 1.6×1016–n0
1.6 ´ 10 - n0 2
n0 = 4 × 1015 Hz
16. E1 for H-atom = – 13.6
12375
Q E= ; when l is in Å
l
12375
\ Energy given to H-atom = eV = 12.07 eV
1028
\ Energy of H-atom after excitation = – 13.6 + 12.07 = – 1.53 eV
E1
Q En =
n2
-13.6
\ n2 = =9;
-1.53
\ n=3

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17. Let us first calculate the energy required to remove an electron from the third orbit of the He+ ion. This energy
will be equal to the energy released (DE) when an electron will drop from ¥ orbit to third orbit. For He+, Z = 2
and for H+, Z = 1, Thus for He+

21.76 ´ 10-19 æ 21.76 ´ 10 -19 ö

DE = – × 22 – çç ´ 22 ÷ = 0 + 9.67 × 10–19 J.
3 2 ÷
¥2 è ø

hc
Now, DE = hn =
l

hc (6.626 ´ 10-34 )(3 ´ 108 )

\ l= = = 2.055 × 10–7 metres.
DE 9.67 ´ 10-19
18. When a nucleus captures a K-electron, a proton is converted to a neutron. So the mass number does not
change but the atomic number reduces by 1 unit. Thus the mass number and atomic number of the resulting
nuclide will be 7 and 3 respectively.

PART - 3
1. Both are in parallel pin.

h
2. l=
P

3. E = hu
Photons have both particles and wave nature.

hc
4. ´ N = 20
l

600 ´10 -9 ´ 20
N=
6.62 ´10 -34 ´ 3 ´10 8
N = 6.04 × 10+19
N = 10–4 NA

æ 1 1 ö
5. 340 = 13.6 22 ç - 2÷
è 12 ¥ ø
2=5
6. Both pair having linear shape
CO2 – 22e–
NO27 – 22e–

Î1 l 2
7. = =2
Î2 l1

11. Sc (21) – 1s22s22p63s23p64s23d1

13. z = 37
1s22s22p63s23p64s23d104P6 5s1
5, 0, 0

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c
14. E = hv = h
l
c
® maximum
l

3 ´10 8
l = 3lm = = 1017
3 ´10 -9

3 ´10 8 3 ´10 8
l = 3pm = = 1020 ;
l = 3A0 = = 1018
3 ´10 -12 3 ´10 -10

10 30 ´10 3
15. No. of moles =
2

10 30 ´10 3
No. of proton = 2 ´ ´ 6.023 ´10 23 = 0.6 × 1057
2
16. 4s
Ca – 1s2 2s2 2p6 3s23p64s2
17. Force of attraction between nucleus is due to meson.
18. An orbital can have maximum 2 electrons.
19. Cu : [Ar] 4s1 3d10
29
; 29
Cu1+ : [Ne] 3s2 3p6 3d10

7
20. v n = 2.18 × 106 × m sec–1
n
7
v 2 = 1.1 × 106 = 2.18 × 106 ×
2

7 2 ´ 1.1´ 10 6 2 .2
v 3 = 2.18 × 106 × = = ´ 10 6 = 7.33 × 105 m/s
3 3 3

21. n=1
l=0
m=0
s = 1/2
sum = 3/2
22. Valence shell is n = 3
So valence e– is 4 (3s2 3p2)
h
23. l=
mv
h
mv =
l
h2
m2v2 =
ml2
1 h2
mv 2 =
2 2ml2

h2 (6.6 ´ 10 -34 )2
KE = = = 2 × 10–6.
2ml2 2 ´ 10 - 4 ´ (3.31´ 10 -29 )2
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24. The organic functional groups undergoes electronic excitations in the range of 200 nm-780 nm range.

r1 r (1)2
25. = = 2
r3 r3 3
\ r3 = 9r
now 2pr = nl
Or 2 × p ×9r = 3l Or l = 6pr
26. 19th e– in Cr enters in 4s subshell.

PART - 4
1. Nodal point
|Y|2 = 0
é æ ö æ r ö
2ù
ê27 - 18ç r ÷ + 2ç ÷ ú r0 18 ± 18 2 - 4 ´ 27 ´ 2 18 ± 10.4
ê ça ÷ ça ÷ ú =0; = =
è 0 ø è 0 ø a0 4 4
ë û

430.53 ´ 103
2.@ EH–H bond dissocation = J per molecule = 7.15 × 10–19 J per molecule
6.023 ´ 1023

hc 6.626 ´ 10-34 ´ 3.0 ´ 108

EPhoton = = = 7.83 × 10–19 J.
l 253.7 ´ 10 -9
Energy converted into kinetic energy = Energy left after dissociation of bond.
\ Energy converted into KE = (7.83 – 7.15) × 1019 J = 0.68 × 10–19 J
0.68 ´ 10-19
\ % of energy converted into KE = × 100 = 8.68%.
7.83 ´ 10-19
3. Given l = 5 × 10–8 m
h h l1 (momentum)2
l= = \ = (momentum)
mv momentum l2 1

1
Since, (momentum)2 = (momentum)1
2
(momentum)1 ´ l1
Or l2 = = 2 × 5 × 10–8 = 10–7 m.
(momentum)2
5. At atmospheric pressure in the cathode tube the generated cathode rays shall face numerous collisions.
Hence the distance traveled by the rays will be infinitisimally small.
Z 2
7. v = 2.18 × 106 × = 2.18 × 106 × = 4.36 × 106 m/s
n 1
v 4.36 ´ 106
Fraction = = = 0.0145
c 3 ´ 108
æ 2 ö
ç 2 ´ 22 ´ 0.529 ´ 1 ´ 10–10 ÷
2pr ç 7 2 ÷
Time taken for one revolution = = ç ÷ = 3.8 × 10 sec,
–17
v 4.36 ´ 106
ç ÷
è ø

v 1
Frequency = = = 2.63 × 1016 revolutions
2pr 3.8 ´ 10–17

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9. For He+ ion,
En+2 – En = 6.172 × 10–19
é 1 1 ù 6.172 ´ 10-19 é 1 1 ù 6.127 ´ 10-19
\ 13.6 (B)2 ê - ú = \ 13.6 ê - ú = = 0.966
2
ëê n (n + 2)2 ûú 1.602 ´ 10-19 2
ëê n (n + 2)2 ûú 4 ´ 1.602 ´ 10-19
Left side of above equation represents difference in energy of (n + 2) state and n state for Hydrogen atom and
Right side of above equation represents difference in energy of 5th state and 3rd state for H atom.
\ n = 3.

h 6.6 ´ 10 –34
10. Dx. Dv = Dv = \ Dv = 2.1 × 10–18 ms–1.
4pm 4 ´ 3.14 ´ 25 ´ 10 -5

c 3 ´ 108
11. l= = = 3.75 × 10–8 m
n 8 ´ 1015

12. S1 : Be2+ ion has 2 electron so Bohr model is not applicable.

S2, S3 and S4 are correct statement.

1
13. mv 2 = h(n – n0) = hDn
2
h h 1 h2
l= = Þ v= h Þ m × 2 2 = hDn
P mv ml 2 m l
h h
Dn = Þ l=
2ml2 2mDn

h 6.63 ´ 10 -34 ´ 1000

14. l= = = 11.05 × 10–34 = 1.105 ×10–33 metres.
mv 60 ´ 10
15. y represent the atomic orbital, y2 is probablity distribution.
16. 26
Fe = 1s2, 2s2, 2p6, 3s2, 3p6, 3d6, 4s2,
Fe++ = 1s2, 2s2, 2p6, 3s2, 3p6, 3d6
The number of d -electrons retained in Fe2+ = 6.
Therefore, (D) is correct option.
17. X-ray are uncharged so no deflection.
18. The electron has minimum energy in the first orbit and its energy increases as n increases. Here n represents
number of orbit, i.e., 1at, 2nd, 3rd ..........The thired line from the red end corresponds. To yellow region i.e., 5.
In order to obtain less energy electron tends to come 1st or 2nd orbit. So jump may be involved either 5 ® 1 or
5 ® 2. Thus option (B) is correct here.

h h h
19. hv = hv 0 + eV0; eV0 = hv – hv 0 or V0 = v– v ; slope1 =
e e 0 e
Similarly, hv = hv 0 + Kmax or Kmax = hv – hv 0 ;
slope 2 h
slope2 = h, slope = =e
1 h/e

20. Factual.
21. The value of l (azimuthal quantum number) for s -electron is equal to zero.
h
Orbital angular momentum = l(l + 1).
2p
h
Substituting the value of l for s-electron = 0(0 + 1). =0
2p

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hc
22. = E1 – E2 = KE2 – KE1
l

2
h æhö 1 1 h2
\ l= (mV)2 = ç ÷ ; mV2 =
mV èlø 2 2m l2

hc h 2
h 2
2mc ìï l21 l22 üï
\ = – . \ l= í 2 ý.
l 2
2m l 2 2m l21 h ïî l1 - l22 ïþ

1
23. lµ
K.E.

KE1 l2 0.99 l1
= =
KE 2 l1 l1

KE1
= (0.99)2
KE 2
KE2 = 1.02 KE1
KE 2 - KE1
% change in KE = × 100 = 2%
KE1

24. I : For n = 5, lmin = 0. \ Orbital angular momentum = l ( l + 1) h = 0.(False)

II : Outermost electronic configuration = 3s1 or 3s2. \ possible atomic number = 11 or 12 (False).
5
III : Mn25 = [Ar] 3d5 4s2. \ 5 unpaired electrons. \ Total spin = ± (False).
2
IV : Inert gases have no unpaired electrons. \ spin magnetic moment = 0 (True).

8R é1 1 ù
26.@ P : For Lyman series, n for second line (3 ® 1) = R(A)2 ê 2 – 2 ú = (C).
ë1 3 û 9

3R é 1 1 ù
Q : For Balmer series, n for second line (4 ® 2) = R(A)2 ê 2 – 2 ú = (D).
ë2 4 û 16
R : In a sample of H-atom for 5 ® 2 transition, maximum number of spectral lines observed
(5 – 2)(5 – 2 + 1)
= = 6 (A).
2
S : In a single isolated H-atom for 3 ® 1 transition, maximum number of spectral lines observed = 2 (3 ® 2,
2 ® 1) (B).
27.@ Total energy liberated during tranition of electron from nth shell to first excited state, (i.e., 2nd shell)
= 10.20 + 17.0 = 27.20 eV
= 27.20 × 1.602 × 10–12 erg
hc é 1 1ù
\ = RH × Z2 × hc ê 2 – 2 ú
l ë2 n û

é 1 1ù
\ 27.20 × 1.602 × 10–12 = RH × Z2 × h × c ê 2 – 2 ú ....(i)
ë2 n û
Similarly, total energy liberated during transition of electron from nth shell to second excited state, (i.e., 3rd
shell)
= 4.25 + 5.95 = 10.20 eV

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= 10.20 × 1.602 × 10–12 erg
é 1 1ù
\ 10.20 × 1.602 × 10–12 = RH × Z2 × h × c ê 2 – 2 ú ...(ii)
ë3 n û
Dividing Equations (i) by (ii)
n=6
On substituting the value of n in Equations (i)
Z=3
So, n +Z = 6 + 3 = 9.

Z2
29. IE = = 21.69 × 10–19 J
n2

20902.2 ´ 103 Z2
= × 21.69 × 10–19
6.023 ´ 1023 1
Z = 4.

d d 300 ´ 1000 3 ´ 105

30. C= ,t= = = = 1 × 10–3 sec = 1
t C 3 ´ 108 3 ´ 108
31. In H–atom, 4 lines are observ ed in Balmer series. So, electron is in n = 6(6 ® 2, 5 ® 2,4 ® 2,3 ® 2).
In He+ ion, one line is observed in Paschen series. So electron is in n = 4 (4 ® 3).
(H) 6 ® 2 = (He+)12 ® 4
\ electron in He+ will jump from n = 4 to n = 12.
32. x + e– ® x–
energy released = E.A1 + E.A2 = 30.87 eV/atom
Let no. of moles of X be a
\ a × Na × 30.87 = 6 × Na × 4.526 + 6 × Na ×13.6 + 6 × Na × 12.75 Þ a = 6 moles
33. In the particular excited state of H-atom, path length is five times the de-Broglie wavelength.
\ 2pr = 5l .... (A)
However, path length in a state n is n times the de-Broglie wavelength.
\ 2pr = nl .... (B)
From (A) & (B), principal quantum number (n) of the excited state = 5. Photon having 2nd highest energy
corresponds to back transition of electron from n = 4 to n = 1
This photon will cause an already excited Li2+ electron to go to some higher state. Let the initial excited state
of Li2+ ion be n1 and final excited state of Li2+ ion be n2

é 1 1ù
é1 1 ù 13.6 (3)2 ê - ú
13.6 (1)2 ê -
2 2ú êë n12 n22 úû
\ 1444442 ë 1444
44 û 43 = 1444442444443
Photon having 2nd highest energy Energy absorbed by Li + ion to make
correspond ing to transition n=4 to n =1 in H-atom a transition from n1 to n2

é1 1 ù é 3 2 32 ù é1 1 ù é 1 1 ù
\ 13.6 ê - ú = 13.6 ê 2 - 2ú or 13.6 ê - ú = 13.6 ê - ú
ë 12 42 û êë n1 n2 úû ë 12 42 û êë (n1 / 3)
2 2
(n2 / 3) úû
On comparing both sides,
n1 n2
=1 & =4 Þ n1 = 3 & n2 = 12
3 3
Thus, the final excited state of Li2+ ion electron is n = 12 Ans.

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34. KE1 = Ephoton – BE n = 1
KE2 = Ephoton – BEn = n
é1 1ù
KE2 – KE1 = BEn = 1 – BEn = n = 13.6 Z2 ê 2 – 2 ú = 12.75 (given).
ë 1 n û
\ n2 = 16 or n = 4.
BE : Binding energy.
35. n=4
l = 0, 1, 2, 3
s, p,d, f
So, number of orbitals = s = 1, p = 3, d = 5, f = 7.
Number of elements = 1 × 3 + 3 × 3 + 5 × 3+ 7 × 3 = 48.
36. In n = 3 shell
1s (3s)
3p (Px, py, pz)
5d (dxy, dyz, dxz, d x 2 - y 2 , d z2 )
* S has no nodal plane.
* Each of Px, py, pz has one nodal plane, which means a total of three nodal planes.
* d z2 has no nodal plane and each of dxy, dxz, dyz, d x 2 - y 2 has two nodal planes which means a total of eight
nodal planes.
Hence n = 3, a total of 11 nodal planes are there.
37. Since the change in mass number is only due to the emission of a-particle, we have
234 - 206
Number of a-particle emitted = =7
4
Now the associated decrease in atomic number would be 14 (= 2 × 7) and thus the atomic number of the
daughter atom would be 76 (= 90– 14). But the actual atomic number of lead is 82 e. the atomic number is six
more than expected. This is because of the emission b-particle. Since there is an increase of one in atomic
number due to the emission of one b-particle, we have
82 - 76
Number of b-particles emitted = =6
1
Hence, number of a-particles emitted = 7
Number of b-particles emitted = 6. Answer is 6 + 7 = 13.
38. Dx = 0.1 × 10–9 m.
DV = 5.27 × 10–27 ms–1.
h
\ Dx × mDV = \ 0.1 × 10–9 × m × 5.27 × 10–27 = 0.527 × 10–34.
4p
\ m = 0.1 kg. = 100 gm.
42. Non integral atomic masses of elements are due to existence of isotopes of that element which have different
masses.
43. If photon A has more energy than photon B, then l of photon A must be less than l of photon B. If lof photon
B is in IR region, l of photon A can be in Infrared region or visible region or ultra violet region.

h 6.626 ´ 10 -34
44. (A) l can be calculated as : l = = = 6.626 × 10–36 m. (very small).
mv 1´ 100
(B) de-Broglie wavelength associated with macroscopic particles is extremely small and so, difficult to observe.
h
(C) de-Broglie wavelength associated with electron can be calculated by using l = .
mv
150 150
(D) KEf = 5 + 20 = 25 eV. \ l= KE f = = 6 Å.
25

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