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Study of various factors on which the internal resistance/EMF of a cell depends
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INDEX
Sho. Topics
Introduction
* intemal Resistance
2: Practical Analysis
© Objective
+ Apparatus
* Theory
+ Circuit Diagram
* Procedure
» Result & inferences
+ Precautions
* Sources of error
3. Flowchart Conclusion
4. BibliographyNe,
INTERNAL RESISTANCE @
dnternal resistance is defined as the resistance offered by the
electrolyte of the cell to the flow of ians.
e Jts SL. unit is Ohm (Q)
For a cell of [Link]. (E) and internal resistance (r), connected to
an external resistance (R) such that (I) is the current flowing
through the circuit,
E=V+lr
Internal Resistance r= E-V
IINTRODUCTION
There is a great need of batteries in our daily use
electronic appliances and the use is increasing every day.
Thus , the batteries need to be made more powerful so
that their potential can be increased greatly .
Thus , this project report is based on practical analysis
Jor the factors affecting the internal resistance of a
cell,
When the internal resistance of the cell is decreased
we can increase the potential difference across it, and
hence make it more reliable.PROCEDURE
[Link] the ends of the connecting wires with
sand paper and make tight connections according
to the circuit diagram.
2. Tighten the plugs of the resistance box.
3. Check the emf of the battery and of the cell and
make sure that [Link]. of the battery is more than that
of the cell, otherwise null or balance point will not
be obtained.
To study variation of internal resistance with distance of
separation
4. Keep both the electrodes at a distance of 16 cm.
5. Take maximum current from the battery, making
rheostat resistance small.
6. Without inserting a plug in key K2, adjust the
rheostat so that a null point is obtained on the last
wire of the potentiometer.
7. Determine the position of the null point accurately
using a set square and measure the balancing length
(1) between the null point and the end P.
8. Next introduce plugs in both keys Ki and K>. At the
same time, take out a small resistance (1 — 5 W) from© is inversely proportional to facing surface area of the
electrodes in electrolyte.
® decreases with increase in temperature of electrolyte.
e is inversely proportional to concentration of
electrolyte.
The internal resistance of a cell is given by:
r=(E-V)/I
CIRCUIT DIAGRAM
Power SupplyPRACTICAL ANALYSIS
OBJECTIVE
To study the various factors on which the internal
resistance of a cell depends.
APPARATUS
A potentiometer, a battery (or battery eliminator), two
one way keys, a rheostat, a galvanometer, a resistance
box, an ammeter, a cell (Leclanche cell), a jockey, a
setsquare, connecting wires and sand paper.
THEORY
The internal resistance of a cell is the resistance offered
by its electrolyte to the flow of ions . The internal
resistance of a cell
© is directly proportional to the distance between the
electrodes.Table for effect of temperature
Sno. | Temperanure Ifem) Lfem) Resistance | Internal Tr
TeQ RQ) | Resistance | (QK)
r(Q)
1 12 326.6 276.9 0.456 0.38 | 301.44 |
2. 25 320.7 219.1 0.95 0.38 | 291.96
3 37 660.5 350.9 1.406 0,38 | 283.87
RESULT & INFERENCES
® The Electromotive Force of the cell is constant and
is equal to E = 0.98 Volt.
© The internal resistance of a cell is directly
proportional to the separation between the
electrodes.
® The internal resistance of a cell is inversely
proportional to the area of the electrodes dipped in
electrolyte.
® The internal resistance of a cell is inversely
proportional to the temperature of electrolytes.
© The internal resistance of a cell is inversely
proportional to the concentration of the electrolyte.16. Keeping all other factors constant, decrease the
concentration of electrolyte by adding distilled water
Jor different observations.
17. Obtain three such observations by repeating step
7 to 10. Record your readings.
OBSERVATIONS
Sina. Ammeter Position of null point¢em) Shunt Internat
Reading Resistance | Resistance
(A) With R Without R RQ) r(Q)
(ty) (bp
L 03 660.5 35.5 1 0.94
2. 0.3 660.5 77.2 2 177
3. 03 660.5 108.3 3 2.51
Table for effect of separation between electrodes
Sno. | Separation | Balancing | Balancing | Internal rid
between point point Resistance
electrodes difem) Lfcm) r(Qy
d (cm)
1 12 326.6 276.9 0.456 0.38
2. 25 320.7 219.1 0.95 0.38
3. 37 660.5 350.9 1,406 0.38.the shunt resistance box connected in parallel with
the cell.
9, Slide the jockey along a potentiometer wire and
obtain the null point.
10. Measure the balancing length (12) from end P.
Record these observations.
11. Now keep the electrodes 12 cm apart.
12. Then remove the plugs of keys Ky and K2. Wait
for some time and repeat steps 7 to 10.
13. Next, keep the electrodes 9 cm apart to obtain
another set of observations.
To study variation of internal resistance with area of
electrodes
14. Keeping all other factors constant, increase
the area of electrodes in the electrolyte by dipping
them into the electrolyte at different depths for each
observation.
15. Obtain three such observations by
repeating steps 7 to 10. Record your readings.
To study variation of internal resistance with
concentration of electrolyteBIBLIOGRAPHY
[Link]
[Link]
[Link]
[Link]
[Link]FLOWCHART
CONCLUSION
i Factors Affecting Internal Resistance of a Cell
Area of J Conc, of
Electrodes ! Electrolyte
Inversely | \ Inversely '
Proportional ‘\, Proportional ;
Distance Temperature >,
between i of \
Electrodes | Electrolytes |
Directly i ‘ Inversely Fi
Proportional ProportionalPRECAUTIONS
1. The connections should be neat , clean and tight.
2. The plugs should be introduced in the keys only
when the observations are to be taken.
3. The positive polls of the battery E and cells E; and
E> should , all be connected to the terminal at the
zero of the wires.
4, The jockey key should not be rubbed along the wire.
It should touch the wire genily.
5. The ammeter reading should remain constant for a
particular set of observation. If necessary , adjust
the rheostat for this purpose.
SOURCES OF ERROR
1. The auxiliary battery may not be fully charged.
2. The potentiometer wire may nat be of uniform cross-
section and material density throughout its length.
3. End resistances may not be zero.