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Alcohol Notes

class 12 chemistry chapter 7 handwritten notes

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49 views40 pages

Alcohol Notes

class 12 chemistry chapter 7 handwritten notes

Uploaded by

ronoroazoro747
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
2 ALCOHOLS, PHENOLS AND al a ETHERS ag > Introduction wag ~ Chassipication we > Nomumetaturs ep Struct ~. 7 Physical » re Propo a s., Uses » wo & Snbductinn wm ‘Alwhst we RH Ron AlKane Aleohot » 2 wo ish Section Methans Nethanot s _ CHs-H SA > Cason @ thom Ethane @ cote Fon Sahat ww = Propors Propanst s saploced ‘e? by Sot? Ld B® + Alcohst s s nlp s o : Chane Or + Ether R-o-H GR R-O-K eaxnenr Cg 0 ~Cate Q2Hs-0-C3H> CHy- 0 - CoH Unsymmetsical ether. CH3-0-Cy Cavs -0-Grts Ca3-0-Cg2 Symmutzicat ether ‘> Thay ove fycheony (OH) derivative of Aliphatic Kydreearbor (e-H), Si erro dorivobives a Avomatic Hydlrocanbon w which at grep ouroynatic: ring: @ scanned with OKEN Scanner “Sho 4 Replacing Myce dsiggem saben of tygdrrocestbom ee ot ‘qxernatig) by OF “bkeny Co-R) oc Arytery (O-Mx) gives othe. CHs- Ho CHs-0-R Matha, Sher hy h Soap CHs-0 ether. xc ass icadism / (A) On the, bowls of 0. of OK group CHy+0H or 2-0 CH, - OH i I Menchydic ton du-oH Dinydric bt.-on Fothyauie on oH chy ‘ © co On ‘ oH Menbhy dat — Dihyobuic “Tri ny date. (® On the basis as fee bond. sp? i) Altphatio. Aleohst. ' b & Aliph x oe -¢-0H —C-C-0H ° -G-C-0H ~— -C-G-0n cout T 1 yl ake " ° 2° 3‘ GD Adie. Aleshot . 4 is OA Gas Oe om no CHE -0H Ruylic : f a Conken ateen Cason 4 * a”? @ scanned with OKEN Scanner PEREERPSPCREEEECEECEELUESEREEE “2c 0H H-C-0H e-g-0H Benayli Gertln re 2° 3° (C) On the Baris of C-OH bond L gp? (Se =) W Viruptic Aleshot Vinyti cayedn Chien CH= ou oH On ° Cha= C8 - CHa YH 2 ww "Cx (ata tna SD Simple $F Aydt (k-0 CHs-0-Hy Cre -O-Gile yop \ Both R ww Sam. ° 3 Vinyle alecshot dew nat oir Cy Oy OG. Oinyduc eh . Gy) Mbud ot Unsymmateical.. (k-0-Rk) CHs—0-C2He Cake 0- CaHa Bows RA Rare diftownt @ scanned with OKEN Scanner a ‘aie o- Buy Aloxnot Intent 7.1 ; wo oH Giyorar Lon — Gb) Oty Oa OH OM « CH3~ Cc 0H S ons ‘ ) wo . . i CH wo W). WY) Aveizcn-t-ok Hey Cyne Os tn - ; as On 7 . 3) @) @ ve Ingent_ 3.2. wh & (ut) aw Mlytic aleohots, & Nomenclature gm or tus bypu of ram © commen raring (Aly! Altahot) @ Teac mamin ng ’ Cornpeund, “Common Name. SUPAC_name. CH30H Metlug Alcohd Methanot CH3-CHa- CHa" OH n-Propigt Aleohet | Prepan-l-ot | y- CH- . ck SH, Isopropyl Alcohot "| Propan-2-ct NCH cH CHs- 0H | m-Butye Alcohet - 7 = CHS GR Ha tls |e Bute fleohot tect Bathyt Aleohat 2-muthyl prepan-2-ot Ce OOH ow ' OR=Hsc- H-on | Errylome Htyco | “Et < : Hrlycercet. “Propane 1,2, 3-Totel, ; @ scanned with OKEN Scanner QF oS ae IUPAC & Rule § 7 + iy ee + Primary Supp, & seantoy 3, 3-dimethyl Penkan-2- C-C- c~¢ aw oH = ¢ c C- Ch +09. NaoH ——> c-e-0Hn c t =~ Q oH Benn — 8s : > < ne ci 7 On. NadH X No Rat? aE From Mena Dbuck Hydsation (Acid, coctalyaed tydnation) H0,H* eH 307 4 ‘ | *Marowntkey rule . (2 ov = Raossromgument of coubecaitton alcohee) | Sndinact tyson (Hye Bexakton ‘onidation) oat * Aleahot 2 *BHe ot Cans), Cdivetane) > 12 20, DH7 * Praf-MoxRevuikey- vale. @ scanned with OKEN Scanner BPELEECECEERECECERBCTETEETELITZ (Y® Dict fychratton (Add catadyard hyduation ) . We OH LCHL=OH, +0 > CH, - Ch at *CHy-CH= G1 -CH3 + 120 —"— CHy~CH — CH- CHa. OH Wn Ht eeu oie —t_, Z CHy- = CHa +420 Govrikoy CHa ~ OH CMa on i re C * CHy-CH EC —CHs +H 0 A CHs- CHa C- CH3 crs As. Mechanism (exhene) StepT? { oh 4,0 +4*—+—= 30" yn an : . Chytecta =, Gn tha ta i < y 9 Step’. its GI Wa hs, > ' ont igh ow © M Mechanism [propent) ri nit HO: eae 30° Seg @ scanned with OKEN Scanner . @ 4 SOW En- dt, +¥ dice Constante). StepIn: CHs— CHE CHs + HO: Secceeaaneneees @ Sndiaet Aydsation. (Hydration Oxidation). Genie Bre cMr= Oy @ 202, H20, 087 dy *CH2=CH2z @ scanned with OKEN Scanner VEREBESSRSETEECECTTTEVETTEEITTZ ac, L8H —> Cyc EF CH cr, cx *CH3-CH= CHa Fit Martomitoy SS Ie ae 8 - He O-8 yo Rg Obs 6 eH ne Cand CH He a (Cis Chacha), 8 < B- CHC CH ‘ BOn+ OH CHa - CHa- CH, (hm BS [Link]. + B(ON)s oH . are) Gy Bate q CH Bb t= Fe ono; wom, oe f WOH 4 ° u u Ae Prem Cosbenye Compound, ( Ai) . 9 : On U1 as Reston oe : R=CAH Aldshycte 5 oO Carbonyh w tae Compound Aleohot . R-CER Ketone °o Reducing agent Uy > Ha, Nilpale R- COR eer > NaBHy, H20 : aie Os > ptanny ; H.0Cexpersine) Ro CHOW Consberytic y ¥ ° al " Goxborye Compound a reductten R- CNHs Ald Amide. FR TR A leohot MOST, - e-otH ho Aleehel, @ scanned with OKEN Scanner wr eee & Ketone . Ona ni Rang 2 cad ~ casey, © wagiy Pa 3 7 Dilriy > O-E4 Alcudya ctor | “ Alwhol GATRaT) 4 ar € & Onn on een wate eb cin9 t é ; @einny u 7? te 1 Ou Cs FC, —*— on, Coa (24) 4 7 ee Ketone 1 2° 3 C-C- en ¢ -¢ u ce on c . AMeshot fates é t =e~é- 2G 29) ° H é 4 * LiAtty > Bak > Why 27 . . a ne ts UALRy > UTE Aut” ISA ( w el a : H+ 4H - ow ¢C ied os Wy fy exe BI. ot oreo Aasily. of Ous te) shevter BL $t will not break ea, @ scanned with OKEN Scanner od) » PPUSSSOSS SSCS CCE SGHR GEES = v @ Prem. & fc fciel £ eltens. diem ree sadued de prémony() alcohol by LIAIHy, dn excellent yield. ° 1 R-C-on ° V R-C~OR © NoBHy, cannat ¥eduex Carbory We Arid & ebtens. {paste Xx. R-COOH gua RCH 0H Hal But LIAIHy ds expensive » 80 commurciol aids awe fivct conerdted inte ester and then into Meohel. R’0H I RCODH "> “Rcoor’ =P Reus 0H + R'OH ® From Gougrand Reagents } Sé86 + & Nigx —> >¢- sup ES Cn OH (avignaxct ent R R, (Crammnattia 7 Ma X(oH) fs cae). gnc) w-Cha + Oly Wya-s > We GH a OH Mathanol . ay cH CD. i a. — Ola" Br HtOn™ piaeer Cy CEH + Gutsy 8 CHs~ CH —— @eu- cH @ ‘Ethanol Cats: Gott ls e oNsa s ou N O-Mat —> PMgO tow se Ne ay ieee st Tt CHy=C- ts or Oy ay” CAs fanaa P Atashe Cmethanol) Barry AWA. Ald? 2° Alcott] Ketone —? 3° Heahek @ scanned with OKEN Scanner Bm revit Crom Prom « Holearwne B hon diaxenivmn Cums. maggie “ @ sos Halearans Cla | ATU, & + Noon 28K, O- 3S Om s @ Prem, Benymesulbhonic act CHBby 180) os OH oldum —=_-"_“ 4) NaOH > © 1 O Nad ° apt : 2 NH SONGXT NaNOz ino Oe Oe Cini Arvin Ww @ Crem Camins 4 CH CH-CHs ole tens on On ut . oO ot ao Cm or foe es Gunuet = HU, H,0 /so- pone dlrep exroric Ov prepyt hydlrep evonide ee : & coe L 2 ) 09 0.9.2 AAAAAMAMAMAAAMAAAARAAM be. @ scanned with OKEN Scanner BS Srtext_ 45 O agen ach, BH cHs CH Hs y On 5 . on \ epost TaN me © (CHi-C-OEH;) _NoBHy Onn CONs \ W é u = a Gee ° aS Estes Ester & CA do not React with NaBHy » @ Ciy- CHa - CH-cHo _Nobly , CH3~ CH, ~CH~CH0H ss Cy Hy = Snctext 7.4 J » O Cis-CH~ C24 from methanal. Ns » | = = ig i alee, PI so, GED t MgxCow) H-C*+H i 1 ” ACHO R x b | = Re CH3~ CH-CHs =» = RE genet OF BO ctw + cr cH MBX > wm EW, cry tNgxlon) t ) 1 = Ms cHy-CH as Ht = = = ad = » @ scanned with OKEN Scanner Hayat opus ® Boiling point oT vol point ef Aleohot au hfphur than fydeuocaxbon amd alealkane, * Londen fora < Of pote ~ Dipole < He bonding CHy CHAe CH304 BP he, er & ote . H-—b-R Wobonding * BP & Mot. Mass CH3 0H < C2Hs0H < C3H30H —_ Het. Mos Ter , BP Ten. c-C-C-¢- €- 0H * oF KSA BP ot ni; Branching C-C-c-C-on Gyan Nes ok Bhbes . nt eae, c-0n j = * Phenol tas ale Shows H-bonding Oras =7OH Hoes Go 9 i PEP APA APAAPAA ADELINE YUAAMAAA A 3 @ scanned with OKEN Scanner we fubtle ™ o | slowe alcohol au high sotuble in water. = "Solubility cowasa with énowaae in motreuan noes of afchoh Be beaut of tydvephobic notin of altyt group. : RS *Sotubility 48 dut to H- bonding bfu alenbot 4 urate amatecults. we “ghar alcohol ae Mus soluble because Jorge hyduocorbon pant (#) sualct H- bending. RS - Ringe ew CHO, power = swaitit ts CalsOW | Aloohel » Hydro Sotubl . Phobic = W® 3& Chemical xeadion of eka and Fhenet. = 1 Y | L a PP Ri inuaing > Rx Lrwolvng —- Aloshol as See we ef oH crave beeaking of a. motecule F blige R-ofH To Prene > Roc withx — Adive metals > Dehydeation > Niteation Ra" with Pls, — — Carboxylic Aad + Heated > Halegenation Fs pm aitso, Acid chloride £ > Seiaation ~Sulphonatizn Ws 2k cu NH Acid. Anhydride ~ Priedel craft - Re" with Ns Gaignard Reagent — Heated Copper Al PR withZn > i > Priedel (x » sist AK nadie " potion ee Exomph 7.3 ) Penton—t-ot » Metnanot < ethanet < Propan=|—ot <.Butan-2-0t< Butan-I-at < Pentan-I- of. b) a! N- butane < ethoryethane < entanal € Rertan-I-ve, a ; @ scanned with OKEN Scanner W Chemical Rx *Alechats axe versatile compocind they saat && both as Chectrophile Hi and” Nu ckeephile , “The bond blo O-H do brokan when, alcohol react aa Nuckeophil "The bond Plo C—O is brokun uthen. oleohol reach aa Clack ophili- (W) 0-H CNuctesphiie) R- eon a | ne. R30 Cuong ZN eben a al ew oat QO-c- ot \ c- \ R- Gi) c- of €tectsephitu). R= fn ah es abies Hy > Hao +(R*) tow oe Re o wes Griaket ' '°S behaveas €* (A) feacttons involwing breaking od. ee bend — (D) Rx* swith anetals- aia ~ Alan RO" + No ——> R-ONak + He x7 CH3-OH + Na. —— CH3- ONG +H CoWe-OH +Na—— Cots -ONOt +H, : © 1 S c-—¢-c-0k +Na—> ~c-c~c-0 Nat? +H \ fo Oe \g tA AAAAA r @ scanned with OKEN Scanner CEUUL ELEC EBVO DEE E TEE EEre Nw . Cua + Ng —? (Ch30), Mg cH 3 \ H3-C -0 * CH30H + AL ——> CcHa0)3 AG ay AL Hs chH3 3 ; cis S- Clty a Troy tay —o oe Tg ths Bak Nn Ab- 0-6 ~ CHa HW cH; as ¢ o- AL- O-¢ b+ Wa CHs CMs ie ots Ws c~ CH,-On + Mg -——> («.-Bo.-) Ma +H, 1 2 Hs Lis ~ Phenot On, onal 5 ex's of Aleohees & gm = Cth Phonats wth, metals Sheu thot reg axa auidic in on 8 odie. Alcohols. & Phenotes ln (cs) en Be Bterated Aide d 2 B+ neo-k B-H +:6-8 on Bose Pei gt a © +A — (dS),n + > Addic Nehor o} Aleohat, Wain and Phenot . fae el, © dlsplacement Chemical effect. Rx® 44 ROH > Reo” tHt ritonide > Ph-ow —— H-o tat on oS Hydaoxi de 2 — tH . \_, Phenozide - @ scanned with OKEN Scanner > & displacement effect @ AlKorxidg, ton > Unstabi (RY O— Unstable *Titect ourto +4 aqjuct of Rgroup. 1 = i‘ c @ H-C} = v = Pr 7 CeCe > ce eeO” , Colony i" fe : oe 6 ye 3° Addio Natu es. W)Phumoride ion — @rftobte die 4 Resonancs. gest Hr QS og * Ge LY — Combine effect Aleohol Water “<> Phenat (R07) (n-07) (3) : 3 Addic Natwy . Tes = Aeohot au weokye acid than water clux to dnd uctive Alkyt group. Tu alkyl group has FI CHeet dyelease etecton on Onygen atom & e-densily Nes on Oxygen atom, So, it dees nel farilitar Ht ton to go, Alcohat oe weakor acid than waton, : @ scanned with OKEN Scanner » * Phenol coe stronger add than alcehet , herd Arrays bb @ into red and! weact with NaOH sot*(Nustralisation Px"), den't do ut. Dur to sesenana , the Oxygen ater Acquirs poxtial +ve charge , it weaken the sxyer O-H bend, so H7 Bx easily ruhased. So ,Phunot amt storgen acid . “The phenoniole Left after release of H” isn, iu abbisd by sussnance but abkolioe wn is not. coe ate “otn 205 o-oo - 3 Dus t paatial +ve Charge, 0-H band Weakens. eye: of niillens eo Aciity of altahot Hemel EK (aH/ecHs >-T eect watt 2" pal &O Hg HY. Cee = yer 8 oie Pea iver eater Ce ek Fe 7 e —_— Stability of OPes, Acidic NotwreTes. @..u 4” ft ae Hola > HCE HCO > HCO i b @ ow. er Us = od Addée Necture Nes. VECETESTEEVUEFTFSSFEBEBETsTD @ scanned with OKEN Scanner “Etat of ‘Aeidt Substteunt on Acidity in Prendt. oH oH O < O ee O EDGY a Gun Adidtty “Tes Os Ons o7 oO O < OQ < NO, , CHO, COOH [2- Holgren ,0cHs 38 xin, © push/donat, e° withdraw i bevy ing dn bergen. ing a To ,e7 density So, at 0, e~ density ew bers Wes, St hecomys “unstable Stable. Clctron Wuithdrasing groups e pulls focm bengem ving (Stobulity ) Electron donating group3 e° push an burayent- ving ( Unstabitty ° Electson withdrawi i group. ~Greyps lik No, Ou. COOH dispeud ve Charge amd stablize phunenicy den & ineimes the acidic strength. 7 0- itso phenot is Uitte teas acidic than p- Nitrophencl due tp Int li i * Little cmon ail ee ing, which man oss of H (roten) ? Counter’ tre number of Ehlb, at tho and paxa, mere acidic la athe phenot, ; ie tA AA AAM AAANAAA AA BAM | a Af MAM. @ scanned with OKEN Scanner » Intvamotecutar Mebondl O-nkS 3 ke Qo sail core’) f weet Plager Wear 3 Pe on on qv P s NO "Ct Noe > C7"s NO cy + ‘es tay Uy Nos No; NO, Aelelte Noda Ter. ow on H th 3s Syne cr SUS > © ? hk? * > v8 NO Se Adelle Nature ‘Pea SUGTCCCECTCeTE Solved Exam ple #4, on > troportl Z Ox OO. < "to" crsaudion < i. no NO. NO, rs Acidic. nature Ter. VUEVELEVTEVES @ scanned with OKEN Scanner Reaction with Coxbexylic Acie . ye catfen 9 ° a ne \ Ro) + R-C-ON =—= Ro-d-e +029 Remove Ramat amat shige aad 3 Tee] Y ao ee shift Tee Ra shift, to Forward & S&F H20 tigi a direction CAcc, +0 da Chathien & x x x x x & Principal) = & = Rx® arith Add Hable. : R-OH + RI-C>K == R- took + Rx aR ara 4 lh ogee a9) - WK A base BF yeact eet Nease Ryridine, Pyridi > Rx with Add Anhydride $ TL caren efrar owt Ke : QO ° = R-C-fon + o-t—R a vy Qe Su a 2 x cats WS a bee tebe % 7 Ester Carboxylic a ad : oO A”céol Any docile x Ck-c0),0 x | ‘ @ scanned with OKEN Scanner yvounvvovuevesneaeeeveeveeessencaar — Avatytatlon of Soley Lie Add. Coon coon ot Ww 0- COW; +{CH3C0),0 ——> Saicy ie, A fey (ie ai acd” Chepizin) + CH3C00H 27 Rx® sEnvolutng cleavage 6k C-0 bond sin alephok. QO ducos Test . discussed anCh-6 . @ Ru" sit Pls and Alle {ae @ Dehydration fentol WO? Srtesmeatt formed Corrbocatien axating og CHa — CH2 g=CH, -+H20 H OH ethene ethanet. HaSOy ‘ CCaus0H) —0-S-0-H } 0 4a ‘ oO Rea . iy Oo S 2 sl nas Alcohol Auohet Aleeh oo 0 Luss Temp.) nigh Ter Ww 4 Ny | it, acid Cenc. Arid) @ scanned with OKEN Scanner S ” Cog on _ FE elect “og vy crc 2. - \ A ic ; He f a M I H-ct © Cua stable) \ x S x x t —o-4 Protenated alcehol Cethye oxenium fen) Step 2 ; w no ww W 7 Are. - Stow 2 We ct noe COG SS +" ga 6 +H20 4 “ wn Hn Ww Ee deteremining atep) . fran OG a Ltqutd B pa aiptt ¢@ Scanned with OKEN Scanner bi be aor entopy a emer at VEELEECECCCECTCCCCUCUTC TEs se Step3 HoH nm vl P > =—C : wet a= te *), . “a Wea “ W ut rae 42 4 ier “Ethene aT at atoer fear) (4) Oxidatinn Hw ae —Y wart chsh ag a Or | w " MatoalKare Reduction Vydrocarben a ONY a wwe a on 2-1) o + 42 Noa a ONTe Coe Oxidation u Alcehet (1°) sy -2n) pala oxidising On agent cH eee A a Inteamebeutan “S50 Bobend Ce a Opie 2 : das St lof “ee ‘oH oO (vou m Thtesmotecwan H~bend (Less votattle) » 9h on Se ~essatnn 5 S" No, 2,4, 6- Tsinitrophenct. (bioe acid) GB Holegertion on 3B%,-Water Br. Br ‘ on 38%, + Buby BF Oo 4 214, 6-Trtbremppneno’ ; 9 on [Bvs,csa ae i) Relies CoHe : ceby ey ce Minor CHU Major 0. 0.1.0 ALARA AAMAAAA @ scanned with OKEN Scanner * Kolbe ’s suaction. ‘i J Noo# WO, toe Noor Gi tur 2- Hyde ry benzoic acid Cathy acid) x Reimen-Tremann reaction. on O7Not Ow, cid Qs “cHOs tam NODY lo CHUa | NaoH o Intexmedion capi Gatti) * e With Zn dust tm +20 % Oxidation oH _NozGi209 _s 2804 3G Bengequinone.., te Some camry, sapHEnTE ts grat 4. Mathanot + CH30H, oso Rndum on “wood spit, *Buoduced by desbauctive dittiuation of weed. © CO F 2H, —EPO= C203, oy 0H 260-300 atm 573 -6IBK Benzoic aud " cHo Bengalderyde VEVLESECCEECUCCCCECCCTIT TTI @ scanned with OKEN Scanner Calowrtiss , peisenous iguid * Coils ob B#5 557K, . ‘Tngeatten Ci Small quantity — Blinds Jose quantity — death “Ud os sobventd in paints, varnish amd 4px mai prmatdenyde. t 2. Cthanot. 2 C2Hs OH, obtained by fermentation 6f sugar. “The Sugar ON Motosses i : A » dugarcant OX Puri such as ok cmvertec 49 luce v3 as Grapes TINVERTASE enc ree Pfruchou } wn the presen of Tnvextose CHar0y + 1,0 Sevestoae _, CeHig0e + Chine Glucese Pru close + Glucese end So : > pusc, sundries tation. tn. the Ce Hy 0g Zumt _s 90 y-0H +2002 ¥ - ethanot : ow the source ofr | = Say he ae pt a contol fond Jon pel? Muga amd She ens come ip “Goumentitton takin Place dn abuenee 6? a ‘ “COa do suleaud during Joumentatin % Obe(amasiebis: conditiony) * Boils a ae al yp The cormmorceial aloohol 44 made unfit Ae Te an COPPER SULPHATE & Preioinetin ae re by “anatuzatlon a aleohet. oie a TAAAAAAAAA AAAAAAMAAMAAAAAAAAA! @ scanned with OKEN Scanner Wy Ether (R-0-€) 4 ! J y inert: Unsymmetaical other ether, *CH3-0-C3 +H -O-CoMs BS KEMP pimethet ether Roe > Etta mattypt ether Name TUPAC aeslireny Methoxy methans name” Mothiony ethane SUssTsy = * CoHs-0- GH © Cott =0-Gort Noming ats 3s =a ats Common Name 7 Crhy! Propye ether PNanetEthoxy Propane. UU C A mon Naming mo en, > Diethyl eter aie a wih Iveac se 0 ank-| IUPAC Naming. Pee eT toaincad pus = Ca, -0- » + CoHa -0- Calta cane : os » Comme? = aipunpuyt ether | g7oup” a > BHethy! Bepyt , C. p> merc > Propory propans Name” PMethory prepare Pz x? ; P ~ 2 65 1 _é ze -C-C-€ p Crore. Caoee ey ey 2 2- ethoxy prepans 3- ethoxy Hexane. » ta ep EeDeee ethony c » z 2 1- cthory 2 methyl prepone. i ? Py ? 4 @ scanned with OKEN Scanner Wan CH=CH, CHscHs 0H W Tastt> CHy CHa— O- CHa Ha Joti a ' Sia mechanism mechan 4 i (IP >2%>ar - Mechanism cc. SH + i Saat MS eo lee ca Bo ‘ on 4 an) Ch, CHa~ On + cH eg, Altochig 7 ? Hach, “O™ poy Molecule’ i) ~—— Lavi jon "9 + ho wh CH; CH. Qnty > CHa cts-0- Ooty + At fos 3° Alcohol —> Alone is formed Substitution X, -€temnination SA AAAAAMAAA AAAAAALAPMAAAA AA MM @ scanned with OKEN Scanner J CH3 tH, CH, 0H (| Geroansy — Ganon oe cap + We cant prefer diffoont alcohol because minty ; ether Sy Tr ne o ave ) ® Williomsen ay nthests. j Symmetvical £ Unsymmetrical ethers , Nomiing Ra” : Fallow Sua mechanism. , Re Qnet +, + i — = -R +Nax > Attac Pin tasiy » pei en AlKoxids > * lagi Ge, KD baeie os a » (c- c-0 No 14( CH3-ch. mae C=C 0+ CH PEO SW , Pog Ves + SRY 29,3 @ Maw ws a aa Usa ) 2 » @ scanned with OKEN Scanner SiS AbadR Hough OT s 7» Bronsted Bast (——2_© (accept H*) c (ns - -ONat> + rn cHc- ch © rs SESS °) Cannot atta . ck slung hine Steric Mera, phat ae ‘ 13 C -~Ck ——— Cha - ct + a Chg On CHy — Natt. | —Cc he F wy +H “> CHyOH + Not Oa CHO NO CE yonste as oy 4 OHs-C + Nath + CHZ0H => Soymed A 3° . q S° Alta Hatido. cu, CSal®) (Alcohol) “tt CAitene) Rati oligo alsetse ce ae oly ; } — Pretete lies user AO ORES Oe tpl 3 soba Ox 2 Not Gr GEG @ scanned with OKEN Scanner & Fhypical Beperites "Te C-0 bend uo thes ae polax & thus ithin hawt a suet dipot. moment. GON, eto Cis CH > Polaw motscut 7 Botting point Hydeocorben < ether << Alephat 4 On gr R-O=H ~ He == Rk vibe ® R oat Dipole _ Dippte~ Dipote. < H-bond, Tha ope i in BP. of aloshol & chin eo dur to the prusene He bonding din alcbhof. * Solubility oii) CAlshot) Lather), H-bond on aa ha-b- H R ond ‘eid Fe pepnote he Sips Tea, Solubility bes. > The misctbility { ethow with water stsembles these of alcohols of some roleclan mass. This io -olur the fact that just Like aleohot Orygun of ether Cam fe alte form H-bend with 1.0 moteculy, VETESCESCSEEEECUCSCCCCUSCCTCCT EET @ scanned with OKEN Scanner emnical Fraperities Cleavoge of C-0 pond dr ether. “Sher au tho tart suactive of, the funclismos Gry the Cleaveg’ of C~0 bond sin ether Pak place under : Condition with exces of Hydrogen Holide.C HX). — Symmetrical ethos - 03K 4 OT R-x + R-OH bas - R-on +H'x ——_—-R-X + H,0 Cexcess) > Ungymmetesl_ ha TE RP ok Oo + Hx- —— oO + RK "R- OER" + py Ss ROH + RIX €t> ve ' CHE S~ cate + AIX? > Caltcon FCHX le group @ c-0 hee bond. atgit ¥ Calls 4 O- Cag + HEX” —s GMex + CoH QOH WI> Hbx PHO <—__ Reactivity te : oid Bean Badd, Because: of Bend tenath. @ scanned with OKEN Scanner Hs “ = COE FN Hae C My ‘ O- CH, +h \ CHy Sua 3 3° >Q°>1° chy ‘ alk. ‘4 > CHy-C— O- Hy + OM c (Qh); c- iy L3 Cs HR i <— CHO Ob CR CHs a Elacttophilic ubittttion Kai’ G et area , ut ate CD U abe YOR OR ei QR dj — Gp Ha5-D-8 S ©@ beominatton. 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