a 1charge
DHhyd size
DHhyd of cation x Icharge of cation 1
ration
DHhyd of anion x 1 charge of anion 1
Kinion
DH Total
Mtx Mteag t Xiong
S H2O a n
DH lattice
X hat hydecation
µ
g g
DHhydcanion
DH Total DHealtice t DHhyd cation t DHhyd anion
DHhyd total
DH Total DH lattice 1 DHhyd total
IE T ve
I I Heattice IDHhyd total as DHtot
supports for more solubility
II DH lattice DH total 70
I Dithyd total
does not support for more solubility
Important facts to remember regarding solubility
i All carbonates are insoluble in water except
those of alkali metals and ammonium
Iii Most of the bicarbonates and nitrates
are water soluble
Iii All chlorides and bromides are soluble
in water except those of the
Agt Cut Hg It pb2t
exists in dimeric form as
Hgz2t
Hgt insoluble in cold water
pbUz Pb BK soluble in hot water
Iv All sulphates are soluble in water except
Bas 04,52504 Pb sq Ca504
HgSog Ag2504
insoluble
slightly soluble
V
soluble alkali metals Sir Ba Tet
oxides and hydroxides slightly soluble Ca OH
insoluble others
Solubilities of hydroxides oxides fluorides
bicarbonates and carbonates of alkali metals
increases down the
group
Lif Liao Li OH Li 203
n r n V solubility
NAF Nago NaOH increases
n n n Nazcoz
n v down the
Kf 1 20 KOH K 03
n n n v group
Rbf
n
Rb20
n
RbOH
r Rb2C03
n
V
Csf Cs20 CsOH Cs Coz
Solubilities hydroxides oxides bicarbonates
of
and oxalates of group 2 metals increases
down the group
Beo MgO Cao Sro Bao
Be 0H1z 011122 Ca OH zCSH0H7z BAGH z
ing
solubilities carbonates sulfonates of
of
group 2 metals decreases down the
group
Beso Mgsq Casey 52504 Basq
Be coz Mgc03 Cacoz Bacoz