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SOLUTIONS
Very_short ams type questions CI Mone)
Bl Why aaah species are mine Or ortable tx, colol
water an im Warm wate, C2018?
Ars Sobublaty of omy Aer decreases WHR jacneage in
Lempaatine of water Hence aqmake 5
comporteoble Sw Cobol Water, Cube |
4gee Tem wot
tate He anain, onku ankoge of
Share *tolity ovr naoloaiy a3 the ume g vontnlsodion®
Ans Mofabity, does not Range with Ramge in fempurake
pale bosib clecreases With Use tn temperaline
Mo Goxit ae . Mokabit: =n
Moray Note solution ms) 4 wit of svent
— tn Dabs inka
9203 Whos 4appens when acetone ts added to pure
Ans len acckore is added to ethomo€ , some of
H-bond belween Be chamk molecules break olown
gesuttong mm am inuease nV Ua, PResBUAe of am ixtine:
The muxture show postive dleviabon fom Raguot's 2a
ethan”
C2020)
84 pefene the followin Lem
MotoL CE |
Ars Dib: Ekevaktontn bovking pome
gabe) =m 2 molality,
The defined os elevation im bowling pont
phon He mol ality, of Be so2ntion is warty
Unt > KEG 2BS Gwe 12050n tn the folborsing :
Measurement of osmw tic pee
fn ae dobemiination, bm eee.
he ‘and. polymers’ (2018 :
fre oe . PS etc sos pls mag nctacle
uw Loage even 6% Vay dhuke Some ee tone te
Mauomolecules Auk, jn ane mot gene, .
mehook us pregerseat
os What oe uoton
Ane Teun Sorkin’Bt Awe reason ‘a a followirg
ELevakuon of Bn point
(mM kee 40 Cutco
meorly dowble han a gate a? “hare “a
ke pete
Ars (Be Rem
ane hed an a
ene
Sugar qoludwon LEE vel
DTb ime gobudson is HOUb™ houble
68 Some Beapek on amixeng fom azentropes - ee oe
az eokop> eer GC 20l)
Ae They qe He spenaty Mrs Z ix Lure of 708 wat
composer. g. Beautol amol
Bone He same
vapour phase amd boils ak constant s :64 ° oie, :
AA Tdent-by whick Beaptoe vith Rave a higher vapour
pues ak 9c if the bokin pout of Bun Bayi A
aml B ane (4c and [BC Aispectevely (2022)
Am The Oequtd with a Lowe, boibing
pout hos a hiigka vapour pene
Hence Hawick A Kos igh vapome pene
He vapour pressing of a 8° Ment ofpected
is ’ solvent” caolw)
ele How
when anon volatile wolute
Ars In Gen non vobotihe podabets added t fhe solvent
Vapow, perane of 40luhon becomes Lowe than
ve seas of pure wohrenk at same te mpernbine
Vopout PGl! Define the following Let
Abnowmak mobos mar Qo)
Ars The moZar mors bik & ether dower o Rages
Heo expected a momma value
= Awmocaknn & Dinouzabion
Lace te Dood 2hL
olz What Loppen when we P
paler gpotone 270ehor) Gave eO#ON c2ols>
Art pue 40 osmasis Water molecules move 2. ooet
cok. AS a pearl blood cor swell amch mag even
Busse:Shovt answer type Lanesbions C2morks?
G13 State Hemy's Dow. W&y our bs olelrsect ch
Rellismn in Hae Lank wed by scuba bic ers”.
Ars The pastoll pauwure of the g™ fn vapour phone i
is proportional bo mole fratton of gas 2) m Aodeas
kus Hemg> :
te
= To avotol bends as were Os - tke hloo
é combuatuon of Nogen i» e
aggect of Rah § ecmuse Boutalu
Git Cah i
- fosdoke ae mnnlanity of 4.8% CW/W) Hobution of
4. Are embity of, 40ludrow ts 02g mo" CM obo mars
H,S0y= 984
Ars — Mass oH, S04 = 9-84 Mol
Mo.
mokanty = er gta?
Max% of solution 10°4
ao hes of, Hy S04 = Mans
iaoCon mn = 0s!
2 48 0.1 ae
ee Ape
Density > = Onl K0°P
lame ae
= 2. 1,02M
aeGIS Write fuwo dif,
eene bets é i
mon tdeok *tprmue el Edeok solution and
Ars
Tdeak solution Non-cdkeal solution
L Obey Racnlt's Low 1. Donnt obey Raonlt's
ak ail Lempaature anc Lous ak ale Lemnpacrtine
Contonbrakion amd. concentration
P, =AiG P, #PiX
2 DNemx $¢O
2 LNemumz0
DH mtx =0 DH mixt 0BIG ra He freezeng pome of & solution
mbounions, 604 of fucose Cmolor ras 180g mae”)
in 2503 of waiter Cke f waters Leek rgmot’) (Bole)
Ars .
Ans mars of glucose = 6° oe
of, tim 3 My 3
Morea, wort = 25 0% 1.86 162 xt
Wh) 2 ee
ke = 186 eam
KE AtTbe ausk
Die= ke™ t i
facertngt 100s Hue
age eee
Diez key Wz xloe0
ux Wy a>2Fo5LkGIt Give season
© o.1mkee Bas Reger bouking pom Ham [Link] g@ucose *
© Meat preservedt be Songer time by salting (202?
ArsO = ATezilth™
ki atte” chose b=! : ;
4g abe? tow okuor. of bong x Nod partis
pome
@® Salk comoves water fom oment by pros
Jenown O% osmosis - Since there mo wokr
tba mead , MAHON, anism ore unabte t
gevmenate Ths Deby te stme moat. fa. Long ex Limeaig What is meant by positive deniation fom Raoulk's
Law? Gwe am example. hoe is the sign fm Danix H
$e positive deviation’ (? 1s)
Ars A-B Unk wattriors ae weater
(nterador . Due fo this Vapour P
hick arsnlt w positive deviation from Raoulk's
6g Ethanol + Acetone
Lean A-A amt B-B
nessure Indenses
Law:
AUimix = NE6l4
Fon §%o weution
of Useo CMoLor mars 260g mot)
Coheubok
0 Hh ;
. eee pussuae of go00/e
Mass of Usa ¢p20.08el Lamm oa
5q% 7
4 toond of soe i
[m= eR) : g_0.0821839°
ne
Boor 60% 108
i : Too°
oe = 1 0.082183 °
in ol
= ap.5| atmiE ee
we azertope. What type $ azeobops
formed by poodve deviation fom Raonte's Caw?
c2es>
Gyre am examp' un
topes u famed b
>
Define azertope What £ype% azeo
eregabwe dovtodion from Raoult’s Caw? ave an exam .
Ane Ménemnumn bouling apectope e Etonol* Woe
C4gfoby Nome
on
Maxtemum bo ing azecwope 4 Nit omc Wate
CO8% by moss)G21 Blood cells a ee ee
a yotonme yi 9 Li
spain alba Rapper % ae Soot coll es
a solubion contdining rants
O12z% Nath go@ution ae
© 047. Nach solution
Ave (Lae Note soubor. ( Rypestonic
phood eth, water wilh $oow one of the cell om
would sBaink:
tonic WU sexpert to
wih ae,
a
@ oH Zo Nae goOteon ts Rypo
phook et, water wil fee Cdn ch amd wonle
swell:Foss wheei Vast Hogs gare’ What type of value
nea gm forming the yoluhor Hee sbule
omnolecule undergo C2014)
; (> Dusoctakon © Anoetation ce
| Are Jt bs defied os the sakn of experimental value
of te cothigative proprey ho the caboubabedt value ob
iollizgabve pps, :
ie seve colina Pepa,
Cabeubaked witigoive pope’
O picowaton v7 l
© Anowakar celShort amswer. type TequestionsC>
BQ Some ethylene glswL HOCH,CHOH oe added to
goum ail cooling system along with Skg of water 1 the
feezing pomb of Water - gfyiol soltuon vt -1S%c. hoe &
poking ports of the soduhiom” Cleb= 0-52 lehgmal ke = 86 KG
15% = 1.86% Wax (00°
Am Ate 2 Ise
G2 x 500°
WW, = 2 o
M,, CHocuychon) =6? Ws sA6re
I.
w= kg Il 2 250°$
Alps kb™
2 item
Je ad
BE | Bip: Kb Wax ooo
\ My W
Ste
Mi XH
= 0.SAXZG500x 1085 = 4.19
some
Th= 3734419 2399 rnO24 Ak 300k, 309 of
wse pusont iw a Bhre of Us
solution £08 an osmoée pressure off 4.98 bar. Ty ne
Osmotic pressure of 0. pucose soGution is |/S2bar ak Ane
same Lemperotine,, bot wouldl be us cont
ae et
Rive
om (2018)
Mp2 RT
a se 300%
yagea xRT [s22 Ca RT
Mav
4.49 = 22421
jsrecpht
Teor i
aa ee
Ts2 6 xc, RTB25 Colculote the bovling poimt: elevation fr a
Aud Dn prepared. +4 adehing 10g of Cah, 40.2008 of woter
Clb fr water = oSalckg ol) Moor mars of [Link] 4)
= Ulhg mare
Ars Cah, — Corte DE ott?
be?
Alpe tke ™
5 kgm Wa x 1000
Paxhh
= ax 082n Joe = 0-F0ak
= 200 ae
ALO26 +
3.99 of bonpoie aoid cusolved wm 44 4 of benzene
shows a depression, dn freezing pome of 162k.
Calculate the vant Hoy fate ome predué the noture
of 40 Cube (orsouiabed & duwociabed) - Gwen Mo kar marsog bene
7 leg 249 Keg mat aud |2 24 /met>
me fe kee
Die ze bye Wa rlovo po b6exe2 A
MxW, aa kee
igre ExYaK BA REEP is 050F
: Te 44 oe
pel amowatinO24
7 oe Of F-CH,-Cooh CMolo mors
* FS ant"!
ae a0, of water. tHe ctosion fs
F-Cy, ed. tobe Ic. Calculate dogec ai
7 | -CoOH. C kp of water = Lae ickge Or he
Ars Waly 2 4S3 Mz 248g mot”!
Wh > 50° 3 ce e
. 4.Sk2
Ate = ike ™ 1.86 x!
f pelote
te UKE ae oY c-cH,cook = p-cH coo THT
vy Wh
ea 1+ Cr“ 0% og» olegree S
nog ahion
I = Ex LO 6K IME x Woe 2? No
48 Boo jor el4 C2-N% povece
roasel 4 dosousto
= Lots-!
= 0.045 = #5%‘026 30g of Urea (Mebogmol') is dusoled m S404
of waren . Coleulote the Vapour prssne of water
fot Hes solution of VOpons pussure of pwe walir ok 247%
23-8 nny: (204?
fre My = 399
°
Ky = 8463 Pa = Pax Xa
Muren > 32-20. 2 23.8% Japa
mrwsoten tT NwCE
mr wobue B16.47 223.8% oF
ie as
= 23.8x 094
. [Link] Ha
=B24 Whe 25
~oeSa, bbe ae af sulphur, wos disotuedl im [00
Caleulake {reezing pont i Lowered by 0.3030 é
fowmulaos Se Ck oo
x Che of Cs, = 3.8ak ig mee ‘
mien $,
ine
Ars
Ars Idi = 2.863 Wy = 1004 (2016)
My: %
= B.93K 2.56% 1007
Ale kpexm @-38>x100
Sapeee| savas
M
Ws pipbeceLon mers 5%
we x BP EASE
x > 26 EF
32
Fowmnuda= 58
09.3832 3.85% 2S 6x 1000
My loo|
|
3° AY Yo sokutionCW/W) of sucnose CM= 242g nant /
kh. Cokeubale
7 Pe fos freezing point of 241.15 é
© freezing pomt of 5 70 gf wse CM= [90g moe"! nw /
a 2 ( Facezing pont of pre woken? 275!
Aws Mavs of Suirose = "§ eel
Mays of InNafe 2 [00-4 aon of aoe ci S
cH.) = 489 bacon Nake Cn) = oi
Digs kex™ i
= W, 100? : his 100?
QEBIS- AFIS ken Meee pres kee be xt
: Ux leek 21S. SSK 102?
; Kets 46 Atle e4S4le eo 45
- i nb 2 REBAS
Ire = 15.58 Kkgmet 1 freezing parka tre!
a 2268: 61kG3! the a uh
ae Vapour pressure of pure BiapihX amd pure Eaubel V
care [20mm of Ha and \6omm of Hg res actively
FY equal moles of Xamd.y axe mixed to form am Edeok solution.
Cakeulake He vop ovr pressure of he whidion? (202
a : amos
— No of emobes of K oma Y= Vv. Pq pure Leaicr * CPx)
:
Moe fraction X= 2 = = |2omm Hg
| Moke fraction g y= V-P 4, puse aA toy cry)
sraeol welubion __ a
: we Pet -
| panubts daw [otalpeame Ene Bay,
2 20xb4 Wort
| 2 6or8°
. Womm Hsci iinsuaaiaennaueemaueueeeennne
B32 OWRy ts the value of Van't Ho :
ackd in 4 enzene chose youn i ca
| @ petamine He osmotic presure Ho ere
ab olisrolving 2.32 xg o IeeSOn Gn QL of, s0CueiOw o£ 28¢)
orbuming Kiso ts completely aingctated’. Ce
|
Ans two morecubes of the ethamote ath amotake
| =O In benzene
ze form dime
2CH,CooK = (CH,COOH2,,
ge Numba solute particles in olution
qreoretical number sebate portirtsacid tn benzene chore 05°
@ petarmtne the osmotic piers ure oO solute
by oiissobving 2. 32 X10" hy k,$0u mn 22 of 20
| arsuming 8 son % comp Lotely dinociated’.
ass O Why 1 the value of Var't Ho fate §% ethancie
|
ar
foes a,
(2023)
amos
Arg
| ABs @D We 232x107 “a Te ase oot Mo Lar mars KS?
Ve ak gg BAKDE BAEK
| kz $04 ak + Sour eres
ies ta"
| re ee kT\
tm pet
= 4g x10 atm
= 3K 2:32K8 0.08 2x 298
UFY XZ833 A solution is prepared by olissolrving 10g of nonvolatile 7
H00uLe in 2003 of water: Tt kas a Vopow. ALAE URC |
31.84 mm Hq af 308k- Calculate the molar mors of he wote
Vv ater ak 308 | = 32mm) ©
Abs Cae eRe *" (ae2s)
= Wye log Pye 32mmHy My = 18g Ine aManks
2
Wy = 200g P= BiBummHe = My =
PoP. %: 7
ae a | Caitude solotan )
a antms
° a M7778
mh. Bs
ats aa 32-31-84 = ley JB
pe Ba Mz 20>
Pi-Pr 2 WaxMi ole cyte My = WRB
PI M,xW), 32 MM, 20 o-16x20 |
| = Wog ine?
4than that of IM glucose solution
© Amon volodtbe solute XC Molar mar = So
when oliroolved in #83
40%. Colonkate te mors
moh")
benzene reduced UA v OpoUr prsome
ox olisokvech mthe so Lution- (20239
o °° BM, |
| Ans © + Nate % £onie amd. vom etoly dismodate 4 f
give 2 éons px molecule whick & not postbte m
vant Hoff sale be a faNa ce and && | for glucose
Alp = tkyem
Tnoeose En boifing point Dil be mate fri Nace than
CLntorefe © Why ts the boiking point: of IMNaLe solution. mate
than that of IM gfusose olution
@ A nonvolatile yobute XC Molar mar = sogmo£”!)
Ben olissolved bn 789 of benzene seduced. 1 vapour presure
4 0%. Colcuhote the mor % X dlosokve mthe so Lution-
(2023)
- Maal,
An @ Ne=? My= 50g met! y2 CoH Se
Wi= #83 roo moved Benzene C= 6 M6 é 78g ime!
VP benzene CEL™ oe
‘ 3290! GF! . °
V.P 4 So@etion CP 0.4 Fe OAPi = We pZP
° PY Soe
5, = te WexMs
Om Me A olP 1. We
ies.
a
1
W, = 9:
Isp