13/11/2024

rotation
Berry pseudo
A mechanistic pathway for theswapping of axial and equatorial ligands they
-
become equivalent
if is the same ligand.

·...
⑧

⑧
·
· ·
The
equatorial plane dynamically changes due to energy
in the atmosphere.

Redox Reactions in coordinate complexes .

In the reaction
CoC
(NH3)s
-
+
corc , Cut
The cobalt atom acts as an oxidant and Oxidizes

mechanisms
This happens using two

1) Inner sphere : uses a bridging ligand

tunneling through
uses electron a solvent .

2) Outer sphere ,

⑧ ⑧

· O
c
-
⑧
O
O

G
O
·⑧
&

"products
①

·
- : It -
Reactants. G
⑧

O · It
·
·

..
precursorex O O

·
successor
⑧
O complex
It
-

..
·
1 #Ligandmovesinterested
O ⑧ ligand,
G & O

o
⑧
O
-
&
O

G
· &
e-

O
⑧
⑧
G O O
⑧
electron flows
from lower
oxidation state to
state.
higher oxidation
 available .
bridging ligands
are
This mechanism
of
is used when there are
ligands which
examples bridging ligands are :-

1) n].
-
Ni

* 4, 4
bipyridine . M/
19

man n=
M

dimethyl pyridine
N
,
N
.

have two sites which can bind to two different metals.

Bridging ligands binding
In of non-availability of bridging ligands outer sphere
case ,
mechanism is used .

-
positive charge

⑧
①
O
O ⑧
G &
oo

·
· Reactant .

O Precursor
⑧ complex
O
6 ⑧

·
G &
①

⑧
O
electron
O O tunnels in
6 ⑧
solvent

·.. 6
⑧
⑧
O

O
Successor
complex.

·..
①
O
⑧ positive charge
G & O O
⑧
6 product

outer sphere
mechanism .