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FOCUS ON GEMSTONE FLUORESCENCE: LOOKING FOR

THE LIGHT
Published in Gem Knowledge

Most of us know about fluorescence in gemstones, but how many use it as part of their
gemmological testing routine? Here, Gem-A gemmology tutor Lily Faber, FGA DGA EG, delves
deeper into fluorescence and explains why it can be both enlightening and enjoyable for
gemmologists.

Luminescence in Gemmology
When we use the term luminescence in gemmology, it generally refers to the term photoluminescence,
which is the emission of a cold, visible light when a gem material (or general substance) is excited by
light of a shorter wavelength. Two examples are fluorescence and phosphorescence.

Fluorescence occurs when a gem material is illuminated by radiation of shorter wavelengths with higher
energy.

A bag of cubic zirconia under LWUV with areas of blue fluorescence that highlights the presence of diamonds.

The visible light emitted stops when the source of illumination is turned off. Phosphorescence, on the
other hand, is a visible light that is emitted by a gem material after the original source of exciting
radiation has been switched off.

THE HOPE DIAMOND PHOSPHORESCENCE

A famous example of a gemstone that strongly phosphoresces is the blue Hope Diamond, which glows a
bright red for several minutes after being excited by short wave UV light. Both fluorescence and
phosphorescence can have varying strengths from very strong to weak. If a material does not either
fluoresce or phosphoresce, it is considered inert.

Quartz under LWUV showing oil inclusions.

The History of Gemstone Fluorescence

Fluorescence has been observed for years, but it was not until Sir George Stokes extensively
documented this effect in relation to gemmology that it officially became part of the scientific lexicon. In
1852, Sir George coined the word fluorescence, named after fluorspar, more commonly known as
fluorite, which is a highly fluorescent material.

The ‘Stokes Law of Fluorescence’ or ‘Stokes Shift’ states that the fluorescent emission of light will
always be that of a longer wavelength than the excitation source, i.e. the light emitted is of a lower
energy than its excitation source.

Why Use Fluorescence to Test Gemstones?

Fluorescence can be a helpful tool when used correctly. Some gemstones have a characteristic or, very
rarely, a diagnostic reaction to UV light. One gemstone that notably both fluoresces and phosphoresces
is a diamond, which typically fluoresces blue in longwave UV light and then phosphoresces yellow.

This is a diagnostic result for a colourless to yellow diamond in the Cape series (Type Ia), but please be
aware that fluorescence is rarely diagnostic as reactions may vary wildly within the same species or
variety of gemstone.

READ MORE: The Fascinating History of Platinum

Fluorescence can indicate or confirm the identity of a stone. For example, citrine quartz is inert to
fluorescence due to the presence of iron, which eliminates fluorescence. If you are testing a yellow
stone that may potentially be a citrine, and it fluoresces orangey-yellow under LWUV and red under
SWUV, it cannot be a citrine and is more likely to be a scapolite.

Scapolite from Ontario under LWUV.

Other reasons to use fluorescence? It is quick and normally takes less than one minute to observe
reactions. You can test gemstones that are loose, set, rough or fashioned, and you can test either single
gemstones or multiple gems at the same time. Finally, it is entertaining!

How Does Fluorescence Occur in Gemstones?

Ultraviolet light (UV) is the most commonly used excitation source. We cannot see UV light as it sits just
below the visible light spectrum (400nm- 700nm) at 10-400nm. UV light enables us to see fluorescence
because a gem material will absorb this radiation source and then emit light that is lower in energy and
therefore visible to the eye. But what is actually happening within the gemstone itself to elicit such a
colourful reaction?

It has to do with electrons. When electrons are excited by a source of radiation, they jump to a higher
energy level around the nucleus of the atom. The excited electron remains in this excited state for a
short period of time until it falls back to its original ground state. As the electron returns to its ground
state, it emits energy either as heat or as visible light (fluorescence).

A: Natural spinel, red paste, synthetic verneuil ruby, almandine garnet and two natural rubies.
B: The same stones under LWUV. C: The results under SWUV.

If you are wondering if all minerals fluoresce, the answer is no. Only 15% of all known mineral species
exhibit this effect, the causes of which can be very complex. One of the more better-known and
documented causes is the presence of activator elements that can be excited by higher energy
wavelengths.

Some activators include chromium (Cr), uranium (U), manganese (Mn), lead (Pb), titanium (Ti) and rare
earth elements (REE). Some elements are considered to be the complete opposite, however, and when
present they eliminate or quench fluorescence, causing a gemstone to be inert. Common quenchers
include iron (Fe) and nickel (Ni).

Kunzite under SWUV.

Using UV Light to Test Gemstones

The types of UV light used in testing are long wave (LWUV) with a principle wavelength of 365nm, and
short wave (SWUV) with a principle wavelength of 254nm. Different testing equipment ranges from UV
keyrings (typically LWUV) to a UV viewing cabinet. When using UV light to test gemstones, it is
important to remember that any exposure to UV light can damage your eyes, but particularly use caution
when using SWUV as it is more dangerous than LWUV. Always wear protective UV goggles or ensure
that your UV cabinet is installed with an eyepiece that filters out UV light.

To properly use a UV keyring, take the following steps:

Never look directly into the light

Turn off surrounding lights so you are in a dark environment.

Place the gemstone table-down if facetted. If table up, the gemstone may reflect the UV light into your
eyes and creating confusing, conflicting or inconclusive results.

Hold the keyring approximately two inches away from the stone and, if testing multiple gems, always
be consistent with the distance at which you hold the light.

Record whether the stone is inert or fluorescing, and the strength of the reaction.

Sometimes you may see some dull purple or red light in the gemstone or on a few facet edges. This
means that the gemstone is reflecting the purple UV light and is not itself a fluorescent reaction.

A: Synthetic verneuil sapphire, scapolite, natural sapphire, topaz and citrine. B: Under LWUV. C: Under SWUV

Understanding Fluorescence Results

While fluorescence is not a diagnostic test, and results can vary dramatically even within the same
gemstone species (variable emerald results, for example), it can be a useful indication of what a
gemstone is. When testing diamonds and colourless, transparent simulants, keep the below chart in
mind.

When testing red to pink gemstones,do keep in mind that natural rubies in particular may have variable
fluorescence based on their iron content. If iron is present, the ruby will have minimal to no fluorescence.
Synthetic rubies tend to have much stronger fluorescent reactions.

When testing green gemstones, fluorescence can be tricky to use for identification purposes. However, it
may be useful in terms of recognising the presence of fillers in emeralds or green jadeite jade, for
example.

Some resin fillers fluoresce a whitish colour under LWUV and if this reaction is seen in either of the
aforementioned stones, it may be an indication that filler is present, especially if the fluorescence is
concentrated in seams or certain areas rather than being evenly distributed across the stone.

Note the natural emerald fluorescing a whitish colour (second from right), hinting that a resin filler may
have been used. Further testing will be needed to confirm this possibility.

Left to Right: synthetic flux emerald, synthetic hydrothermal emerald, natural emerald, chrome diopside.

Additionally, natural emeralds, if they do fluoresce, will have a red to inert reaction under LWUV, and a
weaker inert or green reaction under SWUV. Synthetic emeralds may fluoresce red or, in the case of the
synthetic hydrothermal emerald, they may be inert if doped with iron to imitate a natural inert reaction.

Untreated green jadeite does not fluoresce, so any other reaction should be regarded with suspicion and
further testing will be needed. When testing yellow gemstones the bottom chart may prove useful.

Conclusion - Fluorescence in Gemstones

As is evident, fluorescence can be a helpful tool when testing gemstones, though not always diagnostic.
It is a quick test that is one of the more exciting ones in the world of gemmology. ■

All images courtesy of Lily Faber and Gem-A gemmology tutor, Pat Daly.

COLOURLESS GEMSTONES LWUV SWUV

Strongest reaction, most common is Similar colours to LWUV but it is a

Diamond (natural)
blue, but can be yellow and green weaker reaction

Similar colours to SWUV but it is a Strongest reaction, mainly fluoresce

Diamond (synthetic)
weaker reaction orange to yellow

Weak to inert (usually inert) but same Moderate to strong yellowish-orange

Cubic zirconia
colours as SWUV, yellowish-orange. (apricot), variable

Synthetic moissanite Variable reactions Variable reactions

Synthetic spinel Inert Bright, chalky white or blue/green

Paste Inert Variable, may have chalky white surface

RED AND PINK GEMSTONES LWUV SWUV

Same as LWUV but weaker to inert

Ruby (natural) Variable, strong red to inert
reaction

Bright red, tends to be stronger Red, weaker than LWUV but still brighter
Ruby (synthetic)
than natural ruby than natural ruby

Red spinel Red Red, but weaker than LWUV

Spodumene, var. Kunzite Orange or violet Weaker violet, whitish or inert

Almandine garnet (Iron is present, this stone

Inert Inert
never fluoresces)

Red glass/paste Inert Variable, may have chalky white surface

YELLOW GEMSTONES LWUV SWUV

Quartz, variety cirtrine Inert Inert

Yellow sapphire (natural) Apricot orange to inert Inert

Yellow sapphite (synthetic) Weak red to inert Inert

Yellow scapolite Yellowish Reddish

Yellow topaz Yellowish Whitish

This article originally appeared in Gems&Jewellery Summer 2018/ Volume 27/ No.2

Interested in finding out more about gemmology? Sign-up to one of Gem-A's courses or workshops.

If you would like to subscribe to Gems&Jewellery and The Journal of Gemmology please
visit Membership.

Cover Image: Willemite and calcite fluorescing under SWUV.

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