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Key Addition and Condensation Polymers

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0% found this document useful (0 votes)
72 views2 pages

Key Addition and Condensation Polymers

Uploaded by

Kartik Bhure
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Commercially important addition polymers*

Name of the Constituent Structure of Important Application of


polymer monomer the polymer properties of the polymer in
(type) polymer common life
Low density Ethylene [CH2–CH2] n Density is low Pipes, water lines,
polythene H2C = CH2 (LDPE) insulation in cables.
(homopolymer)
High density Ethylene [CH2–CH2] n Density is high Toys, household
polythene H2C = CH2 (HDPE) articles, laboratory
(homopolymer) apparatus.
Polyvinyl chloride Vinyl chloride – CH2 – CH– Resistant to acids and Adhesives, coatings,
or PVC H2C=CH | bases. Insoluble in fibres, cheap plastic
| Cl n
(homopolymer) water, alcohols and cables and pipes.
Cl
petroleum ether
Polyacrylonitrile Vinyl cyanide – CH2 – CH– Resistant to oil and Electrical and
(homopolymer) H2C=CH | electrolytes cooking ware
| CN n
CN
PolyvinylbenzeneVinyl benzene – CH2 – CH – Poor resistant to Moulded containers,
or polystyrene H2C = CH | weather. TV cabinets, toys,
(homopolymer) | C6H5 n Becomes yellow in air. foamed plastics,
C6H5
insulating material.
Polyvinyl Vinyl pyrrolidone –– CH2 – CH –– Resistant to strong Additive to basic
dye. |
N
pyrrolidone H2C = CH | | chemicals. Deepener to the
(homopolymer) | H2C CO Life saving as colour of dye.
C4H6NO | |
H2C CH2 n blood plasma
|

Polytetrafluoro Tetrafluro [F2 C  CF2 ]n Resistant to acids, Cooking ware,


ethylene ethylene bases and organic lubricant, electrical
or Teflon F2C = CF2 solvents. Strength is insulator.
(homopolymer) unchanged with
temperature
Polymetyl– Methyl CH3 Plexi glass, Substituent to glass,
methacrylate methacrylate | which is unbreakable decorative articles.
–H2C–C ––
or PMMA CH3 | material
(homopolymer) | O
H2C = C |
| CO
OCOCH3 |
CH3
n

Polypropelene Propylene –H2C – CH – Relatively stiff and Pipes, cables, fibres,


(homopolymer) H2C = CH | hard toys and ropes.
| CH3 n
CH3
Commercially important condensation polymers*
Name of the Constituent Structure of polymer Application
polymer monomer(s) (important property) in common
(type) life
Nylon 6 Caprolactum [NH  (CH 2 )5 CO]n Textiles, tyre
or perlon L CH2 – CH2 – CO (High electrical resistance, antiabravisive) cords, ropes
(homopolymer) CH2 | |
| CH2 – CH2 – NH

Terylene or Terephthalic acid Ropes, tents,


Decron or (PET) –OC COO CH2 – CH2 – O – safety belts,
Polyethylene HOOC COOH n tyre cords
terephthalate (Resistant to water, but attacked by NaOH)
(copolymer) Ethylene glycol
HO–CH 2–CH2–OH

Glyptal Phthalic acid Paints,


– OC COO CH2 – CH2 – O –
(copolymer) HOOC COOH lacquers

Ethylene glycol (Resistant to water)


HO–CH 2–CH2–OH
Urea- Urea [HN–CO–NH–CH2] n Laminated
formaldehyde H2N–CO–NH2 (Resistant to water, solvents and has high sheets,
resin Formaldehyde mechanical strength) unbreakable
(copolymer) HCHO cups
Bakelite Phenol OH Gears, prote-
(copolymer) C6H5OH CH2 c t i v e
coatings,
Formaldehyde n laminations
HCHO
(Cures under pressure and bonds layer firmly)
Melamine- Melamine Unbreakable
HN N NH–CH2
fromaldehyde H2N N NH2 crockery
(copolymer) N N
N N
NH
NH2 n
Formaldehyde
HCHO (Stiff and hard material)
Polysiloxane Dihydroxydimethyl R R Surface
(homopolymer) silane coatings in
R HO Si O Si OH aeroplanes,
HO Si OH R n R missiles,
R (High thermal stability. Polymer is aswaxes
available in solid, liquid and gas phases)

Common questions

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Polysiloxane's high thermal stability is crucial for aerospace applications because it can maintain structural integrity under extreme temperatures encountered during flight. Its availability in solid, liquid, and gaseous phases allows versatile use in various components and systems, such as surface coatings that require different physical states for application and performance .

Terylene's resistance to water makes it a highly durable material for textiles and safety equipment such as ropes and tents, which are often exposed to moisture. However, its vulnerability to NaOH means it can degrade upon exposure to strong alkaline environments. This necessitates caution in its use around such substances, potentially limiting its application in settings where alkaline exposure is likely .

Urea-formaldehyde resin plays a critical role in manufacturing laminated sheets and unbreakable cups due to its resistance to water and solvents, as well as its high mechanical strength. These properties make it an excellent choice for products that require durability and stability, such as laminated sheets, which must withstand environmental conditions, and unbreakable cups that need to endure frequent handling and washing .

The main factors allowing polypropylene to be used for stiff and hard toys and ropes include its relative stiffness and hardness, which provide the necessary durability for toys and ropes. Its chemical resistance also adds to its suitability for such uses, making it maintain its properties over time even with exposure to various environmental conditions .

Glyptal is suitable for use in paints and lacquers due to its resistance to water when dry, providing a protective and durable finish. Its chemical composition allows it to adhere well to surfaces, making it an effective choice for binding pigments and providing a continuous layer when applied .

Low-density polyethylene (LDPE) is suitable for use in water lines and cable insulation due to its low density, which makes it lightweight, and its flexibility, allowing it to be easily molded and shaped. Additionally, it provides good resistance to moisture and has excellent insulating properties .

Polytetrafluoroethylene (PTFE) is highly resistant to acids, bases, and organic solvents, making it ideal for use in cooking ware, lubricants, and electrical insulators where chemical resistance is crucial. In contrast, polyacrylonitrile (PAN) is resistant to oils and electrolytes, which makes it more suitable for applications such as electrical cooking ware. While both offer chemical resistance, PTFE is more versatile in its resistance to a wider range of substances .

Bakelite is used in gears and protective coatings due to its ability to cure under pressure, which ensures a strong and durable bond between layers. It also has good mechanical strength, making it suitable for heavy-duty applications like gears. Its resistance to electricity and heat allows it to be used in protective coatings where these properties are crucial .

Polyvinylbenzene, or polystyrene, is unsuitable for outdoor applications despite its wide usage in moulded containers and toys because it has poor resistance to weather, including ultraviolet light exposure, which can cause it to yellow and degrade over time. This limits its use to primarily indoor applications unless stabilized or modified .

Polyvinyl Chloride (PVC) is considered important for making cheap plastic cables and pipes due to its resistance to acids and bases, making it durable in various chemical environments. Additionally, PVC is insoluble in water, alcohols, and petroleum ether, adding to its suitability for these applications. Its cost-effectiveness further enhances its usage in such applications .

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