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Introduction to Materials Science Concepts

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10 views44 pages

Introduction to Materials Science Concepts

Uploaded by

nhoxcry098
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

CHAPTER 1: INTRODUCTION

1.1 Materials science and engineering


1.2 Why study materials science and engineering
1.3 Classification materials
1.4 Atomic structure and Interaction bonding
1.5 The structure of crystalline solids
1.6 Imperfection in Solids
1.7 Materials Structures

1
MATERIALS SCIENCE AND ENGINEERING

2
1.2 WHY STUDY MATERIALS SCIENCE AND ENGINEERING

3
APPLICATION
[Link]

Various composite materials


are used in structures such as
the Boeing 777 because of
their strength, and weight
savings. Composites also offer
resistance to fatigue, corrosion
and impact damage.
4
CHAPTER 1: INTRODUCTION
1.1 Materials science and engineering
1.2 Why study materials science and engineering
1.3 Classification materials
1.4 Atomic structure and Interaction bonding
1.5 The structure of crystalline solids
1.6 Imperfection in Solids
1.7 Materials Structures

5
1.3 CLASSIFICATION OF MATERIALS
[Link]

Metals

Composites

Ceramics Polymers

6
CHAPTER 1: INTRODUCTION
1.1 Materials science and engineering
1.2 Why study materials science and engineering
1.3 Classification materials
1.4 Atomic structure and Interaction bonding
1.5 The structure of crystalline solids
1.6 Imperfection in Solids

7
1.4 ATOMIC STRUCTURE
made up of protons, electrons and neutrons. The protons and neutrons
make up the nucleus of the atom, which is surrounded by the electrons
belonging to the atom

 Proton and neutron, m = 1.67 × 10-27 kg


 Electron, m = 9.11 × 10-31 kg 8
ELECTRONIC CONFIGURATIOM

9
ELECTRONIC CONFIGURATIOM

10
PERIOD TABLE

11
CHAPTER 1: INTRODUCTION
1.1 Materials science and engineering
1.2 Why study materials science and engineering
1.3 Classification materials
1.4 Atomic structure and Interaction bonding
1.5 The structure of crystalline solids
1.6 Imperfection in Solids

12
1.5 STRUCTURE OF CRYSTALLINE SOLIDS
Mạng lưới tinh thể (cấu trúc tinh thể) là mạng lưới không gian ba chiều trong đó các nút
mạng là các đơn vị cấu trúc (nguyên tử, ion, phân tử ...)

a) Mạng tinh thể b) Mặt tinh thể c) Khối cơ bản

* Đặc điểm tinh thể


+ Có hình dạng xác định
+ Có nhiệt nóng chảy xác định, không đổi trong suốt quá trình nóng chảy
+ Có tính di hướng tức là tính chất theo các phương khác nhau là khác nhau
13
UNIT CELL

A unit cell is the smallest portion of a crystal lattice that shows the
three-dimensional pattern of the entire crystal

Unit Cell
14
1. Hằng số mạng: a, b, c, , , 

2. Số phối trí: số nguyên tử gần nhất bao quanh mỗi nguyên tử kim loại.
3. Độ đặc khít:

𝑉𝐶 4
𝑃= , 𝑉𝐶 = 𝜋𝑟 3 : thể tích quả cầu nguyên tử
𝑉ô 𝑐ơ 𝑠ở 3

15
MILLER INDEX
Miller indices can be used to specify directions and planes in a crystal.

[hkl] a direction in the basis of the lattice vectors


{hkl} all planes that are equivalent to (hkl)
<hkl> all directions that are equivalent to [hkl] symmetry

16
MILLER INDEX

17
SIMPLE CUBIC (MẠNG LẬP PHƯƠNG ĐƠN GIẢN)
[Link]

1. Số quả cầu trong một ô cơ sở: ? 1


2. Số phối trí của mỗi nguyên tử kim loại bằng: ? 6
3. Độ đặc khít: ? 52%

18
BODY CENTRAL CUBIC (BCC): Mạng lập phương tâm khối

1. Số quả cầu trong một ô cơ sở: ? 2


2. Số phối trí của mỗi nguyên tử kim loại bằng: ? 8
3. Độ đặc khít: ? 68%

19
FACE CENTRAL CUBIC (FCC): Mạng lập phương tâm diện

1. Số quả cầu trong một ô cơ sở: ? 4


2. Số phối trí của mỗi nguyên tử kim loại bằng: ? 12
3. Độ đặc khít: ? 74%
20
HEXAGONAL CLOSE-PACKED CRYSTAL STRUCTURE

(a) a reduced-sphere unit cell (a and c represent the short and long edge lengths,
respectively), and
(b) an aggregate of many atoms

1. Số quả cầu trong một ô cơ sở: ?


2. Số phối trí của mỗi nguyên tử kim loại bằng: ?
3. Độ đặc khít: ?
21
22
DENSITY COMPUTATION

Problem 1: Copper has an atomic radius of 0.128 nm, an FCC crystal structure,
and an atomic weight of 63.5 g/mol. Compute its theoretical density, and compare
the answer with its measured density

23
STRUCTURE OF CRYSTALLINE SOLIDS
1. Single structure
2. Polycrystalline
3. Anomalous
4. Amorphous

24
Anomalous

25
X-RAY DIFFRACTION
X-rays are a form of electromagnetic radiation that have high
energies and short wavelengths—wavelengths on the order of the
atomic spacings for solids

26
BRAGG’S LAW

27
BRAGG’S LAW

28
BRAGG’S LAW

29
PROBLEM

30
CHAPTER 1: INTRODUCTION
1.1 Materials science and engineering
1.2 Why study materials science and engineering
1.3 Classification materials
1.4 Atomic structure and Interaction bonding
1.5 The structure of crystalline solids
1.6 Defects in Solids

31
1.6 DEFECTS IN SOLID
Defects have a profound impact on the macroscopic properties of materials
Sometimes defects are deliberately created to improve properties of crystal

32
POINT DEFECTS

Point defects are the irregularities or deviations from ideal


arrangement around a point or an atom in a crystalline substance.

33
VACANCY DEFECT
A vacancy is produced when an atom is missing from its original lattice site.

Perfect Crystal Vacancy – Point Defect

 Atom missing from an atomic site


 Occur due to imperfect packing during crystallisation
 Decrease in density of the substance
 Number of vacancy defects depend on temperature
34
INTERSTITIAL DEFECT

Interstitial defect

 Addition of an extra atom within a crystal structure


 Causes atomic distortion
 Decrease in density of the substance
 Vacancy and interstitials are inverse phenomena
35
FRENKEL DEFECT

 Occurs only when cations are smaller when compared to the anions.
 Combination of vacancy and interstitial atom
 No change in the density
 For example: AgI and CaF2

36
SCHOTTKY DEFECT
caused by a mismatch between the number of cations and anions

 Pair of anion and cation vacancies


 To maintain electrical neutrality, the number of missing cations
and anions are equal
 Decrease in density of the substance
 For example, NaCl, KCl, CsCl and AgBr 37
LINE DEFECT
Irregularities or deviations from ideal arrangement in entire row lattice
points.

 Interatomic bonds significantly distorted in immediate vicinity of


dislocation line.
 Dislocation affects the mechanical properties
38
Edge dislocation: Occurs due to absence of extra half plane of atoms
or presence of half plane of atoms.

Screw dislocation: The lattice/atomic planes follow helical (xoắn ốc)


or spiral along the dislocation line
39
SURFACE DEFECT

 Surface defects are associated with boundaries that are separate


regions of the materials and have different crystal structure.
 Two dimensional defect
 Change in orientation of the atomic planes and stacking sequence of
atomic planes.
 Caused during solidification or mechanical or thermal treatment of
material.
 Effect the mechanical properties, electrical resistance and corrosion
resistance.

40
GRAIN BOUNDARY

 Regions between two adjacent grains.


 Slightly disordered
 Low density in grain boundaries: high mobility and high diffusivity

41
TWIST BOUNDARY

 Rotation axis is perpendicular to the boundary plane


 Low angle grain boundaries.

42
STACKING FAULT

 Formed by fault in the stacking sequence of atomic planes in crystals


 Low angle grain boundaries.

43
VOLUME DEFECTS
1. Percipitates (kết tủa): fraction of a micron in size
2. Voids: trapped gases; decreases mechanical strength
3. Inclusions: foreign particles or large precipitate particles; undesirable;
harmful.
4. Dispersants: may be large precipitates, grains, or polygranular
particles distributed through microstructure.

44

Common questions

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Imperfections or defects in solids, such as vacancies, interstitials, and dislocations, significantly influence macroscopic properties like strength, conductivity, and ductility . These defects can disrupt ideal atomic arrangements, leading to changes in material behavior under stress, electrical conductivity variations, and altering the material's chemical reactivity .

Miller indices are a notation system used to describe the orientation of planes and directions within a crystal lattice. They provide crucial information about symmetry and preferred cleavage planes that can significantly affect mechanical and optical properties . These indices help in understanding interatomic spacings and the geometry of the crystal lattice, which are vital for predicting how a material will interact with various forces, such as stress or electromagnetic radiation .

Crystalline solids have a defined shape, a specific melting point, and exhibit anisotropy, meaning their physical properties vary in different directions . This structured arrangement affects material properties such as strength, elasticity, and electrical conductivity by providing consistency and predictability in atomic interactions .

Composite materials in structures like the Boeing 777 provide enhanced strength, weight savings, and improved resistance to fatigue, corrosion, and impact damage . These characteristics result from the synergetic combination of different materials that cater to specific performance needs such as durability and weight efficiency, making them ideal for aerospace applications .

Coordination numbers, indicating the number of nearest atoms surrounding a given atom, and packing density influence the mechanical properties of crystal structures. In FCC structures, with higher coordination numbers and packing densities, materials exhibit increased ductility and toughness. In contrast, BCC structures, with lower packing densities, generally display greater shear strength but less ductility due to fewer atomic interactions, which limit atomic slip .

Vacancies occur when an atom is missing from its lattice site, leading to a decrease in density as fewer atoms occupy the same volume. In contrast, interstitial defects involve the addition of extra atoms in the lattice, causing density fluctuations and atomic distortions . Both defects disrupt the ideal structure, but vacancies generally reduce density, whereas interstitials can cause variations based on the number of added atoms .

Ceramics are used in medical implants due to their biocompatibility, strength, and resistance to wear and corrosion. These properties make ceramics highly suitable for enduring the chemical and mechanical environments within the body without adverse reactions . Their ability to integrate with biological tissues while maintaining structural integrity is particularly crucial for long-term medical applications .

Bragg's Law provides a relationship between the X-ray wavelength and the diffraction angle, allowing for the determination of lattice spacings in crystalline solids. It is significant because it enables the analysis of crystal structures by identifying the arrangement and spacing of atoms, which is crucial for understanding material properties and how materials interact with light and other electromagnetic waves .

The atomic structure, comprising protons, neutrons, and electrons, forms the fundamentals of materials' properties. Protons and neutrons make up the atomic nucleus, while electrons orbit around it, affecting properties like bonding, electronic configurations, and reactivity . The arrangements of these atomic constituents determine bonding strength and type, which influence mechanical, thermal, and electrical properties of materials .

Grain boundaries, being regions between crystal grains, are typically disordered and have high mobility and diffusivity, impacting material properties like electrical resistance and strength . Surface defects alter the orientation and stacking of atomic planes, directly influencing mechanical properties by creating stress points and modifying the material's response to external forces. They also impact electrical properties by creating potential barriers or resistances at interfaces .

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