SAFETY DATA SHEET

PETROGREASE EP 0

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY

Product Name PETROGREASE EP 0

Product Type Lithium-Based Extreme Pressure Grease

Recommended Use Grease Applications for High Load, High Pressure Conditions

Company Information PETRON CORPORATION

JESUS ST., PANDACAN, MANILA
PHILIPPINES

General Contact Numbers (632) 563-3121

(632) 563-8521 loc 220 and 340

Website [Link]

SECTION 2: HAZARDS IDENTIFICATION

GHS CLASSIFICATION Acute Toxicity - Oral, Category 5

Acute Toxicity - Dermal, Category 5
Acute Toxicity - Inhalation, Category 4
Skin Corrosion/Irritation, Category 2
Serious Eye Damage/Eye Irritation, Category 2A
Carcinogenicity, Category 2
Specific Target Organ Toxicity (Single Exposure), Category 2 (lungs)
Specific Target Organ Toxicity (Repeated Exposure),
Category 2 (respiratory system)
Category 2 (liver, hematopoietic system, stomach)
Hazardous to the Aquatic Environment
Acute Hazard, Category 1
Chronic Hazard, Category 1

GHS LABELING

Symbols

Signal Word Warning

Hazard Statements H303 Maybe harmful if swallowed

H313 Maybe harmful in contact with skin
H332 Harmful if inhaled
H315 Causes skin irritation
H319 Causes serious eye damage
H351 Suspected of causing cancer
H371 May cause damage to organs (lungs)
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 H373 May cause damage to organs through prolonged or repeated exposure
(liver, hematopoietic system, stomach)
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects

PRECAUTIONARY STATEMENTS

General Precautionary Statements

P101 If medical advice is needed, have product container or label at hand
P102 Keep out of reach of children
P103 Read label before use

Prevention Precautionary Statements

P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P260 Do not breathe mist/vapors/spray
P264 Wash hands thoroughly after handling
P270 Do not drink, eat, or smoke when using the product
P271 Use only outdoors or in a well-ventilated area
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
P281 Use personal protective equipment as required

Response Precautionary Statements

P302 + P352 IF ON SKIN: Wash with plenty of soap and water
P304 + P340 IF INHALED: Remove victim to a fresh air and keep at rest in a position comfortable for
breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing
P308 + P313 If exposed or concerned: Get medical advice/attention
P309 + P311 If exposed or if you feel unwell: Call a Poison Center or doctor/physician
P312 Call a POISON Center or doctor/physician if you feel unwell
P314 Get medical advice/attention if you feel unwell
P332 + p313 If skin irritation occurs: Get medical advice/attention
P337 + P313 If eye irritation persists: Get medical advice/attention
P362 Take off contaminated clothing and wash before use

Storage Precautionary Statements

P403 + P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up

Disposal Precautionary Statements

P501 Dispose of contents/container in accordance with local/regional/national/international
regulations

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Composition CAS Number % Weight

12-Hydroxystearic acid 106-14-9 5 - 10
Lithium Hydroxide 1310-66-3 1-3
Carbamodithioic acid, dibutyl, methylene ester 10254-57-6 4-8

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 Distillates (Petroleum) solvent refined heavy paraffinic 64741-88-4 85 - 90
Hexane-1,6-diol 629-11-8 <1
Quartz 14808-60-7 <1

In general, the product contain components that may be a significant health and safety hazard thus proper
handling petroleum products and observing precautions must be observed and good standards of industrial and
personal hygiene must be maintained.

SECTION 4: FIRST AID MEASURES

Eye Contact Immediately flush eyes with large amount of water for at least 15 minutes
or until irritation subsides. If irritation persists, get prompt medical
attention.

Skin Contact Immediately flush with large amount of water; use soap if available.
Remove contaminated clothing and shoes, and launder before reuse.

Ingestion If swallowed, DO NOT induce vomiting. If individual is conscious, give milk

or water to dilute stomach contents. Keep warm and quiet. Get immediate
medical attention. DO NOT attempt to give anything by mouth to an
unconscious person.

Inhalation This product is not expected to present an inhalation problem at ambient

temperature. However, if overexposed to oil mist, using proper respiratory
protection, immediately remove the affected person immediately to fresh
air. Administer artificial respiration if breathing is stopped. Keep at rest.
Call for prompt medical attention.

SECTION 5: FIRE-FIGHTING MEASURES

Extinguishing Media In case of fire use foam, carbon dioxide or dry chemical extinguishers.

Special Fire-fighting Procedures Water jets should not be used directly on igniting products. Avoid spraying
water directly into storage containers due to danger of over-boil.
However, water may be used to cool exposed containers, structures and
equipment adjacent to fire. Respiratory and eye protection required for
fire-fighting personnel.

Decomposition Products Fumes, smoke, oxides of sulfur, nitrogen, carbon and other toxic gases
Under Fire Conditions may be formed.

SECTION 6: ACCIDENTAL RELEASE MEASURES

Land Spill Taking normal safety precaution, eliminate sources of ignition. Prevent
additional discharge of material, if possible to do so without hazard. For
small spills, implement cleanup procedures. For large spills, implement
clean-up procedures and, if in public area, keep public away and advise
authorities. Prevent material from entering sewers, water courses, or low
areas. Contain spilled material with sand or earth. Recover by scraping.
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 Consult an expert on disposal of recovered material and ensure conformity
to local disposal regulations.

Water Spill Use booms to confine spills immediately. Remove from water surface by
skimming or with suitable adsorbents. If allowed by local authorities and
environmental agencies, sinking and/or suitable dispersants may be used in
non-confined waters. Consult an expert on disposal of recovered material
and ensure conformity to local disposal regulations.

SECTION 7: HANDLING AND STORAGE

Handling Procedures Keep away from potential sources of ignition. Open container in a well
ventilated area. Avoid breathing vapors. Keep containers closed when not
in use. Wash thoroughly after handling. “Empty” containers with retained
product residue (liquid or vapor) can be dangerous. Do not pressurize, cut,
weld, braze, solder, drill, grind or expose containers to heat, flame,
sparks, static electricity or other sources of ignition; they may explode and
cause death or injury. Empty drums should be completely drained,
properly bunged and promptly returned to a drum re-conditioner, or
properly disposed off.

Storage Procedures Store in a cool dry place with adequate ventilation. Keep at temperature
not exceeding 50°C. Keep containers away from sparks, flame and strong
oxidants.

SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION

Exposure Controls

Components CAS-No. Source Value

12-Hydroxystearic acid 106-14-9 6mg/m3 max
Distillates (Petroleum) solvent refined heavy 64741-88-4 ACGIH 5 mg/m3
paraffinic 10 mg/m3 (STEL)
OSHA 5 mg/m3
Quartz 14808-60-7 NIOSH 50 mg/m3 (IDLH)
0.05 mg/m3 (TWA)
ACGIH 0.025 mg/m3 (TWA)
Lithium Hydroxide 1310-66-3 UK WEL 1mg/m3 (STEL)

Personal Protection

Ventilation Procedures The use of local exhaust ventilation is recommended to control mists or
vapors. Additional ventilation or exhaust may be required to maintain air
concentrations below exposure limits.

Respiratory Protection Respiratory protection is not required under conditions of normal use. If
vapor or mist generated when the materials are heated or handled, use an
organic vapor respirator with dust and mist filter. All respirators must be

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 NIOSH certified. Do not use compressed oxygen in hydrocarbon
atmospheres.

Skin Protection No skin protection is required for single, short duration, exposures. For
prolonged, repeated exposures and if handling hot materials, use
impervious clothing (boots, aprons, etc.) over parts of the body subject to
exposure.

Eye Protection Eye protection is not required under conditions of normal use. If materials
are handled such that they could be splashed into the eyes, wear plastic
face shield or splash-proof safety goggles.

Others Consumption of food and beverage should be avoided in work areas where
hydrocarbons are present. Always wash hands and face with soap and
water before eating and drinking.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Appearance Gray paste

Odor Characteristic of petroleum products
Specific Gravity at 60°F No data
Flash Point, °C No data
Worked Penetration at 25°C, 60X, 100 g, 358
5 secs., mm/10
Dropping Point, °C 182
pH No data
Boiling Point, °C No data
Melting Point, °C No data
Vapor Pressure, kPa No data
Vapor Density No data
Solubility in Water Insoluble
Evaporation Rate No data
Flammability No data
Partition Coefficient No data
Auto-ignition Temp, °C No data
Decomposition Temp, °C No data
Explosion limits No data

SECTION 10: STABILITY AND REACTIVITY

Stability (Thermal, Light, etc.) Stable

Incompatibility Strong oxidizing agents

Polymerization Not Applicable

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Hazardous Decomposition Thermal decomposition or burning may release oxides of carbon, nitrogen
Products and other toxic gases or vapors.

SECTION 11: TOXICOLOGICAL INFORMATION

Acute Toxicity

Lithium Hydroxide Oral, LD50 210 mg/kg

Inhalation, LC50 0.96 mg/L

Carbamodithioic acid, dibutyl, Oral, LD50 16000 mg/kg

methylene ester Dermal, LD50 >2000 mg/kg

Distillates (Petroleum) solvent Oral, LD50 >5000 mg/kg

refined heavy paraffinic Dermal, LD50 >2000 mg/kg
Inhalation, LC50 2.18 mg/L air

Hexane-1,6-diol Oral, LD50 3730 mg/kg

Dermal, LD50 >2500 mg/kg
Inhalation, LC0 3.3 mg/L

Quartz Oral, LD50 500 mg/kg

Skin Corrosion/Irritation Low order of toxicity. Prolonged or repeated contact may result in the
defatting of skin, leading to irritation and possibly dermatitis.

Serious Eye Damage/Irritation Slightly irritating on direct contact

Respiratory/Skin Sensitization There was no evidence of skin sensitization when the product was applied
to human skin.

Germ Cell Mutagenicity No available information

Aspiration Hazard Minimal toxicity

Carcinogenicity

Distillates (Petroleum) solvent Suspected of causing cancer

refined heavy paraffinic Classified by EU, Institute for Health & Consumer Protection as
Carcinogenic Category 2; INCHEM similarly classifies as may cause cancer.

Reproductive Toxicity No available information

Inhalation Product is not expected to present an inhalation hazard at ambient

conditions. Caution should be taken to prevent misting of this product.
Exposures below 5 mg/m3 appear to be without significant health risk.

Specific Target Organ Toxicity Greases consist of solid or semi-solid dispersions of metallic soaps and
other thickeners in base oils. Long-term exposure to small doses of base
oil by inhalation, aspiration or ingestion can lead to lipid pneumonia or
lipid granuloma of the lung. These are low-grade, chronic, localized tissue
reactions. Shortness of breath and cough are most common symptoms.

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SECTION 12: ECOLOGICAL INFORMATION

Acute Toxicity

Distillates (Petroleum) solvent-refined heavy paraffinic

Fish (LL50/96-hours) >100 mg/L (Pimephales promelas)
Crustaceans (EL50/48-hours) 1000 mg/L (Daphnia magna)
Algae (EC50/72-hours) >1000 mg/L (Scenedesmus subspicatus)

Hexane-1,6-diol
Fish (LC50 96-hr) 4600 – 10,000 mg/L (Leuciscus idus)
Crustaceans (EC50/48-hour) 500 mg/L (Daphnia magna)
Algae (EC50/72-hour) 5940 mg/l (Scenedesmus subspicatus)

Carbamodithioic acid, dibutyl, methylene ester

Fish (LC50) 0.06 mg/L (O. mykiss)
Crustaceans (EC50) 0.052 mg/L (Daphnia magna)
Algae (EC50) 0.0325 mg/L (S. subspicatus)

Environmental Mobility Oil component of this product floats and can migrate from water to land.

Environmental Degradability Data have not been determined specifically for this product, but it is not
expected that it will be “readily” biodegradable.

Ecotoxicity & Bioaccumulation Data have not been determined specifically for this product, but it is
expected to be harmful to aquatic organisms.

SECTION 13: DISPOSAL CONSIDERATIONS

Waste Disposal Material, if discarded, is expected to be hazardous waste due to toxicity.

Waste management should be in compliance with local and national
regulations.

SECTION 14: TRANSPORT INFORMATION

Land This product is not regulated for road/rail transport.

Sea IMDG (Packaged Goods and BLCs). This product is not regulated for sea
transport.

Air (ICAO/IATA). This product is not regulated for air transport.

SECTION 15: REGULATORY INFORMATION

The chemical substances present in this product are listed under Philippine Inventory of Chemicals and Chemical
Substances (PICCS).

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SECTION 16: OTHER INFORMATION

Approvals Research and Development Department

Petron Corporation

This is a computer-generated form and does not require a signature.

The information presented herein has been compiled from sources considered to be dependable and is accurate to the best of
Petron Corporation’s knowledge. This information relates only to the specific material designated and may not be valid when
this material is combined with any other material or in any process. However, Petron Corporation makes no warranty or
guarantee as to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself as to the suitability and
completeness of such information for his own particular use. Petron Corporation assumes no responsibility for injury to
recipient or to third persons or for any damage to any property that may occur from the use of this information.

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