Chemical Reactions Overview
Chemical Reactions Overview
S + O2 → N2 + H2 → Na + HOH → K + H2O →
heat heat
Mg + HCl →
KMnO4 → CaCO3 →
Ba + HNO3 →
heat heat
Ca + H2SO4 →
HgO → H2O2 →
Al + HCl →
heat
NaHCO3 → Cu + HCl →
Ca + CH3COOH →
Au + 3HCl + HNO3 →
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CHEMICAL REACTIONS
Other Types of Chemical Reactions
Metal + Base reactions
Acidic oxide + Basic oxide
Only amphotheric metals (Al,Zn) react with strong
bases to form salt and hydrogen gas. Acidic oxides can react with basic oxides to form
only salt
Na2O + CO2 →
Double Displacement reactions
AB + CD → AD + CB Na2O + SO2 →
K2O + P2O3 →
AgNO3 + HCl →
AgNO3 + NaI → Basic oxides react with acids to form salt and water.
Na2O + HNO3 →
AgNO3 + NaOH →
K2O + HBr →
CuCl2 + NaOH →
CaO + HCl →
BaCl2 + H2SO4 →
BaO + H2SO4 →
Neutralization reactions
Acidic oxide + Base
Acids and bases react with each other to form salt and
Acidic oxides react with bases to form salt and
water. (If ammonia reacts as a base, then only salt is
water.
produced.)
CO2 + NaOH →
KOH + HCl →
SO3 + KOH →
NaOH + H2SO4 →
N2O5 + Ca(OH)2 →
LiOH + HNO3 →
P2O5 + Ba(OH)2 →
Ba(OH)2 + HCl →
N2O3 + KOH →
Ca(OH)2 + HNO3 →
CO2 + BaO →
NH3 + HCl →
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CHEMICAL REACTIONS
Some basic oxides are insoluble in water such as MgO,
CuO, FeO
CuO + H2O →
CuO + HCl →
ZnO + HCl →
ZnO + NaOH →
Al2O3 + HCl →
Al2O3 + KOH →
Zn(OH)2 + KOH →
Zn(OH)2 + HCl →
Al(OH)3 + HCl →
Al(OH)3 + NaOH →
CaCO3 + HCl →
Na2CO3 + HNO3 →
KHCO3 + HCl →
BaCO3 + CH3COOH →
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CHEMICAL CALCULATIONS
16. 3×01.1023 molecules of nitrogen and 3.36 L of
Exercises of Advanced Difficulty hydrogen at STP are reacted. How many grams of
ammonia are produced?
Stoichiometric Calculations
17. 18 g of carbon and 8 g of oxygen are reacted to form
1. How many grams of sodium hydroxide are needed to
carbon dioxide. How many grams remain behind?
neutralize 4.9 g of sulfuric acid?
18. Equal volumes of sulfur dioxide and oxygen gases
2. How many liters of hydrogen gas can evolve at STP
are reacted to give 5 liters of sulfur trioxide at the
from the reaction of 5.4 g of aluminum with excess
same conditions. How many liters of which one will
hydrochloric acid solution?
remain unreacted?
3. How many liters and grams of oxygen gas can be
19. Equal weights of sodium and chlorine are reacted to
produced from the electrolysis of 9 g of water at STP?
give 0.1 mole of sodium chloride. How many grams
of which element will remain unreacted?
4. How many liters of oxygen are liberated by heating of
490 g of potassium chlorate at STP?
20. Equal volumes of oxygen and nitrogen monoxide
gases are allowed to form nitrogen dioxide gas at
5. Calculate the volume of air required to burn 4.6 g of
STP. During the reaction there is a decrease of 16
ethyl alcohol at STP.
mL in volume. How many milliliters of nitrogen
dioxide gas are produced at the end of the reaction?
6. What is the volume of carbon dioxide and sulfur
dioxide gases at STP produced from the combustion
Purity Problems
of 304 mL of carbon disulfide ( d=1.25 g/ml )?
21. How many grams of carbon dioxide are released
7. What volume of sulfur dioxide gas at STP is produced when a 53 g of sodium carbonate sample that is 20
from 6.8 g of hydrogen sulfide? % reacts completely with hydrochloric acid?
8. When 710 g of chlorine are reacted with 22 g of 22. A 25 gram sample of iron reacts with 200 g of 14.6
hydrogen, how many grams of hydrochloric acid can % hydrochloric acid solution by mass. Calculate the
be produced at most? percentage of iron in the sample.
9. A 6.35 g of copper is dissolved in 100 g of 26% 23. The reaction of 6 mol of hydrogen with 1.5 mol of
(dilute) nitric acid solution. Find the volume of the nitrogen produces 2.4 mol of ammonia. What is the
formed gas at STP. percent yield of the reaction?
10. There are two beakers on the opposite sides of an 24. How many grams of sodium that is 4 % impure are
equal arm balance. They contain equal amount of required to prepare 3.36 L of hydrogen gas at STP?
hydrochloric acid solution. A 2.975 g of tin is
dissolved in one beaker. How many grams of iron 25. How many liters of oxygen at STP can be liberated
must be dissolved in the other beaker to provide from 1700 g of a solution which is 3 % hydrogen
equilibrium again? peroxide by weight?
11. There are two open beakers that contain equal 26. How many tons of steel that contains 4 % carbon can
masses of sodium hydroxide and hydrochloric acid be obtained from 928 tons of pure magnetite
separately. When 10 g of ammonium chloride are (Fe3O4)?
added to the container containing sodium hydroxide,
27. By heating 126.4 g of potassium permanganate, 6.72
how many grams of magnesium carbonate must be
liters of oxygen were produced at STP. Calculate the
added to the other container containing hydrochloric
efficiency of the reaction. And, determine the
acid in order to provide equilibrium again?
amounts of remaining solids.
12. A solution containing 39.2 g of phosphoric acid is
Consecutive Problems
reacted with 44 g of sodium hydroxide. Find the
amount of formed salt(s). 28. How many grams of oxygen are required to burn the
hydrogen gas obtained from the reaction of 10 g of
Limiting and Excess Reagent calcium with excess water?
13. If 2.8 g of carbon monoxide and 3.2 g of oxygen are
29. How many grams of hydrochloric acid are required to
mixed and reacted to give carbon dioxide, how many
dissolve aluminum oxide prepared by the reaction of
grams of carbon dioxide can be produced at most?
27 g of aluminum and 16 g of oxygen?
14. Equal weights of calcium and oxygen gas are reacted
30. What is the maximum gram of nitric acid that can be
in a closed container to give 112 g of calcium oxide.
produced by starting with 11.2 L of ammonia at STP?
Which element and how many grams will remain
behind?
31. What mass of sulfuric acid will be produced from 100
g sample that is 96 % sulfur by mass?
15. How many grams of water can be produced at most
when 4 g of hydrogen and 8 g of oxygen are reacted?
32. How many grams of phosphoric acid can be
produced at most from 31 g of calcium phosphate?
31
CHEMICAL CALCULATIONS
33. The hydrogen gas produced by the reaction of a grams of this mixture are reduced, 0.423 g. of water
quantity of aluminum with 500 g of sulfuric acid is obtained. Calculate percentage composition of the
solution is completely used to reduce 144 g copper initial mixture.
from copper (II) oxide. What is the mass percentage
of sulfuric acid in the solution? 47. Calculate how many grams of 10 % sulfur trioxide in
pure sulfuric acid (oleum) and 60 % sulfuric acid
34. By passing 2.46 L of CO2 through the sodium solution are required for the preparation of 480 g of
hydroxide solution, 11.44 g of a mixture of sodium 90 % sulfuric acid solution.
carbonate and bicarbonate is obtained. Find the
percentages in the mixture. Empirical Formula Determination
48. A 2.2 g compound containing carbon and hydrogen
35. Carbon dioxide gas, which is obtained from the
is burned and 3.36 liters of carbon dioxide can be
combustion of 6 g of carbon, is passed through 300
produced at STP. What is the empirical formula of the
mL of 10 % NaOH solution (d = 1.07 g/ml). Calculate
compound?
mass percentage each salt formed in the final
solution.
49. When a 2.3 g compound containing carbon,
hydrogen, and oxygen is burned, 4.4 g of carbon
Mixture and Simultaneous Problems
dioxide and 2.7 g of water are produced. Find the
36. When a 50 g alloy of copper and aluminum reacts empirical formula of the compound.
with sufficient amount of hydrochloric acid, 22.4 L of
hydrogen at STP is produced. What is the mass 50. The combustion of 0.25 mole of compound
percentage of copper in the alloy? containing carbon, hydrogen, and oxygen requires
1.25 mole of oxygen and produces 1 mole of carbon
37. To burn 30 liters of a mixture of methane and dioxide and 1 mole of water. What is the formula of
propane gases, 90 liters of oxygen are needed at the the compound?
same conditions. Calculate the volume of methane in
the mixture. 51. Nicotine is a compound that contains N, C and H
elements. When 121.5 g of pure Nicotine are burnt
38. 11.9 g of an alloy made from aluminum and zinc is with sufficient Oxygen, 330 g CO2, 94.5 g H2O and
reacted with sufficient amount of hydrochloric acid 21 g N2 are produced. Find the empirical and
and 8.96 L of hydrogen at STP is produced. What is molecular formula of Nicotine if its molecular weight
the mass percentage of aluminum in the mixture? is 162 g/mol?
32
CHEMICAL CALCULATIONS
33
SOLUTIONS
39
REDOX and ELECTROLYSIS
3. A 10 g sample of Fe plate is put into a 200 mL of 0.1 15. What is the mass of hydrochloric acid obtained by
M solution of copper (II) sulfate. What will be the the electrolysis of aqueous sodium chloride
total mass of plate after reaction? solution. If a current of 5A is given to the solution for
2 hours?
4. A 50 g zinc plate is put into copper (II) sulfate. After
16. When 400 g of 8.5 % silver nitrate solution are
a while, the mass of plate becomes 49.82 g. Find
electrolyzed, the mass of solution decreases by 25
the mass of copper (II) sulfate in the solution.
g. At the end of the reaction, what is the
concentration of solution and find the masses of
5. The cupric plate with a mass of 20 g was placed into
substances collected in anode and cathode.
the mercury (II) nitrate solution. Its mass increased
by 2.73 g. Then, the plate was tempered and it came
17. During the electrolysis of a molten chloride of
to its initial form. How did its mass change in this
unknown metal, 6.4 A of current are given for 30
process?
minutes. And, 1.07 g of metal is collected at
cathode. Find the metal.
6. The mass of a metallic plate with a mass of 50 g
decreased by 1.68 % after staying in the
18. A 1000 g of 5 % aqueous solution of NaNO3 is
hydrochloric acid solution. 0.336 L of gas was
electrolyzed and 80 L of gas are collected at 25 0C
evolved with it. From which metal is this plate made?
and 1.24×105 Pa. After electrolysis, find the mass
percentage of salt in final solution.
7. Two plates with equal masses were made from the
same metal (oxidation state is equal to 2). The 19. When water solution of sodium salt of a mono
plates were placed into the solutions of the copper carboxylic acid is electrolyzed, it gives a gas and a
and silver salts with the same concentration. After liquid that contains 84.21 % carbon by mass in
some time they were taken out, dried up and anode. Find the unknown salt and write the
weighed. The mass of the first plate increased by electrolysis reaction.
0.8 %, of the second plate by 16 %. From which
metal are these plates made?
44