Assignment
CHAPTER- EQUILIBRIUM
[Link] why pure liquids and solids can be ignored while writing the
equilibrium constant expression?
2. Which one can act as Arrhenius Acid ? [1]
(a) NH3 (b) H2O (c) HCl (d) C6H5OH
[Link] LeChatelier’s Principle?
[Link] the three group into which chemical equilibrium can be classified.
5. Hydrolysis of sucrose gives, Sucrose + water Glucose + Fructose
Equilibrium constant, Kc for the reaction is 3x1011 at 300 K. Calculate G at
300 K?
6. For the equilibrium, 2NOCl(g)⇌2NO(g)+Cl2
The value of equilibrium constant,Kc is 4.30 x 10-6 at 1069 K. calculate the
Kp for the reaction at this temperature?
7. Write a relation between ΔG and Q and define the meaning of each term
and answer the following : (a) Why a reaction proceeds forward when Q < K
and no net reaction occurs when Q = K.
(b) Explain the effect of increase in pressure in terms of reaction quotient Q.
for the reaction : CO (g) + 3H2 (g) -> CH4 (g) + H2O (g)
8. On the basis of Le Chatelier principle explain how temperature and
pressure can be adjusted to increase the yield of ammonia in the following
reaction. N2 (g) + 3H2 (g) - 2NH3 (g) Δ H = – 92.38 kJ mol–1 What will be the
effect of addition of argon to the above reaction mixture at constant volume?
9. Following data is given for the reaction:
CaC03(s) → CaO(s) + C02(g)
∆fH° [CaO(s)] = -635.1 kJ mol–1
∆fH° [CO2(g)] = -393.5 kJ mol–1
∆fH° [CaC03(s)] = -1206.9 kJ mol–1
Predict the effect of temperature on the equilibrium constant of the above
reaction.
10. Consider the reaction :
2SO2 (g)+O2 (g) 2SO3 (g)
Indicate the direction in which the equilibrium will shift when :
a. temperature is increased.
b. pressure is decreased.
c. an inert gas is added at constant Volume and
d. inert gas is added at constant pressure?