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Periodic Table Trends and Properties

CHEMISTRY M1

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0% found this document useful (0 votes)
39 views2 pages

Periodic Table Trends and Properties

CHEMISTRY M1

Uploaded by

Simp Son
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd

PERIODIC TABLE TRENDS

The Periodic Law

Dmitri Mendeleev
- the first scientist to publish an organize periodic table of the known elements
- was perpetually in trouble with Russian government and the Russian orthodox church, but he
was brilliant never-the-less.
- not only predicted the existence of 2 (at the time) undiscovered elements, but predicted the
properties too, and he was right!
- was very accurate in his predictions, which led the world to accept his ideas about periodicity
and a logical periodic table.
- He ordered a periodic table according to atomic mass which makes sense.
Henry Moseley (1913)
- He decided to arrange the periodic table by the number of protons, a.k.a. “the atomic
number”
Mendeleev and Moseley understood the “periodic Law” which states.
When arrange by increasing atomic number, the chemical elements display a regular and
repeating pattern of chemical and physical properties.
- Atoms with similar properties appear in groups or families.
-They are similar because they all have the same number of valence (outer shell) electrons,
which governs their chemical behaviors.
Metals
- lustrous (shiny), malleable ductile and good conductors of heat and electricity
- mostly solids at room temperature
Nonmetals
- dull, brittle, nonconductors (insulator)
-some are solid but many are gases, and Bromine is a liquid
Metalloids (Semi-metals)
- shiny but brittle
- semiconductors
Periodic Trends
- specific patterns in the properties of elements that can be observed in the Periodic Table.

Five (5) Common Periodic Trends


Atomic Radius
- one-half the distance between the nuclei of identical atoms that are side by side
Metallic Property
- level of reactivity of metals when it loses an electron in a chemical reaction
Electronegativity
- measures the tendency of an atom to attract
Octet Rule
- most atoms need a total of eight valence electrons to become stable.
Ionization Energy
- minimum amount of energy required to remove an electron from a neutral atom in its
gaseous phase
Electron Affinity
- amount of energy released when an atom accepts an electron.

Common questions

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Mendeleev organized the periodic table according to atomic mass, which was revolutionary at the time because it allowed for the prediction of the existence and properties of undiscovered elements. His approach provided a logical framework that led to the wide acceptance of the concept of periodicity. Later, Henry Moseley refined this by arranging elements by atomic number, which corrected anomalies in Mendeleev's table and reinforced the periodic law's accuracy .

Metalloids exhibit mixed characteristics of metals and nonmetals, such as being shiny yet brittle and functioning as semiconductors. These properties make them valuable in industrial applications like electronics, where they serve as intermediaries in the control of electrical conductance. The ability to modify conductivity through doping is crucial for the production of electronic components such as transistors and diodes, highlighting their importance in technology .

Metallic properties, which include luster, malleability, ductility, and good conductivity, are more pronounced in elements on the left side of the periodic table and decrease moving to the right. This trend correlates with the tendency of metals to lose electrons and form positive ions, explaining their conductivity and malleability. Nonmetals, found on the right side, exhibit properties such as brittleness and poor conductivity due to their higher ionization energies and preference for gaining electrons .

The development of the periodic table marks a shift from qualitative chemistry to a more structured, quantitative science. Mendeleev's initial arrangement by atomic mass was a breakthrough in organizing elements systematically, enabling predictions about unknown elements and fostering the acceptance of periodicity. Moseley's subsequent revision, based on atomic numbers, further refined this by resolving inconsistencies and aligning chemically similar elements—showcasing an evolution towards data-driven approaches and enhancing the table's predictive power .

Electronegativity refers to the tendency of an atom to attract electrons within a chemical bond. Elements with high electronegativity (typically nonmetals) will attract electrons more strongly than those with lower electronegativity (typically metals). This difference in electronegativity values helps predict bond type: large differences result in ionic bonds, while smaller differences result in covalent bonds. Elements with similar electronegativities tend to form nonpolar covalent bonds .

The periodic table's structure, based on increasing atomic numbers and recurring chemical properties, allows for the prediction of unknown elements' behaviors by locating their likely position. Similarities within groups indicate similar valence electron configurations, predicting reactivity and compound formation. For example, an unknown element in the same group as halogens is expected to be highly reactive and form similar compounds, such as salts, due to comparable electron affinities and valence electron counts .

The periodic law states that when elements are arranged by increasing atomic number, they exhibit regular and repeating patterns in chemical and physical properties. This concept is crucial for understanding why elements with similar chemical behaviors are grouped into families on the table, which is due to the same number of valence electrons dictating chemical behavior. Thus, the arrangement of the periodic table reflects periodicity, providing a powerful predictive tool for the properties of elements .

Atomic radius decreases across a period due to increased nuclear charge, which pulls electrons closer, and increases down a group as added electron shells outweigh the nuclear charge effect. Elements with smaller atomic radii across a period typically have higher ionization energies and electronegativities, correlating with nonmetallic character, while larger radii down a group usually indicate more metallic character and reactivity due to lower ionization energies .

The Octet Rule states that atoms tend to form compounds in ways that give them eight valence electrons, emulating the stability of noble gases. This principle is foundational in explaining why certain elements are more reactive, as those with incomplete valence shells will seek to fill or empty their outer levels through bonding. It dictates chemical bonding tendencies, with metals usually losing electrons to achieve a stable configuration, while nonmetals gain or share electrons to satisfy the rule .

Ionization energy, the energy required to remove an electron from an atom, typically decreases from right to left across a period and increases down a group. Metals typically have lower ionization energies compared to nonmetals, which means they more readily lose electrons, making them more reactive in terms of forming positive ions. In contrast, nonmetals have higher ionization energies, indicating less tendency to lose electrons, and are more likely to gain electrons .

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